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Polymers, Volume 9, Issue 6

2017 June - 55 articles

Cover Story: This paper reports the principal discoveries which have played a major role in the polyolefin field and have positioned polyolefins as the most produced plastics. The early development of polyolefins covering the production of LDPE at ICI and the discovery of Phillips or Ziegler-Natta catalysts are highlighted in a first section. In a second part the impact of the implementation of molecular catalysts on the research in polyolefins is discussed together with the last advances leading to high performance tailor made resins. View the paper
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Articles (55)

  • Review
  • Open Access
95 Citations
15,581 Views
25 Pages

Catalytic Oxidation of Lignin in Solvent Systems for Production of Renewable Chemicals: A Review

  • Chongbo Cheng,
  • Jinzhi Wang,
  • Dekui Shen,
  • Jiangtao Xue,
  • Sipian Guan,
  • Sai Gu and
  • Kai Hong Luo

21 June 2017

Lignin as the most abundant source of aromatic chemicals in nature has attracted a great deal of attention in both academia and industry. Solvolysis is one of the promising methods to convert lignin to a number of petroleum-based aromatic chemicals....

  • Article
  • Open Access
2 Citations
7,526 Views

RETRACTED: Controlled Light Cross-Linking Technique to Prepare Healable Materials

  • Soliman Abdalla,
  • Fahad Al-Marzouki,
  • Abdullah Obaid and
  • Fatma Bahabri

21 June 2017

Detection of defects, damages and cracks in structural polymers is very difficult, and even if they are detected, they will be very hard to be repaired. This is because different kinds of stress can reduce the mechanical efficiency of structural and...

(This article belongs to the Collection Polymeric Adhesives)
  • Article
  • Open Access
29 Citations
8,207 Views
17 Pages

20 June 2017

In this work, the influence of composition and cold-drawing on nano- and micro-scale morphology and tensile mechanical properties of PE/organoclay nanocomposite fibers was investigated. Nanocomposites were prepared by melt compounding in a twin-screw...

(This article belongs to the Special Issue Polymer Nanocomposites)
  • Article
  • Open Access
12 Citations
7,235 Views
15 Pages

20 June 2017

A novel kind of graphene oxide (GO)-containing bilayer hydrogel system with excellent self-healing and detachment properties stimulated by near-infrared irradiation is successively fabricated via a two-step in situ free radical polymerization. In add...

  • Article
  • Open Access
17 Citations
8,144 Views
19 Pages

20 June 2017

Isothermal and non-isothermal crystallization behaviours of the blends of long chain branched polypropylene (LCB PP) and poly(ethylene-co-octene) (PEOc) with different weight ratios were studied under quiescent and shear flow using polarized optical...

(This article belongs to the Special Issue Olefin Polymerization and Polyolefin)
  • Communication
  • Open Access
55 Citations
11,990 Views
9 Pages

20 June 2017

We report a near-infrared (NIR) light-responsive hydrogel that is capable of undergoing the gel to sol transition upon 785 nm light exposure based on a photothermal effect. The new hydrogel design relies on loading gold nanorods (AuNRs) in an ABA-typ...

(This article belongs to the Special Issue Photo-Responsive Polymers)
  • Article
  • Open Access
7 Citations
8,184 Views
13 Pages

Preparation of Pendant Group-Functionalized Diblock Copolymers with Adjustable Thermogelling Behavior

  • Bo Keun Lee,
  • Ji Hoon Park,
  • Seung Hun Park,
  • Jae Ho Kim,
  • Se Heang Oh,
  • Sang Jin Lee,
  • Bun Yeoul Lee and
  • Moon Suk Kim

20 June 2017

Recently, several thermogelling materials have been developed for biomedical applications. In this study, we prepared methoxy polyethylene glycol (MPEG)-b-(poly(ε-caprolactone)-ran-poly(2-chloride-ε-caprolactone) (PCL-ran-PfCL)) (MP-Cl) diblock copol...

(This article belongs to the Special Issue Advance of Polymers Applied to Biomedical Applications: Cell Scaffolds)
  • Article
  • Open Access
10 Citations
6,420 Views
16 Pages

18 June 2017

In this study, reduced graphene oxide (RGO)/polymethyl methacrylate (PMMA) nanocomposites were prepared by employing in situ polymerization and solution blending methods. In terms of mechanical properties, RGO loading increased the Young’s modulus bu...

