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Article

Processes Associated with Multiphase Dolomitization and Other Related Diagenetic Events in the Jurassic Samana Suk Formation, Himalayan Foreland Basin, NW Pakistan

by
Hamad-ur- Rahim
1,2,
Shazia Qamar
1,3,
Mumtaz Muhammad Shah
1,*,
Mercè Corbella
4,
Juan Diego Martín-Martín
5,
Hammad Tariq Janjuhah
6,*,
Dídac Navarro-Ciurana
4,5,
Vasiliki Lianou
7 and
George Kontakiotis
7
1
Department of Earth Sciences, Quaid-i-Azam University, Islamabad 45320, Pakistan
2
Earth Sciences Division, Pakistan Museum of Natural History, Islamabad 44000, Pakistan
3
Institute of Geology, University of Azad Jammu and Kashmir, Muzaffarabad 13100, Pakistan
4
Departament de Geologia, Facultat de Ciencies, Universitat Autonoma de Barcelona, Edifici Cs s/n, 08193 Bellaterra, Spain
5
Departament de Mineralogia, Petrologia i Geologia Aplicada, Facultat de Geologia, Universitat de Barcelona (UB), Martí i Franquès s/n, 08028 Barcelona, Spain
6
Department of Geology, Shaheed Benazir Bhutto University, Sheringal 18050, KP, Pakistan
7
Department of Historical Geology-Paleontology, Faculty of Geology and Geoenvironment, School of Earth Sciences, National and Kapodistrian University of Athens, Panepistimiopolis, Zografou, 15784 Athens, Greece
*
Authors to whom correspondence should be addressed.
Minerals 2022, 12(10), 1320; https://doi.org/10.3390/min12101320
Submission received: 8 September 2022 / Revised: 1 October 2022 / Accepted: 17 October 2022 / Published: 19 October 2022
(This article belongs to the Special Issue Diagenesis and Geochemistry of Carbonates)

Abstract

Foreland fold and thrust belts always represent a complex diagenetic history of carbonate succession, particularly multiphase dolomitization, due to the multi-sourcing nature of fluids affecting syn-to post-depositional successions. The present work documents a comprehensive study on the diagenetic changes, particularly dolomitization patterns in the Jurassic carbonates (Samana Suk Fm) in the Lesser Himalayan fold and thrust belt, NW Pakistan. To better understand the processes involved, integrated field/petrographic, geochemical, isotopic, and micro-thermometric studies were carried out. Field observations indicate that dolostones appear as light grey to brown stratabound and patchy units within the formation. Petrographic analysis reveals that fabric destructive matrix dolomite (RD-I) and fabric preserving replacive dolomite (RD-II) phases are present as distinct units. In addition, saddle dolomite cement (SD) and fracture-filling calcite (CC) are also observed in association with replacive dolomite cement. Geochemical analysis (EPMA) showed that Fe, Mn, and Ba concentrations in matrix dolomite are relatively less than those of replacive/saddle dolomite and fracture-filling calcite, suggesting a hydrothermal source of replacive/saddle dolomite in reducing conditions. Furthermore, stable isotope studies of RD-I showed non-depleted δ18O values, which represent coeval seawater signatures of Jurassic carbonates. RD shows depleted δ18O values and non-depleted δ13C, respectively, indicating burial or elevated temperature of dolomitization. Fracture-filled calcite represents lighter δ18O values and δ13C, indicative of relatively high temperatures. 87Sr/86Sr ratios of all diagenetic phases range from 0.707718 to 0.710747, showing more radiogenic values indicates interaction fluids with more radiogenic sources. Fluid inclusion micro-thermometry data of saddle dolomite shows TH ranging from 102.8 to 186 °C, and salinity ranging from 11.7 to 19.4 eq. wt.% NaCl, suggesting hot saline brines are responsible for the dolomitization. Fracture-filling calcite shows TH ranging from 68.0 to 98.4 °C and salinity ranging from 6.9 to 13.1 eq. wt.%. NaCl suggests moderately hot and saline solutions are responsible for their formation. In conclusion, the above-mentioned studies indicate two distinct processes of dolomitization are involved in the formation of matrix and replacive/saddle-type dolomites. RD-I has formed in the evaporative setting, whereas RD has formed due to the interaction of hydrothermal fluids during burial. Fracture-filling calcite is produced from hot subsurface solutions during uplift related to the Himalayan orogeny.
Keywords: Samana Suk Formation; dolomitization; stable and radiogenic isotopes; homogenization temperature; shallow marine carbonates; diagenetic processes; depositional environment; carbonate geochemistry; paleoenvironmental reconstruction Samana Suk Formation; dolomitization; stable and radiogenic isotopes; homogenization temperature; shallow marine carbonates; diagenetic processes; depositional environment; carbonate geochemistry; paleoenvironmental reconstruction

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MDPI and ACS Style

Rahim, H.-u.-; Qamar, S.; Shah, M.M.; Corbella, M.; Martín-Martín, J.D.; Janjuhah, H.T.; Navarro-Ciurana, D.; Lianou, V.; Kontakiotis, G. Processes Associated with Multiphase Dolomitization and Other Related Diagenetic Events in the Jurassic Samana Suk Formation, Himalayan Foreland Basin, NW Pakistan. Minerals 2022, 12, 1320. https://doi.org/10.3390/min12101320

AMA Style

Rahim H-u-, Qamar S, Shah MM, Corbella M, Martín-Martín JD, Janjuhah HT, Navarro-Ciurana D, Lianou V, Kontakiotis G. Processes Associated with Multiphase Dolomitization and Other Related Diagenetic Events in the Jurassic Samana Suk Formation, Himalayan Foreland Basin, NW Pakistan. Minerals. 2022; 12(10):1320. https://doi.org/10.3390/min12101320

Chicago/Turabian Style

Rahim, Hamad-ur-, Shazia Qamar, Mumtaz Muhammad Shah, Mercè Corbella, Juan Diego Martín-Martín, Hammad Tariq Janjuhah, Dídac Navarro-Ciurana, Vasiliki Lianou, and George Kontakiotis. 2022. "Processes Associated with Multiphase Dolomitization and Other Related Diagenetic Events in the Jurassic Samana Suk Formation, Himalayan Foreland Basin, NW Pakistan" Minerals 12, no. 10: 1320. https://doi.org/10.3390/min12101320

APA Style

Rahim, H.-u.-, Qamar, S., Shah, M. M., Corbella, M., Martín-Martín, J. D., Janjuhah, H. T., Navarro-Ciurana, D., Lianou, V., & Kontakiotis, G. (2022). Processes Associated with Multiphase Dolomitization and Other Related Diagenetic Events in the Jurassic Samana Suk Formation, Himalayan Foreland Basin, NW Pakistan. Minerals, 12(10), 1320. https://doi.org/10.3390/min12101320

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