Search Results (110)

In comparison to shallow coal seams, deep coal seams exhibit characteristics of high temperature, pressure, and in-situ stress, leading to significant differences in reservoir properties that constrain the effective development of deep coalbed methane (CBM). This study takes the Carboniferous deep 8# coal seam in the Yulin area of Ordos basin as the research subject. Based on the test results from core drilling wells, a comprehensive analysis of the characteristics and variation patterns of coal reservoir properties and a comparative analysis of the exploration and development potential of deep CBM are conducted, aiming to provide guidance for the development of deep CBM in the Ordos basin. The research results indicate that the coal seams are primarily composed of primary structure coal, with semi-bright to bright being the dominant macroscopic coal types. The maximum vitrinite reflectance (R_o,max) ranges between 1.99% and 2.24%, the organic is type III, and the high Vitrinite content provides a substantial material basis for the generation of CBM. Longitudinally, influenced by sedimentary environment and plant types, the lower part of the coal seam exhibits higher Vitrinite content and fixed carbon (FC_ad). The pore morphology is mainly characterized by wedge-shaped/parallel plate-shaped pores and open ventilation pores, with good connectivity, which is favorable for the storage and output of CBM. Micropores (<2 nm) have the highest volume proportion, showing an increasing trend with burial depth, and due to interlayer sliding and capillary condensation, the pore size (<2 nm) distribution follows an N shape. The full-scale pore heterogeneity (fractal dimension) gradually increases with increasing buried depth. Macroscopic fractures are mostly found in bright coal bands, while microscopic fractures are more developed in Vitrinite, showing a positive correlation between fracture density and Vitrinite content. The porosity and permeability conditions of reservoirs are comparable to the Daning–Jixian block, mostly constituting oversaturated gas reservoirs with a critical depth of 2400–2600 m and a high proportion of free gas, exhibiting promising development prospects, and the middle and upper coal seams are favorable intervals. In terms of resource conditions, preservation conditions, and reservoir alterability, the development potential of CBM from the Carboniferous deep 8# coal seam is comparable to the Linxing block but inferior to the Daning–Jixian block and Baijiahai uplift. Full article

Two-dimensional (2D) materials have been proposed for use in a multitude of applications, with graphene being one of the most well-known 2D materials. Despite their potential to contribute to innovative solutions, the fabrication of such devices still faces significant challenges. One of the key challenges is the fabrication at a wafer-level scale, a fundamental step for allowing reliable and reproducible fabrication of a large volume of devices with predictable properties. Overcoming this barrier will allow further integration with sensors and actuators, as well as enabling the fabrication of complex circuits based on 2D materials. This work presents the fabrication steps for a process that allows the on-wafer fabrication of active and passive radiofrequency (RF) devices enabled by graphene. Two fabrication processes are presented. In the first one, graphene is transferred to a back gate surface using critical point drying to prevent cracks in the graphene. In the second process, graphene is transferred to a flat surface planarized by ion milling, with the gate being buried beneath the graphene. The fabrication employs a damascene-like process, ensuring a flat surface that preserves the graphene lattice. RF transistors, passive RF components, and antennas designed for backscatter applications are fabricated and measured, illustrating the versatility and potential of the proposed method for 2D material-based RF devices. The integration of graphene on devices is also demonstrated in an antenna. This aimed to demonstrate that graphene can also be used as a passive device. Through this device, it is possible to measure different backscatter responses according to the applied graphene gating voltage, demonstrating the possibility of wireless sensor development. With the proposed fabrication processes, a flat graphene with good quality is achieved, leading to the fabrication of RF active devices (graphene transistors) with intrinsic f_T and f_max of 14 GHz and 80 GHz, respectively. Excellent yield and reproducibility are achieved through these methods. Furthermore, since the graphene membranes are grown by Chemical Vapor Deposition (CVD), it is expected that this process can also be applied to other 2D materials. Full article

