Search Results (3,208)

Secondary hypereutectic Al-Si alloys are attractive for sustainable manufacturing, yet their application is often limited by low strength and electrical conductivity due to impurity-induced microstructural defects. Achieving a balance between mechanical and conductive performance remains a significant challenge. In this work, nickel-coated carbon nanotubes (Ni-CNTs) were introduced into secondary Al-20Si alloys to tailor the microstructure and enhance properties through interfacial engineering. Composites containing 0 to 0.4 wt.% Ni-CNTs were fabricated by conventional casting and systematically characterized. The addition of 0.1 wt.% Ni-CNTs resulted in the best combination of properties, with a tensile strength of 170.13 MPa and electrical conductivity of 27.60% IACS. These improvements stem from refined α-Al dendrites, uniform eutectic Si distribution, and strong interfacial bonding. Strengthening was achieved through grain refinement, Orowan looping, dislocation generation from thermal mismatch, and the formation of reinforcing interfacial phases such as AlNi₃C₀.₉ and Al₄SiC₄. At higher Ni-CNT contents, property degradation occurred due to agglomeration and phase coarsening. This study presents an effective and scalable strategy for achieving strength–conductivity synergy in secondary aluminum alloys via nanoscale interfacial design, offering guidance for the development of multifunctional lightweight materials. Full article

Quarry dust (QD) landfill causes environmental issues that cannot be ignored. In this study, we systematically explore its potential application as a supplementary cementitious material (SCM) in cemented paste backfill (CPB), revealing the activated mechanism of modified QD (MQD) and exploring the hydration process and workability of CPB containing QD/MQD. The experimental results show that quartz, clinochlore and amphibole components react with CaO to form reactive dicalcium silicate (C₂S) and amorphous glass phases, promoting pozzolanic reactivity in MQD. QD promotes early aluminocarbonate (M_c) formation through CaCO₃-derived CO₃²⁻ release but shifts to hemicarboaluminate (H_c) dominance at 28 d. MQD releases active Al³⁺/Si⁴⁺ due to calcination and deconstruction, significantly increasing the amount of ettringite (AFt) in the later stage. With the synergistic effect of coarse–fine particle gradation, MQD-type fresh backfill can achieve a 161 mm flow spread at 20% replacement. Even if this replacement rate reaches 50%, a strength of 19.87 MPa can still be maintained for 28 days. The good workability and low carbon footprint of MQD-type backfill provide theoretical support for—and technical paths toward—QD recycling and the development of low-carbon building materials. Full article

Understanding the limitations of cold-formed aluminum alloys in practice applications is essential, particularly due to the risk of substructural changes and a reduction in strength when exposed to elevated temperatures. In this study, the thermal stability of the ultra-fine-grained (UFG) structure formed by equal channel angular pressing (ECAP) at room temperature and the mechanical properties of the AlSi7MgCu0.5 alloy were investigated. Prior to ECAP, the plasticity of the as-cast alloy was enhanced by a heat treatment consisting of solution annealing, quenching, and artificial aging to achieve an overaged state. Four repetitive passes via ECAP route A resulted in the homogenization of eutectic Si particles within the α-solid solution, the formation of ultra-fine grains and/or subgrains with high dislocation density, and a significant improvement in alloy strength due to strain hardening. The main objective of this work was to assess the microstructural and mechanical stability of the alloy after post-ECAP annealing in the temperature range of 373–573 K. The UFG microstructure was found to be thermally stable up to 523 K, above which notable grain and/or subgrain coarsening occurred as a result of discontinuous recrystallization of the solid solution. Mechanical properties remained stable up to 423 K; above this temperature, a considerable decrease in strength and a simultaneous increase in ductility were observed. Synchrotron radiation X-ray diffraction (XRD) was employed to analyze the phase composition and crystallographic characteristics, while transmission electron microscopy (TEM) was used to investigate substructural evolution. Mechanical properties were evaluated through tensile testing, impact toughness testing, and hardness measurements. Full article

