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34 pages, 7297 KiB  
Article
Passive Design for Residential Buildings in Arid Desert Climates: Insights from the Solar Decathlon Middle East
by Esra Trepci and Edwin Rodriguez-Ubinas
Buildings 2025, 15(15), 2731; https://doi.org/10.3390/buildings15152731 - 2 Aug 2025
Viewed by 237
Abstract
This study investigates the effectiveness of passive design in low-rise residential buildings located in arid desert climates, using the Dubai Solar Decathlon Middle East (SDME) competition as a case study. This full-scale experiment offers a unique opportunity to evaluate design solutions under controlled, [...] Read more.
This study investigates the effectiveness of passive design in low-rise residential buildings located in arid desert climates, using the Dubai Solar Decathlon Middle East (SDME) competition as a case study. This full-scale experiment offers a unique opportunity to evaluate design solutions under controlled, realistic conditions; prescriptive, modeled performance; and monitored performance assessments. The prescriptive assessment reviews geometry, orientation, envelope thermal properties, and shading. Most houses adopt compact forms, with envelope-to-volume and envelope-to-floor area ratios averaging 1 and 3.7, respectively, and window-to-wall ratios of approximately 17%, favoring north-facing openings to optimize daylight while reducing heat gain. Shading is strategically applied, horizontal on south façades and vertical on east and west. The thermal properties significantly exceed the local code requirements, with wall performance up to 80% better than that mandated. The modeled assessment uses Building Energy Models (BEMs) to simulate the impact of prescriptive measures on energy performance. Three variations are applied: assigning minimum local code requirements to all the houses to isolate the geometry (baseline); removing shading; and applying actual envelope properties. Geometry alone accounts for up to 60% of the variation in cooling intensity; shading reduces loads by 6.5%, and enhanced envelopes lower demand by 14%. The monitored assessment uses contest-period data. Indoor temperatures remain stable (22–25 °C) despite outdoor fluctuations. Energy use confirms that houses with good designs and airtightness have lower cooling loads. Airtightness varies widely (avg. 14.5 m3/h/m2), with some well-designed houses underperforming due to construction flaws. These findings highlight the critical role of passive design as the first layer for improving the energy performance of the built environment and advancing toward net-zero targets, specifically in arid desert climates. Full article
(This article belongs to the Special Issue Climate-Responsive Architectural and Urban Design)
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21 pages, 6272 KiB  
Article
Numerical Study of Gas Dynamics and Condensate Removal in Energy-Efficient Recirculation Modes in Train Cabins
by Ivan Panfilov, Alexey N. Beskopylny, Besarion Meskhi and Sergei F. Podust
Fluids 2025, 10(8), 197; https://doi.org/10.3390/fluids10080197 - 29 Jul 2025
Viewed by 158
Abstract
Maintaining the required relative humidity values in the vehicle cabin is an important HVAC task, along with considerations related to the temperature, velocity, air pressure and noise. Deviation from the optimal values worsens the psycho-physiological state of the driver and affects the energy [...] Read more.
Maintaining the required relative humidity values in the vehicle cabin is an important HVAC task, along with considerations related to the temperature, velocity, air pressure and noise. Deviation from the optimal values worsens the psycho-physiological state of the driver and affects the energy efficiency of the train. In this study, a model of liquid film formation on and removal from various cabin surfaces was constructed using the fundamental Navier–Stokes hydrodynamic equations. A special transport model based on the liquid vapor diffusion equation was used to simulate the air environment inside the cabin. The evaporation and condensation of surface films were simulated using the Euler film model, which directly considers liquid–gas and gas–liquid transitions. Numerical results were obtained using the RANS equations and a turbulence model by means of the finite volume method in Ansys CFD. Conjugate fields of temperature, velocity and moisture concentration were constructed for various time intervals, and the dependence values for the film thicknesses on various surfaces relative to time were determined. The verification was conducted in comparison with the experimental data, based on the protocol for measuring the microclimate indicators in workplaces, as applied to the train cabin: the average ranges encompassed temperature changes from 11% to 18%, and relative humidity ranges from 16% to 26%. Comparison with the results of other studies, without considering the phase transition and condensation, shows that, for the warm mode, the average air temperature in the cabin with condensation is 12.5% lower than without condensation, which is related to the process of liquid evaporation from the heated walls. The difference in temperature values for the model with and without condensation ranged from −12.5% to +4.9%. We demonstrate that, with an effective mode of removing condensate film from the window surface, including recirculation modes, the energy consumption of the climate control system improves significantly, but this requires a more accurate consideration of thermodynamic parameters and relative humidity. Thus, considering the moisture condensation model reveals that this variable can significantly affect other parameters of the microclimate in cabins: in particular, the temperature. This means that it should be considered in the numerical modeling, along with the basic heat transfer equations. Full article
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14 pages, 3376 KiB  
Case Report
Clinicopathologic Features, Surgical Treatment, and Pathological Characterization of Canine Dacryops with Different Localization
by Barbara Lamagna, Luigi Navas, Francesco Prisco, Dario Costanza, Valeria Russo, Francesco Lamagna, Cristina Di Palma, Valeria Uccello, Giuseppina Mennonna, Orlando Paciello, Flaviana La Peruta, Giovanni Flauto and Giovanni Della Valle
Vet. Sci. 2025, 12(8), 705; https://doi.org/10.3390/vetsci12080705 - 28 Jul 2025
Viewed by 183
Abstract
Lacrimal cysts (dacryops), which involve lacrimal tissue, are uncommon in dogs with an obscure/unclear pathogenesis. Compared to the current available literature, this report describes the clinicopathologic and immunohistochemical features of two cases of unusual dacryops in brachycephalic dogs. A three-year-old male Cane Corso [...] Read more.
