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Catalysts, Volume 7, Issue 9

September 2017 - 37 articles

Cover Story: Non-edible lignocellulosic biomass can be converted into drop-in biofuels via various routes among which much attention has been recently paid to a combination of biological and chemical transformations. The promising example is that fermentation-derived acetone and alcohols can be catalytically transformed into long-chain hydrocarbons of fuel range. In the chemical transformation are involved two reaction steps such as alcohol dehydrogenation into aldehyde over metallic sites and aldol condensation between acetone of enol/enolate type and in-situ formed aldehyde over basic sites. This desired conversion is achieved by Cu catalysts supported on the ceria-zirconia of ceria rich. View Paper here
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Articles (37)

  • Article
  • Open Access
23 Citations
6,399 Views
23 Pages

13 September 2017

In this study, the application of a calcium-based bifunctional catalyst/sorbent is investigated in modified chemical looping steam methane reforming (CLSMR) process for in situ CO2 sorption and H2 production. The yttrium promoted Ca-Co samples were s...

  • Article
  • Open Access
15 Citations
6,372 Views
11 Pages

Pulse Microcalorimetry Study of Methane Dry Reforming Reaction on Ni/Ceria-Zirconia Catalyst

  • Mikhail N. Simonov,
  • Vladimir A. Rogov,
  • Marina Yu. Smirnova and
  • Vladislav A. Sadykov

12 September 2017

For Ni/CeZrO catalyst prepared in supercritical isopropanol main features of methane dry reforming reaction mechanism were studied by the pulse microcalorimetric technique. The reaction scheme is described by a step-wise redox mechanism with independ...

  • Article
  • Open Access
28 Citations
5,414 Views
13 Pages

Selective Acetylation of Small Biomolecules and Their Derivatives Catalyzed by Er(OTf)3

  • Monica Nardi,
  • Maria Luisa Di Gioia,
  • Paola Costanzo,
  • Antonio De Nino,
  • Loredana Maiuolo,
  • Manuela Oliverio,
  • Fabrizio Olivito and
  • Antonio Procopio

12 September 2017

It is of great significance to develop sustainable processes of catalytic reaction. We report a selective procedure for the synthesis of acetylated bioactive compounds in water. The use of 1-acetylimidazole combined with Er(OTf)3 as a Lewis acid cata...

  • Article
  • Open Access
2 Citations
5,067 Views
13 Pages

11 September 2017

The flower-like Bi2WO6 microsphere was synthesized through a simple hydrothermal route, and three catalysts, Au/Bi2WO6, CuO/Bi2WO6, and Au–CuO/Bi2WO6, were prepared by a deposition–precipitation method. The morphology and structure of the catalysts w...

  • Feature Paper
  • Review
  • Open Access
100 Citations
13,717 Views
40 Pages

7 September 2017

Hydrodeoxygenation (HDO) of bio-oils, lignin and their model compounds is summarized in this review. The main emphasis is put on elucidating the reaction network, catalyst stability and time-on-stream behavior, in order to better understand the prere...

  • Article
  • Open Access
3 Citations
6,751 Views
15 Pages

5 September 2017

Density functional theory (DFT) calculations have been performed to investigate the 2° alcohol oxidation to acetophenone catalyzed by the CuI/L-Proline-2,2,6,6- tetramethylpiperidinyloxy (TEMPO) catalyst system. Seven possible pathways (paths A→F) ar...

  • Article
  • Open Access
20 Citations
7,353 Views
15 Pages

Regioselective Synthesis of Lactulose Esters by Candida antarctica and Thermomyces lanuginosus Lipases

  • Luis F. Chávez-Flores,
  • Hiram Isaac Beltran,
  • Daniel Arrieta-Baez and
  • Dolores Reyes-Duarte

3 September 2017

The interest in sugar esters as emulsifiers has been increasing in recent years because they have tunable surfactant properties that depend on the chain length of the fatty acid and the type of the sugar, covering a wide range of hydrophilic-lipophil...

  • Feature Paper
  • Article
  • Open Access
13 Citations
5,119 Views
12 Pages

1 September 2017

Mesoporous HZSM-5 prepared by alkaline treatment (also termed desilication) has drawn significant attention due to its potential in large-scale production and in versatile applications, such as separation and catalysis. Alkali-treated HZSM-5 contains...

  • Review
  • Open Access
106 Citations
17,865 Views
17 Pages

1 September 2017

Layered double hydroxides (LDHs) are an important large class of two-dimensional (2D) anionic lamellar materials that possess flexible modular structure, facile exchangeability of inter-lamellar guest anions and uniform distribution of metal cations...

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Catalysts - ISSN 2073-4344