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Polymers, Volume 10, Issue 1

2018 January - 105 articles

Cover Story: Bio-based PLA-mb-PBS copolymers are fascinating double crystalline materials whose properties can be tailored by composition, stereocomplexation and thermal treatments. When they are cooled from the melt, the PLA component crystallizes, creating superstructures, such as spherulites or axialites, which constitute templates within which the PBS component crystallizes when the sample is cooled down further. Solution mixtures of PLLA-mb-PBS and PLDA-mb-PBS copolymers, as well as copolymer/homopolymer blends, form stereocomplexes of PLLA and PDLA chain segments. The PBS chain segments can perturb or enhance PLA stereocomplexation depending on their content. View this paper
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Articles (105)

  • Article
  • Open Access
43 Citations
10,133 Views
17 Pages

Highly Zeolite-Loaded Polyvinyl Alcohol Composite Membranes for Alkaline Fuel-Cell Electrolytes

  • Po-Ya Hsu,
  • Ting-Yu Hu,
  • Selvaraj Rajesh Kumar,
  • Chia-Hao Chang,
  • Kevin C.-W. Wu,
  • Kuo-Lun Tung and
  • Shingjiang Jessie Lue

22 January 2018

Having a secure and stable energy supply is a top priority for the global community. Fuel-cell technology is recognized as a promising electrical energy generation system for the twenty-first century. Polyvinyl alcohol/zeolitic imidazolate framework-...

  • Communication
  • Open Access
11 Citations
7,002 Views
8 Pages

Magnetically Tunable Vibration Transmissibility for Polyurethane Magnetic Elastomers

  • Hiroyuki Endo,
  • Shunsuke Kato,
  • Mayuko Watanebe,
  • Takehito Kikuchi,
  • Mika Kawai and
  • Tetsu Mitsumata

22 January 2018

The effect of a weak magnetic field on vibration transmissibility was investigated for magnetic elastomers with various volume fractions of magnetic particles. Polyurethane elastomers without magnetic particles exhibited a natural frequency at 53 Hz...

  • Article
  • Open Access
37 Citations
13,813 Views
16 Pages

22 January 2018

A machine learning strategy is presented for the rapid discovery of new polymeric materials satisfying multiple desirable properties. Of particular interest is the design of high refractive index polymers. Our in silico approach employs a series of q...

  • Article
  • Open Access
28 Citations
7,167 Views
17 Pages

22 January 2018

Mixed Pluronic micelles from very hydrophobic and very hydrophilic copolymers were selected to scrutinize the synergistic effect on the self-assembly process as well as the solubilization capacity of ibuprofen. The tendency of mixing behavior between...

  • Article
  • Open Access
7 Citations
4,989 Views
16 Pages

A Combined Self-Consistent Method to Estimate the Effective Properties of Polypropylene/Calcium Carbonate Composites

  • Zhongqiang Xiong,
  • Shaorong Lu,
  • Junkun Liu,
  • Guangsheng Lv,
  • Yuqi Li and
  • Jinhong Yu

21 January 2018

In this work, trying to avoid difficulty of application due to the irregular filler shapes in experiments, self-consistent and differential self-consistent methods were combined to obtain a decoupled equation. The combined method suggests a tenor γ i...

  • Article
  • Open Access
9 Citations
6,572 Views
19 Pages

Novel Antibacterial Polyglycidols: Relationship between Structure and Properties

  • Fabian Marquardt,
  • Cornelia Stöcker,
  • Rita Gartzen,
  • Elisabeth Heine,
  • Helmut Keul and
  • Martin Möller

20 January 2018

Antimicrobial polymers are an attractive alternative to low molecular weight biocides, because they are non-volatile, chemically stable, and can be used as non-releasing additives. Polymers with pendant quaternary ammonium groups and hydrophobic chai...

  • Article
  • Open Access
14 Citations
5,035 Views
11 Pages

Synthesis of Molecularly Imprinted Cryogels to Deplete Abundant Proteins from Bovine Serum

  • Chun Yang,
  • Yan Zhang,
  • Wei-Qin Cao,
  • Xiao-Feng Ji,
  • Jian Wang,
  • Ya-Nan Yan,
  • Tao-Lin Zhong and
  • Yu Wang

20 January 2018

Molecularly imprinted polyacrylamide cryogels were synthesized with pending templates (bovine serums of different concentrations). As the serum concentrations increased in the monomer solutions, the resulting cryogels could adsorb and deplete more pr...

