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Search Results (1,085)

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Keywords = surface energy balance

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16 pages, 2576 KiB  
Article
Modeling and Spatiotemporal Analysis of Actual Evapotranspiration in a Desert Steppe Based on SEBS
by Yanlin Feng, Lixia Wang, Chunwei Liu, Baozhong Zhang, Jun Wang, Pei Zhang and Ranghui Wang
Hydrology 2025, 12(8), 205; https://doi.org/10.3390/hydrology12080205 - 6 Aug 2025
Abstract
Accurate estimation of actual evapotranspiration (ET) is critical for understanding hydrothermal cycles and ecosystem functioning in arid regions, where water scarcity governs ecological resilience. To address persistent gaps in ET quantification, this study integrates multi-source remote sensing data, energy balance modeling, and ground-based [...] Read more.
Accurate estimation of actual evapotranspiration (ET) is critical for understanding hydrothermal cycles and ecosystem functioning in arid regions, where water scarcity governs ecological resilience. To address persistent gaps in ET quantification, this study integrates multi-source remote sensing data, energy balance modeling, and ground-based validation that significantly enhances spatiotemporal ET accuracy in the vulnerable desert steppe ecosystems. The study utilized meteorological data from several national stations and Landsat-8 imagery to process monthly remote sensing images in 2019. The Surface Energy Balance System (SEBS) model, chosen for its ability to estimate ET over large areas, was applied to derive modeled daily ET values, which were validated by a large-weighted lysimeter. It was shown that ET varied seasonally, peaking in July at 6.40 mm/day, and reaching a minimum value in winter with 1.83 mm/day in December. ET was significantly higher in southern regions compared to central and northern areas. SEBS-derived ET showed strong agreement with lysimeter measurements, with a mean relative error of 4.30%, which also consistently outperformed MOD16A2 ET products in accuracy. This spatial heterogeneity was driven by greater vegetation coverage and enhanced precipitation in the southeast. The steppe ET showed a strong positive correlation with surface temperatures and vegetation density. Moreover, the precipitation gradients and land use were primary controllers of spatial ET patterns. The process-based SEBS frameworks demonstrate dual functionality as resource-optimized computational platforms while enabling multi-scale quantification of ET spatiotemporal heterogeneity; it was therefore a reliable tool for ecohydrological assessments in an arid steppe, providing critical insights for water resource management and drought monitoring. Full article
(This article belongs to the Section Hydrological and Hydrodynamic Processes and Modelling)
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21 pages, 3570 KiB  
Article
Performance Studies on a Scaled Model of Dual Oscillating-Buoys WEC with One Pneumatic PTO
by Peiyu Liu, Xiang Rao, Bijun Wu, Zhiwen Yuan and Fuming Zhang
Energies 2025, 18(15), 4151; https://doi.org/10.3390/en18154151 - 5 Aug 2025
Abstract
A hybrid wave energy conversion (WEC) system, integrating a backward bent duct buoy (BBDB) with an oscillating buoy (OB) via a flexible mooring chain, is introduced in this study. Unlike existing hybrid WECs, the proposed system dispenses with rigid mechanical linkages and enables [...] Read more.
A hybrid wave energy conversion (WEC) system, integrating a backward bent duct buoy (BBDB) with an oscillating buoy (OB) via a flexible mooring chain, is introduced in this study. Unlike existing hybrid WECs, the proposed system dispenses with rigid mechanical linkages and enables flexible offshore deployment. Flared BBDB and buoy models with spherical, cylindrical, and semi-capsule shapes are designed and tested experimentally in a wave flume using both regular and irregular wave conditions. The effects of nozzle ratio (NR), coupling distance, buoy draft, and buoy geometry are systematically examined to investigate the hydrodynamic performance and energy conversion characteristics. It is found that NR at 110 under unidirectional airflow produces an optimal balance between pressure response, free surface displacement, and energy conversion efficiency. Energy extraction is significantly influenced by the coupling distance, with the hybrid system achieving maximum performance at a specific normalized spacing. The semi-capsule buoy improves power extraction ability and expands effective bandwidth due to asymmetric shape and coupled motion. These findings provide valuable insights into the coupling mechanism and geometric optimization for hybrid WECs. Full article
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38 pages, 16643 KiB  
Article
Numerical Investigation of Inclination Effects on a Submerged Plate as Breakwater and Wave Energy Converter Under Realistic Sea State Waves
by Vitor Eduardo Motta, Gabrielle Ücker Thum, Maycon da Silveira Paiva, Rafael Adriano Alves Camargo Gonçalves, Luiz Alberto Oliveira Rocha, Elizaldo Domingues dos Santos, Bianca Neves Machado and Liércio André Isoldi
J. Mar. Sci. Eng. 2025, 13(8), 1438; https://doi.org/10.3390/jmse13081438 - 28 Jul 2025
Viewed by 220
Abstract
This study investigates the influence of inclination on a submerged plate (SP) device acting as both a breakwater (BW) and a wave energy converter (WEC) subjected to representative regular and realistic irregular waves of a sea state across 11 inclination angles. Numerical simulations [...] Read more.