Lacrimal cysts (dacryops), which involve lacrimal tissue, are uncommon in dogs with an obscure/unclear pathogenesis. Compared to the current available literature, this report describes the clinicopathologic and immunohistochemical features of two cases of unusual dacryops in brachycephalic dogs. A three-year-old male Cane Corso was referred with a 1-month history of swelling ventromedial to the left eye associated with blepharospasm and epiphora. Furthermore, a severe lower and upper eyelid entropion and a deep corneal ulcer were present. B-mode ultrasonography and a CT scan revealed a subcutaneous cyst, closely adherent to the maxillary bone. Surgical removal and the correction of entropion were performed. No recurrence and/or complication was detected by seven-year follow-up. Histopathology revealed a cystic structure with single- to double-cell-layered, nonciliated, cuboidal epithelia. Alcian blue stain revealed rare, disseminated goblet cells admixed with epithelial cells. The epithelium was strongly Cytokeratin-positive by immunohistochemistry and appeared lined by several layers of smooth muscle actin (SMA)-positive myoepithelial cells. A 1-year-old male French Bulldog with a 3-month lesion of the third eyelid of the right eye. The lesion (15 mm × 7 mm) beneath the conjunctiva appeared pale-pink, smooth, and multilobulated. Excision was performed by blunt dissection through the conjunctiva on the palpebral surface of the third eyelid. Recovery was uncomplicated, and no recurrence has been noted at three-year follow-up. Cytology of the cystic fluid and histopathology and immunohistochemistry of the cyst wall revealed findings for case 1. To further characterize the SMA-positive spindle cells located directly beneath the cyst-lining epithelium, double-color immunofluorescence for SMA and p63 (a myoepithelial cell marker) was performed on the sample from case 2. The analysis revealed that the SMA-positive cells lacked p63 expression, indicating a non-myoepithelial phenotype. The histological findings in our cases are consistent with previous reports of canine dacryops. The positivity of immunohistochemical staining for SMA in cells directly beneath the epithelium of dacryops in the cases here described in two brachycephalic dogs is consistent with previous reports in dogs and horses but in contrast with a retrospective study about a human dacryops. These results support the conclusion that the pathogenesis of dacryops in dogs should exclude failure of ductular “neuromuscular” contractility. Full article
(This article belongs to the Special Issue Spotlight on Ophthalmologic Pathology in Animals)
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17 pages, 6623 KiB  
Article
Numerical Study on Flow Field Optimization and Wear Mitigation Strategies for 600 MW Pulverized Coal Boilers
by Lijun Sun, Miao Wang, Peian Chong, Yunhao Shao and Lei Deng
Energies 2025, 18(15), 3947; https://doi.org/10.3390/en18153947 - 24 Jul 2025
Viewed by 165
Abstract
To compensate for the instability of renewable energy sources during China’s energy transition, large thermal power plants must provide critical operational flexibility, primarily through deep peaking. To investigate the combustion performance and wear and tear of a 600 MW pulverized coal boiler under [...] Read more.
