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Nanomaterials, Volume 7, Issue 10

2017 October - 63 articles

Cover Story: The most efficient removal of organic pollutants is achieved with enzymatic reagents grafted on nanocarriers. However, enzymes are easily deactivated in the presence of heavy metal cations. In this work, the inactivation of urease was avoided using magnetic particles provided with additional DTPA complexonate functions. Improved stability of the enzymatic function ensured unchanged activity in at least 18 cycles of urea decomposition preserved together with high adsorption capacity towards heavy metals. View the paper here.
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Articles (63)

  • Article
  • Open Access
12 Citations
4,621 Views
11 Pages

24 October 2017

Dye-sensitized solar cells (DSSCs) were fabricated with closed- or open-ended freestanding TiO2 nanotube arrays as photoelectrodes that were decorated with carbon materials and large TiO2 nanoparticles (NPs) to enhance energy conversion efficiency. T...

  • Article
  • Open Access
15 Citations
4,130 Views
10 Pages

23 October 2017

Effects of binary mixtures of six metal oxide nanoparticles (NPs; 54 combinations) on the activities of seed germination and bacterial bioluminescence were investigated using the theory of probability. The observed toxicities of various NPs combinati...

  • Article
  • Open Access
19 Citations
4,670 Views
12 Pages

Ti-Based Biomedical Material Modified with TiOx/TiNx Duplex Bioactivity Film via Micro-Arc Oxidation and Nitrogen Ion Implantation

  • Peng Zhang,
  • Xiaojian Wang,
  • Zhidan Lin,
  • Huaijun Lin,
  • Zhiguo Zhang,
  • Wei Li,
  • Xianfeng Yang and
  • Jie Cui

23 October 2017

Titanium (Ti) and Ti-based alloy are widely used in the biomedical field owing to their excellent mechanical compatibility and biocompatibility. However, the bioinert bioactivity and biotribological properties of titanium limit its clinical applicati...

  • Feature Paper
  • Article
  • Open Access
5 Citations
5,671 Views
11 Pages

Flotation Assembly of Large-Area Ultrathin MWCNT Nanofilms for Construction of Bioelectrodes

  • Andrew J. Gross,
  • Jules L. Hammond,
  • Michael Holzinger and
  • Serge Cosnier

21 October 2017

We report a simple, versatile, and rapid method for the fabrication of optically-transparent large-area carbon nanotube (CNT) films via flotation assembly. After solvent-induced assembly, floating films were transferred to a flat supporting substrate...

  • Article
  • Open Access
31 Citations
5,314 Views
12 Pages

21 October 2017

This paper demonstrates the application of a broadband luminescent downshifting (LDS) layer with multiple species of europium (Eu)-doped silicate phosphors using spin-on film technique to enhance the photovoltaic efficiency of crystalline silicon sol...

  • Article
  • Open Access
10 Citations
5,355 Views
15 Pages

21 October 2017

This paper reports our findings on how to prepare a graphene oxide-based gas sensor for sensing fast pulses of volatile organic compounds with a better signal-to-noise ratio. We use rapid acetone pulses of varying concentrations to test the sensors....

  • Feature Paper
  • Review
  • Open Access
113 Citations
8,392 Views
20 Pages

Advances in Single-Chain Nanoparticles for Catalysis Applications

  • Jon Rubio-Cervilla,
  • Edurne González and
  • José A. Pomposo

21 October 2017

Enzymes are the most efficient catalysts known for working in an aqueous environment near room temperature. The folding of individual polymer chains to functional single-chain nanoparticles (SCNPs) offers many opportunities for the development of art...

  • Article
  • Open Access
28 Citations
5,362 Views
9 Pages

Study of the Photodynamic Activity of N-Doped TiO2 Nanoparticles Conjugated with Aluminum Phthalocyanine

  • Xiaobo Pan,
  • Xinyue Liang,
  • Longfang Yao,
  • Xinyi Wang,
  • Yueyue Jing,
  • Jiong Ma,
  • Yiyan Fei,
  • Li Chen and
  • Lan Mi

20 October 2017

TiO2 nanoparticles modified with phthalocyanines (Pc) have been proven to be a potential photosensitizer in the application of photodynamic therapy (PDT). However, the generation of reactive oxygen species (ROS) by TiO2 nanoparticles modified with Pc...