This study investigates the influence of inclination on a submerged plate (SP) device acting as both a breakwater (BW) and a wave energy converter (WEC) subjected to representative regular and realistic irregular waves of a sea state across 11 inclination angles. Numerical simulations were conducted using ANSYS Fluent. Regular waves were generated by Stokes’s second-order theory, while the WaveMIMO technique was employed to generate irregular waves. Using the volume of fluid (VOF) method to model the water–air interaction, both approaches generate waves by imposing their vertical and horizontal velocity components at the inlet of the wave flume. The SP’s performance as a BW was analyzed based on the upstream and downstream free surface elevations of the device; in turn, its performance as a WEC was determined through its axial velocity beneath the plate. The results indicate that performance varies between regular and irregular wave conditions, underscoring the importance of accurately characterizing the sea state at the intended installation site. These findings demonstrate that the inclination of the SP plays a critical role in balancing its dual functionality, with certain configurations enhancing WEC efficiency by over 50% while still offering relevant BW performance, even under realistic irregular sea conditions. Full article
(This article belongs to the Section Coastal Engineering)
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15 pages, 4855 KiB  
Article
An Investigation of the Surface-Regulating Mechanism of Tungsten Alloys Using the Electrochemical Polishing Process
by Yachun Mao, Yanqiu Xu, Shiru Le, Maozhong An, Zhijiang Wang and Yuhan Zhang
Solids 2025, 6(3), 39; https://doi.org/10.3390/solids6030039 - 24 Jul 2025
Viewed by 258
Abstract
Tungsten and tungsten alloys are widely used in important industrial fields due to their high density, hardness, melting point, and corrosion resistance. However, machining often leaves processing marks on their surface, significantly affecting the surface quality of precision components in industrial applications. Electrolytic [...] Read more.
Tungsten and tungsten alloys are widely used in important industrial fields due to their high density, hardness, melting point, and corrosion resistance. However, machining often leaves processing marks on their surface, significantly affecting the surface quality of precision components in industrial applications. Electrolytic polishing offers high efficiency, low workpiece wear, and simple processing. In this study, an electrolytic polishing method is adopted and a novel trisodium phosphate–sodium hydroxide electrolytic polishing electrolyte is developed to study the effects of temperature, voltage, polishing time, and solution composition on the surface roughness of a tungsten–nickel–iron alloy. The optimal voltage, temperature, and polishing time are determined to be 15 V, 55 °C, and 35 s, respectively, when the concentrations of trisodium phosphate and sodium hydroxide are 100 g·L−1 and 6 g·L−1. In addition, glycerol is introduced into the electrolyte as an additive. The calculated LUMO value of glycerol is −5.90 eV and the HOMO value is 0.40 eV. Moreover, electron enrichment in the hydroxyl region of glycerol can form an adsorption layer on the surface of the tungsten alloy, inhibit the formation of micro-pits, balance ion diffusion, and thus promote the formation of a smooth surface. At 100 mL·L−1 of glycerol, the roughness of the tungsten–nickel–iron alloy decreases significantly from 1.134 μm to 0.582 μm. The electrochemical polishing mechanism of the tungsten alloy in a trisodium phosphate electrolyte is further investigated and explained according to viscous film theory. This study demonstrates that the trisodium phosphate–sodium hydroxide–glycerol electrolyte is suitable for electropolishing tungsten–nickel–iron alloys. Overall, the results support the application of tungsten–nickel–iron alloy in the electronics, medical, and atomic energy industries. Full article
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20 pages, 1446 KiB  
Article
Astaxanthin from Shrimp By-Products Enhances Oxidative Stability of Lard During Storage
by Olga Draghici
Foods 2025, 14(15), 2585; https://doi.org/10.3390/foods14152585 - 23 Jul 2025
Viewed by 252
Abstract
Previous research has primarily focused on the antioxidant effect of astaxanthin (AX) in various vegetable oils, with limited attention given to its behavior in lard. This study aimed to evaluate the degradation of AX during lard storage and to assess the physicochemical changes [...] Read more.