To compensate for the instability of renewable energy sources during China’s energy transition, large thermal power plants must provide critical operational flexibility, primarily through deep peaking. To investigate the combustion performance and wear and tear of a 600 MW pulverized coal boiler under deep peaking, the gas–solid flow characteristics and distributions of flue gas temperature, wall heat flux, and wall wear rate in a 600 MW tangentially fired pulverized coal boiler under variable loads (353 MW, 431 MW, 519 MW, and 600 MW) are investigated in this study employing computational fluid dynamics numerical simulation method. Results demonstrate that increasing the boiler load significantly amplifies gas velocity, wall heat flux, and wall wear rate. The maximum gas velocity in the furnace rises from 20.9 m·s−1 (353 MW) to 37.6 m·s−1 (600 MW), with tangential airflow forming a low-velocity central zone and high-velocity peripheral regions. Meanwhile, the tangential circle diameter expands by ~15% as the load increases. The flue gas temperature distribution exhibits a “low-high-low” profile along the furnace height. As the load increases from 353 MW to 600 MW, the primary combustion zone’s peak temperature rises from 1750 K to 1980 K, accompanied by a ~30% expansion in the coverage area of the high-temperature zone. Wall heat flux correlates strongly with temperature distribution, peaking at 2.29 × 105 W·m−2 (353 MW) and 2.75 × 105 W·m−2 (600 MW) in the primary combustion zone. Wear analysis highlights severe erosion in the economizer due to elevated flue gas velocities, with wall wear rates escalating from 3.29 × 10−7 kg·m−2·s−1 (353 MW) to 1.23 × 10−5 kg·m−2·s−1 (600 MW), representing a 40-fold increase under full-load conditions. Mitigation strategies, including ash removal optimization, anti-wear covers, and thermal spray coatings, are proposed to enhance operational safety. This work provides critical insights into flow field optimization and wear management for large-scale coal-fired boilers under flexible load operation. Full article
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14 pages, 1030 KiB  
Article
Lumen-Apposing Metal Stents for Endoscopic Transgastric Drainage of Pancreatic Fluid Collections in Children—A Case Report and Review of Safety and Efficacy
by Irene Wen Hui Tu, Zong Jie Koh, Khek Yu Ho, Sivaramakrishnan Venkatesh Karthik and Vidyadhar Padmakar Mali
Children 2025, 12(8), 965; https://doi.org/10.3390/children12080965 (registering DOI) - 23 Jul 2025
Viewed by 187
Abstract
Background/Objectives: Pancreatic fluid collections (PFCs) in acute pancreatitis require drainage when symptomatic or infected. Walled-off necrosis (WON) is difficult to drain with plastic stents alone. A lumen-apposing metal stent (LAMS) offers larger calibre drainage, lower migration risk than conventional methods, and the option [...] Read more.
Background/Objectives: Pancreatic fluid collections (PFCs) in acute pancreatitis require drainage when symptomatic or infected. Walled-off necrosis (WON) is difficult to drain with plastic stents alone. A lumen-apposing metal stent (LAMS) offers larger calibre drainage, lower migration risk than conventional methods, and the option of direct endoscopic necrosectomy through the stent. However, the paediatric literature on LAMSs is sparse. We report our institutional experience, and summarise current evidence on the feasibility, efficacy and safety of LAMSs for PFC drainage in children. Methods: We performed a retrospective study at the National University Hospital (NUH) and a full review of the literature on LAMS use in children for endoscopic trans-gastric drainage of PFCs from April 2012 to September 2024. Results: There were, respectively, 2 (males, 10 and 17 years) and 18 children who underwent endoscopic trans-gastric LAMS insertion for drainage of PFCs in acute pancreatitis in the NUH and across the nine included studies, which were published between 2015 and 2024. The technical and clinical success was 100%. There were no complications during insertion or indwell time (28 and 50 days in the NUH and 40 days, range of 7–100 days in the systematic review, respectively). Endoscopic removal of LAMSs was uneventful. There were no recurrent PFCs over a 4-month (1,7 months) and 12-month (range, 2–44 months) follow-up, respectively. Migration of LAMSs to colon following the collapse of the WON was reported in one case. Conclusions: An transgastric LAMS (with trans-stent necrosectomy) is a technically feasible method of drainage of WON following acute pancreatitis in children with minimal complications. Full article
(This article belongs to the Section Pediatric Surgery)
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31 pages, 7931 KiB  
Article
Enhanced Pool Boiling via Binder-Jetting 3D-Printed Porous Copper Structures: CHF and HTC Investigation
by Lilian Aketch Okwiri, Takeshi Mochizuki, Kairi Koito, Noriaki Fukui and Koji Enoki
Appl. Sci. 2025, 15(14), 7892; https://doi.org/10.3390/app15147892 - 15 Jul 2025
Viewed by 264
Abstract
The escalating heat flux densities in high-performance electronics necessitate superior thermal management. This study enhanced pool-boiling heat transfer, a method offering high heat removal capacity, by leveraging Binder Jetting 3D Printing (BJ3DP) to create complex porous copper structures without the need for chemical [...] Read more.