  • Article
  • Open Access
28 Citations
11,732 Views
11 Pages

18 June 2017

Resorcinol-formaldehyde (RF) resin is a kind of excellent exterior-grade wood structural adhesive, which can be conveniently cold-set for various applications. In order to decrease the production cost, pyrolysis bio-oil from renewable bioresources wa...

(This article belongs to the Collection Polymeric Adhesives)
  • Article
  • Open Access
18 Citations
8,122 Views
14 Pages

18 June 2017

Through the reversible addition–fragmentation chain transfer (RAFT) copolymerization of 3-ethyl-1-vinyl-2-pyrrolidone (C2NVP) and N-vinylpyrrolidone (NVP), a series of well-defined P(C2NVP-co-NVP) copolymers were synthesized (Mn = ca. 8000 to 16,000...

(This article belongs to the Special Issue Functionally Responsive Polymeric Materials)
  • Article
  • Open Access
11 Citations
10,460 Views
10 Pages

18 June 2017

Vertical alignment of liquid crystal (LC) was achieved in an easy and effective way: in situ photopolymerization of dodecyl acrylate (DA) monomers initiated by polyimide based on 3,3′,4,4′-benzophenonetetracarboxylic dianhydride and 3,3′-dimethyl-4,4...

(This article belongs to the Special Issue Photo-Responsive Polymers)
  • Article
  • Open Access
13 Citations
5,326 Views
17 Pages

16 June 2017

A heterogalactan, named ACW0, was extracted from Antrodia camphorata and purified by anion exchange and gel permeation chromatography. It was composed of galactose (94.98%), traces of mannose (2.41%), and fucose (2.61%), with its molecular weight est...

  • Article
  • Open Access
16 Citations
8,837 Views
13 Pages

16 June 2017

It is well known that elastic instabilities induce pattern transformations when a soft cellular structure is compressed beyond critical limits. The nonlinear phenomena of pattern transformations make them a prime candidate for controlling macroscopic...

(This article belongs to the Special Issue Functionally Responsive Polymeric Materials)
  • Article
  • Open Access
45 Citations
11,218 Views
13 Pages

15 June 2017

Here we reported the use of electropolymerization to achieve the transformation of aqueous hydroquinone to solid-phase polyhydroquinone (PHQ) with pseudocapacitive characteristics, and the application of this redox-active product to shuttle electron...

(This article belongs to the Special Issue Conductive Polymers 2017)
  • Article
  • Open Access
5 Citations
6,204 Views
14 Pages

15 June 2017

A novel cationic water-soluble conjugated polyelectrolyte (CPE) of polyfluorene that contains 15% fraction of 2,1,3-benzothiadiazole (BT) units (PFC3NBT) has been obtained. PFC3NBT demonstrates intramolecular energy transfer from the fluorene segment...

(This article belongs to the Special Issue Polymers for Chemosensing)
  • Article
  • Open Access
33 Citations
11,334 Views
14 Pages

14 June 2017

Because of the complex mechanisms mediating cancer onset, prognosis, and metastatic behavior, different therapeutic approaches targeting these mechanisms have been investigated. Recent advancements in nanocarrier-based drug and gene delivery methods...

(This article belongs to the Special Issue Polymers and Nanogels for Gene Therapy)
  • Erratum
  • Open Access
26 Citations
5,136 Views
2 Pages

Erratum: pH Sensitive Hydrogels in Drug Delivery: Brief History, Properties, Swelling, and Release Mechanism, Material Selection and Applications. Polymers 2017, 9, 137

  • Muhammad Rizwan,
  • Rosiyah Yahya,
  • Aziz Hassan,
  • Muhammad Yar,
  • Ahmad Danial Azzahari,
  • Vidhya Selvanathan,
  • Faridah Sonsudin and
  • Cheyma Naceur Abouloula

14 June 2017

The authors wish to make a change to their published paper [1]. [...]

