Search Results (790)

In the present paper, the interaction between metal oxide nanoparticles and carbon materials was studied, and the results showed a synergetic effect, leading to an improvement in the properties of the obtained hybrid composites. The In₂O₃ NPs were prepared by the precipitation method and thermal treatment at 550 °C. The composites were obtained using an ex situ method, by mixing the In₂O₃ NPs with reduced oxide graphene (rGO) in a ratio of 10:1. The structural, morphological, and chemical composition studies of the In₂O₃ NPs and In₂O₃-rGO composites were investigates by FTIR and EDX spectroscopy, SEM microscopy, and XRD analysis. These techniques have highlighted the obtaining of In₂O₃ of high purity, and crystallinity, with the mean particle size in the range of 8–25 nm, but also, the dispersion of In₂O₃ NPs onto rGO sheets. We examined the influence of the In₂O₃ nanostructure morphology and In₂O₃-rGO composites on the electrochemical properties using cyclic voltammetry. The surface properties of the In₂O₃ and composite films were studied by contact angles, which indicate the maintenance of the hydrophilic nature. The obtained results establish the synergy between the main components to form In₂O₃-rGO, which can be used for the development of biosensors to enhance the device performance. Full article

Lithium-ion batteries (LIBs) have attracted extensive attention as a distinguished electrochemical energy storage system due to their high energy density and long cycle life. However, the initial irreversible lithium loss during the first cycle caused by the formation of the solid electrolyte interphase (SEI) leads to the prominent reduction in the energy density of LIBs. Notably, lithium formate (HCOOLi, LFM) is regarded as a promising cathode prelithiation reagent for effective lithium supplementation due to its high theoretical capacity of 515 mAh·g⁻¹. Nevertheless, the stable Li-O bond of LFM brings out the high reaction barrier accompanied by the high decomposition potential, which impedes its practical applications. To address this issue, a feasible strategy for reducing the reaction barrier has been proposed, in which the decomposition potential of LFM from 4.84 V to 4.23 V resulted from the synergetic effects of improving the electron/ion transport kinetics and catalysis of transition metal oxides. The addition of LFM to full cells consisting of graphite anodes and LiNi_0.834Co_0.11Mn_0.056O₂ cathodes significantly enhanced the electrochemical performance, increasing the reversible discharge capacity from 156 to 169 mAh·g⁻¹ at 0.1 C (2.65–4.25 V). Remarkably, the capacity retention after 100 cycles improved from 72.8% to 94.7%. Our strategy effectively enables LFM to serve as an efficient prelithiation additive for commercial cathode materials. Full article

To achieve the ‘zero carbon’ target, offshore renewable energy exploration plays a key role in many countries. Offshore wind energy and wave energy are both important offshore renewable energies. With the target to reduce the cost of energy, a new combined wind and wave energy converter is proposed in this work. The new concept consists of a spar-type floating wind turbine and a multi-section pitch-type wave energy converter (WEC). The WEC is attached to the spar column and consists of multiple sections with different lengths to absorb wave energy at different wave frequencies, i.e., multi-band absorption. Through multi-band wave energy absorption, the total power is expected to increase. In addition, through synergetic design, the dynamic motions of the platform are expected to decrease. In this paper, a fully coupled numerical model of the concept is established, based on the hybrid time–frequency-domain simulation framework. The frequency-domain hydrodynamic properties were transferred to the time domain. Then, the dynamic performance of the combined concept under wind–wave conditions was studied, especially under operational conditions. Mechanical couplings among multiple floating bodies were taken into account. To demonstrate the WEC effects on the floating wind turbine, the dynamic performance of the combined wind–wave energy converter concept was compared with the segregated floating wind turbine, with a focus on motions and output power. It was expected that the average overall output power of the multi-section WEC could be above 160 kW. The advantages of the combined concept are demonstrated. Full article