  • Article
  • Open Access
12 Citations
5,801 Views
12 Pages

Raman Enhancement and Photo-Bleaching of Organic Dyes in the Presence of Chemical Vapor Deposition-Grown Graphene

  • Jiaxin Weng,
  • Shichao Zhao,
  • Zhiting Li,
  • Karen B. Ricardo,
  • Feng Zhou,
  • Hyojeong Kim and
  • Haitao Liu

19 October 2017

Fluorescent organic dyes photobleach under intense light. Graphene has been shown to improve the photo-stability of organic dyes. In this paper, we investigated the Raman spectroscopy and photo-bleaching kinetics of dyes in the absence/presence of ch...

  • Article
  • Open Access
5 Citations
4,973 Views
12 Pages

19 October 2017

Placing nanowires at the predetermined locations on a substrate represents one of the significant hurdles to be tackled for realization of heterogeneous nanowire systems. Here, we demonstrate spatially-controlled assembly of a single nanowire at the...

  • Article
  • Open Access
31 Citations
5,796 Views
11 Pages

19 October 2017

Novel TiO2/Sn3O4 heterostructure photocatalysts were ingeniously synthesized via a scalable two-step method. The impressive photocatalytic abilities of the TiO2/Sn3O4 sphere nanocomposites were validated by the degradation test of methyl orange and •...

  • Feature Paper
  • Article
  • Open Access
46 Citations
17,456 Views
10 Pages

PMA-Induced THP-1 Macrophage Differentiation is Not Impaired by Citrate-Coated Platinum Nanoparticles

  • Francesca Gatto,
  • Roberta Cagliani,
  • Tiziano Catelani,
  • Daniela Guarnieri,
  • Mauro Moglianetti,
  • Pier Paolo Pompa and
  • Giuseppe Bardi

17 October 2017

The innate immune system consists of several complex cellular and molecular mechanisms. During inflammatory responses, blood-circulating monocytes are driven to the sites of inflammation, where they differentiate into tissue macrophages. The research...

  • Article
  • Open Access
33 Citations
5,637 Views
12 Pages

AuPd Bimetallic Nanocrystals Embedded in Magnetic Halloysite Nanotubes: Facile Synthesis and Catalytic Reduction of Nitroaromatic Compounds

  • Lei Jia,
  • Tao Zhou,
  • Jun Xu,
  • Fenghai Li,
  • Zhouqing Xu,
  • Beibei Zhang,
  • Shengli Guo,
  • Xiaoke Shen and
  • Wensheng Zhang

17 October 2017

In this research, a facile and effective approach was developed for the preparation of well-designed AuPd alloyed catalysts supported on magnetic halloysite nanotubes (HNTs@Fe3O4@AuPd). The microstructure and the magnetic properties of HNTs@Fe3O4@AuP...

  • Article
  • Open Access
8 Citations
4,450 Views
7 Pages

Microstructuring of Mesoporous Titania Films Loaded with Silver Salts to Enhance the Photocatalytic Degradation of Methyl Blue under Visible Light

  • Nicolas Crespo-Monteiro,
  • Anthony Cazier,
  • Francis Vocanson,
  • Yaya Lefkir,
  • Stéphanie Reynaud,
  • Jean-Yves Michalon,
  • Thomas Kämpfe,
  • Nathalie Destouches and
  • Yves Jourlin

17 October 2017

The microstructuring of the distribution of silver nanoparticles (NPs) in mesoporous titania films loaded with silver salts, using two-beam interference lithography leading to 1 Dimension (1D) grating, induces variations in the photocatalytic efficie...

  • Article
  • Open Access
7 Citations
4,074 Views
14 Pages

16 October 2017

Gold nanorods (GNRs) have been fabricated by a novel polymer-immobilised seed mediated method using ultraviolet (UV) photoreduced gold-polymethylmethacrylate (Au–PMMA) nanocomposites as a seed platform and characterised at sub-micron scale regime wit...

  • Feature Paper
  • Article
  • Open Access
27 Citations
5,918 Views
11 Pages

16 October 2017

The quantitative relationships between the activity of zebrafish ZHE1 enzyme and a series of experimental and physicochemical features of 24 metal oxide nanoparticles were revealed. Vital characteristics of the nanoparticles’ structure were reflected...