This article deals with the effect of Kr¹⁵⁺ ion irradiation on the structure and properties of partially stabilized zirconium dioxide (ZrO₂ + 3 mol. % Y₂O₃) ceramics. Ion irradiation is used to simulate radiation damage typical of operating conditions in nuclear reactors and space technology. It is shown that with an increase in the irradiation fluence, point defects are formed, dislocations accumulate, and the crystal lattice parameters change. At high fluences (>10¹³ ions/cm²), a phase transition of the monoclinic (m-ZrO₂) phase to the tetragonal (t-ZrO₂) and cubic (c-ZrO₂) modifications is observed, which is accompanied by a decrease in the crystallite size and an increase in internal stresses. Changes in the mechanical properties of the material were also observed: at moderate irradiation fluences, strengthening is observed due to the formation of dislocation structures, whereas at high fluences (>10¹⁴ ions/cm²), a decrease in strength and a potential amorphization of the structure begins. The change in the phase composition was confirmed by X-ray phase analysis and Raman spectroscopy. The results obtained allow a deeper understanding of the mechanisms of radiation-induced phase transformations in stabilized ZrO₂ and can be used in the development of ceramic materials with increased radiation resistance. Full article

This study demonstrates the successful fabrication of high-performance reaction-bonded silicon carbide (RBSC) ceramics through an optimized liquid silicon infiltration (LSI) process employing multi-modal SiC particle gradation and nano-carbon black (0.6 µm) additives. By engineering porous preforms with hierarchical SiC distributions and tailored carbon sources, the resulting ceramics achieved a compressive strength of 2393 MPa and a flexural strength of 380 MPa, surpassing conventional RBSC systems. Microstructural analyses revealed homogeneous β-SiC formation and crack deflection mechanisms as key contributors to mechanical enhancement. Ultrafine SiC particles (0.5–2 µm) refined pore architectures and mediated capillary dynamics during infiltration, enabling nanoscale dispersion of residual silicon phases and minimizing interfacial defects. Compared to coarse-grained counterparts, the ultrafine SiC system exhibited a 23% increase in compressive strength, attributed to reduced sintering defects and enhanced load transfer efficiency. This work establishes a scalable strategy for designing RBSC ceramics for extreme mechanical environments, bridging material innovation with applications in high-stress structural components. Full article

Zwitterionic hydrogels have emerged as eco-friendly anti-fouling materials owing to their superior hydration-mediated resistance to biofouling. Nevertheless, their practical utility remains constrained by intrinsically poor mechanical robustness. Herein, this study proposes a novel strategy to develop novel tough zwitterionic hydrogels by freezing the gels’ polymer network. As a proof of concept, a zwitterionic hydrogel was synthesized via copolymerization of hydrophobic monomer phenyl methacrylate (PMA) and hydrophilic cationic monomer N-(3-dimethylaminopropyl) methacrylamide (DMAPMA), followed by post-oxidation to yield a zwitterionic structure. At service temperature, the rigid and hydrophobic PMA segments remain frozen, while the hydrophilic zwitterionic units maintain substantial water content by osmotic pressure. Synergistically, the zwitterionic hydrogel achieves robust toughness and adhesiveness, with high rigidity (66 MPa), strength (4.78 MPa), and toughness (2.53 MJ/m³). Moreover, the hydrogel exhibits a distinct temperature-dependent behavior by manifesting softer and more stretchable behavior after heating, since the thawing of the gel network at high temperatures increases segmental mobility. Therefore, it achieved satisfactory adhesiveness to substrates (80 kPa). Additionally, the hydrogel demonstrated remarkable anti-fouling performance, effectively suppressing biofilm formation and larval attachment. In summary, this work opens up promising prospects for the development of zwitterionic hydrogels with high application potential. Full article