The coal reservoir in the Ordos Mizhi block is buried at a depth of over 2000 m. This study aims to obtain the characteristics of the coal reservoir in the Mizhi block through various experimental methods and combine the gas-bearing characteristics obtained from on-site desorption experiments to analyze the gas content and logging response characteristics of the study area. On this basis, a reservoir parameter interpretation model for the study area is established. This provides a reference for the exploration and development of coal-rock gas in the Mizhi block. The research results show that: (1) The study area is characterized by the development of the No. 8 coal reservoirs of the Benxi Formation, with a thickness ranging from 2 to 11.6 m, averaging 7.2 m. The thicker coal reservoirs provide favorable conditions for the formation and storage of coal-rock gas. The lithotypes are mainly semi-bright and semi-dark. The coal maceral is dominated by the content of the vitrinite, followed by the inertinite, and the exinite is the least. The degree of metamorphism is high, making it a high-grade coal. In the proximate analysis, the moisture ranges from 0.36 to 1.09%, averaging 0.65%. The ash ranges from 2.34 to 42.17%, averaging 16.57%. The volatile ranges from 9.18 to 15.7%, averaging 11.50%. The fixed carbon ranges from 45.24 to 87.51%, averaging 71.28%. (2) According to the results of scanning electron microscopy (SEM), the coal samples in the Mizhi block have developed fractures and pores. Based on the results of the carbon dioxide adsorption experiment, the micropore adsorption capacity is 7.8728–20.3395 cm³/g, with an average of 15.2621 cm³/g. The pore volume is 0.02492–0.063 cm³/g, with an average of 0.04799 cm³/g. The specific surface area of micropores is 79.514–202.3744 m²/g, with an average of 153.5118 m²/g. The micropore parameters are of great significance for the occurrence of coal-rock gas. Based on the results of the desorption experiment, the gas content of the coal rock samples in the study area is 12.97–33.96 m³/t, with an average of 21.8229 m³/t, which is relatively high. (3) Through the correlation analysis of the logging parameters of the coal reservoir, the main logging response parameters of the reservoir are obtained. Based on the results of the logging sensitivity analysis of the coal reservoir, the interpretation model of the reservoir parameters is constructed and verified. Logging interpretation models for parameters such as industrial components, microscopic components, micropore pore parameters, and gas content are obtained. The interpretation models have interpretation effects on the reservoir parameters in the study area. Full article

The automatic flushing valve (AFV) enables automatic flushing of drip irrigation systems, improving their anti-clogging performance. This study focuses on a subsurface drip irrigation system (SDI) for alfalfa, selecting T20 and T70 AFVs (with designed flushing durations of 20 and 70 s, respectively) installed at the end of the dripline and a buried dripline without an AFV as a control. The aim of this study was to explore the variations in AFV hydraulic performance over two years of operation and the impact on the irrigation uniformity of SDI systems. The results revealed that the flushing duration (FD) and flushing water volume (FQ) of both T20 and T70 fluctuated over time, with an average coefficient of variation (CV) of 13.2%. The FD and FQ of the two types of AFVs are affected by the daily average temperature (T), and when T increases from 20.1 °C to 25.7 °C, the FD and FQ increased by an average of 22.6%. After 2 years of operation, the average relative flow rate (Dra) and irrigation uniformity (Cu) of the T20 and T70 SDI emitters were 93.7% and 96.8%. Both the Dra and Cu were significantly influenced by FD (p < 0.05). Compared with CK and T20, T70 significantly increased the Dra and Cu by 6.3% and 4.6%, respectively. The order of degree of clogging at different positions in the dripline was rear > middle > front for the CK and T20 treatments, whereas for T70, it was middle > front > rear. With the installation of the T70 AFV, the time required for the SDI system to reach moderate clogging (Dra = 50~80%) was extended from 3~7 years to 8~20 years, resulting in a 180% increase in operation time. The T70 AFV is recommended for use in the alfalfa SDI of this study. Full article