Previous research has primarily focused on the antioxidant effect of astaxanthin (AX) in various vegetable oils, with limited attention given to its behavior in lard. This study aimed to evaluate the degradation of AX during lard storage and to assess the physicochemical changes occurring in lard containing different AX concentrations over time. The variation in AX concentration was monitored using spectrophotometric analysis. To characterize the changes in lard, both thermal and chemical methods were employed: thermal analysis was used to determine the onset oxidation temperature (To) and activation energy (Ea), while chemical methods included peroxide value (PV) and thiobarbituric acid reactive substance (TBA) assays. Optimization of AX concentration and temporal evaluation of its antioxidant effect were performed using Response Surface Methodology (RSM). The results indicated a significant degradation of AX after 30 days of storage. An AX concentration of approximately 3 mg/g was identified as optimal, as it provided the highest thermal stability and the lowest levels of oxidation markers, offering a well-balanced compromise between technological performance and preservative effectiveness in lard during storage. Additionally, the color of the lard was found to be more strongly influenced by the presence of AX itself rather than by its specific concentration. Full article
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39 pages, 18290 KiB  
Article
Turning Construction, Renovation, and Demolition (CRD) Wood Waste into Biochar: A Scalable and Sustainable Solution for Energy and Environmental Applications
by Aravind Ganesan, Simon Barnabé, Younès Bareha, Simon Langlois, Olivier Rezazgui and Cyrine Boussabbeh
Energies 2025, 18(15), 3902; https://doi.org/10.3390/en18153902 - 22 Jul 2025
Viewed by 357
Abstract
This study investigates the pyrolysis of construction, renovation, and demolition (CRD) wood waste to produce biochar, with a focus on its robustness, scalability, and characterization for energy and environmental applications. Pyrolysis conditions, including the temperature, biomass residence time (BRT), and feedstock mass, were [...] Read more.
This study investigates the pyrolysis of construction, renovation, and demolition (CRD) wood waste to produce biochar, with a focus on its robustness, scalability, and characterization for energy and environmental applications. Pyrolysis conditions, including the temperature, biomass residence time (BRT), and feedstock mass, were varied to evaluate their effects on biochar properties. High-temperature biochars (B800) showed the highest fixed carbon (FC) (87%) and thermostable fraction (TSF) (96%) and the lowest volatile carbon (VC) (9%), with a high carbon content (92%), a large BET surface area (300 m2/g), and a high micropore volume (0.146 cm3/g). However, the hydrogen (0.9%) and oxygen (2.2%) content, Van-Krevelen parameters (H/C: 0.1; O/C: 0.02), and biochar yield (21%) decreased with increasing temperature. Moderate-temperature biochars (B600) have balanced physicochemical properties and yields, making them suitable for adsorption applications. Methyl orange dye removal exceeded 90% under the optimal conditions, with B600 fitting well with the Freundlich isotherm model (R2 = 0.97; 1/n = 0.5) and pseudo-second-order kinetic model (R2 = 1). The study highlights biochar’s suitability for varied applications, emphasizing the need for scalability in CRD wood pyrolysis. Full article
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20 pages, 4023 KiB  
Article
Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
by Xing Hu, Hu Xu, Chenglin Ding, Yupeng Tian and Kuo Yang
Batteries 2025, 11(7), 280; https://doi.org/10.3390/batteries11070280 - 21 Jul 2025
Viewed by 444
Abstract
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics [...] Read more.