Seeking to advance mutual clustering of the tourism economy and cultural industries while safeguarding cultural sustainability in tourism, this paper delves into the patterns of co-development and the contributing forces across spatial and temporal dimensions in the Yellow River Basin. Using a combined spatial and temporal analytical lens, along with spatial autocorrelation testing and a spatial Durbin model embedded in a synergetic systems approach, the present study analyzes the evolutionary characteristics of the spatiotemporal pattern of the collaborative agglomeration of the Yellow River Basin’s tourism and cultural industries in 2011 and 2021 and the internal mechanism of its influencing factors. We then propose countermeasures and suggestions to boost the quality–efficiency synergy agglomeration of the basin’s tourism and cultural industries. The results showed the following: ① From 2011 to 2021, a positive overall spatial autocorrelation was noted in the basin’s tourism and cultural industries. Temporally, it presented a variation trend of “rise–fall–rise”, and spatially, it presented a distribution characteristic of “higher in the central and eastern regions versus in its western parts”. ② From 2011 to 2021, the local spatial autocorrelation (LSA) of the basin’s tourism and cultural industries remained at a low level. Moreover, significant differences were noted in the LSA among different regions. In spatial terms, the clustering intensity of tourism and cultural industries was stronger in the central and eastern parts of the basin versus in its western parts. ③ Influencing variables for tourism–culture collaborative agglomeration across the basin involve both temporal superposition effects and spatial radiation driving effects. The industrial economy, policies, and innovation exert enduring effects on the development and cross-regional spillover outcomes of the two collaborative agglomerations. Serving as a theoretical reference and policy resource, this study addresses how to promote the quality–efficiency synergy in the Yellow River Basin’s tourism and cultural industries while enhancing cultural sustainability in the tourism industry. Moreover, it can also provide experiences and references for other similar regions. Full article

Background: The effect of antibiotics can be severely affected by external factors. Combining the oxidative impact of photodynamic therapy with antibiotics is largely unexplored, which may result in positive results with great impact on clinical applications. In particular, that can be relevant in the case of antibiotic resistance. Objectives: In this study, we examined the effects of aPDT using the photosensitizers (PSs), methylene blue (MB) or Photodithazine (PDZ), both alone and in combination with the antibiotics ciprofloxacin (CIP), gentamicin (GEN), and ceftriaxone (CEF), against the Gram-negative bacterium Klebsiella pneumoniae. Methods: A standard suspension of K. pneumoniae was subjected to PDT with varying doses of MB and PDZ solutions, using a 75 mW/cm² LED emitting at 660 nm with an energy of 15 J/cm². The MICs of CIP, GEN, and CEF were determined using the broth dilution method. We also tested the photosensitizers MB or PDZ as potentiating agents for synergistic combinations with antibiotics CIP, GEN, and CEF against K. pneumoniae. Results: The results showed that MB was more effective in inhibiting survival and killing K. pneumoniae compared to PDZ. The tested antibiotics CIP, GEN, and CEF suppressed bacterial growth (as shown by reduced MIC values) and effectively killed K. pneumoniae (reduced Log CFU/mL). While antibiotic treatment or aPDT alone showed a moderate effect (1 Log₁₀ to 2 Log₁₀ CFU reduction) on killing K. pneumoniae, the combination therapy significantly increased bacterial death, resulting in a ≥3 Log₁₀ to 6 Log₁₀ CFU reduction. Conclusions: Our study indicates that pre-treating bacteria with PDT makes them more susceptible to antibiotics and could serve as an alternative for treating local infections caused by resistant bacteria or even reduce the required antibiotic dosage. This work explores numerous possible combinations of PDT and antibiotics, emphasizing their interdependence in controlling infections and the unique properties each PS-antibiotic combination offers. Clinical application for the combination is a promising reality since both are individually already adopted in clinical use. Full article

This paper presents the results of an investigation into the catalytic activity and selectivity of rhodium-based catalysts supported on natural zeolite clinoptilolite from the Shankanai field (Kazakhstan) in the dehydrogenation of light alkanes from associated petroleum gas (APG). Three modifications of the catalyst have been studied: basic 1%Rh/HCpt, modified with tin 1%Rh/10%SnO/HCpt, and combined with additives of tin and potassium 1%Rh/10%SnO/5%K₂O/HCpt. It has been shown that the addition of tin contributes to increased thermal stability and a decreased coking rate, while the addition of potassium suppresses side reactions (cracking and isomerization), increasing the selectivity for olefins. The highest yield of olefins (~30%) is achieved with the 1%Rh/10%SnO/5%K₂O/HCpt catalyst in the presence of water vapor. Using scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM), improved distribution of active components and reduced catalyst deactivation have been confirmed. The obtained data demonstrate the potential of the developed systems for the efficient processing of APG and the selective synthesis of olefins. Full article