  • Review
  • Open Access
42 Citations
10,699 Views
28 Pages

Recent Progresses and Development of Advanced Atomic Layer Deposition towards High-Performance Li-Ion Batteries

  • Wei Lu,
  • Longwei Liang,
  • Xuan Sun,
  • Xiaofei Sun,
  • Chen Wu,
  • Linrui Hou,
  • Jinfeng Sun and
  • Changzhou Yuan

14 October 2017

Electrode materials and electrolytes play a vital role in device-level performance of rechargeable Li-ion batteries (LIBs). However, electrode structure/component degeneration and electrode-electrolyte sur-/interface evolution are identified as the m...

  • Article
  • Open Access
23 Citations
5,238 Views
21 Pages

The Effect of TiO2 Doped Photocatalytic Nano-Additives on the Hydration and Microstructure of Portland and High Alumina Cements

  • María Pérez-Nicolás,
  • Íñigo Navarro-Blasco,
  • José M. Fernández and
  • José Ignacio Alvarez

14 October 2017

Mortars with two different binders (Portland cement (PC) and high alumina cement (HAC)) were modified upon the bulk incorporation of nano-structured photocatalytic additives (bare TiO2, and TiO2 doped with either iron (Fe-TiO2) or vanadium (V-TiO2))....

  • Article
  • Open Access
16 Citations
5,464 Views
15 Pages

14 October 2017

Three non-metallic elements, sulfur, fluorine, and iodine, were used to dope the ultrathin two-dimensional TiO2 nanosheets, which would regulate their electroanalytical properties toward heavy metal ions. Among these doped materials, fluorine-doped T...

  • Article
  • Open Access
28 Citations
7,307 Views
18 Pages

14 October 2017

A pattern gel has been fabricated using sodium hyaluronate (HA) and 1,4-butanediol diglycidyl ether (BDDGE) through the micro-molding technique. The cellular behavior of osteoblast cells (MC3T3) in the presence and absence of dimethyloxalylglycine (D...

  • Article
  • Open Access
123 Citations
9,357 Views
16 Pages

Transformation of CuO Nanoparticles in the Aquatic Environment: Influence of pH, Electrolytes and Natural Organic Matter

  • Cheng Peng,
  • Chensi Shen,
  • Siyuan Zheng,
  • Weiling Yang,
  • Hang Hu,
  • Jianshe Liu and
  • Jiyan Shi

14 October 2017

Many studies have shown the effect of solution chemistry on the environmental behavior of metal-based nanoparticles (NPs), except CuO NPs. Here, we investigated the agglomeration, sedimentation, dissolution, and speciation of CuO NPs by varying pH, i...

  • Article
  • Open Access
12 Citations
4,525 Views
13 Pages

Porcine Dental Epithelial Cells Differentiated in a Cell Sheet Constructed by Magnetic Nanotechnology

  • Wataru Koto,
  • Yoshinori Shinohara,
  • Kazuyuki Kitamura,
  • Takanori Wachi,
  • Seicho Makihira and
  • Kiyoshi Koyano

13 October 2017

Magnetic nanoparticles (MNPs) are widely used in medical examinations, treatments, and basic research, including magnetic resonance imaging, drug delivery systems, and tissue engineering. In this study, MNPs with magnetic force were applied to tissue...

  • Article
  • Open Access
8 Citations
4,576 Views
9 Pages

Bioactive Coating with Two-Layer Hierarchy of Relief Obtained by Sol-Gel Method with Shock Drying and Osteoblast Response of Its Structure

  • Elena G. Zemtsova,
  • Andrei Y. Arbenin,
  • Natalia M. Yudintceva,
  • Ruslan Z. Valiev,
  • Evgeniy V. Orekhov and
  • Vladimir M. Smirnov

13 October 2017

In this work, we analyze the efficiency of the modification of the implant surface. This modification was reached by the formation of a two-level relief hierarchy by means of a sol-gel approach that included dip coating with subsequent shock drying....

