Search Results (110)

The present work proposes a holistic techno-economic framework for the production of green hydrogen and synthetic methane from a dedicated 18.8 MW renewable park (13.8 MW wind and 5 MW photovoltaic) in southern Italy. A Mixed-Integer Linear Programme optimises the hourly dispatch of the electrolyser, the battery, and the bi-directional grid connection over a full-year horizon (8760 h) while meeting an annual target of 600,000 kg_H2. Two downstream pathways are compared: compressed-hydrogen transport by tube trailer at 200, 400, and 600 km, and on-site catalytic methanation via the Sabatier reaction. The assessment is deliberately restricted to the cost side, so that the two carriers are compared on a robust, price-agnostic levelised cost basis. Operated in an import-free mode to guarantee hydrogen with zero operational carbon emissions, the optimisation co-determines a cost-optimal battery capacity of 18 MWh. The levelised cost of hydrogen (LCOH) ranges between 9.55 and 10.27 €/kg_H2 at the gate, rising to 11.17–12.33 €/kg_H2 with transport, whereas the levelised cost of synthetic methane is 5.67 €/kg_CH4. On an energy basis, hydrogen is more competitive (0.335–0.370 €/kWh) compared to methane (0.409 €/kWh). A structured sensitivity analysis shows that a grid connection of 10 MW or more renders the battery unnecessary and lowers the gate LCOH to 8.26 €/kg, and ranks the renewable CAPEX and the discount rate as the dominant cost drivers. The produced hydrogen is essentially carbon-free at the gate, with the only residual emissions (0.014–0.041 kgCO₂/kWh) arising from its diesel trucking. Full article

The global transition toward carbon-neutral energy solutions has established Solid Oxide Fuel Cells (SOFCs) as a key technology for next-generation power generation. This work presents a comprehensive numerical study and multi-factor statistical analysis of an anode-supported SOFC fueled by synthetic diesel. A three-dimensional computational fluid dynamics model, validated against experimental data, was integrated with a Taguchi L₂₇ orthogonal array to systematically evaluate the influence of six key parameters: temperature, fuel mass flow rate, operating pressure, current load, flow channel configuration, and methane molar fraction. Statistical analysis through the signal-to-noise ratio and analysis of variance identified the operating current as the most significant factor affecting cell voltage, followed by the fuel mass flow rate and temperature. The experiments showed that the highest levels of all factors (except for the current, which had the lowest level) maximize electrochemical performance while maintaining a steam-to-carbon ratio (S/C) within a range of 0.83 to 0.92, calculated based on total carbon content, ensuring sufficient humidification for internal reforming across all tested fuel compositions. Furthermore, a multiple linear regression model was developed as a computationally efficient surrogate, demonstrating exceptional predictive accuracy with an R² of 0.9954 and a mean relative error of 1.76% across independent validation cases. These results provide a robust methodology for rapid design and sensitivity analysis of internal-reforming SOFCs, offering a precise tool for optimizing fuel utilization in high-temperature electrochemical systems. Full article

This review analyzes the catalytic routes for the Power-to-X (PtX) conversion of hydrogen to methane, methanol, ammonia, formic acid, and synthetic hydrocarbon fuels. The key reactive synthesis technologies and catalysts for each vector are described. Recent studies and pilot projects summarizing the reaction pathways of each vector and the associated catalyst technologies are also discussed. The analysis indicates that catalyst selection critically influences the efficiency and selectivity of these reactive systems. Some catalyst synthesis routes rely on expensive critical minerals (e.g., Ru and Rh), which raise technical and economic challenges for their industrial application. Catalyst deactivation and scale-up limitations are also relevant issues to be resolved. Emerging catalysts (e.g., Fe–Co or Co–Ni bimetallics, core–shell materials, metal-organic frameworks (MOFs), electrides, covalent-organic frameworks (COFs), and perovskites) are being explored to enhance stability, selectivity, and deactivation. Europe leads PtX development to consolidate the industrial production of hydrogen-based vectors with strong policy support, while the industrial initiatives in Latin America are limited (for instance, Chile’s green methanol and ammonia projects are examples) despite its great potential to generate renewable energy. In summary, Power-to-X can store renewable energy and close the carbon loop; however, its industrial consolidation demands catalyst innovation and supportive regulatory frameworks to overcome the challenges highlighted in this review. Full article