  • Article
  • Open Access
86 Citations
15,745 Views
15 Pages

14 June 2017

Thiol-ene photo-click hydrogels were prepared via step-growth polymerisation using thiol-functionalised type-I collagen and 8-arm poly(ethylene glycol) norbornene-terminated (PEG-NB), as a potential injectable regenerative device. Type-I collagen was...

(This article belongs to the Special Issue Hydrogels in Tissue Engineering and Regenerative Medicine)
  • Article
  • Open Access
17 Citations
8,494 Views
23 Pages

13 June 2017

The interphase in short fiber thermoplastic composites is defined as a three-dimensional, several hundred nanometers-wide boundary region at the interface of fibers and the polymer matrix, exhibiting altered mechanical properties. This region is of k...

  • Article
  • Open Access
79 Citations
14,137 Views
17 Pages

13 June 2017

In recent years, the interest for bio-sources is rising exponentially and tannins extracts are one of the most interesting, easily-available, phenolic building blocks. The condensed tannins or proanthocyanidins are already known for their polymerizat...

(This article belongs to the Special Issue Bio-inspired and Bio-based Polymers)
  • Article
  • Open Access
55 Citations
12,828 Views
13 Pages

Reinforcement of Gelatin-Based Nanofilled Polymer Biocomposite by Crystalline Cellulose from Cotton for Advanced Wound Dressing Applications

  • Shukanta Bhowmik,
  • Jahid M. M. Islam,
  • Tonmoy Debnath,
  • Muhammed Yusuf Miah,
  • Shovon Bhattacharjee and
  • Mubarak A. Khan

13 June 2017

This study is designed to extract crystalline cellulose from cotton and reinforcing gelatin film for biomedical applications, especially as a wound dressing material for its exceptional biocompatibility and bio-activity. Moreover, gelatin helps in wo...

(This article belongs to the Collection Polysaccharides)
  • Article
  • Open Access
56 Citations
8,986 Views
12 Pages

12 June 2017

Mussel-inspired polydopamine (PDA) chemistry and electroless deposition approaches were used to prepare stable superhydrophobic coatings on wood surfaces. The as-formed PDA coating on a wood surface exhibited a hierarchical micro/nano roughness struc...

  • Article
  • Open Access
3 Citations
7,354 Views
13 Pages

Electrowetting Performances of Novel Fluorinated Polymer Dielectric Layer Based on Poly(1H,1H,2H,2H-perfluoroctylmethacrylate) Nanoemulsion

  • Jiaxin Hou,
  • Wenwen Ding,
  • Yancong Feng,
  • Lingling Shui,
  • Yao Wang,
  • Hao Li,
  • Nan Li and
  • Guofu Zhou

11 June 2017

In electrowetting devices, hydrophobic insulating layer, namely dielectric layer, is capable of reversibly switching surface wettability through applied electric field. It is critically important but limited by material defects in dielectricity, reve...

(This article belongs to the Special Issue Polymers and Block Copolymers at Interfaces and Surfaces)
  • Article
  • Open Access
10 Citations
6,430 Views
14 Pages

10 June 2017

In vitro drug screening using reliable and predictable liver models remains a challenge. The identification of an ideal biological substrate is essential to maintain hepatocyte functions during in vitro culture. Here, we developed a fiber-embedded po...

  • Article
  • Open Access
25 Citations
11,875 Views
14 Pages

10 June 2017

In this paper; we compare double hydrophobic polystyrene-b-poly(solketal methacrylate) (PS-b-PSMA) and amphiphilic polystyrene-b-poly(glyceryl methacrylate) (PS-b-PGMA) diblock copolymer membranes which are prepared by combining the block copolymer s...

(This article belongs to the Special Issue Polymers and Block Copolymers at Interfaces and Surfaces)
  • Article
  • Open Access
17 Citations
6,736 Views
12 Pages

9 June 2017

The application of molecular imprinting technology in the separation and purification of active ingredients in natural products was widely reported, but remains a challenge. Enrichment and separation are especially limited. A surface imprinting techn...