  • Article
  • Open Access
16 Citations
7,830 Views
13 Pages

Temperature-Responsive Polymer Microgel-Gold Nanorods Composite Particles: Physicochemical Characterization and Cytocompatibility

  • Aslam Khan,
  • Tajdar Husain Khan,
  • Maqusood Ahamed,
  • Ahmed Mohamed El-Toni,
  • Ali Aldalbahi,
  • Javed Alam and
  • Tansir Ahamad

20 January 2018

In this paper, we report an easy route for preparing new metal nanorod-polymer composites consisting of gold nanorods, Au NRs, and temperature responsive copolymer “microgel” particles. The microgel particles of ~200 nm in size, which contain carboxy...

  • Communication
  • Open Access
5 Citations
5,483 Views
8 Pages

Photoluminescence Enhancement of Poly(3-methylthiophene) Nanowires upon Length Variable DNA Hybridization

  • Jingyuan Huang,
  • Jinho Choi,
  • Gil Sun Lee,
  • Fengchun Chen,
  • Chunzhi Cui,
  • Long Yi Jin and
  • Dong Hyuk Park

20 January 2018

The use of low-dimensional inorganic or organic nanomaterials has advantages for DNA and protein recognition due to their sensitivity, accuracy, and physical size matching. In this research, poly(3-methylthiophene) (P3MT) nanowires (NWs) are electroc...

  • Article
  • Open Access
44 Citations
7,148 Views
19 Pages

Flexural Behaviour of Carbon Textile-Reinforced Concrete with Prestress and Steel Fibres

  • Yunxing Du,
  • Xinying Zhang,
  • Lingling Liu,
  • Fen Zhou,
  • Deju Zhu and
  • Wei Pan

20 January 2018

Four-point bending tests were adopted to investigate the influences of the number of textile layers, volume content of steel fibres, and prestress on the flexural behaviour of carbon textile-reinforced concrete (TRC). The failure mode of the specimen...

  • Feature Paper
  • Article
  • Open Access
17 Citations
6,611 Views
11 Pages

Aggregation of Cationic Amphiphilic Block and Random Copoly(vinyl ether)s with Antimicrobial Activity

  • Yukari Oda,
  • Kazuma Yasuhara,
  • Shokyoku Kanaoka,
  • Takahiro Sato,
  • Sadahito Aoshima and
  • Kenichi Kuroda

19 January 2018

In this study, we investigated the aggregation behaviors of amphiphilic poly(vinyl ether)s with antimicrobial activity. We synthesized a di-block poly(vinyl ether), B3826, composed of cationic primary amine and hydrophobic isobutyl (iBu) side chains,...

  • Article
  • Open Access
39 Citations
9,341 Views
10 Pages

Temperature Scanning Stress Relaxation of an Autonomous Self-Healing Elastomer Containing Non-Covalent Reversible Network Junctions

  • Amit Das,
  • Aladdin Sallat,
  • Frank Böhme,
  • Essi Sarlin,
  • Jyrki Vuorinen,
  • Norbert Vennemann,
  • Gert Heinrich and
  • Klaus Werner Stöckelhuber

19 January 2018

In this work, we report about the mechanical relaxation characteristics of an intrinsically self-healable imidazole modified commercial rubber. This kind of self-healing rubber was prepared by melt mixing of 1-butyl imidazole with bromo-butyl rubber...

  • Article
  • Open Access
33 Citations
9,407 Views
12 Pages

19 January 2018

A series of highly branched random copolymers of acrylamide (AM) and N-isopropylacrylamide (NIPAM) have been prepared from a waxy potato starch-based macroinitiator by aqueous Cu0-mediated living radical polymerization (Cu0-mediated LRP). The NIPAM i...