Bio-CO₂ is part of the natural carbon cycle and represents a sustainable carbon source for the production of Renewable Fuels of Non-Biological Origin (RFNBOs), such as synthetic methanol. This study addresses the critical knowledge gap in aligning diverse biogenic CO₂ sources with e-methanol requirements in the EU by providing harmonized mapping, based on datasets, literature sources, and reported industrial statistics at the sectoral and country level. Bio-CO₂ streams from biogas and biogas upgrading, biomass combustion, pulp and paper, bioethanol production, and the food and beverage sector are evaluated for total emissions, CO₂ concentrations and purity, the geographical distribution, seasonality, and impurity profiles. Results show that approximately 350 Mtpa of bio-CO₂ are emitted across the EU, with highly heterogeneous characteristics. Biogas upgrading and fermentation-based processes generate highly pure CO₂ streams (>98–99%), yet their small and dispersed nature complicates logistics. In contrast, biomass-combustion and pulp and paper sectors provide large volumes (around 214.6–298.2 Mtpa and 73.9 Mtpa CO₂, respectively), but in diluted streams (typically 3–15% and 10–20%). Replacing just 10% of the EU maritime fuel demand with e-methanol would require 53.6 Mtpa of bio-CO₂ and 58 GW of electrolyzer capacity, a stark contrast to the current operational 385 MW. The findings highlight the need for infrastructure planning and aggregation hubs to enable the large-scale deployment of RFNBO methanol in the maritime sector. Full article

The problem of adequate quantitative analysis of anthropogenic film pollution of water areas according to synthetic aperture radar (SAR) satellite imagery is addressed here. A quantitative analysis of anthropogenic film pollution (AFP) in the studied coastal water areas of the north sector of the Black Sea and Avacha Gulf has been conducted. The analysis utilized a method that involved the statistical processing of data related to AFP identified within the cells of a regular spatial grid. Time series of Sentinel-1 SAR satellite imagery were used as initial data. Spatiotemporal distributions of the proposed quantitative criterion (e_AFP, ppm) have been calculated and analyzed. This criterion characterizes the intensity of AFP impact within the selected regions of marine waters based on measuring the relative frequency of an AFP event. Among them, the area of the emergency fuel oil spill that occurred in 2024–2025 near the Kerch Strait was investigated (e_AFP values near the wreckage of tankers reached ~13,000 ppm), as well as the area of the emergency oil spill near the Novorossiysk terminal that occurred in 2021 (e_AFP ≤ 6000 ppm). Accidents led to an approximately 3–6-fold increase in e_AFP values against the background level of 0–2000 ppm. The spatiotemporal variability of e_AFP across various water areas and under different conditions has been demonstrated and discussed. Full article

Developing efficient and durable oxygen reduction reaction (ORR) catalysts is crucial for advancing fuel cell technology and sustainable energy conversion. In this study, a scalable strategy was employed to synthesize ZIF-derived nitrogen-sulfur co-doped carbon nanosheets embedded with in situ generated ZnS and Co₉S₈ nanoparticles. The synergistic effect of heteroatom doping and metal sulfide modification effectively modulated the electronic structure, optimized charge transfer pathways, and enhanced structural stability. The optimized catalyst exhibited a half-wave potential of 0.83 V vs. RHE, close to that of commercial 20 wt% Pt/C (0.85 V), excellent 4e⁻ ORR selectivity, and exceptional stability, with only a ~15 mV degradation after 10,000 cycles. These results demonstrate that the combination of nitrogen sulfur co-doping and in situ metal sulfide addition pro-vides an effective approach for designing highly active and durable non-precious metal catalysts for the ORR. This synthetic concept provides practical guidance for the scalable preparation of multifunctional nanomaterial-based catalysts for electrochemical energy applications. Full article