The escalating heat flux densities in high-performance electronics necessitate superior thermal management. This study enhanced pool-boiling heat transfer, a method offering high heat removal capacity, by leveraging Binder Jetting 3D Printing (BJ3DP) to create complex porous copper structures without the need for chemical treatments. This approach enables a reliable utilization of phenomena like capillarity for improved performance. Three types of porous copper structures, namely Large Lattice, Small Lattice, and Staggered, were fabricated on pure copper substrates and tested via pool boiling of de-ionized and de-gassed water at atmospheric pressure. Compared to a plain polished copper surface, which exhibited a critical heat flux (CHF) of 782 kW/m2 at a wall superheat of 18 K, the 3D-printed porous copper surfaces showed significantly improved heat transfer performance. The Staggered surface achieved a conventional CHF of 2342.4 kW/m2 (a 199.7% enhancement) at a wall superheat of 24.6 K. Notably, the Large Lattice and Small Lattice structures demonstrated exceptionally stable boiling without reaching the typical catastrophic CHF within the experimental parameters. These geometries continued to increase in heat flux, reaching maximums of 2397.7 kW/m2 (206.8% higher at a wall superheat of 55.6 K) and 2577.2 kW/m2 (229.7% higher at a wall superheat of 39.5 K), respectively. Subsequently, a gradual decline in heat flux was observed with an increasing wall superheat, demonstrating an outstanding resistance to the boiling crisis. These improvements are attributed to the formation of distinct vapor–liquid pathways within the porous structures, which promotes the efficient rewetting of the heated surface through capillary action. This mechanism supports a highly efficient, self-sustaining boiling configuration, emphasizing the superior rewetting and vapor management capabilities of these 3D-printed porous structures, which extend the boundaries of sustained high heat flux performance. The porous surfaces also demonstrated a higher heat transfer coefficient (HTC), particularly at lower heat fluxes (≤750 kW/m2). High-speed digital camera visualization provided further insight into the boiling phenomenon. Overall, the findings demonstrate that these BJ3DP structured surfaces produce optimized vapor–liquid pathways and capillary-enhanced rewetting, offering significantly superior heat transfer performance compared to smooth surfaces and highlighting their potential for advanced thermal management. Full article
(This article belongs to the Section Energy Science and Technology)
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25 pages, 10123 KiB  
Article
Fabrication of Micro-Holes with High Aspect Ratios in Cf/SiC Composites Using Coaxial Waterjet-Assisted Nanosecond Laser Drilling
by Chenhu Yuan, Zenggan Bian, Yue Cao, Yinan Xiao, Bin Wang, Jianting Guo and Liyuan Sheng
Micromachines 2025, 16(7), 811; https://doi.org/10.3390/mi16070811 - 14 Jul 2025
Viewed by 267
Abstract
In the present study, the coaxial waterjet-assisted nanosecond laser drilling of micro-holes in Cf/SiC composites, coupled with nanosecond laser drilling in air for fabricating micro-holes with high aspect ratios, were investigated. The surface morphology, reaction products, and micro-hole shapes were thoroughly [...] Read more.
In the present study, the coaxial waterjet-assisted nanosecond laser drilling of micro-holes in Cf/SiC composites, coupled with nanosecond laser drilling in air for fabricating micro-holes with high aspect ratios, were investigated. The surface morphology, reaction products, and micro-hole shapes were thoroughly examined. The results reveal that, for the coaxial waterjet-assisted nanosecond laser drilling of micro-holes in the Cf/SiC composite, the increasing of waterjet velocity enhances the material removal rate and micro-hole depth, but reduces the micro-hole diameter and taper angle. The coaxial waterjet isolates the laser-ablated region and cools down the corresponding region rapidly, leading to the formation of a mixture of SiC, SiO2, and Si on the surface. As the coaxial waterjet velocity increases, the morphology of residual surface products changes from a net-like structure to individual spheres. Coaxial waterjet-assisted nanosecond laser drilling, with a waterjet velocity of 9.61 m/s, achieves micro-holes with a good balance between efficiency and quality. For the fabrication of micro-holes with a high aspect ratio in Cf/SiC composites, micro-holes fabricated by nanosecond laser drilling in air exhibit obvious taper features, which should be ascribed to the combined effects of spattering slag, plasma, and energy dissipation. The application of coaxial waterjet-assisted nanosecond laser drilling on micro-holes fabricated by laser drilling in air effectively expands the hole diameter. The fabricated micro-holes have very small taper angles, with clean wall surfaces and almost no reaction products. This approach, combining nanosecond laser drilling in air followed by coaxial waterjet-assisted nanosecond laser drilling, offers a promising technique for fabricating high-quality micro-holes with high aspect ratios in Cf/SiC composites. Full article
(This article belongs to the Special Issue Optical and Laser Material Processing, 2nd Edition)
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18 pages, 4312 KiB  
Article
Influence of Rare Earth Elements on the Radiation-Shielding Behavior of Serpentinite-Based Materials
by Ayşe Didem Kılıç and Demet Yılmaz
Appl. Sci. 2025, 15(14), 7837; https://doi.org/10.3390/app15147837 - 13 Jul 2025
Viewed by 444
Abstract
In this study, the neutron and gamma radiation-shielding properties of serpentinites from the Guleman ophiolite complex were investigated, and results were evaluated in comparison with rare earth element (REE) content. The linear and mass attenuation coefficients (LAC and MAC), half-value layer (HVL), mean [...] Read more.