  • Article
  • Open Access
52 Citations
7,901 Views
18 Pages

Toughening of Poly(lactic acid) and Thermoplastic Cassava Starch Reactive Blends Using Graphene Nanoplatelets

  • Anibal Bher,
  • Ilke Uysal Unalan,
  • Rafael Auras,
  • Maria Rubino and
  • Carlos E. Schvezov

19 January 2018

Poly(lactic acid) (PLA) was reactively blended with thermoplastic cassava starch (TPCS) and functionalized with commercial graphene (GRH) nanoplatelets in a twin-screw extruder, and films were produced by cast-film extrusion. Reactive compatibilizati...

  • Review
  • Open Access
25 Citations
7,483 Views
21 Pages

Integration of Heterogeneous Materials for Wearable Sensors

  • Yaser M. Haddara and
  • Matiar M. R. Howlader

18 January 2018

Wearable sensors are of interest for several application areas, most importantly for their potential to allow for the design of personal continuous health monitoring systems. For wearable sensors, flexibility is required and imperceptibility is desir...

  • Article
  • Open Access
22 Citations
6,954 Views
14 Pages

18 January 2018

Alkali-soluble resins (ASRs) are a type of electrosteric emulsifiers of high interest because they can profitably improve the features of waterborne dispersions. In this work, they have been synthesized in-situ through a one-pot approach and they hav...

  • Article
  • Open Access
38 Citations
6,992 Views
16 Pages

Poly(carbonate urethane)-Based Thermogels with Enhanced Drug Release Efficacy for Chemotherapeutic Applications

  • Benjamin Qi Yu Chan,
  • Hongwei Cheng,
  • Sing Shy Liow,
  • Qingqing Dou,
  • Yun-Long Wu,
  • Xian Jun Loh and
  • Zibiao Li

18 January 2018

In this study, we report the synthesis and characterisation of a thermogelling poly(carbonate urethane) system comprising poly(ethylene glycol) (PEG), poly(propylene glycol) (PPG) and poly(polytetrahydrofuran carbonate) (PTHF carbonate). The incorpor...

  • Review
  • Open Access
186 Citations
16,695 Views
28 Pages

18 January 2018

Throughout the last decades, magnetic nanoparticles (MNP) have gained tremendous interest in different fields of applications like biomedicine (e.g., magnetic resonance imaging (MRI), drug delivery, hyperthermia), but also more technical applications...

  • Article
  • Open Access
67 Citations
7,442 Views
13 Pages

18 January 2018

Poly(ethylene succinate) (PES), poly(butylene succinate) (PBS), and poly(hexylene succinate) (PHS), were synthesized using succinic acid and different dihydric alcohols as materials. Enzymatic degradability by cutinase of the three kinds of polyester...

  • Article
  • Open Access
56 Citations
8,096 Views
15 Pages

17 January 2018

Organic montmorillonite (MMT) modified by 1,3-dihexadecyl-3H-benzimidazolium bromide (Bz) was used to prepare polyphenylene sulfide (PPS)/MMT composites by melting intercalation. The PPS/MMT composites showed mixed morphology, being comprised of exfo...

  • Article
  • Open Access
8 Citations
6,484 Views
25 Pages

17 January 2018

We used the self-consistent field (SCF) formalism of Scheutjens and Fleer (SF-SCF) to complement existing theoretical investigations on the phase behavior of block copolymer melts. This method employs the freely jointed chain (FJC) model for finite c...

  • Article
  • Open Access
37 Citations
7,899 Views
18 Pages

The Effect of Reactive Ionic Liquid or Plasticizer Incorporation on the Physicochemical and Transport Properties of Cellulose Acetate Propionate-Based Membranes

  • Edyta Rynkowska,
  • Kateryna Fatyeyeva,
  • Joanna Kujawa,
  • Krzysztof Dzieszkowski,
  • Andrzej Wolan and
  • Wojciech Kujawski

17 January 2018

Pervaporation is a membrane-separation technique which uses polymeric and/or ceramic membranes. In the case of pervaporation processes applied to dehydration, the membrane should transport water molecules preferentially. Reactive ionic liquid (RIL) (...