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics equations such as Fick’s law, Ohm’s law, and the Butler–Volmer equation, to resolve coupled electrochemical and thermal dynamics, with temperature-dependent parameters calibrated via the Arrhenius equation. Simulations under varying discharge rates reveal that high-rate discharges exacerbate internal heat accumulation. Low ambient temperatures amplify polarization effects. Forced convection cooling reduces surface temperatures but exacerbates core-to-surface thermal gradients. Structural optimization strategies demonstrate that enhancing through-thickness thermal conductivity reduces temperature differences. These findings underscore the necessity of balancing energy density and thermal management in lithium-ion battery design, proposing actionable insights such as preheating protocols for low-temperature operation, optimized cooling systems for high-rate scenarios, and material-level enhancements for improved thermal uniformity. Full article
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18 pages, 4607 KiB  
Article
Multi-Objective Machine Learning Optimization of Cylindrical TPMS Lattices for Bone Implants
by Mansoureh Rezapourian, Ali Cheloee Darabi, Mohammadreza Khoshbin and Irina Hussainova
Biomimetics 2025, 10(7), 475; https://doi.org/10.3390/biomimetics10070475 - 18 Jul 2025
Viewed by 546
Abstract
This study presents a multi-objective optimization framework for designing cylindrical triply periodic minimal surface (TPMS) lattices tailored for bone implant applications. Using an artificial neural network (ANN) as a surrogate model trained on simulated data, four key properties—ultimate stress (U), energy absorption (EA), [...] Read more.
This study presents a multi-objective optimization framework for designing cylindrical triply periodic minimal surface (TPMS) lattices tailored for bone implant applications. Using an artificial neural network (ANN) as a surrogate model trained on simulated data, four key properties—ultimate stress (U), energy absorption (EA), surface area-to-volume ratio (SA/VR), and relative density (RD)—were predicted from seven lattice design parameters. To address anatomical variability, a novel implant size-based categorization (small, medium, and large) was introduced, and separate optimization runs were conducted for each group. The optimization was performed via the NSGA-II algorithm to maximize mechanical performance (U and EA) and surface efficiency (SA/VR), while filtering for biologically relevant RD values (20–40%). Separate optimization runs were conducted for small, medium, and large implant size groups. A total of 105 Pareto-optimal designs were identified, with 75 designs retained after RD filtering. SHapley Additive exPlanations (SHAP) analysis revealed the dominant influence of thickness and unit cell size on target properties. Kernel density and boxplot comparisons confirmed distinct performance trends across size groups. The framework effectively balances competing design goals and enables the selection of size-specific lattices. The proposed approach provides a reproducible pathway for optimizing bioarchitectures, with the potential to accelerate the development of lattice-based implants in personalized medicine. Full article
(This article belongs to the Special Issue Biomimicry and Functional Materials: 5th Edition)
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35 pages, 2895 KiB  
Review
Ventilated Facades for Low-Carbon Buildings: A Review
by Pinar Mert Cuce and Erdem Cuce
Processes 2025, 13(7), 2275; https://doi.org/10.3390/pr13072275 - 17 Jul 2025
Viewed by 643
Abstract
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding [...] Read more.
The construction sector presently consumes about 40% of global energy and generates 36% of CO2 emissions, making facade retrofits a priority for decarbonising buildings. This review clarifies how ventilated facades (VFs), wall assemblies that interpose a ventilated air cavity between outer cladding and the insulated structure, address that challenge. First, the paper categorises VFs by structural configuration, ventilation strategy and functional control into four principal families: double-skin, rainscreen, hybrid/adaptive and active–passive systems, with further extensions such as BIPV, PCM and green-wall integrations that couple energy generation or storage with envelope performance. Heat-transfer analysis shows that the cavity interrupts conductive paths, promotes buoyancy- or wind-driven convection, and curtails radiative exchange. Key design parameters, including cavity depth, vent-area ratio, airflow velocity and surface emissivity, govern this balance, while hybrid ventilation offers the most excellent peak-load mitigation with modest energy input. A synthesis of simulation and field studies indicates