Search Results (364)

Bulk metallic glasses (BMGs), classified as metastable materials, necessitate melt quenching at critical cooling rates higher than 10² K/s to kinetically bypass crystalline phase formation during solidification. Owing to this rapid quenching, the microstructure of BMGs can be regarded as melt quenched. This study examines how their melt state governs the thermal stability, structural characteristics, and plasticity behavior of Zr₅₀Cu₄₀Al₁₀ BMG. Rod samples were prepared via injection casting at controlled melt temperatures and suction casting. Experimental observations demonstrated a positive correlation between elevated melt temperatures and enhanced glass forming ability (GFA) along with improved thermal stability (T-A) in BMGs during processing. Structural analyses confirmed the glassy nature of the prepared BMGs with different melt states and revealed their temperature-dependent atomic-scale heterogeneity: the samples quenched at low melt temperatures exhibited significant Cu-rich clustering as determined via energy-dispersive X-ray spectroscopy (EDS) mapping, and those at high melt temperatures formed homogeneous structures. This structure heterogeneity was directly correlated with good plastic deformation behavior, i.e., the rod sample prepared at the lowest melt temperature achieved 9.7% plastic strain. The transition is attributed to liquid-liquid phase transition (LLPT): below the LLPT threshold, metastable Cu-rich clusters persist in the melt and are retained upon quenching, creating structural defects that facilitate shear band multiplication. These findings highlight melt temperature as a crucial factor in tailoring the structure characteristic and mechanical behavior of Zr₅₀Cu₄₀Al₁₀ BMGs. Full article

Anion exchange membrane fuel cells (AEMFCs) represent a promising class of clean energy devices, with their performance being critically dependent on the efficiency of the cathode oxygen reduction reaction (ORR) catalyst. Manganese-cobalt spinel (Mn_1.5Co_1.5O₄, MCS) has been demonstrated to be a highly active ORR catalyst. Herein, we report a strategy of incorporating Cu (MCCS) and Fe (MCFS) into MCS to form ternary spinel oxides for tuning ORR activity. Among them, MCS exhibits the best ORR performance, with a half-wave potential (E_1/2) of 0.736 V vs. RHE in 0.1 M KOH and a peak power density (PPD) of 248.3 mW·cm⁻² for the fuel cell test. In contrast, MCCS and MCFS show divergent behaviors in a rotating disk-ring electrode (RRDE) and fuel cell tests. X-ray diffraction (XRD) analyses and X-ray photoelectron spectroscopy (XPS) analyses reveal that the introduction of Cu²⁺ and Fe³⁺ induces a phase transformation in the spinel structure, leading to a reduction in oxygen vacancies and an increase in the valence state of Mn, thereby degrading catalytic activity. However, the incorporation of these elements also modulates the hydration capability of the catalysts, which is critical for the ion and charge transfer in the fuel cell environment and has been validated in the distribution of relaxation time (DRT) analysis of the fuel cell test. This study provides a valuable strategy for designing and synthesizing low-cost, highly efficient, and stable ternary spinel electrocatalysts for AEMFC applications, and bridges the gap between RRDE evaluation and fuel cell testing through DRT analysis. Full article