  • Article
  • Open Access
31 Citations
5,603 Views
14 Pages

Mucoadhesive Interpolyelectrolyte Complexes for the Buccal Delivery of Clobetasol

  • Venera R. Garipova,
  • Chiara G. M. Gennari,
  • Francesca Selmin,
  • Francesco Cilurzo and
  • Rouslan I. Moustafine

17 January 2018

This work aimed to investigate the feasibility to design: (a) a mucoadhesive interpolyelectrolyte complex (IPEC) loaded with clobetasol propionate (CP) intended to treat oral lichen planus and (b) individuate an orodispersible dosage form suitable fo...

  • Article
  • Open Access
23 Citations
7,024 Views
17 Pages

17 January 2018

Epoxy bonded steel plates (externally bonded reinforcemen: EBR) for the strengthening of concrete structures were introduced to the construction industry in the late 1960s, and the use of fibre reinforced polymers (FRPs) was introduced in the 1990s,...

  • Article
  • Open Access
20 Citations
7,087 Views
14 Pages

Mechanical Properties Changes of Irradiated Thermoplastic Elastomer

  • David Manas,
  • Ales Mizera,
  • Miroslav Manas,
  • Martin Ovsik,
  • Lenka Hylova,
  • Stanislav Sehnalek and
  • Pavel Stoklasek

17 January 2018

Some polymers need a cross-linking agent for the controlled cross-linking process of polymers with a tendency to degradation during the radiation cross-linking process. While, on the other hand, other polymers do not need a cross-linking agent—predom...

  • Article
  • Open Access
60 Citations
8,602 Views
18 Pages

Antimicrobial Carvacrol-Containing Polypropylene Films: Composition, Structure and Function

  • Max Krepker,
  • Ofer Prinz-Setter,
  • Rotem Shemesh,
  • Anita Vaxman,
  • David Alperstein and
  • Ester Segal

16 January 2018

Significant research has been directed toward the incorporation of bioactive plant extracts or essential oils (EOs) into polymers to endow the latter with antimicrobial functionality. EOs offer a unique combination of having broad antimicrobial activ...

  • Article
  • Open Access
39 Citations
7,173 Views
12 Pages

16 January 2018

The common method to impregnate wood with polyethylene glycol (PEG) is to store the samples for several weeks in aqueous PEG-solution, allowing for diffusion of PEG into the wood. As this method is poorly suited for industrial application, an alterna...

  • Article
  • Open Access
3 Citations
6,052 Views
10 Pages

16 January 2018

Polymers prepared by controlled radical polymerization (CRP) can be employed in subsequent chain-end joining reactions, yet accurately assessing the extent of coupling in mechanistically unique paths is not straightforward. Precisely known mixtures o...

  • Article
  • Open Access
3 Citations
4,840 Views
10 Pages

Quartz Microcrystal-Hybridized Organosilicone Encapsulant with Enhanced Optical and Thermal Performances

  • Xin Chen,
  • Yancong Feng,
  • Xiao Wang,
  • En Li,
  • Yao Wang,
  • Lingling Shui,
  • Hao Li,
  • Nan Li and
  • Guofu Zhou

16 January 2018

Encapsulant is one determining factor underpinning the device lifetimes of organic optoelectronics. However, encapsulant seriously needs improvement in optical, thermal, and mechanical properties, especially to develop organic light emitting diodes....

  • Article
  • Open Access
13 Citations
6,015 Views
16 Pages

Electrical, Mechanical and Electromechanical Properties of Graphene-Thermoset Polymer Composites Produced Using Acetone-DMF Solvents

  • Alessandro Giuseppe D’Aloia,
  • Alessandro Proietti,
  • Hossein Cheraghi Bidsorkhi,
  • Alessio Tamburrano,
  • Giovanni De Bellis,
  • Fabrizio Marra,
  • Agnese Bregnocchi and
  • Maria Sabrina Sarto

16 January 2018

Recently, graphene-polymer composites gained a central role in advanced stress and strain sensing. A fundamental step in the production of epoxy-composites filled with graphene nanoplatelets (GNPs) consists in the exfoliation and dispersion of expand...