  • Article
  • Open Access
13 Citations
8,511 Views
11 Pages

Multifunctional Polymer Nanoparticles for Dual Drug Release and Cancer Cell Targeting

  • Yu-Han Wen,
  • Tsung-Ying Lee,
  • Ping-Chuan Fu,
  • Chun-Liang Lo and
  • Yi-Ting Chiang

9 June 2017

Multifunctional polymer nanoparticles have been developed for cancer treatment because they could be easily designed to target cancer cells and to enhance therapeutic efficacy according to cancer hallmarks. In this study, we synthesized a pH-sensitiv...

(This article belongs to the Special Issue Functionally Responsive Polymeric Materials)
  • Article
  • Open Access
18 Citations
8,459 Views
20 Pages

DNA Binding with Acetate Bis(1,10-phenanthroline)silver(I) Monohydrate in a Solution and Metallization of Formed Structures

  • Nina Kasyanenko,
  • Zhang Qiushi,
  • Vladimir Bakulev,
  • Mikhail Osolodkov,
  • Petr Sokolov and
  • Viktor Demidov

8 June 2017

The study of DNA interaction with the acetate bis(1,10-phenanthroline)silver(I) monohydrate in a solution is of interest both for understanding the mechanism of biological activity of silver compound and for forming ordered structures (DNA fibrils) t...

(This article belongs to the Special Issue Bio-inspired and Bio-based Polymers)
  • Review
  • Open Access
96 Citations
16,448 Views
25 Pages

8 June 2017

Morphology of conjugated polymers is a critical factor that significantly affects intrinsic charge transport characteristics and in turn performance of polymer-based devices. Morphological defects including misaligned crystalline grains and grain bou...

(This article belongs to the Special Issue Conductive Polymers 2017)
  • Article
  • Open Access
23 Citations
8,261 Views
12 Pages

7 June 2017

In this study, 2-[(Acryloyloxy)ethyl]trimethylammonium chloride was graft polymerized onto chitosan (CS) to form quaternary ammonium CS (QAC) by using ammonium persulfate as a redox initiator. Alginate (ALG) microspheres loaded with a water-soluble m...

(This article belongs to the Collection Polysaccharides)
  • Article
  • Open Access
32 Citations
7,216 Views
15 Pages

Unique Halloysite Nanotubes–Polyvinyl Alcohol–Polyvinylpyrrolidone Composite Complemented with Physico–Chemical Characterization

  • Tayser Sumer Gaaz,
  • Abdul Amir H. Kadhum,
  • Patina Kiah Anak Michael,
  • Ahmed A. Al-Amiery,
  • Abu Bakar Sulong,
  • Mohamed H. Nassir and
  • Ahed Hameed Jaaz

6 June 2017

A halloysite nanotubes–polyvinyl alcohol–polyvinylpyrrolidone (HNTs–PVA–PVP) composite has been investigated for a quite long time aiming at improving the physico–chemical characterization of HNTs. In this work, HNTs–PVA–PVP composite were prepared b...

  • Review
  • Open Access
39 Citations
11,395 Views
23 Pages

6 June 2017

The remarkable ability of polymeric additives to reduce the level of frictional drag significantly in turbulent flow, even under extremely low dilutions, is known as turbulent drag-reduction behavior. Several bio-polymers have been assessed as promis...

(This article belongs to the Special Issue Bio-inspired and Bio-based Polymers)
  • Article
  • Open Access
19 Citations
9,834 Views
15 Pages

Analysis of the Cross-Linking Reaction of Lignin with Triethyl Phosphate by MALDI-TOF and 13C NMR

  • María Cecilia Basso,
  • Antonio Pizzi,
  • Luc Delmotte and
  • Soliman Abdalla

4 June 2017

The reaction of condensation and cross-linking of desulfurized kraft lignin with triethyl phosphate (TEP) was explored. Catechol, a simple model of the aromatic ring of lignin, and glycerol, a model compound of the aliphatic hydroyl groups of the sid...

(This article belongs to the Collection Polymeric Adhesives)
  • Review
  • Open Access
11 Citations
13,222 Views
45 Pages

Micelles Formed by Polypeptide Containing Polymers Synthesized Via N-Carboxy Anhydrides and Their Application for Cancer Treatment

  • Dimitrios Skoulas,
  • Panagiotis Christakopoulos,
  • Dimitra Stavroulaki,
  • Konstantinos Santorinaios,
  • Varvara Athanasiou and
  • Hermis Iatrou

4 June 2017

The development of multifunctional polymeric materials for biological applications is mainly guided by the goal of achieving the encapsulation of pharmaceutical compounds through a self-assembly process to form nanoconstructs that control the biodist...