ZnO/SiC nanocomposite materials possess significant potential for various technological fields due to their extraordinary optical, electrical, thermal, and mechanical properties. The synthesis methods, material properties, and diverse applications of ZnO/SiC composites have been systematically explored in this study. The potential application areas of this nanocomposite include their roles in photocatalysis, optoelectronic devices, gas sensors, and photovoltaic systems. The synergetic effects of ZnO and SiC are analyzed to highlight their advantages over their individual components. Future research directions must focus on the remaining challenges to optimize these nanoscale composite materials for industrial and emerging applications. Full article

Nickel-rich layered oxides such as LiNi_xMn_yCo_zO₂ (NMC), LiNi_xCo_yAl_zO₂ (NCA), and LiNi_xMn_yCo_zAl_{(1–x–y–z)}O₂ (NMCA), where x ≥ 0.6, have emerged as key cathode materials in lithium-ion batteries due to their high operating voltage and superior energy density. These materials, characterized by low cobalt content, offer a promising path toward sustainable and cost-effective energy storage solutions. However, their electrochemical performance remains below theoretical expectations, primarily due to challenges related to structural instability, limited thermal safety, and suboptimal cycle life. Intensive research efforts have been devoted to addressing these issues, resulting in substantial performance improvements and enabling the development of next-generation lithium-ion batteries with higher nickel content and reduced cobalt dependency. In this review, we present recent advances in material design and engineering strategies to overcome the problems limiting their electrochemical performance (cation mixing, phase stability, oxygen release, microcracks during cycling). These strategies include synthesis methods to optimize the morphology (size of the particles, core–shell and gradient structures), surface modifications of the Ni-rich particles, and doping. A detailed comparison between these strategies and the synergetic effects of their combination is presented. We also highlight the synergistic role of compatible lithium salts and electrolytes in achieving state-of-the-art nickel-rich lithium-ion batteries. Full article

The imbalance between urban and rural development has become a global structural problem that needs to be solved urgently. In this context, the tourism industry, with its strong correlation and cross-regional integration characteristics, provides a key practical entry point and mechanism for systematically promoting integrated development by stimulating factor flow, reconstructing the value chain, and reshaping local identity. Based on the synergetic theory, this paper constructs the theoretical framework of the synergetic evolution of the tourism industry and urban–rural integration, and analyzes the synergetic effect of the tourism industry and urban–rural integration in 58 prefecture-level cities in the Yellow River Basin from 2007 to 2021 and the dynamic characteristics of its spatio-temporal evolution by using the entropy TOPSIS, Haken model, and spatial Markov chain methods. The results show the following: ① As the order parameter of synergistic evolution, the tourism industry dominates the evolution direction of the whole system, mainly showing positive feedback effect, showing a significant stage characteristic in general, and gradually reducing the difference from the initial regional differentiation to the middle stage, finally reaching a higher level of unity. ② The synergic evolution of the tourism industry and urban–rural integration in the Yellow River Basin presents significant temporal and spatial differences in the upstream, midstream, and downstream, with the overall characteristics of “collaborative improvement in the upstream, significant agglomeration in the midstream, and reverse decoupling in the downstream”. ③ The dynamic evolution of the synergistic development of the tourism industry and urban–rural integration in the Yellow River Basin has significant characteristics of spatial interaction and dynamic transfer. Its level has the effect of “path dependence”, showing a good trend of upward transfer, and the spatial neighborhood has a significant impact on the synergetic level transfer. The development trend of each region shows that “the upstream region is upward and stable, the midstream region has significant agglomeration and diffusion effects, and the downstream region is driven by polar nuclei and spatial differentiation”. Full article