In this study, a carbon felt (CF)-based ternary composite anode was developed through the decoration of nickel cobaltite (NiCo₂O₄) nano-needles and subsequent in situ electropolymerization of polypyrrole (PPy). The structural and electrochemical properties of the modified electrodes were systematically characterized. The CF/NiCo₂O₄/PPy anode demonstrated significantly enhanced bioelectrochemical activity, achieving a peak current density of 96.0 A/m² and a steady-state current density of 28.9 A/m², which were 4.85 and 5.90 times higher than those of bare carbon felt, respectively. Geobacteriaceae is a type of electrogenic bacteria. It was hardly detected on the bare CF substrate; however, in the ternary CF/NiCo2O4/PPy electrode, the relative abundance of Geobacteriaceae significantly increased to 43%. Moreover, the composite electrode exhibited superior charge storage performance, with a total charge (Q_t) of 32,509.0 C/m² and a stored charge (Q_s) of 3609.0 C/m² measured under a 1000 s charging/discharging period. The MFC configured with the CF/NiCo₂O₄/PPy anode reached a maximum power density of 1901.25 mW/m² at an external resistance of 200 Ω, nearly six times that of the unmodified CF-based MFC. These improvements are attributed to the synergistic interaction between the pseudocapacitive NiCo₂O₄ and conductive PPy, which collectively facilitate electron transfer, promote microbial colonization, and enhance interfacial redox kinetics. This work provides an effective strategy for designing high-performance MFC electrodes with dual functionality in energy storage and power delivery. Full article

Accurate thermal modeling of Terminal Test Masses (TTMs) is crucial for optimizing the sensitivity of gravitational wave interferometers like Virgo. In fact, in such gravitational wave detectors even minimal laser power absorption can induce performance-limiting thermal effects. This paper presents a detailed investigation into the steady-state thermal behavior of TTMs. In particular, future scenarios of increased intracavity laser beam power and optical coating absorption are considered. We develop and compare two numerical models: a comprehensive model incorporating volumetric heat absorption in both the multilayer coating and the bulk substrate, and a simplified reduced model where the coating’s thermal impact is represented as an effective surface boundary condition on the substrate. Our simulations were focused on a ternary coating design, which is a candidate for use in next-generation detectors. Results reveal that higher coating absorption localizes peak temperatures near the coating–vacuum interface. Importantly, the comparative analysis demonstrates that temperature predictions from the reduced model differ from the detailed model by only milli-Kelvins, a discrepancy often within the experimental uncertainties of the system’s thermo-physical parameters. This finding suggests that computationally efficient reduced models can provide sufficiently accurate results for thermal management and first-order distortion analyses. Moreover, the critical role of accurately characterizing the total power absorbed by the coating is emphasized. Full article

The subset-sum problem, a foundational NP-hard problem in theoretical computer science, serves as a critical building block for cryptographic constructions. This work introduces novel classical and quantum heuristic algorithms for the random subset-sum problem at density $d=1$, where exactly one solution is expected. Classically, we propose the first algorithm based on a ternary tree representation structure, inspired by recent advances in lattice-based cryptanalysis. Through numerical optimization, our method achieves a time complexity of $\widetilde{𝒪}\left(2^{0.2400n}\right)$ and space complexity of $\widetilde{𝒪}\left(2^{0.2221n}\right)$, improving upon the previous best classical heuristic result of $\widetilde{𝒪}\left(2^{0.2830n}\right)$. In the quantum setting, we develop a corresponding algorithm by integrating the classical ternary representation technique with a quantum walk search framework. The optimized quantum algorithm attains a time and space complexity of $\widetilde{𝒪}\left(2^{0.1843n}\right)$, surpassing the prior state-of-the-art quantum heuristic of $\widetilde{𝒪}\left(2^{0.2182n}\right)$. Furthermore, we apply our algorithms to information set decoding in code-based cryptography. For half-distance decoding, our classical algorithm improves the time complexity to $\widetilde{𝒪}\left(2^{0.0453n}\right)$, surpassing the previous best of $\widetilde{𝒪}\left(2^{0.0465n}\right)$. For full-distance decoding, we achieve a quantum complexity of $\widetilde{𝒪}\left(2^{0.058326n}\right)$, advancing beyond the prior best quantum result of $\widetilde{𝒪}\left(2^{0.058696n}\right)$. These findings demonstrate the broad applicability and efficiency of our ternary representation technique across both classical and quantum computational models. Full article