This study examined the comprehensive properties of Mg-Zn-Nd-Zr alloys in order to achieve both high strength and thermal conductivity simultaneously. The impact of rolling on the microstructure, mechanical properties, and thermal conductivity was analyzed for Mg-5Zn-xNd-0.4Zr alloys (x = 1, 2). The results indicate that the addition of Nd promotes the formation of the W phase (Mg₃Zn₃RE₂), which contributes to grain boundary strengthening and enhances the overall strength. Moreover, dynamic precipitation during the rolling process leads to the formation of nanoscale MgZn₂ and Zn₂Zr phases, significantly improving both the strength and thermal conductivity. After rolling, both the Mg-5Zn-1Nd-0.4Zr (ZNK510) and Mg-5Zn-2Nd-0.4Zr (ZNK520) alloys exhibited a notable enhancement in thermal conductivity, with ZNK520 demonstrating superior properties due to its higher Nd content. This study highlights that optimizing alloy composition and phase evolution through rolling can markedly enhance both the mechanical and thermal properties, offering a promising strategy for the development of high-performance magnesium alloys. Full article

In this work, the W element, with a larger atomic radius compared to Co, Fe, and Ni, was added to modify the microstructure and enhance the yield strength of CoFeNi medium entropy alloy (MEA). A detailed study was conducted to clarify the effects of W additions and annealing temperatures on the microstructure evolution and mechanical properties of CoFeNiW_x (x = 0, 0.1, and 0.3) MEAs. CoFeNiW_0.1 retained a single FCC structure without the formation of precipitates in the FCC phase, indicating that W, with a larger atomic radius, can completely dissolve in CoFeNiW_0.1. For CoFeNiW_0.3 MEA, coarse particles with an average diameter of ~2 μm appeared after homogenizing. Nevertheless, when the alloy was annealed at 800 °C and 900 °C, fine particles formed, with the average diameters of approximately 144 nm and 225 nm, respectively. After annealing at 800 °C, the CoFeNiW_0.3 with a partially recrystallized microstructure exhibited better comprehensive mechanical properties. Full article

This study involved the fabrication of poly (vinyl alcohol) (PVA) nanocomposite films using the solution-casting process, which incorporated strontium-coated silver oxide (Sr-Ag₂O) nanoparticles generated by a plant-extract assisted method. Various characterization techniques, such as XRD, SEM, TEM, UV, and FTIR, showed the formation and uniform distribution of Sr-Ag₂O nanoparticles in the PVA film, which are biocompatible nanocomposite films. The presence of hydroxyl groups leads to appreciable mixing and interaction between the Sr-Ag₂O nanoparticles and the PVA polymer. Mechanical and thermal results suggest enhanced tensile strength and increased thermal stability. In addition, the sample of PVA/Sr-Ag₂O (1.94/0.06 wt. ratio) nanocomposite film showed decreased hydrophilicity, lower hemolysis, non-toxicity, and appreciable cell migration activity, with nearly 19.95% cell migration compared to the standard drug, and the presence of Sr-Ag₂O nanoparticles favored the adhesion and spreading of cells, which triggered the reduction in the gaps. These research findings suggest that PVA/Sr-Ag₂O nanocomposite films with good mechanical, antimicrobial, non-toxic, and biocompatible properties could be applied in biological wound-healing applications. Full article