(This article belongs to the Special Issue Bio-inspired and Bio-based Polymers)
  • Article
  • Open Access
10 Citations
5,925 Views
12 Pages

3 June 2017

The exponential Phan–Tien and Tanner (PTT), Giesekus, Leonov, and modified extended Pom–Pom (mXPP) differential constitutive models are evaluated in two ways: with regard to steady shear characteristics and with regard to large amplitude oscillatory...

(This article belongs to the Special Issue Complex Fluid Rheology)
  • Article
  • Open Access
58 Citations
9,318 Views
10 Pages

Epoxidized Jatropha Oil as a Sustainable Plasticizer to Poly(lactic Acid)

  • Buong Woei Chieng,
  • Nor Azowa Ibrahim,
  • Yoon Yee Then and
  • Yuet Ying Loo

2 June 2017

A renewable resource, epoxidized jatropha oil (EJO), was used as a green plasticizer and added to poly(lactic acid) (PLA). EJO was compounded into PLA at different contents. The addition of 3 wt % EJO to the PLA demonstrates significant improvement i...

(This article belongs to the Special Issue Biodegradable and Biobased Polyesters)
  • Article
  • Open Access
16 Citations
12,624 Views
9 Pages

2 June 2017

Base-catalyzed urea–formaldehyde condensation reactions were investigated by using a quantum chemistry method. It was found that monomethylolurea or N,N’-dimethylolurea can produce the methyleneurea intermediate (–HN–CO–N=CH2) with the catalysis of b...

(This article belongs to the Collection Polymeric Adhesives)
  • Review
  • Open Access
191 Citations
13,028 Views
19 Pages

1 June 2017

Periodontal tissue regeneration is the ultimate goal of the treatment for periodontitis-affected teeth. The success of regenerative modalities relies heavily on the utilization of appropriate biomaterials with specific properties. Poly (lactic-co-gly...

  • Article
  • Open Access
15 Citations
12,596 Views
12 Pages

31 May 2017

In the present work, a soft lithographic process is used to create nanometer-sized line patterns of gold nanoparticles (Au NPs) on PEG-based hydrogels. Hereby nanometer-sized wrinkles on polydimethylsiloxane (PDMS) are first fabricated, then function...

(This article belongs to the Special Issue Bio-inspired and Bio-based Polymers)
  • Review
  • Open Access
31 Citations
12,328 Views
16 Pages

Phenylboronic Acid-Functionalized Layer-by-Layer Assemblies for Biomedical Applications

  • Baozhen Wang,
  • Kentaro Yoshida,
  • Katsuhiko Sato and
  • Jun-ichi Anzai

31 May 2017

Recent progress in the development of phenylboronic acid (PBA)-functionalized layer-by-layer (LbL) assemblies and their biomedical applications was reviewed. Stimuli-sensitive LbL films and microcapsules that exhibit permeability changes or decompose...

(This article belongs to the Special Issue Advance of Polymers Applied to Biomedical Applications: Biointerface)
  • Article
  • Open Access
38 Citations
7,197 Views
15 Pages

β-Cyclodextrin Modified Poly(Acrylonitrule-co-Acrylic Acid) Hydrogel for Thorium(IV) Adsorption

  • Guojian Duan,
  • Qiangqiang Zhong,
  • Lei Bi,
  • Liu Yang,
  • Tonghuan Liu,
  • Xiaoning Shi and
  • Wangsuo Wu

31 May 2017

In this report, the β-CD(AN-co-AA) hydrogel was used to remove the thorium(IV) [Th(IV)] from the water system, and the new adsorbent was characterized through Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-r...

(This article belongs to the Special Issue Electroactive Polymers and Gels)
  • Article
  • Open Access
129 Citations
10,581 Views
16 Pages

30 May 2017

In this paper, the sample preparation of polymer nanocomposites based on methyl cellulose (MC) with small optical bandgaps has been discussed. Copper monosulfide (CuS) nanoparticles have been synthesized from the sodium sulphide (Na2S) and copper chl...