The power system is evolving with the integration of new technologies, including electronic devices and renewable energy sources, which are increasingly used to support new applications, reduce dependence on fossil fuels, and drive system innovation. However, this shift brings a significant drawback: a reduction in power quality (PQ). The literature extensively discusses the impact of poor PQ on electrical assets and explores potential solutions to this new challenge. Building on this foundation, this paper introduces new PQ indices derived from existing metrics and validated on both synthetic and real signals to assess their effectiveness. The aim is to provide researchers and system operators with simple and efficient tools for the clear identification of PQ issues in monitored networks. These new indices are designed to be flexible and independent of acquisition conditions, making them suitable for a wide range of frequencies (e.g., 50 Hz–150 kHz) and applications. After an overview of the PQ landscape, the paper demonstrates the use of these indices on various voltage waveforms, including a case study from a measurement campaign. The promising results indicate that, when combined with existing indices, these new metrics can form a strong foundation for a deeper understanding and more accurate classification of PQ issues in power networks. Full article

The decarbonization of hard-to-defossilize sectors, such as international maritime transport, requires innovative, and at times disruptive, energy solutions that combine efficiency, scalability, and climate benefits. Therefore, power-to-liquid (PtL) routes have stood out for their potential to use low-emission electricity for the production of synthetic fuels, via electrolytic hydrogen and CO₂ capture. However, the high energy demand inherent to these routes poses significant challenges to large-scale implementation. Moreover, PtL routes are usually at most neutral in terms of CO₂ emissions. This study evaluates, from a thermo-energetic perspective, the optimization potential of an e-methanol synthesis route through integration with a biomass oxy-fuel combustion process, making use of electrolytic oxygen as the oxidizing agent and the captured CO₂ as the carbon source. From the standpoint of a first-law thermodynamic analysis, mass and energy balances were developed considering the full oxygen supply for oxy-fuel combustion to be met through alkaline electrolysis, thus eliminating the energy penalty associated with conventional oxygen production via air separation units. The balance closure was based on a small-scale plant with a capacity of around 100 kta of methanol. In this integrated configuration, additional CO₂ surpluses beyond methanol synthesis demand can be directed to geological storage, which, when combined with bioenergy with carbon capture and storage (BECCS) strategies, may lead to net negative CO₂ emissions. The results demonstrate that electrolytic oxygen valorization is a promising pathway to enhance the efficiency and climate performance of PtL processes. Full article

The mitigation of climate change impacts from the automotive sector is important for sustainable development, and for that purpose, synthetic liquid fuel vehicles (SLF-Vs) are being considered as a potential clean option alongside electric vehicles (EVs). However, the energy-intensive production of synthetic liquid fuels (SLFs) requires a thorough life-cycle analysis, as CO₂ emissions vary significantly depending on the power sources and feedstock production technologies. This study evaluates the life-cycle CO₂ emissions of SLF-Vs in Japan through long-term multiple scenarios up to 2050 and compares them with those of gasoline vehicles (GVs), hybrid electric vehicles (HEVs), and battery electric vehicles (BEVs). The results reveal that, in 2020, SLF-Vs’ life-cycle CO₂ emissions were more than 2.9 times higher than those of GVs. By 2050, SLF-Vs’ emissions could only decrease to BEV-like levels if Japan achieves significant decarbonization of its power grid. Even if hydrogen is produced via water electrolysis in Australia, where renewable energy is abundant, and then imported, emissions remain high if Japan’s power grid remains insufficiently decarbonized. This highlights the critical importance of expanding domestic decarbonized power sources, particularly renewable energy, to reduce the life-cycle CO₂ emissions of SLF-Vs in Japan. Full article