  • Article
  • Open Access
14 Citations
4,325 Views
12 Pages

13 October 2017

Superhydrophobic surface, as a promising micro/nano material, has tremendous applications in biological and artificial investigations. The electrohydrodynamics (EHD) technique is a versatile and effective method for fabricating micro- to nanoscale fi...

  • Article
  • Open Access
35 Citations
6,138 Views
20 Pages

13 October 2017

The strong structural integrity of polymer nanocomposite is influenced in the moist environment; but the fundamental mechanism is unclear, including the basis for the interactions between the absorbed water molecules and the structure, which prevents...

  • Article
  • Open Access
14 Citations
4,832 Views
8 Pages

12 October 2017

TiO2 nanowire networks were prepared, using the corrosion of Ti foils in alkaline (potassium hydroxide, KOH) solution at different temperatures, and then a further ion-exchange process. The prepared nanostructures were characterized by field emission...

  • Article
  • Open Access
10 Citations
6,611 Views
18 Pages

Evaluation of the Ability of Nanostructured PEI-Coated Iron Oxide Nanoparticles to Incorporate Cisplatin during Synthesis

  • Raluca Tutuianu,
  • Laura Madalina Popescu,
  • Mihai Bogdan Preda,
  • Ana-Maria Rosca,
  • Roxana Mioara Piticescu and
  • Alexandrina Burlacu

12 October 2017

Nanoparticles (NPs) have a high potential for biological applications as they can be used as carriers for the controlled release of bioactive factors. Here we focused on poly(ethylenimine) (PEI)-coated iron oxide hybrid NPs obtained by hydrothermal s...

  • Article
  • Open Access
7 Citations
4,259 Views
7 Pages

Periodic TiO2 Nanostructures with Improved Aspect and Line/Space Ratio Realized by Colloidal Photolithography Technique

  • Loïc Berthod,
  • Olga Shavdina,
  • Isabelle Verrier,
  • Thomas Kämpfe,
  • Olivier Dellea,
  • Francis Vocanson,
  • Maxime Bichotte,
  • Damien Jamon and
  • Yves Jourlin

12 October 2017

This paper presents substantial improvements of the colloidal photolithography technique (also called microsphere lithography) with the goal of better controlling the geometry of the fabricated nano-scale structures—in this case, hexagonally arranged...

  • Article
  • Open Access
24 Citations
6,068 Views
9 Pages

12 October 2017

Vertical graphene (VG) sheets were single-step synthesized via inductively coupled plasma (ICP)-enhanced chemical vapor deposition (PECVD) using waste lard oil as a sustainable and economical carbon source. Interweaved few-layer VG sheets, H2, and ot...

  • Feature Paper
  • Article
  • Open Access
82 Citations
13,770 Views
15 Pages

Nanometric MIL-125-NH2 Metal–Organic Framework as a Potential Nerve Agent Antidote Carrier

  • Sérgio M. F. Vilela,
  • Pablo Salcedo-Abraira,
  • Isabelle Colinet,
  • Fabrice Salles,
  • Martijn C. De Koning,
  • Marloes J. A. Joosen,
  • Christian Serre and
  • Patricia Horcajada

12 October 2017

The three-dimensional (3D) microporous titanium aminoterephthalate MIL-125-NH2 (MIL: Material of Institut Lavoisier) was successfully isolated as monodispersed nanoparticles, which are compatible with intravenous administration, by using a simple, sa...

  • Article
  • Open Access
41 Citations
6,966 Views
16 Pages

Hierarchical AuNPs-Loaded Fe3O4/Polymers Nanocomposites Constructed by Electrospinning with Enhanced and Magnetically Recyclable Catalytic Capacities

  • Rong Guo,
  • Tifeng Jiao,
  • Ruirui Xing,
  • Yan Chen,
  • Wanchun Guo,
  • Jingxin Zhou,
  • Lexin Zhang and
  • Qiuming Peng

12 October 2017

Gold nanoparticles (AuNPs) have attracted widespread attention for their excellent catalytic activity, as well as their unusual physical and chemical properties. The main challenges come from the agglomeration and time-consuming separation of gold na...

  • Article
  • Open Access
43 Citations
5,728 Views
13 Pages

12 October 2017

This paper investigates the morphology, thermal, and electrical properties of LDPE (low-density polyethylene)-based nanocomposites after thermal aging. The FTIR (Fourier transform infrared spectroscopy) spectra results show that thermo-oxidative reac...