Grapevines in cold regions are prone to frost damage in winter. Due to its adverse effects on soil structure, plant damage, high operational costs, and limited mechanization feasibility, buried soil overwintering has been gradually replaced by no-burial overwintering techniques, which are now the primary focus for mitigating frost damage in wine grapes. While current research focuses on the selection of thermal insulation materials, less attention has been paid to the insulation mechanism of covering materials and covering methods. In this study, we investigated the insulation performance of two covering materials (tarpaulin and insulation blanket) combined with six height treatments (5–30 cm) to analyze the effect of insulation space volume on no-buried-soil overwintering. The results show that the thermal insulation performance of the insulation blanket is significantly better than that of the tarpaulin. The 5 cm height treatment under the tarpaulin cover and the 25 cm height treatment under the insulation blanket cover exhibited the best thermal insulation performance. Using a neural network machine learning approach, we constructed a model related to the height of the insulation material and facilitate the model’s accurate predictions, in which tarpaulin R²_branches = 0.92, R²_{20 cm} = 0.99, and R²_{40 cm} = 0.99 and insulation blanket R²_branches = 0.89, R²_{20 cm} = 0.98, and R²_{40 cm} = 0.99. The model predicted optimal insulation heights of 6 cm for the tarpaulin and 22 cm for the insulation blanket. Factors like solar radiation within the insulation space, ground radiation, airflow, and material thermal conductivity affect the optimal insulation height for different materials. This study used a neural network model to predict the optimal insulation heights for different materials, providing systematic theoretical guidance for the overwintering cultivation of wine grapes and aiding the safe development of the wine grape industry in cold regions. Full article

Deep-buried subsea tunnels are often under high water pressure conditions, and the influence of the seepage field on the tunnel cannot be ignored. Existing studies generally assume that the surrounding rock exhibits permeability isotropy; this study developed a model of deep-buried subsea tunnel that considers the permeability anisotropy of surrounding rock and investigated the effects of permeability differences between the surrounding rock and lining structure on tunnel seepage flow and plastic zone extent. By employing coordinate transformation and conformal mapping methods, the hydraulic head and the seepage discharge for each region are determined for each section of the tunnel. Based on the analytical solution of the seepage field, the seepage force is treated as a body force, and using the Mohr–Coulomb criterion, an elastoplastic analytical solution for the lining and surrounding rock under anisotropic seepage is derived. Using the Shenzhen MaWan Sea-Crossing Passage as a case study, numerical simulations are conducted using Abaqus2021, and the results are compared with the analytical solution to verify the accuracy of the study. The research shows that the permeability anisotropy of surrounding rock increases the seepage discharge, and this effect becomes more significant with increasing burial depth. If the anisotropy is 10 times greater than its previous value, the tunnel seepage volume will increase by 35.6%. When the surrounding rock permeability is sufficiently large, the impact of permeability anisotropy on the seepage discharge is relatively weak, with the seepage discharge primarily dominated by the permeability of the lining. In the tunnel stress field, due to the significant difference in stiffness between the lining and the surrounding rock, the hoop stress in the lining is much larger than that in the surrounding rock, and there is a stress discontinuity at their interface. When the permeability of the elastic zone of the surrounding rock is 100 times greater than that of the plastic zone, the plastic radius of the tunnel will increase by 2 to 3 times compared to the previous value. Reducing the permeability of the plastic zone in the surrounding rock effectively limits the seepage body force acting on the lining, thereby enhancing the stability of the lining structure and reducing the risk of damage to the tunnel. Full article

To address the problem of large deformation in deep-buried high geostress soft rock tunnels, the Yuelongmen Tunnel was selected as the research subject and adopting the methods of on-site measurements, laboratory experiments and theories, the characteristics of large deformation and its mechanism in high geostress soft rock tunnels are studied in depth, and based on the mechanism of large deformation in tunnels and the concept of active and passive synergistic control, an optimized support scheme that dynamically adapts to the deformation of the surrounding rock is put forward. The results show that (1) the deformation volume and rate of tunnel surrounding rock is large, the duration is long, and the deformation damage is serious; (2) the main factors of tunnel surrounding rock deformation damage are high geostress and stratum lithology, followed by geological structure, groundwater and support scheme; (3) the tunnel deformation hierarchical control scheme effectively controls the deformation of surrounding rock, and reduces the deformation of steel arch and the risk of sprayed concrete cracking, which verifies the applicability of this scheme to the project. It verifies its engineering applicability. The research results provide important technical reference and theoretical support for the design and construction of similar projects. Full article