that properly detailed VFs reduce envelope cooling loads by 20–55% across diverse climates and cut winter heating demand by 10–20% when vents are seasonally managed or coupled with heat-recovery devices. These thermal benefits translate into steadier interior surface temperatures, lower radiant asymmetry and fewer drafts, thereby expanding the hours occupants remain within comfort bands without mechanical conditioning. Climate-responsive guidance emerges in tropical and arid regions, favouring highly ventilated, low-absorptance cladding; temperate and continental zones gain from adaptive vents, movable insulation or PCM layers; multi-skin adaptive facades promise balanced year-round savings by re-configuring in real time. Overall, the review demonstrates that VFs constitute a versatile, passive-plus platform for low-carbon buildings, simultaneously enhancing energy efficiency, durability and indoor comfort. Future advances in smart controls, bio-based materials and integrated energy-recovery systems are poised to unlock further performance gains and accelerate the sector’s transition to net-zero. Emerging multifunctional materials such as phase-change composites, nanostructured coatings, and perovskite-integrated systems also show promise in enhancing facade adaptability and energy responsiveness. Full article
(This article belongs to the Special Issue Sustainable Development of Energy and Environment in Buildings)
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25 pages, 10123 KiB  
Article
Fabrication of Micro-Holes with High Aspect Ratios in Cf/SiC Composites Using Coaxial Waterjet-Assisted Nanosecond Laser Drilling
by Chenhu Yuan, Zenggan Bian, Yue Cao, Yinan Xiao, Bin Wang, Jianting Guo and Liyuan Sheng
Micromachines 2025, 16(7), 811; https://doi.org/10.3390/mi16070811 - 14 Jul 2025
Viewed by 272
Abstract
In the present study, the coaxial waterjet-assisted nanosecond laser drilling of micro-holes in Cf/SiC composites, coupled with nanosecond laser drilling in air for fabricating micro-holes with high aspect ratios, were investigated. The surface morphology, reaction products, and micro-hole shapes were thoroughly [...] Read more.
In the present study, the coaxial waterjet-assisted nanosecond laser drilling of micro-holes in Cf/SiC composites, coupled with nanosecond laser drilling in air for fabricating micro-holes with high aspect ratios, were investigated. The surface morphology, reaction products, and micro-hole shapes were thoroughly examined. The results reveal that, for the coaxial waterjet-assisted nanosecond laser drilling of micro-holes in the Cf/SiC composite, the increasing of waterjet velocity enhances the material removal rate and micro-hole depth, but reduces the micro-hole diameter and taper angle. The coaxial waterjet isolates the laser-ablated region and cools down the corresponding region rapidly, leading to the formation of a mixture of SiC, SiO2, and Si on the surface. As the coaxial waterjet velocity increases, the morphology of residual surface products changes from a net-like structure to individual spheres. Coaxial waterjet-assisted nanosecond laser drilling, with a waterjet velocity of 9.61 m/s, achieves micro-holes with a good balance between efficiency and quality. For the fabrication of micro-holes with a high aspect ratio in Cf/SiC composites, micro-holes fabricated by nanosecond laser drilling in air exhibit obvious taper features, which should be ascribed to the combined effects of spattering slag, plasma, and energy dissipation. The application of coaxial waterjet-assisted nanosecond laser drilling on micro-holes fabricated by laser drilling in air effectively expands the hole diameter. The fabricated micro-holes have very small taper angles, with clean wall surfaces and almost no reaction products. This approach, combining nanosecond laser drilling in air followed by coaxial waterjet-assisted nanosecond laser drilling, offers a promising technique for fabricating high-quality micro-holes with high aspect ratios in Cf/SiC composites. Full article
(This article belongs to the Special Issue Optical and Laser Material Processing, 2nd Edition)
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23 pages, 5245 KiB  
Article
Machine Learning Reconstruction of Wyrtki Jet Seasonal Variability in the Equatorial Indian Ocean
by Dandan Li, Shaojun Zheng, Chenyu Zheng, Lingling Xie and Li Yan
Algorithms 2025, 18(7), 431; https://doi.org/10.3390/a18070431 - 14 Jul 2025
Viewed by 276
Abstract
The Wyrtki Jet (WJ), a pivotal surface circulation system in the equatorial Indian Ocean, exerts significant regulatory control over regional climate dynamics through its intense eastward transport characteristics, which modulate water mass exchange, thermohaline balance, and cross-basin energy transfer. To address the scarcity [...] Read more.