  • Article
  • Open Access
42 Citations
8,748 Views
15 Pages

Bleomycin-Loaded pH-Sensitive Polymer–Lipid-Incorporated Liposomes for Cancer Chemotherapy

  • Eiji Yuba,
  • Tomohiro Osaki,
  • Misato Ono,
  • Shinjae Park,
  • Atsushi Harada,
  • Masamichi Yamashita,
  • Kazuo Azuma,
  • Takeshi Tsuka,
  • Norihiko Ito and
  • Yoshiharu Okamoto
  • + 1 author

15 January 2018

Cancer chemotherapeutic systems with high antitumor effects and less adverse effects are eagerly desired. Here, a pH-sensitive delivery system for bleomycin (BLM) was developed using egg yolk phosphatidylcholine liposomes modified with poly(ethylene...

  • Article
  • Open Access
25 Citations
5,805 Views
12 Pages

15 January 2018

In order to improve the dispensability of graphene oxide (GO) in waterborne polyurethane (WPU), sulfonated graphene (SGO) with superior dispersity was prepared by modifying graphene oxide with sodium 2-chloroethane sulfonate to introduce hydrophilic...

  • Article
  • Open Access
30 Citations
7,829 Views
18 Pages

15 January 2018

The temperature and pH dependent self-assembly of three star shaped ethylene oxide-propylene oxide (EO-PO) block copolymers (Tetronics® 304, 904 and 908) with widely different hydrophobicity was examined in aqueous solutions. Physico-chemical methods...

  • Article
  • Open Access
13 Citations
5,076 Views
12 Pages

14 January 2018

We have investigated the dispersion state of a perfluorosulfonated ionomer (PFSI; Nafion®) in aqueous dispersion and the effect of methanol (MeOH) added to the aqueous dispersion by small-angle X-ray scattering (SAXS) as well as static and dynamic li...

  • Article
  • Open Access
9 Citations
7,122 Views
13 Pages

14 January 2018

The mixing Gibbs energy Δgm for the flower-micelle phase of amphiphilic random and periodic (including alternating) copolymers was formulated on the basis of the lattice model. The formulated Δgm predicts (1) the inverse proportionality of the aggreg...

  • Article
  • Open Access
15 Citations
5,866 Views
13 Pages

13 January 2018

The aim of this study was to determine the effect of the maltodextrins prepared from chemically modified starches (crosslinked, stabilized, crosslinked and stabilized) on the stability and rheological properties of model oil-in-water (o/w) emulsions....

  • Article
  • Open Access
15 Citations
5,606 Views
10 Pages

Photoinduced Cu(II)-Mediated RDRP to P(VDF-co-CTFE)-g-PAN

  • Xin Hu,
  • Guopeng Cui,
  • Ning Zhu,
  • Jinglin Zhai and
  • Kai Guo

13 January 2018

Photoinduced Cu(II)-mediated reversible deactivation radical polymerization (RDRP) was employed to synthesize poly(vinylidene fluoride-co-chlorotrifluoroethylene)-graft-polyacrylonitrile (P(VDF-co-CTFE)-g-PAN). The concentration of copper catalyst (C...

  • Article
  • Open Access
4 Citations
4,477 Views
23 Pages

13 January 2018

The effect of configuration of an asymmetric bulky initiator 2,2′-[1,1′-binaphtyl-2,2′-diyl- bis-(nitrylomethilidyne)]diphenoxy aluminum isopropoxide (Ini) on structure of copolymer of asymmetric monomer l,l-lactide (Lac) with symmetric comonomer tri...

  • Article
  • Open Access
65 Citations
7,021 Views
13 Pages

13 January 2018

An active film was prepared by incorporating cortex Phellodendron extract (CPE, an active agent) into a soybean protein isolate (SPI). Different concentrations of CPE (0%, 10%, 12.5%, 15%, 17.5%, 20%, or 22.5%, w/w, based on SPI) were mixed into the...

  • Article
  • Open Access
23 Citations
10,332 Views
11 Pages

11 January 2018

In this work, molecular dynamics (MD) and molecular mechanics (MM) simulations are used to study well-equilibrated models of 4,4′-bis(3,4-dicyanophenoxy)biphenyl (BPh)–1,3-bis(3-aminophenoxy)benzene (m-APB) phthalonitrile (PN) system with a range of...