In this study, the neutron and gamma radiation-shielding properties of serpentinites from the Guleman ophiolite complex were investigated, and results were evaluated in comparison with rare earth element (REE) content. The linear and mass attenuation coefficients (LAC and MAC), half-value layer (HVL), mean free path (MFP), and effective atomic numbers (Zeff) of serpentinite samples were experimentally measured in the energy range of 80.99–383.85 keV. Theoretical MAC values were calculated. Additionally, fast neutron removal cross-sections, as well as thermal and fast neutron macroscopic cross-sections, were theoretically determined. The absorbed equivalent dose rates of serpentinite samples were also measured. The radiation protection efficiency (RPE) for gamma rays and neutrons were determined. It was observed that the presence of rare earth elements within serpentinite structure has a significant impact on thermal neutron cross-sections, while crystalline water content (LOI) plays an influential role in fast neutron cross-sections. Moreover, it has been observed that the concentration of gadolinium exerts a more substantial influence on the macroscopic cross-sections of thermal neutrons than on those of fast neutrons. The research results reveal the mineralogical, geochemical, morphological and radiation-shielding properties of serpentinite rocks contribute significantly to new visions for the use of this naturally occurring rock as a geological repository for nuclear waste or as a wall-covering material in radiotherapy centers and nuclear facilities instead of concrete. Full article
(This article belongs to the Special Issue Advanced Functional Materials and Their Applications)
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15 pages, 1683 KiB  
Review
Three-Dimensional Printing and CAD/CAM Milling in Prosthodontics: A Scoping Review of Key Metrics Towards Future Perspectives
by Catalina Cioloca Holban, Monica Tatarciuc, Anca Mihaela Vitalariu, Roxana-Ionela Vasluianu, Magda Antohe, Diana Antonela Diaconu, Ovidiu Stamatin and Ana Maria Dima
J. Clin. Med. 2025, 14(14), 4837; https://doi.org/10.3390/jcm14144837 - 8 Jul 2025
Viewed by 431
Abstract
Background/Objectives: Digital prosthodontics increasingly utilize both additive (3D printing) and subtractive Computer-Aided Design/Computer-Aided Manufacturing (CAD/CAM), yet comprehensive comparisons remain limited. This scoping review evaluates their relative performance across prosthodontic applications. Methods: Systematic searches (PubMed, Scopus, Web of Science, Embase, 2015–2025) identified [...] Read more.
Background/Objectives: Digital prosthodontics increasingly utilize both additive (3D printing) and subtractive Computer-Aided Design/Computer-Aided Manufacturing (CAD/CAM), yet comprehensive comparisons remain limited. This scoping review evaluates their relative performance across prosthodontic applications. Methods: Systematic searches (PubMed, Scopus, Web of Science, Embase, 2015–2025) identified 28 studies (27 in vitro, 1 retrospective). Data were extracted on accuracy, efficiency, materials, and outcomes. Results: CAD/CAM milling demonstrated superior accuracy for fixed prostheses, with marginal gaps for milled zirconia (123.89 ± 56.89 µm), comparable to optimized 3D-printed interim crowns (123.87 ± 67.42 µm, p = 0.760). For removable prostheses, milled denture bases achieved a trueness of 65 ± 6 µm, while SLA-printed dentures post-processed at 40 °C for 30 min showed the lowest root mean square error (RMSE) (30 min/40 °C group). Three-dimensional printing excelled in material efficiency (<5% waste vs. milling > 30–40%) and complex geometries, such as hollow-pontic fixed dental prostheses (FDPs) (2.0 mm wall thickness reduced gaps by 33%). Build orientation (45° for crowns, 30–45° for veneers) and post-processing protocols significantly influenced accuracy. Milled resins exhibited superior color stability (ΔE00: 1.2 ± 0.3 vs. 3D-printed: 4.5 ± 1.1, p < 0.05), while 3D-printed Co-Cr frameworks (SLM) showed marginal fits of 8.4 ± 3.2 µm, surpassing milling (130.3 ± 13.8 µm). Digital workflows reduced chairside time by 29% (154.31 ± 13.19 min vs. 218.00 ± 20.75 min). All methods met clinical thresholds (<120 µm gaps). Conclusions: Milling remains preferred for high-precision fixed prostheses, while 3D printing offers advantages in material efficiency, complex designs, and removable applications. Critical gaps include long-term clinical data and standardized protocols. Future research should prioritize hybrid workflows, advanced materials, and AI-driven optimization to bridge technical and clinical gaps. Full article
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15 pages, 2296 KiB  
Review
A Review of the Effects and Influencing Factors of Vertical Greening Systems in Wastewater Treatment
by Wencong Zhu, Xiangyong Zheng, Min Zhao, Huijun Xiang, Suyang Zhang and Wenjuan Han
Sustainability 2025, 17(13), 6138; https://doi.org/10.3390/su17136138 - 4 Jul 2025
Viewed by 246
Abstract
Vertical greening systems (VGSs) serve as an advanced ecological wastewater treatment technology, offering advantages such as a small spatial footprint and increased green space coverage. VGSs have been widely applied to treat various types of wastewaters, including blackwater and greywater. However, a systematic [...] Read more.
