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Materials, Volume 6, Issue 4

2013 April - 24 articles

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Articles (24)

  • Article
  • Open Access
29 Citations
6,895 Views
12 Pages

Preparation of Palladium-Supported Periodic Mesoporous Organosilicas and their Use as Catalysts in the Suzuki Cross-Coupling Reaction

  • Jorge A. Corral,
  • María I. López,
  • Dolores Esquivel,
  • Manuel Mora,
  • César Jiménez-Sanchidrián and
  • Francisco J. Romero-Salguero

17 April 2013

Three periodic mesoporous materials, i.e., two organosilicas with either ethylene or phenylene bridges and one silica, have been used as supports for Pd nanoparticles. All Pd-supported samples (1.0 wt%) were prepared by the incipient wetness method a...

  • Article
  • Open Access
9 Citations
6,804 Views
11 Pages

Growth of Hexagonal Columnar Nanograin Structured SiC Thin Films on Silicon Substrates with Graphene–Graphitic Carbon Nanoflakes Templates from Solid Carbon Sources

  • Xingfang Liu,
  • Guosheng Sun,
  • Bin Liu,
  • Guoguo Yan,
  • Min Guan,
  • Yang Zhang,
  • Feng Zhang,
  • Yu Chen,
  • Lin Dong and
  • Yiping Zeng
  • + 5 authors

16 April 2013

We report a new method for growing hexagonal columnar nanograin structured silicon carbide (SiC) thin films on silicon substrates by using graphene–graphitic carbon nanoflakes (GGNs) templates from solid carbon sources. The growth was carried out in...

  • Article
  • Open Access
54 Citations
7,692 Views
10 Pages

15 April 2013

A novel kind of α-Fe2O3-filled ordered mesoporous carbon nanorods has been synthesized by a facial hydrothermal method. Compared with dendritic α-Fe2O3 micropines, both a broader effective absorption range—from 10.5 GHz to 16.5 GHz with reflection lo...

  • Article
  • Open Access
41 Citations
6,379 Views
13 Pages

15 April 2013

The novel complex photocatalytic material was prepared by coating TiO2 nanoparticles on tourmaline using the sol-gel method, and used in the degradation of the herbicide 2,4-D. The results indicated that coating TiO2 with tourmaline enhanced the phot...

  • Article
  • Open Access
26 Citations
6,453 Views
10 Pages

Randomness and Statistical Laws of Indentation-Induced Pop-Out in Single Crystal Silicon

  • Hu Huang,
  • Hongwei Zhao,
  • Chengli Shi,
  • Lin Zhang,
  • Shunguang Wan and
  • Chunyang Geng

12 April 2013

Randomness and discreteness for appearance of pop-out of the single crystal silicon with a (100) orientation were studied by a self-made indentation device. For a given maximum penetration load, the load Ppo for appearance of pop-out fluctuates in a...

  • Article
  • Open Access
16 Citations
7,057 Views
14 Pages

Green Synthesis, Molecular Characterization and Associative Behavior of Some Gemini Surfactants without a Spacer Group

  • Carla Villa,
  • Sara Baldassari,
  • Delia F. Chillura Martino,
  • Alberto Spinella and
  • Eugenio Caponetti

12 April 2013

A series of new gemini surfactants without a spacer group, disodium 2,3-dialkyl-1,2,3,4-butanetetracarboxylates, were synthesized in a green chemistry context minimizing the use of organic solvents and applying microwaves (MW) when activation energy...

  • Article
  • Open Access
17 Citations
6,491 Views
15 Pages

Dehydration Process of Hofmann-Type Layered Solids

  • Omar Reyes-Martinez,
  • Enelio Torres-García,
  • Geonel Rodríguez-Gattorno and
  • Edilso Reguera

9 April 2013

In the present work the dehydration process of layered solids with formula unit M(H2O)2[Ni(CN)4nH2O, M = Ni, Co, Mn; n = 1, 2, 4 is studied using modulated thermogravimetry. The results show that water molecules need to overcome an energetic barrie...