We present a freeze-out approach for describing the formation of heavy elements in expanding nuclear matter. Applying concepts used in modeling heavy-ion collisions or ternary fission, we determine the abundances of heavy elements taking into account in-medium effects such as Pauli blocking and the Mott effect, which describes the dissolution of nuclei at high densities of nuclear matter. With this approach, we search for a universal initial distribution in a quasi-equilibrium state from which the coarse-grained pattern of the solar abundances of heavy elements freezes out and evolves by radioactive decay of the excited states. The universal initial state is characterized by the Lagrange parameters, which are related to temperature and chemical potentials of neutrons and protons. We show that such a state exists and determine a temperature of 5.266 MeV, a neutron chemical potential of 940.317 MeV and a proton chemical potential of 845.069 MeV, with a baryon number density of 0.013 fm⁻³ and a proton fraction of $0.13$. Heavy neutron-rich nuclei such as the hypothetical double-magic nucleus ³⁵⁸Sn appear in the initial distribution and contribute to the observed abundances after fission. We discuss astrophysical scenarios for the realization of this universal initial distribution for heavy-element nucleosynthesis, including supernova explosions, neutron star mergers and the inhomogeneous Big Bang. The latter scenario may be of interest in the light of early massive objects observed with the James Webb Space Telescope and opens new perspectives on the universality of the observed r-process patterns and the lack of observations of population III stars. Full article

Metal–organic compounds, and especially those containing well-known antioxidant natural flavonoids (Chrysin, Chr) and metal ions (Ti(IV)), attract keen interest for their potential biological activity nutritionally and pharmacologically. To that end, chemical reactivity profiling in binary/ternary systems was investigated synthetically, revealing unique structural correlations between mononuclear (Ti(IV)-Chr) and tetranuclear assemblies (Ti(IV)-Chr-phen). Chemical profiling involved physicochemical characterization through elemental analysis, FT-IR, UV–Visible, 1D-2D NMR, ESI-MS spectrometry, solid-state luminescence, and X-ray crystallography, with theoretical work on intra(inter)molecular interactions of 3D assemblies pursued through Hirshfeld analysis and BVS calculations. An in-depth study of their chemical reactivity shed light onto specific structural properties in the solid-state and in solution, while concurrently exemplifying quenching behavior due to their distinct flavonoid pattern. In the framework of biological activity, the materials were investigated for their antibacterial properties toward Gram(−)-E. coli and Gram(+)-S. aureus, exhibiting an enhanced effect compared to the free ligand and metal ion. Further investigation of BSA denaturation revealed strong anti-inflammatory properties compared to Chr and Diclofenac, an anti-inflammatory agent. Finally, in vitro studies using physiological and cancer cell lines, including breast (MCF10A, MCF7) and lung tissues (MRC-5, A549), formulated a structure–tissue relation reactivity profile, thus justifying their potential as future metallodrugs. Full article

Protective coatings are essential for extending the service life of components exposed to harsh conditions, such as pipes used in industrial systems, where wear and corrosion remain constant challenges. This study explores the development of a nano-sized TiO₂-reinforced electroless nickel-based ternary (Ni-W-P) alloy and composite coating on API X60 steel, a high-strength carbon steel pipe grade widely used in oil and gas pipelines, using an alkaline hypophosphite-reduced bath. The surface morphology, microstructure, elemental composition, structure, phase evolution, adhesion, and roughness of the coatings were analyzed using optical microscopy, FESEM, EDS, XRD, AFM, cross-cut tape test, and 3D profilometry. The tribological performance was evaluated via Vickers microhardness measurements and reciprocating wear tests conducted under dry conditions at a 5 N load. The TiO₂ nanoparticle-reinforced composite coating achieved a consistent thickness of approximately 24 µm and exhibited enhanced microhardness and reduced coefficient of friction (COF), although the addition of nanoparticles increased surface roughness (S_a). Annealing the electroless composites at 400 °C led to a significant improvement in their tribological properties, primarily owing to the grain growth, phase transformation, and Ni₃P crystallization. XRD analysis revealed phase evolution from an amorphous state to crystalline Ni₃P upon annealing. Both the alloy and composite coatings exhibited excellent adhesion performances. The combined effect of TiO₂ nanoparticles, tungsten, and Ni₃P crystallization greatly improved the wear resistance, with abrasive and adhesive wear identified as the dominant mechanisms, making these coatings well suited for high-wear applications. Full article