Vertical greening systems (VGSs) serve as an advanced ecological wastewater treatment technology, offering advantages such as a small spatial footprint and increased green space coverage. VGSs have been widely applied to treat various types of wastewaters, including blackwater and greywater. However, a systematic review of the pollutant removal efficiency of VGSs in treating blackwater and greywater, as well as the influencing factors, remains lacking. This study compiles data on the removal efficiencies of chemical oxygen demand (COD), total phosphorus (TP), total nitrogen (TN), and ammonium nitrogen (NH4+-N) from greywater and blackwater using VGSs. Additionally, the effects of the hydraulic loading rate, substrate type, and the number of system layers on pollutant removal performance are assessed. When treating blackwater, the pollutant removal efficiency showed a positive correlation with hydraulic loading within the range of 85 L × (m2 × d)−1 to 200 L × (m2 × d)−1; substrates such as zeolite or vermiculite exhibited superior removal performance, and increasing the number of system layers enhanced the pollutant removal efficiency. When treating greywater, the hydraulic loading rate and system layers have limited influence on COD and TN removal, while excessive hydraulic loading or system layers may negatively affect TP removal. Substrate mixtures composed of perlite and coconut coir achieved a higher pollutant removal efficiency. In conclusion, optimizing key parameters such as the hydraulic loading rate, substrate composition, and the number of system layers can significantly enhance the pollutant removal efficiency of VGSs. Full article
(This article belongs to the Section Sustainable Water Management)
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29 pages, 5081 KiB  
Article
Production, Characterization, and Application of KOH-Activated Biochar from Rice Straw for Azo Dye Adsorption
by Megananda Eka Wahyu, Damayanti Damayanti and Ho Shing Wu
Biomass 2025, 5(3), 40; https://doi.org/10.3390/biomass5030040 - 1 Jul 2025
Viewed by 423
Abstract
This study explored the production and activation of biochar from rice straw residue for dye adsorption applications. Rice straw, a widely available but underutilized biomass, was processed to isolate lignin and generate biochar through pyrolysis at 450 °C and 550 °C. Activation using [...] Read more.
This study explored the production and activation of biochar from rice straw residue for dye adsorption applications. Rice straw, a widely available but underutilized biomass, was processed to isolate lignin and generate biochar through pyrolysis at 450 °C and 550 °C. Activation using chemical agents (e.g., KOH and NaOH) was performed to enhance surface area and porosity. Among the tested conditions, KOH activation at a char-to-agent ratio of 1:3 produced activated carbon at 800 °C with the highest BET surface area (835.2 m2/g), and high fixed carbon (44.4%) after HCl washing. Thermogravimetric analysis was used to investigate pyrolysis kinetics, with activation energies determined using the Kissinger, Flynn–Wall–Ozawa, and Kissinger–Akahira–Sunose models. The brown solid showed a higher activation energy (264 kJ/mol) compared to isolated lignin (194 kJ/mol), indicating that more energy is required for decomposition. The AC was evaluated for the adsorption of methylene blue (MB) and methyl orange (MO) from aqueous solutions. Both dyes followed the Langmuir isotherm model, indicating that monolayer adsorption occurred. The maximum adsorption capacities reached 222 mg/g for MB and 244 mg/g for MO at 303 K, with higher values at elevated temperatures. Adsorption followed a pseudo-second-order kinetic model and was governed by a physisorption mechanism, as supported by thermodynamic analysis (ΔH < 20 kJ/mol and Ea < 40 kJ/mol). These findings demonstrate that KOH-activated biochar from rice straw residue is a high-performance, low-cost adsorbent for dye removal, contributing to sustainable biomass utilization and wastewater treatment. Full article
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11 pages, 2968 KiB  
Article
Physiological and Transcriptome Analysis Revealed the Effect of ABA on Promoting Persimmon Fruit Postharvest Deastringency
by Han Zhou, Jiao-Jiao Nie, Meng-Lin Ren, Yu-Duan Ding, Ya-Xiu Xu and Qing-Gang Zhu
Life 2025, 15(7), 1027; https://doi.org/10.3390/life15071027 - 27 Jun 2025
Viewed by 294
Abstract
Persimmon (Diospyros kaki Thunb.) fruit can accumulate proanthocyanidins (tannins) during development, which causes astringency and affects consumption. The hormone abscisic acid (ABA) has been reported to play a key role in fruit ripening and softening. However, the effect of ABA on postharvest [...] Read more.