The Wyrtki Jet (WJ), a pivotal surface circulation system in the equatorial Indian Ocean, exerts significant regulatory control over regional climate dynamics through its intense eastward transport characteristics, which modulate water mass exchange, thermohaline balance, and cross-basin energy transfer. To address the scarcity of in situ observational data, this study developed a satellite remote sensing-driven multi-parameter coupled model and reconstructed the WJ’s seasonal variations using the XGBoost machine learning algorithm. The results revealed that wind stress components, sea surface temperature, and wind stress curl serve as the primary drivers of its seasonal dynamics. The XGBoost model demonstrated superior performance in reconstructing WJ’s seasonal variations, achieving coefficients of determination (R2) exceeding 0.97 across all seasons and maintaining root mean square errors (RMSE) below 0.2 m/s across all seasons. The reconstructed currents exhibited strong consistency with the Ocean Surface Current Analysis Real-time (OSCAR) dataset, showing errors below 0.05 m/s in spring and autumn and under 0.1 m/s in summer and winter. The proposed multi-feature integrated modeling framework delivers a high spatiotemporal resolution analytical tool for tropical Indian Ocean circulation dynamics research, while simultaneously establishing critical data infrastructure to decode monsoon current coupling mechanisms, advancing early warning systems for extreme climatic events, and optimizing regional marine resource governance. Full article
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20 pages, 9491 KiB  
Article
A General Model for Converting All-Wave Net Radiation at Instantaneous to Daily Scales Under Clear Sky
by Jiakun Han, Bo Jiang, Yu Zhao, Jianghai Peng, Shaopeng Li, Hui Liang, Xiuwan Yin and Yingping Chen
Remote Sens. 2025, 17(14), 2364; https://doi.org/10.3390/rs17142364 - 9 Jul 2025
Viewed by 215
Abstract
Surface all-wave net radiation (Rn) is one of the essential parameters to describe surface radiative energy balance, and it is of great significance in scientific research and practical applications. Among various acquisition approaches, the estimation of Rn from satellite [...] Read more.
Surface all-wave net radiation (Rn) is one of the essential parameters to describe surface radiative energy balance, and it is of great significance in scientific research and practical applications. Among various acquisition approaches, the estimation of Rn from satellite data is gaining more and more attention. In order to obtain the daily Rn (Rnd) from the instantaneous satellite observations, a parameter Cd, which is defined as the ratio between the Rn at daily and at instantaneous under clear sky was proposed and has been widely applied. Inspired by the sinusoidal model, a new model for Cd estimation, namely New Model, was proposed based on the comprehensive clear-sky Rn measurements collected from 105 global sites in this study. Compared with existing models, New Model could estimate Cd at any moment during 9:30~14:30 h, only depending on the length of daytime. Against the measurements, New Model was evaluated by validating and comparing it with two popular existing models. The results demonstrated that the Rnd obtained by multiplying Cd from New Model had the best accuracy, yielding an overall R2 of 0.95, root mean square error (RMSE) of 14.07 Wm−2, and Bias of −0.21 Wm−2. Additionally, New Model performed relatively better over vegetated surfaces than over non- or less-vegetated surfaces with a relative RMSE (rRMSE) of 11.1% and 17.89%, respectively. Afterwards, the New Model Cd estimate was applied with MODIS data to calculate Rnd. After validation, the Rnd computed from Cd was much better than that from the sinusoidal model, especially for the case MODIS transiting only once in a day, with Rnd-validated R2 of 0.88 and 0.84, RMSEs of 19.60 and 27.70 Wm−2, and Biases of −0.76 and 8.88 Wm−2. Finally, more analysis on New Model further pointed out the robustness of this model under various conditions in terms of moments, land cover types, and geolocations, but the model is suggested to be applied at a time scale of 30 min. In summary, although the new Cd  model only works for clear-sky, it has the strong potential to be used in estimating Rnd from satellite data, especially for those having fine spatial resolution but low temporal resolution. Full article
(This article belongs to the Special Issue Remote Sensing of Solar Radiation Absorbed by Land Surfaces)
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24 pages, 7448 KiB  
Article
A Novel Approach to Quantitatively Account on Deposition Efficiency by Direct Energy Deposition: Case of Hardfacing-Coated AISI 304 SS
by Gabriele Grima, Kamal Sleem, Alberto Santoni, Gianni Virgili, Vincenzo Foti, Marcello Cabibbo and Eleonora Santecchia
Crystals 2025, 15(7), 626; https://doi.org/10.3390/cryst15070626 - 5 Jul 2025
Viewed by 344
Abstract
Nickel-based coatings have been demonstrated to effectively enhance the surface performance of stainless-steel components. The present study investigates the deposition efficiency and quality of Colmonoy 227-F nickel alloy coatings on AISI 304 stainless steel using direct energy deposition (DED). The work focuses on [...] Read more.