With the rapid growth of energy demand, the development of efficient energy-conversion technologies (e.g., water splitting, fuel cells, metal-air batteries, etc.) becomes an important way to circumvent the problems of fossil fuel depletion and environmental pollution, which motivates the pursuit of high-performance electrocatalysts with controllable compositions and morphologies. Among them, two-dimensional (2D) Pt-group metallic electrocatalysts show a series of distinctive architectural merits, including a high surface-to-volume ratio, numerous unsaturated metal atoms, an ameliorative electronic structure, and abundant electron/ion transfers channels, thus holding great potential in realizing good selectivity, rapid kinetics, and high efficiency for various energy-conversion devices. Considering that great progress on this topic has been made in recent years, here we present a panoramic review of recent advancements in 2D Pt-group metallic nanocrystals, which covers diverse synthetic methods, structural analysis, and their applications as electrode catalysts for various energy-conversion technologies. At the end, the paper also outlines the research challenges and future opportunities in this emerging area. Full article

Gasification of municipal solid waste and other biogenic residues (e.g., biomass and biowaste) is increasingly recognized as a promising thermochemical pathway for converting non-recyclable fractions into valuable energy carriers, with applications in electricity generation, district heating, hydrogen production, and synthetic fuels. This paper provides a comprehensive analysis of major gasification technologies, including fixed bed, fluidized bed, entrained flow, plasma, supercritical water, microwave-assisted, high-temperature steam, and rotary kiln systems. Key aspects such as feedstock compatibility, operating parameters, technology readiness level, and integration within circular economy frameworks are critically evaluated. A comparative assessment of incineration and pyrolysis highlights the environmental and energetic advantages of gasification. The valorization pathways for main product (syngas) and by-products (syngas, ash, tar, and biochar) are also explored, emphasizing their reuse in environmental, agricultural, and industrial applications. Despite progress, large-scale adoption in Europe is constrained by economic, legislative, and technical barriers. Future research should prioritize scaling emerging systems, optimizing by-product recovery, and improving integration with carbon capture and circular energy infrastructures. Supported by recent European policy frameworks, gasification is positioned to play a key role in sustainable waste-to-energy strategies, biomass valorization, and the transition to a low-emission economy. Full article

In pursuit of zero-emission targets, increasing sustainability concerns have prompted urban centers to adopt more environmentally friendly modes of transportation, notably through the deployment of electric vehicles (EVs). A prominent manifestation of this shift is the transition from conventional fuel-powered buses to electric buses (e-buses), which, despite their environmental benefits, introduce significant operational challenges—chief among them, the management of battery systems, the most critical and complex component of e-buses. The development of efficient and reliable Battery Management Systems (BMSs) is thus central to ensuring battery longevity, operational safety, and overall vehicle performance. This study examines the potential of intelligent BMSs to improve battery health diagnostics, extend service life, and optimize system performance through the integration of simulation, real-time analytics, and advanced deep learning techniques. Particular emphasis is placed on the estimation of battery state of health (SoH), a key metric for predictive maintenance and operational planning. Two widely recognized deep learning models—Multilayer Perceptron (MLP) and Long Short-Term Memory (LSTM)—are evaluated for their efficacy in predicting SoH. These models are embedded within a unified framework that combines synthetic data generated by a physics-informed battery simulation model with empirical measurements obtained from real-world battery aging datasets. The proposed approach demonstrates a viable pathway for enhancing SoH prediction by leveraging both simulation-based data augmentation and deep learning. Experimental evaluations confirm the effectiveness of the framework in handling diverse data inputs, thereby supporting more robust and scalable battery management solutions for next-generation electric urban transportation systems. Full article