Persimmon (Diospyros kaki Thunb.) fruit can accumulate proanthocyanidins (tannins) during development, which causes astringency and affects consumption. The hormone abscisic acid (ABA) has been reported to play a key role in fruit ripening and softening. However, the effect of ABA on postharvest persimmon fruit deastringency remains unclear. In this study, we found that 300 mg/L ABA treatment could decrease the content of soluble tannins, thus leading removal of persimmon fruit astringency. The contents of acetaldehyde and ethanol did not increase during the storage time, indicating that ABA treatment-promoted persimmon fruit deastringency was not due to the acetaldehyde interaction with soluble tannins. Furthermore, the transcriptome analysis showed that 6713 differentially expressed genes (DEGs) were identified, and the WGCNA (weighted gene co-expression network analysis) showed that one module, which comprises 575 DEGs, significantly correlated with the contents of soluble and resoluble tannins. The analysis based on the carbohydrate metabolism pathway indicated that 37 differentially expressed structural genes involved in acetaldehyde metabolism were upregulated by ABA. Real-time quantitative PCR showed that the previously reported key genes, including structural genes and transcription factors, were all upregulated by ABA treatment. The obtained results indicate that ABA treatment, promoting persimmon fruit astringency removal, may occur through gel polymerization of cell wall materials with soluble tannins. Full article
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20 pages, 5699 KiB  
Article
Upcycling of Agro-Waste: Research on Performance of a Novel Super-Hygroscopic Material Prepared by Exploiting the Porous Structure of Steam-Exploded Modified Corn Stalk Pith
by Nan Wang, Chuntao Xia, Tingting Liu and Dawei Wang
Polymers 2025, 17(13), 1779; https://doi.org/10.3390/polym17131779 - 27 Jun 2025
Viewed by 281
Abstract
Herein, a novel super-hygroscopic material, steam-exploded modified corn stalk pith (SE-CSP), was developed from corn stalk pith (CSP) via the steam explosion (SE) method, and its hygroscopic properties and mechanisms were evaluated. The results confirmed that SE effectively removed lignin and hemicellulose, disrupted [...] Read more.
Herein, a novel super-hygroscopic material, steam-exploded modified corn stalk pith (SE-CSP), was developed from corn stalk pith (CSP) via the steam explosion (SE) method, and its hygroscopic properties and mechanisms were evaluated. The results confirmed that SE effectively removed lignin and hemicellulose, disrupted the thin cell walls of natural CSP, and formed an aligned porous structure with capillary channels. SE changed the bonding distribution and surface morphology, and enhanced the crystallinity and thermal stability of CSP. The equilibrium hygroscopic percentage of SE-CSP (62.50%) was higher than that of CSP (44.01%) at 25 °C and 80% relative humidity (RH), indicating significantly greater hygroscopicity. The hygroscopic process of SE-CSP followed a Type III isotherm and fitted the Guggenheim–Anderson–de Boer (GAB), Peleg, and pseudo-first-order kinetic models. This process exhibited multi-layer adsorption with enthalpy-driven, exothermic behavior, primarily through physical adsorption involving hydrogen bonds and van der Waals forces. This work offered a new approach for advancing sorption dehumidification technology. Full article
(This article belongs to the Special Issue Applications of Polymer-Based Absorbent Materials)
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11 pages, 2178 KiB  
Article
Actuator-Driven, Purge-Free Formaldehyde Gas Sensor Based on Single-Walled Carbon Nanotubes
by Shinsuke Ishihara, Mandeep K. Chahal, Jan Labuta, Takeshi Tanaka, Hiromichi Kataura, Jonathan P. Hill and Takashi Nakanishi
Nanomaterials 2025, 15(13), 962; https://doi.org/10.3390/nano15130962 - 21 Jun 2025
Viewed by 390
Abstract
Formaldehyde vapor (HCHO) is a harmful chemical substance and a potential air contaminant, with a permissible level in indoor spaces below 0.08 ppm (80 ppb). Thus, highly sensitive gas sensors for the continuous monitoring of HCHO are in demand. The electrical conductivity of [...] Read more.