In May 2008, Chaitén volcano entered an eruptive process, leading to one of the world’s largest eruptions in recent decades. The magnitude of tephra ejected by the eruption left different types of disturbances and caused diverse forms of environmental damage that were heterogeneously distributed across the surrounding area. We went to the field to assess the early vegetation responses a year after the eruption in September 2009. We evaluated the lateral-blast disturbance zone. We distributed a set of plots in three disturbed sites and one in an undisturbed site. In each of these sites, in a rectangular plot of 1000 m², we marked all standing trees, recording whether they were alive, resprouting, or dead. Additionally, in each site of 80 small plots (~4 m²), we tallied the regenerated plants, their coverage, and the log volume. We described whether the plant regeneration was occurring on a mineral or organic substrate (i.e., ash or leaf litter, respectively). In the blast zone, the eruption created a gradient of disturbance. Close to the crater, we found high levels of devastation marked by no surviving species, scarcely standing-dead trees and logs, and no tree regeneration. At the other extreme end of the disturbance zone, the trees with damaged crowns were resprouting, small plants were regrowing, and seedlings were more dispersed. The main form of regeneration was the resprouting of trunks or buried roots; additionally, a few seedlings were observed in the small plots and elsewhere in disturbed areas. The results suggest that the early stages of succession are shaped by life history traits like dispersion syndrome and regeneration strategy (i.e., vegetative), as was found after other volcanic eruptions. Likewise, the distribution of biological legacies, which is related to disturbance intensity, can cause certain species traits to thrive. For instance, in the blow-down zone, surviving species were chiefly those dispersed by the wind, while in the standing-dead zone, survivors were those dispersed by frugivorous birds. Additionally, we suggest that disturbance intensity variations are related to the elevation gradient. The varying intensities of disturbance further contribute to these ecological dynamics. The early succession in the blast zone of Chaitén volcano is influenced by the interaction between species-specific life history, altitudinal gradient, and biological legacies. Further studies are required to observe the current successional patterns that occur directly in the blast zone and compare these results with those obtained following other volcanic disturbances. Full article

This theoretical study investigates the high molecular weight (Mw) production in copolymerization of ethylene and 1-octene using heteroatom-substituted constrained geometry catalysts (CGCs). The research explores the correlation between chain termination reactions and polymer molecular weight, revealing that the Gibbs free energy barrier of the chain termination reactions is positively linked to the molecular weight. Quantitative structure–property relationship models were constructed, indicating that molecular descriptors such as atom charge, orbital energy, and buried volume significantly influence the polymer molecular weight. Full article

This study highlights the importance of quantifying groundwater resources for the Monahans and Kermit dune fields in the northern Chihuahua Desert, West Texas, USA, as potential contributors to the regional Pecos Valley Aquifer (PVA). Dunal aquifers in arid environments are often unquantified, may augment regional groundwater resources, and can be compromised by anthropogenic activity. Sedimentary architecture models of these dune fields show perched aquifers with water tables 1–10 m below the surface and southwestern groundwater flow sub-parallel to a Pleistocene/Pliocene aquitard. The deuterium and oxygen isotopic ratios for groundwater from the Kermit and Monahans dune fields show pronounced evaporative isotopic depletion and less isotopic variability than corresponding rainfall, particularly for deuterium values. The radiocarbon and δ¹³C analyses of dissolved inorganic carbon (DIC) indicate that recharge occurs through enhanced capture of recent precipitation on mostly bare active dunes where infiltration rates are >250 mm/h. In contrast, more evolved ¹⁴C values at the western margin (FM = 0.84) and at 30 m below the surface (FM = 0.76) of the dunes, similar to proximal Fm values from the PVA (0.89–0.82), may indicate dissolution of older (>100 ka) DIC from buried playa-lake sediments and less direct atmospheric influence. Mixing models for DIC source partitioning highlighted possible groundwater contamination with hydrocarbon up to 24% in the PVA and in the dunal aquifers. The perched aquifers of the Monahans and Kermit dune fields each contain water volumes >0.1 km³ and may contribute up to 18% of the total annual recharge to the PVA. Full article