  • Article
  • Open Access
3 Citations
4,041 Views
8 Pages

11 October 2017

Photoluminescence (PL) of Er and Ge co-doped ZnO films synthesized by radio frequency magnetron co-sputtering was investigated. X-ray diffraction (XRD) patterns showed that the annealing process at 400–800 °C led to the formation of nanocrystal (nc)...

  • Article
  • Open Access
39 Citations
5,148 Views
16 Pages

11 October 2017

The main object of this study is the improvement of the dynamics of NO2 sensors based on ZnO nanostructures. Investigations presented in this paper showed that the combination of temperature and ultraviolet (UV) activation of the sensors can signific...

  • Article
  • Open Access
23 Citations
6,605 Views
9 Pages

Three-Dimensional Porous Nitrogen-Doped NiO Nanostructures as Highly Sensitive NO2 Sensors

  • Van Hoang Luan,
  • Huynh Ngoc Tien,
  • Seung Hyun Hur,
  • Jong Hun Han and
  • Wonoh Lee

11 October 2017

Nickel oxide has been widely used in chemical sensing applications, because it has an excellent p-type semiconducting property with high chemical stability. Here, we present a novel technique of fabricating three-dimensional porous nitrogen-doped nic...

  • Review
  • Open Access
56 Citations
7,821 Views
18 Pages

9 October 2017

TiO2-based composites have been paid significant attention in the photocatalysis field. The size, crystallinity and nanomorphology of TiO2 materials have an important effect on the photocatalytic efficiency. The synthesis and photocatalytic activity...

  • Addendum
  • Open Access
3 Citations
3,653 Views
2 Pages
  • Article
  • Open Access
20 Citations
5,554 Views
10 Pages

Flexible Piezoelectric Generators by Using the Bending Motion Method of Direct-Grown-PZT Nanoparticles on Carbon Nanotubes

  • Jin Kyu Han,
  • Do Hyun Jeon,
  • Sam Yeon Cho,
  • Sin Wook Kang,
  • Jongsun Lim and
  • Sang Don Bu

7 October 2017

Recently, composite-type nanogenerators (NGs) formed from piezoelectric nanostructures and multi-walled carbon nanotubes (CNTs), have become one of the excellent candidates for future energy harvesting because of their ability to apply the excellent...

  • Review
  • Open Access
80 Citations
11,133 Views
26 Pages

Potential Toxicity and Underlying Mechanisms Associated with Pulmonary Exposure to Iron Oxide Nanoparticles: Conflicting Literature and Unclear Risk

  • Tiffany G. Kornberg,
  • Todd A. Stueckle,
  • James A. Antonini,
  • Yon Rojanasakul,
  • Vincent Castranova,
  • Yong Yang and
  • Liying Wang

6 October 2017

Abstract: Fine/micron-sized iron oxide particulates are incidentally released from a number of industrial processes, including iron ore mining, steel processing, welding, and pyrite production. Some research suggests that occupational exposure to the...

  • Article
  • Open Access
134 Citations
10,966 Views
17 Pages

Surface Functionalization of Iron Oxide Nanoparticles with Gallic Acid as Potential Antioxidant and Antimicrobial Agents

  • Syed Tawab Shah,
  • Wageeh A Yehya,
  • Omer Saad,
  • Khanom Simarani,
  • Zaira Chowdhury,
  • Abeer A. Alhadi and
  • Lina A. Al-Ani

5 October 2017

In this research, we report the size-controlled synthesis and surface-functionalization of magnetite with the natural antioxidant gallic acid (GA) as a ligand, using in situ and post-synthesis methods. GA functionalization provided narrow size distri...

  • Feature Paper
  • Review
  • Open Access
133 Citations
25,616 Views
28 Pages

1 October 2017

Liquid crystals are an integral part of a mature display technology, also establishing themselves in other applications, such as spatial light modulators, telecommunication technology, photonics, or sensors, just to name a few of the non-display appl...