To overcome the negative effects of the biochemical application of nano-substances in medicine (toxicity problem), using the example of fullerene C₆₀’s first derivative (fullerenol, FD-C₆₀), we show that their biophysical effect is possible through non-covalent hydrogen bonds when around FD-C₆₀ water layers are formed. SD-C₆₀ (Zeta potential is −43.29 mV) is much more stable than fullerol (Zeta potential is −25.85 mV), so agglomeration/fragmentation of the fullerol structure, due to instability, can cause toxic effects. When fullerol in solution was exposed to an oscillatory magnetic field with Re (real) part [250/−92 mT, H(ωt) = Acos(ωt)], water layers around FD-C₆₀ (fullerenol) are formed according to the Penrose process of 3D tiling formation, and the second derivative, SD-C₆₀ (or 3HFWC), is self-organized. However, when Im (imaginary) part [250/−92 mT, H(ωt) = Bisin (ωt)] of the external magnetic field is applied in addition to SD-C₆₀, ordered water chains and bubbling of water (“micelle”) are formed as a third derivative (TD-C₆₀). Fullerol (FD-C₆₀) interacts with biological structures biochemically, while the second (SD-C₆₀) and third (TD-C₆₀) derivatives act biophysically via non-covalent hydrogen bond oscillation. SD-C₆₀ and TD-C₆₀ significantly increased water solubility and reduced toxicity. The paper explains the synthesis of SD-C60 and TD-C60 from FD-C60 (fullerol) as a precursor by the influence of an oscillatory magnetic field (“Yin-Yang” principle) on hydrogen bonds in order to create water layers around fullerol. Examples of biomedical applications (cancer and Alzheimer’s) of this synergetic complex are given. This study shows that the “Yin-Yang” machinery, based on the nanophysics of C₆₀ molecules and non-covalent hydrogen bonds, is possible. The first attempt has been composed to synthesize nanomaterial for biophysical vibrational nanomedicine. Full article

The utilization of electric vehicles (EVs) has grown significantly and continuously in recent years, encouraging the creation of new implementation opportunities. The battery electric vehicle (BEV) charging system can be effectively used during peak load periods, for voltage regulation, and for the improvement of power system stability within the smart grid. It provides an efficient bidirectional interface for charging the battery from the grid and discharging the battery into the grid. These two operation modes are referred to as grid-to-vehicle (G2V) and vehicle-to-grid (V2G), respectively. The management of power flow in both directions is highly complex and sensitive, which requires employing a robust control scheme. In this paper, an Integral Fast Terminal Synergetic Control Scheme (IFTSC) is designed to control the BEV charger system through accurately tracking the required current and voltage in both G2V and V2G system modes. Moreover, the Black-Winged Kite Algorithm is introduced to select the optimal gains of the proposed IFTS control scheme. The system stability is checked using the Lyapunov stability method. Comprehensive simulations using MATLAB/Simulink are conducted to assess the safety and efficacy of the suggested optimal IFTSC in comparison with IFTSC, optimal integral synergetic, and conventional PID controllers. Furthermore, processor-in-the-loop (PIL) co-simulation is carried out for the studied system using the C2000 launchxl-f28379d digital signal processing (DSP) board to confirm the practicability and effectiveness of the proposed OIFTS. The analysis of the obtained quantitative comparison proves that the proposed optimal IFTSC provides higher control performance under several critical testing scenarios. Full article

Fabricating efficient photocatalysts that can be used in solar-to-fuel conversion and to enhance the photochemical reaction rate is essential to the current energy crisis and climate changes due to the excessive usage of nonrenewable fossil fuels. To attain high photo-to-chemical conversion efficiency, it is important to fabricate cost-effective and durable catalysts with high activity. One-dimensional cadmium sulfides (1D CdS), with higher surface area, charge carrier separation along the linear direction, and visible light harvesting properties, are promising candidates for converting solar energy to H₂, reducing CO₂ to commodity chemicals, and remediating environmental pollutants. The main disadvantage of CdS is photocorrosion due to the leaching of S²⁻ ions during the photochemical reactions, and further charge recombination rate leads to low quantum efficiency. Therefore, the implementation of core–shell heterostructured morphology, i.e., the growth of the shell on the surface of the 1D CdS, which offers unique features such as protection of CdS from photocorrosion, a tunable interface between the core CdS and shell, and photogenerated charge carrier separation via heterojunctions, provides additional active sites and enhanced visible light harvesting. Therefore, the viability of the core–shell synthesis strategy and synergetic effects offer a new way of designing photocatalysts with enhanced stability and improved charge separation in solar energy conversion systems. This review highlights some critical aspects of synthesizing 1D CdS core–shell heterostructures, underlying reaction mechanisms, and their performance in photoredox reactions. Finally, some challenges and considerations in the fabrication of 1D CdS-based core–shell nanostructures that can overcome the current barriers in industrial applications are discussed. Full article