Reservoir quality prediction in deeply buried reservoirs represents a complex challenge to geoscientists. In sandstones, reservoir quality is determined by the extent of compaction and cementation during burial. During compaction, porosity is lost through the rearrangement and fracture of rigid grains and the deformation of ductile grains. During cementation, porosity is predominantly lost through the growth of quartz cement, although carbonate and clay mineral growth can be locally important. The degree of quartz cementation is influenced by the surface area of quartz available for overgrowth nucleation and thermal history. Clay grain coats can significantly reduce the surface area of quartz available for overgrowth nucleation, preventing extensive cementation. Using a coupled-effect compaction and cementation model, we have forward-modelled porosity evolution of surface sediments from the modern Ravenglass Estuary under different maximum burial conditions, between 2000 and 5000 m depth, to aid the understanding of reservoir quality distribution in a marginal marine setting. Seven sand-dominated sub-depositional environments were subject to five burial models to assess porosity-preservation in sedimentary facies. Under relatively shallow burial conditions (<3000 m), modelled porosity is highest (34 to 36%) in medium to coarse-grained outer-estuary sediments due to moderate sorting and minimal fine-grained matrix material. Fine-grained tidal flat sediments (mixed flats) experience a higher degree of porosity loss due to elevated matrix volumes (20 to 31%). Sediments subjected to deep burial (>4000 m) experience a significant reduction in porosity due to extensive quartz cementation. Porosity is reduced to 1% in outer estuary sediments that lack grain-coating clays. However, in tidal flat sediments with continuous clay grain coats, porosity values of up to 30% are maintained due to quartz cement inhibition. The modelling approach powerfully emphasises the value of collecting quantitative data from modern analogue sedimentary environments to reveal how optimum reservoir quality is not always in the coarsest or cleanest clastic sediments. Full article

We developed a spatiotemporal mapping approach utilizing multiple techniques for distinguishing and mapping known reclaimed mine sites from “unreclaimed” mine sites in a historic uranium mining district along the South Texas Coastal Plains. Lidar laser scanning penetrates the vegetation canopy to expose anthropogenic modifications to the landscape. The Lidar analysis (bare earth elevation surface, slope, topographic contours, topographic textures, and overland-flow hydrography) revealed mine features. Visual interpretation of Landsat imagery and time-series analysis augmented the Lidar analysis revealing the temporal life cycle of mining. The combination of bare earth texture with time-lapse and time-series analyses revealed areas of disturbance for reclaimed mines. The spatiotemporal mapping approach proved to be most useful in identifying and characterizing the known mine pit and pile features, reclamation status, and areas of disturbance due to mining. Two mine waste volume estimation methods resulted in a 21% difference indicating that although the approach helps to map mine features and areas of mining disturbance for the purposes of mine land inventory, additional information is needed to improve the estimation of buried mine waste at reclaimed mine sites. Full article

Primarily, breast-conserving therapy is an oncological intervention, but eventually it is judged by its cosmetic result. Remaining cavities from tumor resection can promote seromas, delay healing and cause lasting discomfort. Additionally, volume loss, dislocation of nipple/areola and fat necrosis lead to (cosmetically) unfavorable results, aggravated by radiotherapy. Oncoplastic surgery can reduce these sequelae. A local flap that has rarely been used in breast cancer surgery is the Limberg rhombic flap. The tumor defect is planned as a rhombus. The sides of the rhombus are of equal length and ideally have an angle of 60° and 120°. The flap that closes the defect is planned as an extension of equal length of the short diagonal. The second incision of the flap is placed according to the defect angle of 60°, running parallel to the defect at the same length. This creates a second rhombus. The flap is transposed into the defect, and the donor area is primarily closed. It is axially perfused and safe with a 1:1 length-to-width ratio. Compared to local perforator flaps, defect closure is easily managed without microsurgical skills. In the breast, the flap can be used in volume replacement and volume displacement techniques as an all-layer flap to cover defects, or it can be deepithelialized and buried. In the axilla, it can cover full-thickness defects when skin is involved. The advantages of the rhombic flap are its safety and simplicity to add volume and close defects, thus reducing the complexity of oncoplastic surgery. Full article