This research investigates resonator width optimization for simultaneously enhancing electrical performance and mechanical reliability in wideband RF MEMS filters through systematic evaluation of three configurations: 0% (L1), 60% (L2), and 100% (L3) matching ratios between cap and bottom wafers using Au-Au thermocompression bonding. The study demonstrates that resonator width alignment significantly influences both electromagnetic field coupling and bonding interface integrity. The L3 configuration with complete width matching achieved optimal RF performance, demonstrating 3.34 dB insertion loss across 4.5 GHz bandwidth (25% fractional bandwidth), outperforming L2 (3.56 dB) and L1 (3.10 dB), while providing enhanced electromagnetic wave coupling and minimized contact resistance. Mechanical reliability testing revealed superior bonding strength for the L3 configuration, withstanding up to 7.14 Kgf in shear pull tests, significantly exceeding L1 (4.22 Kgf) and L2 (2.24 Kgf). SEM analysis confirmed uniform bonding interfaces with minimal void formation (~180 nm), while Q-factor measurements showed L3 achieved optimal loaded Q-factor (Q_L = 3.31) suitable for wideband operation. Comprehensive environmental testing, including thermal cycling (−50 °C to +145 °C) and humidity exposure per MIL-STD-810E standards, validated long-term stability across all configurations. This investigation establishes that complete resonator width matching between cap and bottom wafers optimizes both electromagnetic performance and mechanical bonding reliability, providing a validated framework for developing high-performance, reliable RF MEMS devices for next-generation communication, radar, and sensing applications. Full article

Construction wood has a high economic value, and its construction waste also has multiple consumption values. Natural wood has many advantages, such as thermal, environmental, and esthetic properties; however, wood sourced from artificial fast-growing forests is found to be deficient in mechanical strength. This shortcoming makes it less competitive in certain applications, leading many markets to remain dominated by non-renewable materials. To address this issue, various modification methods have been explored, with a focus on enhancing the plasticity and strength of wood. Studies have shown that hydrogen bonds in the internal structure of wood have a significant impact on its operational performance. Whether it is organic modification, inorganic modification, or a combination thereof, these methods will lead to a change in the shape of the hydrogen bond network between the components of the wood or will affect the process of its breaking and recombination, while increasing the formation of hydrogen bonds and related molecular synergistic effects and improving the overall operational performance of the wood. These modification methods not only increase productivity and meet the needs of efficient use and sustainable environmental protection but also elevate the wood industry to a higher level of technological advancement. This paper reviews the role of hydrogen bonding in wood modification, summarizes the mechanisms by which organic, inorganic, and composite modification methods regulate hydrogen bond networks, discusses their impacts on wood mechanical properties, dimensional stability, and environmental sustainability, and provides an important resource for future research and development. Full article

The anode assembly, as a key component in the electrolytic aluminum process, is composed of steel claws and aluminum guide rods. The connection quality between the steel claws and guide rods directly affects the current conduction efficiency, energy consumption, and operational stability of equipment. Achieving high-quality joining between the aluminum alloy and steel has become a key process in the preparation of the anode assembly. To join the guide rods and steel claws, this work uses Cold Metal Transfer (CMT) technology to clad aluminum on the steel surface and employs machine vision to detect surface forming defects in the cladding layer. The influence of different currents on the interfacial microstructure and mechanical properties of aluminum alloy cladding on the steel surface was investigated. The results show that increasing the cladding current leads to an increase in the width of the fusion line and grain size and the formation of layered Fe₂Al₅ intermetallic compounds (IMCs) at the interface. As the current increases from 90 A to 110 A, the thickness of the Al-Fe IMC layer increases from 1.46 μm to 2.06 μm. When the current reaches 110 A, the thickness of the interfacial brittle phase is the largest, at 2 ± 0.5 μm. The interfacial region where aluminum and steel are fused has the highest hardness, and the tensile strength first increases and then decreases with the current. The highest tensile strength is 120.45 MPa at 100 A. All the fracture surfaces exhibit a brittle fracture. Full article