This study presents the development of Cu-doped NiMo/TiO₂ photoelectrocatalysts for simultaneous green hydrogen production and pharmaceutical pollutant removal under simulated solar irradiation. The catalysts were synthesized via wet impregnation (15 wt.% total metal loading with 0.6 wt.% Cu) and thermally treated at 400 °C and 900 °C to investigate structural transformations and catalytic performance. Comprehensive characterization (XRD, BET, SEM, XPS) revealed phase transitions, enhanced crystallinity, and redistribution of redox states upon Cu incorporation, particularly the formation of NiTiO₃ and an increase in oxygen vacancies. Crystallite sizes for anatase, rutile, and brookite ranged from 21 to 47 nm at NiMoCu400, while NiMoCu900 exhibited only the rutile phase with 55 nm crystallites. BET analysis showed a surface area of 44.4 m²·g⁻¹ for NiMoCu400, and electrochemical measurements confirmed its higher electrochemically active surface area (ECSA, 2.4 cm²), indicating enhanced surface accessibility. In contrast, NiMoCu900 exhibited a much lower BET surface area (1.4 m²·g⁻¹) and ECSA (1.4 cm²), consistent with its inferior photoelectrocatalytic performance. Compared to previously reported binary NiMo/TiO₂ systems, the ternary NiMoCu/TiO₂ catalysts demonstrated significantly improved hydrogen production activity and more efficient photoelectrochemical degradation of paracetamol. Specifically, NiMoCu400 showed an anodic peak current of 0.24 mA·cm⁻² for paracetamol oxidation, representing a 60% increase over NiMo400 and a cathodic current of −0.46 mA·cm⁻² at −0.1 V vs. RHE under illumination, nearly six times higher than the undoped counterpart (–0.08 mA·cm⁻²). Mott–Schottky analysis further revealed that NiMoCu400 retained n-type behavior, while NiMoCu900 exhibited an unusual inversion to p-type, likely due to Cu migration and rutile-phase-induced realignment of donor states. Despite its higher photosensitivity, NiMoCu900 showed negligible photocurrent, confirming that structural preservation and surface redox activity are critical for photoelectrochemical performance. This work provides mechanistic insight into Cu-mediated photoelectrocatalysis and identifies NiMoCu/TiO₂ as a promising bifunctional platform for integrated solar-driven water treatment and sustainable hydrogen production. Full article

In the present study, a polarization rotation switch (PRS)-based all-optical ternary inverter circuit and ternary clocked SR flip-flop (TCSR) are proposed and discussed. The present scheme is designed by the polarization rotation of light in a waveguide coupled with a micro-ring resonator (MRR). The proposed scheme uses linear polarization-encoded light. Here, the ternary (radix = 3) logical states are expressed by the different polarized light. PRS-MRR explores the polarization-encoded methodology, which depends on polarization conversion from one state to another. All-optical ultrafast switching technology is employed to design the ternary NAND gate. We develop the ternary clocked SR flip-flop by employing the NAND gate; it produces a greater number of possible outputs as compared to the binary logic clocked SR flip-flop circuit. The performance of the proposed design is measured by the Jones parameter and Stokes parameter. The results of the polarization rotation-based ternary inverter and clocked SR flip-flop are realized using a pump–probe structure in the MRR. The numerical simulation results are confirmed by the well-known Jones vector (azimuth angle and ellipticity angle) and Stokes parameter (S₁, S₂, S₃) using Ansys Lumerical Interconnect simulation software. Full article