Marine sand, in addition to oil and gas resources, is the second-largest marine mineral resource. The rational development and utilization of marine sand resources are conducive to the growth of the marine economy. In the process of marketing marine sand in China, local authorities are required to delineate auctioned sand mining areas after a general survey, commonly referred to as preliminary exploration. Marine sand can be categorized into surface marine sand and buried marine sand. Buried marine sand deposits are buried beneath the sea floor, making it challenging to locate them due to their thin thickness. Consequently, there exist numerous technical difficulties associated with marine sand exploration. We conducted the preliminary research work in the waters off Guangdong Province of the South China Sea, employing a reduced drilling and identifying a potentially extensive deposit of marine sand ore. In this study, various geophysical methods such as sub-bottom profile survey, single-channel seismic survey, and drilling engineering were employed in the northern offshore waters of the South China Sea. As a result, two distinct marine sand bodies were delineated within the study area. Additionally, five reflective interfaces (R₁, R₂, R₃, R₄, and R₅) were identified from top to bottom. These interfaces can be divided into five seismic sequences: A₁, B₁, C₁, D₁, and E₁, respectively. Three sets of strata were recognized: the Holocene Marine facies sediment layer (Q₄^m), the Pleistocene alluvial and pluvial facies sediment layer (Q₃^al+pl), as well as the Pleistocene Marine facies sedimentary layer (Q₃^m). In total, two placers containing marine sand have been discovered during this study. We estimated the volume of marine sand and achieved highly favorable results of the concept that we are proposing a geologic exploration approach that does not involve any previous outcropping analogue study. Full article

The present study focused on the Permian to Jurassic sequence in the Northern Highlands area, NW Jordan. The Permian to Jurassic sequence in this area is thick and deeply buried, consisting mainly of carbonate intercalated with clastic shale. This study integrated various datasets, including total organic carbon (TOC, wt%), Rock-Eval pyrolysis, visual kerogen examination, gross composition, lipid biomarkers, vitrinite reflectance (VRo%), and bottom-hole temperature measurements. The main aim was to investigate the source rock characteristics of these strata regarding organic richness, kerogen type, depositional setting, thermal maturity, and hydrocarbon generation timing. The Permian strata are poor to fair source rocks, primarily containing kerogen type (KT) III. They are immature in the AJ-1 well and over-mature in the NH-2 well. The Upper Triassic strata are poor source rocks in the NH-1 well and fair to marginally good source rocks in the NH-2 well, containing highly mature terrestrial KT III. These strata are immature to early mature in the AJ-1 well and at the peak oil window stage in the NH-2 well. The Jurassic strata are poor source rocks, dominated by KT III and KT II-III. They are immature to early mature in the AJ-1 well and have reached the oil window in the NH-2 well. Biomarker-related ratios indicate that the Upper Triassic oils and Jurassic samples are source rocks that received mainly terrestrial organic input accumulated in shallow marine environments under highly reducing conditions. These strata are composed mostly of clay-rich lithologies with evidence of deposition in hypersaline and/or stratified water columns. 1D basin models revealed that the Upper Triassic strata reached the peak oil window from the Early Cretaceous (~80 Ma) to the present day in the NH-1 well and from ~130 Ma (Early Cretaceous) to ~90 Ma (Late Cretaceous) in the NH-2 well, with the late stage of hydrocarbon generation continuing from ~90 Ma to the present time. The present-day transformation ratio equals 77% in the Upper Triassic source rocks, suggesting that these rocks have expelled substantial volumes of hydrocarbons in the NH-2 well. To achieve future successful hydrocarbon discoveries in NW Jordan, accurate seismic studies and further geochemical analyses are recommended to precisely define the migration pathways. Full article