  • Article
  • Open Access
43 Citations
7,062 Views
12 Pages

30 September 2017

N-doped graphene with low intrinsic defect densities was obtained by combining a solid source doping technique and chemical vapor deposition (CVD). The solid source for N-doping was embedded into the copper substrate by NH3 plasma immersion. During t...

  • Article
  • Open Access
31 Citations
7,659 Views
19 Pages

30 September 2017

With a large specific surface area, high reactivity, and excellent adsorption properties, nano zerovalent iron (nZVI) can degrade a wide variety of contaminants in wastewater. However, aggregation, oxidation, and separation issues greatly impede its...

  • Article
  • Open Access
27 Citations
5,507 Views
12 Pages

30 September 2017

The prolonged and aggressive nature of scaling to augment the performance of silicon integrated circuits (ICs) and the technical challenges and costs associated with this has led to the study of alternative materials that can use processing schemes a...

  • Article
  • Open Access
19 Citations
6,215 Views
11 Pages

29 September 2017

Supported ionic liquid membranes (SILMs) have a promising prospect of application in flue gas separation, owing to its high permeability and selectivity of CO2. However, existing SILMs have the disadvantage of poor stability due to the loss of ionic...

  • Article
  • Open Access
57 Citations
7,211 Views
17 Pages

Pro-Inflammatory versus Immunomodulatory Effects of Silver Nanoparticles in the Lung: The Critical Role of Dose, Size and Surface Modification

  • Francesca Alessandrini,
  • Antje Vennemann,
  • Silvia Gschwendtner,
  • Avidan U. Neumann,
  • Michael Rothballer,
  • Tanja Seher,
  • Maria Wimmer,
  • Susanne Kublik,
  • Claudia Traidl-Hoffmann and
  • Carsten B. Schmidt-Weber
  • + 2 authors

29 September 2017

The growing use of silver nanoparticles (Ag-NPs) in consumer products raises concerns about their toxicological potential. The purpose of the study was to investigate the size- and coating-dependent pulmonary toxicity of Ag-NPs in vitro and in vivo,...

  • Article
  • Open Access
98 Citations
9,089 Views
20 Pages

29 September 2017

Graphene quantum dots (GQDs), derived from functionalized graphene precursors are graphene sheets a few nanometers in the lateral dimension having a several-layer thickness. They are zero-dimensional materials with quantum confinement and edge site e...

  • Feature Paper
  • Article
  • Open Access
14 Citations
6,218 Views
16 Pages

Ionic Liquids as Surfactants for Layered Double Hydroxide Fillers: Effect on the Final Properties of Poly(Butylene Adipate-Co-Terephthalate)

  • Sébastien Livi,
  • Luanda Chaves Lins,
  • Jakub Peter,
  • Hynek Benes,
  • Jana Kredatusova,
  • Ricardo K. Donato and
  • Sébastien Pruvost

28 September 2017

In this work, phosphonium ionic liquids (ILs) based on tetra-alkylphosphonium cations combined with carboxylate, phosphate and phosphinate anions, were used for organic modification of layered double hydroxide (LDH). Two different amounts (2 and 5 wt...

  • Feature Paper
  • Article
  • Open Access
27 Citations
6,620 Views
17 Pages

Sol-Gel Derived Adsorbents with Enzymatic and Complexonate Functions for Complex Water Remediation

  • Roman P. Pogorilyi,
  • Ievgen Pylypchuk,
  • Inna V. Melnyk,
  • Yurii L. Zub,
  • Gulaim A. Seisenbaeva and
  • Vadim G. Kessler

28 September 2017

Sol-gel technology is a versatile tool for preparation of complex silica-based materials with targeting functions for use as adsorbents in water purification. Most efficient removal of organic pollutants is achieved by using enzymatic reagents grafte...

  • Article
  • Open Access
37 Citations
7,617 Views
15 Pages

Poly-L-arginine Coated Silver Nanoprisms and Their Anti-Bacterial Properties

  • Fouzia Tanvir,
  • Atif Yaqub,
  • Shazia Tanvir and
  • William A. Anderson

27 September 2017

The aim of this study was to test the effect of two different morphologies of silver nanoparticles, spheres, and prisms, on their antibacterial properties when coated with poly-L-arginine (poly-Arg) to enhance the interactions with cells. Silver nano...

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Nanomaterials - ISSN 2079-4991