  • Article
  • Open Access
7 Citations
7,834 Views
18 Pages

Organized Silica Films Generated by Evaporation-Induced Self-Assembly as Hosts for Iron Oxide Nanoparticles

  • Ioanna Andreou,
  • Heinz Amenitsch,
  • Vlassis Likodimos,
  • Polycarpos Falaras,
  • Petros G. Koutsoukos and
  • Epameinondas Leontidis

9 April 2013

In this work, we prepared oriented mesoporous thin films of silica on various solid substrates using the pluronic block copolymer P123 as a template. We attempted to insert guest iron oxide (FexOy) nanoparticles into these films by two different meth...

  • Article
  • Open Access
119 Citations
9,639 Views
11 Pages

9 April 2013

This paper presents workability, compressive strength and microstructure for geopolymer pastes and mortars made of class C fly ash at mass ratios of water-to-fly ash from 0.30 to 0.35. Fluidity was in the range of 145–173 mm for pastes and 131–136 mm...

  • Article
  • Open Access
29 Citations
7,424 Views
18 Pages

Evaluation of Superficial and Dimensional Quality Features in Metallic Micro-Channels Manufactured by Micro-End-Milling

  • Karla P. Monroy-Vázquez,
  • Aldo Attanasio,
  • Elisabetta Ceretti,
  • Héctor R. Siller,
  • Nicolás J. Hendrichs-Troeglen and
  • Claudio Giardini

3 April 2013

Miniaturization encourages the development of new manufacturing processes capable of fabricating features, like micro-channels, in order to use them for different applications, such as in fuel cells, heat exchangers, microfluidic devices and micro-e...

  • Article
  • Open Access
1 Citations
6,041 Views
17 Pages

Extraction of Perchlorate Using Porous Organosilicate Materials

  • Brandy J. Johnson,
  • Iwona A. Leska,
  • Brian J. Melde,
  • Ronald L. Siefert,
  • Anthony P. Malanoski,
  • Martin H. Moore,
  • Jenna R. Taft and
  • Jeffrey R. Deschamps

2 April 2013

Sorbent materials were developed utilizing two morphological structures, comprising either hexagonally packed pores (HX) or a disordered pore arrangement (CF). The sorbents were functionalized with combinations of two types of alkylammonium groups. W...

  • Article
  • Open Access
115 Citations
8,269 Views
12 Pages

A Novel Hydrazinecarbothioamide as a Potential Corrosion Inhibitor for Mild Steel in HCl

  • Ahmed A. Al-Amiery,
  • Abdul Amir H. Kadhum,
  • Abu Bakar Mohamad and
  • Sutiana Junaedi

2 April 2013

2-(1-methyl-4-((E)-(2-methylbenzylidene)amino)-2-phenyl-1H-pyrazol-3(2H)-ylidene)-hydrazineecarbothioamide (HCB) was synthesized as a corrosion inhibitor from the reaction of 4-aminoantipyrine, thiosemicarbazide and 2-methylbenzaldehyde. The corrosio...

  • Correction
  • Open Access
1 Citations
4,593 Views
2 Pages

2 April 2013

Due to an oversight by the authors, Table 4 in the aforementioned review article [1] should have been referred to as obtained from reference [2]: Khajavi, S. Separation of Process Water Using Hydroxy Sodalite Membranes. PhD Thesis, Delft University...

  • Review
  • Open Access
60 Citations
14,267 Views
27 Pages

How Can Nanotechnology Help to Repair the Body? Advances in Cardiac, Skin, Bone, Cartilage and Nerve Tissue Regeneration

  • Macarena Perán,
  • María Angel García,
  • Elena Lopez-Ruiz,
  • Gema Jiménez and
  • Juan Antonio Marchal

28 March 2013

Nanotechnologists have become involved in regenerative medicine via creation of biomaterials and nanostructures with potential clinical implications. Their aim is to develop systems that can mimic, reinforce or even create in vivo tissue repair strat...

  • Article
  • Open Access
115 Citations
10,772 Views
17 Pages

Magnetic Graphene Oxide: Effect of Preparation Route on Reactive Black 5 Adsorption

  • George Z. Kyzas,
  • Nikolina A. Travlou,
  • Orestis Kalogirou and
  • Eleni A. Deliyanni

28 March 2013

In this study, the effect of preparation route of magnetic graphene oxide (mGO) on Reactive Black 5 (RB5) adsorption was investigated. The synthesis of mGO was achieved both with (i) impregnation method (mGOi nanoparticles), and (ii) co-precipitation...