Unmanned ships, equipped with self-navigation and image processing capabilities, are progressively expanding their applications in fields such as mining, fisheries, and marine environments. Along with this development, issues concerning waterborne traffic safety are gradually emerging. To address the challenges of navigation and obstacle detection on the water’s surface, this paper presents CDS-YOLOv7, an enhanced obstacle-detection framework for aquatic environments, architecturally evolved from YOLOv7. The proposed system implements three key innovations: (1) Architectural optimization through replacement of the Spatial Pyramid Pooling Cross Stage Partial Connections (SPPCSPC) module with GhostSPPCSPC for expanded receptive field representation. (2) Integration of a parameter-free attention mechanism (SimAM) with refined pooling configurations to boost multi-scale detection sensitivity, and (3) Strategic deployment of depthwise separable convolutions (DSC) to reduce computational complexity while maintaining detection fidelity. Furthermore, we develop a Spatial–Channel Synergetic Attention (SCSA) mechanism to counteract feature degradation in convolutional operations, embedding this module within the Extended Effective Long-Range Aggregation Network (E-ELAN) network to enhance contextual awareness. Experimental results reveal the model’s superiority over baseline YOLOv7, achieving 4.9% mean average precision@0.5 (mAP@0.5), +4.3% precision (P), and +6.9% recall (R) alongside a 22.8% reduction in Giga Floating-point Operations Per Second (GFLOPS). Full article

The importance and challenges of ethylene detection based on combustion-type low-cost commercial sensors for agricultural and industrial applications are well-established. This work summarizes the significant progress in ethylene detection based on an innovative Gas Metal Oxide Semiconductor (GMOS) sensor and a new catalytic composition of metallic nanoparticles. The paper presents a study on ethylene and ethanol sensing using a miniature catalytic sensor fabricated by Complementary Metal Oxide Semiconductor–Silicon-on-Insulator–Micro-Electro-Mechanical System (CMOS-SOI-MEMS) technology. The GMOS performance with bimetallic palladium–platinum (Pd-Pt) and monometallic palladium (Pd) and platinum (Pt) catalysts is compared. The synergetic effect of the Pd-Pt catalyst is observed, which is expressed in the shift of combustion reaction ignition to lower catalyst temperatures as well as increased sensitivity compared to monometallic components. The optimal catalysts and their temperature regimes for low and high ethylene concentrations are chosen, resulting in lower power consumption by the sensor. Full article

This study proposes a novel integrated biorefinery approach that combines Hermetia illucens (Black Soldier Fly) larvae treatment, anaerobic digestion (AD), and hydrothermal carbonization (HTC) to enhance the valorisation of fat-rich food residues. The process was designed to improve biogas yields while mitigating the inhibitory effects of lipid accumulation in AD systems. Results from larval bioconversion showed effective fat removal and a promising potential for protein and biomass valorisation. Downstream integration with AD and HTC enabled thermal self-sufficiency, enhanced energy recovery, and improved digestate dewaterability. Additionally, HTC process water recirculation to the AD unit was evaluated, considering its acidic nature and impact on biomethane production. A thermally integrated process flow was proposed, enabling efficient heat exchange and reduced external energy input. The overall system allows for multi-product recovery—including biogas, hydrochar, and larval biomass—offering a sustainable pathway for circular bioeconomy applications. This study illustrates the feasibility of a synergetic process chain that maximises energy recovery and resource efficiency from food industry waste streams. Full article