  • Article
  • Open Access
36 Citations
6,854 Views
18 Pages

11 January 2018

This paper provides new insights regarding jute fibers functionalization with silver nanoparticles (Ag NPs) with improved conductivity values and highlights the sustainability of the processes involved. These NPs were applied onto jute fabrics by two...

  • Article
  • Open Access
36 Citations
6,073 Views
7 Pages

Gold Nanospheres Dispersed Light Responsive Epoxy Vitrimers

  • Zhenhua Wang,
  • Zhen Li,
  • Yen Wei and
  • Yan Ji

11 January 2018

Vitrimers represent a new class of smart materials. They are covalently crosslinked like thermosets, yet they can be reprocessed like thermoplastics. The underlying mechanism is the rapid exchange reactions which form new bonds while breaking the old...

  • Article
  • Open Access
24 Citations
5,477 Views
17 Pages

11 January 2018

Polypropylene (PP) light weight meshes are commonly used as hernioplasty implants. Nevertheless, the growth of bacteria within textile knitted mesh intersections can occur after surgical mesh implantation, causing infections. Thus, bacterial reproduc...

  • Article
  • Open Access
9 Citations
4,473 Views
14 Pages

11 January 2018

Efficient transfer of load between concrete substrate and fibre reinforced polymer (FRP) by the bonding agent is the key factor in any FRP strengthening system. An innovative high-strength self-compacting non-polymer cementitious adhesive (IHSSC-CA)...

  • Review
  • Open Access
78 Citations
12,856 Views
26 Pages

11 January 2018

This review is an attempt to update the recent advances in the self-assembly of amphiphilic block and graft copolymers. Their micellization behavior is highlighted for linear AB, ABC triblock terpolymers, and graft structures in non-aqueous selective...

  • Article
  • Open Access
13 Citations
4,951 Views
16 Pages

Cross-Flow Catalysis Behavior of a PVDF/SiO2@Ag Nanoparticles Composite Membrane

  • Wenqiang Wang,
  • Xi Chen,
  • Chu Zhao,
  • Bowu Zhao,
  • Hualin Dong,
  • Shengkui Ma,
  • Liying Li,
  • Li Chen and
  • Bin Zhang

10 January 2018

A blend of Polyvinylidene Fluoride (PVDF) and SiO2 microspheres in N,N-Dimethylformamide (DMF) underwent phase inversion to form a PVDF/SiO2 membrane with SiO2 microspheres in the membrane’s pores. Subsequently, the SiO2 microspheres have been used a...

  • Article
  • Open Access
18 Citations
6,966 Views
11 Pages

Influence of Temperature on the Mechanical Properties and Reactive Behavior of Al-PTFE under Quasi-Static Compression

  • Huai-Xi Wang,
  • Xiang Fang,
  • Bin Feng,
  • Zhen-Ru Gao,
  • Shuang-Zhang Wu and
  • Yu-Chun Li

10 January 2018

Al-PTFE (aluminum-polytetrafluoroethylene) is a typical kind of Reactive Material (RM), which has a variety of potential applications in weapon systems. In this paper, quasi-static compression experiments were carried out for a pressed and sintered m...

  • Review
  • Open Access
49 Citations
12,472 Views
28 Pages

Intercalation Polymerization Approach for Preparing Graphene/Polymer Composites

  • Yifan Guo,
  • Fuxi Peng,
  • Huagao Wang,
  • Fei Huang,
  • Fanbin Meng,
  • David Hui and
  • Zuowan Zhou

10 January 2018

The rapid development of society has promoted increasing demand for various polymer materials. A large variety of efforts have been applied in order for graphene strengthened polymer composites to satisfy different requirements. Graphene/polymer comp...

  • Article
  • Open Access
13 Citations
8,122 Views
11 Pages

Facile and Rapid Formation of Giant Vesicles from Glass Beads

  • Radu Tanasescu,
  • Ute Mettal,
  • Adai Colom,
  • Aurélien Roux and
  • Andreas Zumbuehl

9 January 2018

Giant vesicles (GVs) are widely-used model systems for biological membranes. The formulation of these vesicles, however, can be problematic and artifacts, such as degraded molecules or left-over oil, may be present in the final liposomes. The rapid f...

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Polymers - ISSN 2073-4360