This study evaluated the bone regeneration effect and mechanical properties of “Sticky bone”, a mixture of platelet-rich fibrin (PRF) and synthetic bone grafts (SBGs), in the repair of large femoral bone defects in rabbits. Eighteen New Zealand white rabbits were included and randomly divided into a Sticky bone group and an SBG alone group. Bone graft samples were collected and analyzed at 4, 8, and 12 weeks after surgery. Micro- computed tomography (CT) analysis showed that the amount of the Sticky bone group in the grayscale ranges of 255–140 (highly mineralized tissue or unabsorbed bone powder) and 140–90 (representing new cancellous bone) was higher than that of the SBG group at each time point and decreased with the number of weeks. The compression strength test showed that the average compression strength of the Sticky bone group reached 5.17 MPa at the 12th week, which was 1.62 times that of the intact bone (3.19 MPa) and was significantly better than that of the SBG group (about 4.12 MPa). This study also confirmed for the first time that the use of a new polyethylene terephthalate (PET) blood collection tube to prepare PRF can stably release key growth factors such as platelet-derived growth factor-BB (PDGF-BB) and vascular endothelial growth factor (VEGF), which are conducive to early bone vascularization and cell proliferation. In summary, Sticky bone has the potential to promote bone formation, enhance tissue integration and mechanical stability, and can be used as an effective alternative material for repairing large-scale bone defects in clinical practice in the future. Full article

The increasing demand for sustainable construction materials has driven research into low-carbon geopolymers that mitigate both cement-related emissions and plastic and glass waste accumulation. This study explores the development of geopolymer concrete incorporating fly ash (FA), slag (S), and FA + S blends, with 10% recycled crushed glass (RCG) and recycled plastic waste (RPW) as partial coarse aggregate replacements. Compressive strength testing revealed that FA + S-based geopolymers (25FA + S) with 100% ordinary Portland cement (OPC) replacement achieved a 7-day strength of 24.6 MPa, representing a 98% improvement over control specimens. Slag-based geopolymers demonstrated water absorption properties comparable to OPC, indicating enhanced durability. Microstructural analyses using SEM, XRD, and EDS confirmed the formation of a dense aluminosilicate matrix, with slag promoting FA reactivity and reinforcing interfacial transition zone (ITZ). These effects contributed to superior mechanical performance and water resistance. Despite minor shrinkage-induced cracking, full OPC replacement with S or FA + S geopolymers outperformed control specimens, consistently exceeding the target strength of 15 MPa required for low-impact, single-story housing applications within seven days. These findings underscore the potential of geopolymer systems for rapid and sustainable construction, offering an effective solution for reducing carbon footprints and repurposing industrial waste. Full article

The dramatic increase in urban construction waste poses severe environmental challenges. Utilizing waste concrete to produce recycled aggregates (RA) for manufacturing recycled concrete (RC) represents an effective strategy for resource utilization. However, inherent defects in RA, such as high porosity, microcracks, and adherent old mortar layers, lead to significant performance degradation of the resulting RC, limiting its widespread application. Traditional methods for enhancing RA often suffer from limitations, including high energy consumption, increased costs, or the introduction of new pollutants. MICP offers an innovative approach for enhancing RC performance. This technique employs the metabolic activity of specific microorganisms to induce the formation of a three-dimensionally interwoven calcium carbonate gel network within the pores and on the surface of RA. This gel network can improve the inherent defects of RA, thereby enhancing the performance of RC. Compared to conventional techniques, this approach demonstrates significant environmental benefits and enhances concrete compressive strength by 5–30%. Furthermore, embedding mineralizing microbial spores within the pores of RA enables the production of self-healing RC. This review systematically explores recent research advances in microbial mineral gel network for improving RC performance. It begins by delineating the fundamental mechanisms underlying microbial mineralization, detailing the key biochemical reactions driving the formation of calcium carbonate (CaCO₃) gel, and introducing the common types of microorganisms involved. Subsequently, it critically discusses the key environmental factors influencing the effectiveness of MICP treatment on RA and strategies for their optimization. The analysis focuses on the enhancement of critical mechanical properties of RC achieved through MICP treatment, elucidating the underlying strengthening mechanisms at the microscale. Furthermore, the review synthesizes findings on the self-healing efficiency of MICP-based RC, including such metrics as crack width healing ratio, permeability recovery, and restoration of mechanical properties. Key factors influencing self-healing effectiveness are also discussed. Finally, building upon the current research landscape, the review provides perspectives on future research directions for advancing microbial mineralization gel techniques to enhance RC performance, offering a theoretical reference for translating this technology into practical engineering applications. Full article