The maritime industry remains a significant contributor to global greenhouse gas (GHG) emissions. In this article, a systematic study has been performed on the alternative fuel emissions of large cargo ships under different route scenarios and propulsion systems. For this purpose, a set of key performance indicators (KPIs) are evaluated, including total equivalent CO₂ emissions (CO_2eq), CO_2eq emissions per unit of transport mass and CO_2eq emissions per unit of transport mass per distance. The emissions analysis demonstrates that Liquified Natural Gas (LNG) paired with Marine Gas Oil (MGO) emerges as the most viable short-term solution in comparison with the conventional fuel oil propulsion. Synthetic methanol (eMeOH) paired with synthetic diesel (eDiesel) is identified as the most promising long-term fuel combination. When comparing the European Union (EU) emission calculation system (FuelEU) with the International Maritime Organization (IMO) emission metrics, a discrepancy in emissions reduction outcomes has been observed. The IMO approach appears to favor methanol (MeOH) and liquefied natural gas (LNG) over conventional fuel oil. This is attributed to the fact that the IMO metrics do not consider unburned methane emissions (methane slip) and emissions in the production of fuels (Well-to-Tank). Full article

The agricultural sector faces growing pressure to enhance productivity and sustainability, prompting innovation in machinery design. Traditional materials such as steel still dominate but are a cause of increased weight, soil compaction, increased fuel consumption, and corrosion. Composite materials—and, more specifically, fiber-reinforced polymers (FRPs)—offer appealing alternatives due to their high specific strength and stiffness, corrosion resistance, and design flexibility. Meanwhile, increasing environmental awareness has triggered interest in biocomposites, which contain natural fibers (e.g., flax, hemp, straw) and/or bio-based resins (e.g., PLA, biopolyesters), aligned with circular economy principles. This review offers a comprehensive overview of synthetic composites and biocomposites for agricultural machinery and equipment (AME). It briefly presents their fundamental constituents—fibers, matrices, and fillers—and recapitulates relevant mechanical and environmental properties. Key manufacturing processes such as hand lay-up, compression molding, resin transfer molding (RTM), pultrusion, and injection molding are discussed in terms of their applicability, benefits, and limits for the manufacture of AME. Current applications in tractors, sprayers, harvesters, and planters are covered in the article, with advantages such as lightweighting, corrosion resistance, flexibility and sustainability. Challenges are also reviewed, including the cost, repairability of damage, and end-of-life (EoL) issues for composites and the moisture sensitivity, performance variation, and standardization for biocomposites. Finally, principal research needs are outlined, including material development, long-term performance testing, sustainable and scalable production, recycling, and the development of industry-specific standards. This synthesis is a practical guide for researchers, engineers, and manufacturers who want to introduce innovative material solutions for more efficient, longer lasting, and more sustainable agricultural machinery. Full article

The Magallanes region, in southern Chile, is positioned as a strategic hub for the production of green hydrogen (GH2), green ammonia, and synthetic fuels, thanks to its exceptional wind potential and commitment to sustainability. This article analyzes the opportunities and challenges of these energy vectors in the context of global decarbonization, highlighting the key role of the Magallanes region in the energy transition. Green hydrogen production, through wind-powered electrolysis, takes advantage of the region’s constant, high-speed winds, enabling competitive, low-emission generation. In turn, green ammonia, derived from GH2, emerges as a sustainable alternative for the agricultural industry and maritime transport, while synthetic fuels (e-fuels) offer a solution for sectors that are difficult to electrify, such as aviation. The sustainability approach addresses not only emissions reduction but also the responsible use of water resources, the protection of biodiversity, and integration with local communities. The article presents the following structure: (i) introduction, (ii) wind resource potential, (iii) water resource potential, (iv) different forms of hydrogen and its derivatives production (green hydrogen, green ammonia, and synthetic fuels), (v) pilot-scale demonstration plant for Haru Oni GH2 production, (vi) future industrial-scale GH2 production projects, (vii) discussion, and (viii) conclusions. In addition, the article discusses public policies, economic incentives, and international collaborations that promote these projects, positioning Magallanes as a clean energy export hub. Finally, the article concludes that the region can lead the production of green fuels, contributing to global energy security and the fulfillment of the Sustainable Development Goals (SDGs). However, advances in infrastructure, regulation, and social acceptance are required to guarantee a balanced development between technological innovation and environmental conservation. Full article