(This article belongs to the Collection Polysaccharides)
  • Article
  • Open Access
7 Citations
9,301 Views
11 Pages

30 May 2017

In order to further understand the mechanism of volume hologram formation in photosensitive polymers, light-induced material response is analyzed in commonly used epoxy-based negative photoresist Epon SU-8. For this purpose, time-resolved investigati...

(This article belongs to the Special Issue Photo-Responsive Polymers)
  • Article
  • Open Access
30 Citations
8,361 Views
11 Pages

30 May 2017

Based on the Diels–Alder reaction and hydroxyl-terminated polybutadiene (HTPB) binders of solid propellants, two novel compounds—furfuryl-terminated polybutadiene (FTPB) and trifurfuryl propane (TFP)—were designed and synthesized, and their structure...

  • Article
  • Open Access
2 Citations
4,778 Views
9 Pages

29 May 2017

We propose a stochastic method to generate exactly the overdamped Langevin dynamics of semi-flexible Gaussian chains, conditioned to evolve between given initial and final conformations in a preassigned time. The initial and final conformations have...

(This article belongs to the Special Issue Knotted and Catenated Polymers)
  • Article
  • Open Access
17 Citations
11,980 Views
18 Pages

29 May 2017

The use of tumor-specific therapeutic agents is a promising option for efficient and safe nonviral gene transfer in gene therapy. In this study, we describe the efficacy of polyamidoamine (PAMAM)-based nonviral gene delivery carriers, namely, an orni...

(This article belongs to the Special Issue Polymers and Nanogels for Gene Therapy)
  • Article
  • Open Access
38 Citations
10,031 Views
16 Pages

Effect of Interfacial Polarization and Water Absorption on the Dielectric Properties of Epoxy-Nanocomposites

  • Philipp Marx,
  • Andrea J. Wanner,
  • Zucong Zhang,
  • Huifei Jin,
  • Ioannis-Alexandros Tsekmes,
  • Johan J. Smit,
  • Wolfgang Kern and
  • Frank Wiesbrock

28 May 2017

Five types of nanofillers, namely, silica, surface-silylated silica, alumina, surface-silylated alumina, and boron nitride, were tested in this study. Nanocomposites composed of an epoxy/amine resin and one of the five types of nanoparticles were tes...

(This article belongs to the Special Issue Polymer Nanocomposites)
  • Communication
  • Open Access
14 Citations
10,079 Views
8 Pages

27 May 2017

Herein, we demonstrate a facile methodology to synthesis a novel methacrylic phosphonic acid (PA)-functionalized polyhedral oligomeric silsesquioxanes (POSSs) via thiol-ene click reaction using octamercapto thiol-POSS and ethylene glycol methacrylate...

(This article belongs to the Collection Silicon-Containing Polymeric Materials)
  • Article
  • Open Access
40 Citations
13,920 Views
11 Pages

27 May 2017

DMF is one the most commonly-used solvents for preparing graphene nanocomposites. Various processing variables for DMF are being used for the preparation of epoxy/graphene nanocomposites. Whilst the emphasis of all of these reported studies are on th...

  • Article
  • Open Access
26 Citations
9,720 Views
11 Pages

In Vitro Biocompatibility, Radiopacity, and Physical Property Tests of Nano-Fe3O4 Incorporated Poly-l-lactide Bone Screws

  • Hsin-Ta Wang,
  • Pao-Chang Chiang,
  • Jy-Jiunn Tzeng,
  • Ting-Lin Wu,
  • Yu-Hwa Pan,
  • Wei-Jen Chang and
  • Haw-Ming Huang

26 May 2017

The aim of this study was to fabricate biodegradable poly-l-lactic acid (PLLA) bone screws containing iron oxide (Fe3O4) nanoparticles, which are radiopaque and 3D-printable. The PLLA composites were fabricated by loading 20%, 30%, and 40% Fe3O4 nano...

(This article belongs to the Special Issue Advance of Polymers Applied to Biomedical Applications: Cell Scaffolds)

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Polymers - ISSN 2073-4360