Three-dimensional (3D) concrete printing (3DCP) has gained significant attention over the last decade due to its many claimed benefits. The absence of effective real-time quality control mechanisms, however, can lead to inconsistencies in extrusion, compromising the integrity of 3D-printed structures. Although the importance of quality control in 3DCP is broadly acknowledged, research lacks systematic methods. This research investigates the feasibility of using ultrasonic pulse velocity (UPV) as a practical, in situ, real-time monitoring tool for 3DCP. Two different groups of binders were investigated: limestone calcined clay (LC³) and zeolite-based mixes in binary and ternary blends. Filaments of 200 mm were extruded every 5 min, and UPV, pocket hand vane, flow table, and viscometer tests were performed to measure pulse velocity, shear strength, relative deformation, yield stress, and plastic viscosity, respectively, in the fresh state. Once the filaments presented printing defects (e.g., filament tearing, filament width reduction), the tests were concluded, and the open time was recorded. Isothermal calorimetry tests were conducted to obtain the initial heat release and reactivity of the supplementary cementitious materials (SCMs). Results showed a strong correlation (R² = 0.93) between UPV and initial heat release, indicating that early hydration (ettringite formation) influenced UPV and determined printability across different mixes. No correlation was observed between the other tests and hydration kinetics. UPV demonstrated potential as a real-time monitoring tool, provided the mix-specific pulse velocity is established beforehand. Further research is needed to evaluate UPV performance during active printing when there is an active flow through the printer. Full article

The objective of the current research is to investigate the role of Neusilin US2 as a porous carrier for improving the drug loading and stability of Ezetimibe (EZB) by hot melt extrusion (HME). The amorphous solid dispersions (ASDs) were developed from 10–40% of drug loading using Kollidon VA 64 (Copovidone) as a polymer matrix and Neusilin US2 as a porous carrier. The solid-state characterization of EZB was studied using differential scanning calorimetry (DSC), powder X-ray diffraction (PXRD), and Fourier transform infrared spectroscopy (FTIR). The formulation blends were characterized for flow properties, and CTC (compressibility, tabletability, compactibility) profile. The in-vitro drug release profiles were studied in 0.1 N HCl (pH 1.2). The incorporation of Neusilin US2 has facilitated the development of ASDs up to 40% of drug loading. The CTC profile has demonstrated excellent tabletability for the ternary (EZB, copovidone and Neusilin) dispersions over binary dispersion (EZB and copovidone) formulations. The tablet formulations with binary (20%) and ternary (30% and 40%) dispersions have demonstrated complete dissolution of the drug in 30 min in 0.1 N HCl (pH 1.2). The incorporation of copovidone has prevented the recrystallization of the drug in the solution state. Upon storage of formulations at accelerated conditions, the stability of ternary dispersion tablets was preserved attributing to the entrapment of the drug within Neusilin pores thereby inhibiting molecular mobility. Based on the observations, the current research concludes that it is feasible to incorporate Neusilin US2 to improve the drug loading and stability of ASD systems. Full article

Eskebornite (CuFeSe₂), a member of the I–III–VI₂ ternary semiconductor family, was explored in this study as a potential thermoelectric material, offering new insights into its synthesis, structural characteristics, and transport behavior. Structurally analogous to chalcopyrite (CuFeS₂)—an extensively studied antiferromagnetic semiconductor—eskebornite remains relatively underexplored, particularly regarding its solid-state synthesis and thermoelectric performance. To address this gap, pure eskebornite was synthesized via mechanical alloying followed by hot pressing, a method that enables the fine control of its phase composition and microstructural features. The synthesized undoped CuFeSe₂ exhibited p-type nondegenerate semiconducting behavior, with electrical conductivity increasing monotonically over the temperature range of 323–623 K, indicative of thermally activated carrier transport. Simultaneously, a decreasing trend in thermal conductivity with temperature was observed, likely resulting from intensified phonon scattering, which serves to suppress heat transport and enhance the thermoelectric efficiency by maintaining a thermal gradient across the material. A peak in the Seebeck coefficient occurred between 473 and 523 K, suggesting the onset of intrinsic carrier excitation and a transition in dominant carrier transport mechanisms. The material exhibited a maximum power factor of 1.55 μWm⁻¹K⁻², while the dimensionless thermoelectric figure of merit (ZT) reached a peak value of 0.37 × 10⁻³ at 523 K. Although the ZT remains low, these results underscore the potential of eskebornite as a thermoelectric candidate, with substantial room for optimization through chemical doping, microstructural engineering, or nanostructuring approaches to enhance the carrier mobility and reduce the lattice thermal conductivity. Full article