Formaldehyde vapor (HCHO) is a harmful chemical substance and a potential air contaminant, with a permissible level in indoor spaces below 0.08 ppm (80 ppb). Thus, highly sensitive gas sensors for the continuous monitoring of HCHO are in demand. The electrical conductivity of semiconducting nanomaterials (e.g., single-walled carbon nanotubes (SWCNTs)) makes them sensitive to chemical substances adsorbed on their surfaces, and a variety of portable and highly sensitive chemiresistive gas sensors, including those capable of detecting HCHO, have been developed. However, when monitoring low levels of vapors (<1 ppm) found in ambient air, most chemiresistive sensors face practical issues, including false responses to interfering effects (e.g., fluctuations in room temperature and humidity), baseline drift, and the need to apply a purge gas. Here, we report an actuator-driven, purge-free chemiresistive gas sensor that is capable of reliably detecting 0.05 ppm of HCHO in the air. This sensor is composed of an HCHO→HCl converter (powdery hydroxylamine salt, HA), an HCl detector (a SWCNT-based chemiresistor), and an HCl blocker (a thin plastic plate). Upon exposure to HCHO, the HA emits HCl vapor, which diffuses onto the adjacent SWCNTs, increasing their electrical conductivity through p-doping. Meanwhile, inserting a plastic plate between HA and SWCNTs makes the conductivity of SWCNTs insensitive to HCHO. Thus, via periodic actuation (insertion and removal) of the plastic plate, HCHO can be detected reliably over a wide concentration range (0.05–15 ppm) with excellent selectivity over other volatile organic compounds. This actuator-driven system is beneficial because it does not require a purge gas for sensor recovery or baseline correction. Moreover, since the response to HCHO is synchronized with the actuation timing of the plate, even small (~0.8%) responses to 0.05 ppm of HCHO can be clearly separated from larger noise responses (>1%) caused by interfering effects and baseline drift. We believe that this work provides substantial insights into the practical implementation of nanomaterial-based chemiresistive gas sensors. Full article
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20 pages, 3913 KiB  
Article
Thermal Management Design for the Be Target of an Accelerator-Based Boron Neutron Capture Therapy System Using Numerical Simulations with Boiling Heat Transfer Models
by Bo-Jun Lu, Yuh-Ming Ferng, Tzung-Yi Lin, Cheng-Ji Lu and Wei-Lin Chen
Processes 2025, 13(6), 1929; https://doi.org/10.3390/pr13061929 - 18 Jun 2025
Viewed by 1285
Abstract
Recently, studies on accelerator-based boron neutron capture therapy (AB-BNCT) systems for cancer treatment have attracted the attention of researchers around the world. A neutron source can be obtained through the impingement of high-intensity proton beams emitted from the accelerator onto the target. This [...] Read more.
Recently, studies on accelerator-based boron neutron capture therapy (AB-BNCT) systems for cancer treatment have attracted the attention of researchers around the world. A neutron source can be obtained through the impingement of high-intensity proton beams emitted from the accelerator onto the target. This process would deposit a large amount of heat within this target. A thermal management system design is needed for AB-BNCT systems to prevent the degradation of the target due to thermal/mechanical loading. However, there are few studies that investigate this topic. In this paper, a cooling channel with a boiling heat transfer mechanism is numerically designed for thermal management in order to remove heat deposited in the Be target of the AB-BNCT system of Heron Neutron Medical Corp. A three-dimensional (3D) CFD methodology with a two-fluid model and an RPI wall boiling model is developed to investigate its availability. Two subcooled boiling experiments from previous works are adopted to validate the present CFD boiling model. This validated model can be confidently applied to assist in thermal management design for the AB-BNCT system. Based on the simulation results under the typical operating conditions of the AB-BNCT system set by Heron Neutron Medical Corp., the present coolant channel employing the boiling heat transfer mechanism can efficiently remove the heat deposited in the Be target, as well as maintain its integrity during long-term operation. In addition, compared with the channel with the single-phase convection traditionally designed for an AB-BNCT system, the boiling heat transfer mechanism can result in a lower peak temperature in the Be target and its corresponding deformation. Full article
(This article belongs to the Special Issue Numerical Simulation of Flow and Heat Transfer Processes)
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