  • Article
  • Open Access
26 Citations
7,911 Views
14 Pages

Cellulose Perversions

  • João P. Canejo and
  • Maria H. Godinho

28 March 2013

Cellulose micro/nano-fibers can be produced by electrospinning from liquid crystalline solutions. Scanning electron microscopy (SEM), as well as atomic force microscopy (AFM) and polarizing optical microscopy (POM) measurements showed that cellulose-...

  • Article
  • Open Access
24 Citations
8,231 Views
12 Pages

Chitosonic® Acid as a Novel Cosmetic Ingredient: Evaluation of its Antimicrobial, Antioxidant and Hydration Activities

  • Shu-Mei Lee,
  • Kun-Ho Liu,
  • Yen-Yu Liu,
  • Yen-Po Chang,
  • Chih-Chien Lin and
  • Yi-Shyan Chen

28 March 2013

Chitosonic® Acid, carboxymethyl hexanoyl chitosan, is a novel chitosan material that has recently been accepted by the Personal Care Products Council as a new cosmetic ingredient with the INCI (International Nomenclature of Cosmetic Ingredients) name...

  • Review
  • Open Access
380 Citations
27,371 Views
16 Pages

Lithium Ion Battery Anode Aging Mechanisms

  • Victor Agubra and
  • Jeffrey Fergus

27 March 2013

Degradation mechanisms such as lithium plating, growth of the passivated surface film layer on the electrodes and loss of both recyclable lithium ions and electrode material adversely affect the longevity of the lithium ion battery. The anode electro...

  • Article
  • Open Access
39 Citations
7,912 Views
7 Pages

Half-Heusler (TiZrHf)NiSn Unileg Module with High Powder Density

  • Sascha Populoh,
  • Oliver C. Brunko,
  • Krzysztof Gałązka,
  • Wenjie Xie and
  • Anke Weidenkaff

27 March 2013

(TiZrHf)NiSn half-Heusler compounds were prepared by arc melting and their thermoelectric properties characterized in the temperature range between 325 K and 857 K, resulting in a Figure of Merit ZT ≈ 0.45. Furthermore, the prepared samples were used...

  • Article
  • Open Access
135 Citations
12,318 Views
15 Pages

26 March 2013

More and more attention has been paid to environmentally friendly bio-based renewable materials as the substitution of fossil-based materials, due to the increasing environmental concerns. In this study, regenerated cellulose films with enhanced mech...

  • Review
  • Open Access
1,205 Citations
40,145 Views
25 Pages

26 March 2013

Alginate is a natural polysaccharide exhibiting excellent biocompatibility and biodegradability, having many different applications in the field of biomedicine. Alginate is readily processable for applicable three-dimensional scaffolding materials su...

  • Review
  • Open Access
37 Citations
7,040 Views
32 Pages

25 March 2013

In this review, the main synthetic aspects and properties of fluorinated arylenevinylene compounds, both oligomers and polymers, are summarized and analyzed. Starting from vinyl organotin derivatives and aryl halides, the Stille cross-coupling reacti...

  • Article
  • Open Access
34 Citations
7,554 Views
18 Pages

Characterization of an Exopolymeric Flocculant Produced by a Brachybacterium sp.

  • Uchechukwu U. Nwodo,
  • Mayowa O. Agunbiade,
  • Ezekiel Green,
  • Mutshinyalo Nwamadi,
  • Karl Rumbold and
  • Anthony I. Okoh

25 March 2013

We evaluated the bioflocculant production potential of an Actinobacteria, which was isolated from a freshwater environment in the Eastern Cape province of South Africa. 16S rDNA nucleotide sequencing analyses revealed that the actinobacteria belongs...

  • Article
  • Open Access
61 Citations
9,114 Views
15 Pages

25 March 2013

An ultrasensitive portable electrochemical immunosensor for human immunodeficiency virus p24 (HIV p24) antigen detection has been developed, whereby the detection sensitivity was 1000 times higher than that of the ELISA method. Firstly, a novel HRP e...

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Materials - ISSN 1996-1944