The aim of this research is to thoroughly investigate the influence of the 2025 Donald Trump Presidential Inauguration on informational efficiency of the U.S. exchange-traded fund market in the context of political risk. The data set includes daily observations for twenty U.S. Exchange-Traded Funds (ETFs). The whole sample comprises the period from 20 October 2024 to 20 April 2025. Since the Presidential Inauguration of Donald Trump took place on 20 January 2025, two sub-samples of an equal length are analyzed: (1) the period before the 2025 U.S. Presidential Inauguration from 20 October 2024 to 19 January 2025 and (2) the period after the 2025 U.S. Presidential Inauguration from 20 January 2025 to 20 April 2025. Since the whole sample period is not long (six months), to estimate market efficiency, modified Shannon entropy based on symbolic encoding with two thresholds is used. The empirical findings are visualized by symbol-sequence histograms. The proposed research hypothesis states that the U.S. ETF market’s informational efficiency, as measured by entropy, substantially decreased during the turbulent period after the Donald Trump Presidential Inauguration compared to the period before the Inauguration. The results unambiguously confirm the research hypothesis and indicate that political risk could affect the informational efficiency of markets. To the best of the author’s knowledge, this is the first study exploring the influence of the Donald Trump Presidential Inauguration on the informational efficiency of the U.S. ETF market. Full article

Internal Dry Reforming of Methane (IDRM) in biogas fed Solid Oxide Fuel Cells (SOFCs) was investigated on Fe-Au modified Ni/GDC electrolyte-supported cells at 900 and 850 °C. The aim was to clarify the synergistic interaction between Fe and Au, focusing on the effect of X wt.% of Au loading (where X = 1 or 3 wt.%) in binary Au-Ni/GDC and ternary 0.5 wt.% Fe-Au-Ni/GDC fuel electrodes. The investigation combined i-V, Impedance Spectroscopy and Gas Chromatography electrocatalytic measurements. It was found that modification with 0.5Fe-Au enhanced significantly the electrocatalytic activity of Ni/GDC for the IDRM reaction, whereas the low wt.% Au content had the most promoting effect. The positive interaction of 0.5 wt.% Fe with 1 wt.% Au increased the conductivity of Ni/GDC and enhanced the corresponding IDRM charge transfer electrochemical processes, especially those in the intermediate frequency region. Comparative long-term measurements, between cells comprising Ni/GDC and 0.5Fe-1Au-Ni/GDC, highlighted the significantly higher IDRM electrocatalytic activity of the modified electrode. The latter operated for almost twice the time (280 h instead of 160 h for Ni/GDC) with a lower degradation rate (0.44 mV/h instead of 0.51 mV/h). Ni/GDC degradation was ascribed to inhibited charge transfer processes in the intermediate frequencies region and to deteriorated ohmic resistance. Stoichiometric analysis on the (post-mortem) surface state of each fuel electrode showed that the wt.% content of reduced nickel on Ni/GDC was lower, compared to 0.5Fe-1Au-Ni/GDC, verifying the lower re-oxidation degree of the latter. This was further correlated to the hindered H₂O production during IDRM operation, due to the lower selectivity of the modified electrode for the non-desired RWGS reaction. Full article