Abstract
This paper presents a practical thermal control strategy to enhance the output performance of oxide-based all-solid-state batteries (ASSBs), which typically exhibit low ionic conductivity at room temperature. A lightweight polyimide (PI) film heater was designed, fabricated, and integrated into the cell stack to locally maintain the optimal operating temperature range (≈65–75 °C) for electrolyte activation. Unlike previous studies limited to liquid or sulfide-based batteries, this work demonstrates the direct integration and coupled numerical–experimental validation of a PI film heater within oxide-based ASSBs. The proposed design achieves high heating efficiency (~92%) with minimal thickness (<100 μm) and long-term stability, enabling reliable and scalable thermal management. Finite-element simulations and experimental verification confirmed that the proposed heater achieved rapid and uniform heating with less than a 10 °C temperature deviation between the cell and heater surfaces. These findings provide a foundation for smart battery management systems with distributed temperature sensing and feedback control, supporting the development of high-performance and reliable solid-state battery platforms.