Nickel-based coatings have been demonstrated to effectively enhance the surface performance of stainless-steel components. The present study investigates the deposition efficiency and quality of Colmonoy 227-F nickel alloy coatings on AISI 304 stainless steel using direct energy deposition (DED). The work focuses on the relationships between process parameters, microstructural features, and mechanical properties. A total of sixteen process parameter combinations were studied, varying laser power and scanning speed to establish optimal deposition conditions and to evaluate coating morphology, surface topology, dilution behavior, and mechanical performance. The surface geometry was analyzed using three-dimensional digital confocal microscopy. New material distribution (MD) indices were developed to quantify spatial uniformity and integrity of single coating scan tracks (CSTs) across the XY, XZ, and YZ planes. The optimal process was identified around 900 W laser power, balancing deposition efficiency and structural integrity. Scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) reveal a gradual compositional transition between coating and substrate. The results of the microhardness test demonstrate a consistent gradient in mechanical properties, extending from the coating to the substrate. Coatings were found to achieve a hardness level of up to 600 HK. These findings establish a new benchmark for evaluating DED high-performance coatings and offer a scalable methodology for optimizing additive manufacturing processes in surface engineering applications. Full article
(This article belongs to the Special Issue Recent Advances in Microstructure and Properties of Metals and Alloys)
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18 pages, 7268 KiB  
Article
Effects of Pyrolysis and Activation Conditions on SO2 and NO Adsorption by Biochar and Its Environmental Impact
by Kyungil Cho, Hyeonrok Choi and Yongwoon Lee
Sustainability 2025, 17(13), 6137; https://doi.org/10.3390/su17136137 - 4 Jul 2025
Viewed by 348
Abstract
This study investigates the adsorption performance of biochar synthesized under varying pyrolysis and CO2 activation conditions for the simultaneous removal of nitrogen monoxide (NO) and sulfur dioxide (SO2), with an additional focus on its environmental impacts via life cycle assessment [...] Read more.
This study investigates the adsorption performance of biochar synthesized under varying pyrolysis and CO2 activation conditions for the simultaneous removal of nitrogen monoxide (NO) and sulfur dioxide (SO2), with an additional focus on its environmental impacts via life cycle assessment (LCA). Biochar was produced from Hinoki cypress using a two-stage process comprising initial pyrolysis followed by CO2 activation, and its physicochemical properties were evaluated through pore structure analysis. Adsorption experiments were conducted under both single- and combined-gas conditions to assess the synergistic or competitive behaviors of NO and SO2 adsorption. The results indicated that activation conditions significantly influenced the surface area and pore volume of biochar, leading to enhanced gas adsorption capacities. A trade-off between biochar yield and pollutant removal efficiency was observed, suggesting an optimal activation temperature balancing these two factors. Furthermore, the LCA approach, employing IPCC 2021 GWP 100 metrics, quantified the environmental impacts of biochar production under different thermal conditions. The findings revealed that although higher activation temperatures improved adsorption efficiency, they also resulted in increased energy consumption and associated greenhouse gas emissions. These outcomes demonstrate the necessity of optimizing activation parameters not only for functional performance but also for environmental sustainability. This work provides insight into designing efficient biochar-based gas treatment systems and supports their potential application as eco-friendly alternatives in industrial emission control strategies. Full article
(This article belongs to the Special Issue Biomass Transformation and Sustainability)
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12 pages, 4460 KiB  
Article
Influence of Laser Energy Variation on the Composition and Properties of Gradient-Structured Cemented Carbide Layers Produced by LP-DED
by Yorihiro Yamashita, Kenta Kawabata, Hayato Mori, Eito Ose and Takahiro Kunimine
J. Manuf. Mater. Process. 2025, 9(7), 218; https://doi.org/10.3390/jmmp9070218 - 27 Jun 2025
Viewed by 328
Abstract
In this study, graded cemented carbide layers were fabricated using Laser Powder-Directed Energy Deposition (LP-DED) to investigate the effects of laser input energy and WC content on crack formation, compositional distribution, and hardness. Two-layer structures were formed, with the first layer containing either [...] Read more.
In this study, graded cemented carbide layers were fabricated using Laser Powder-Directed Energy Deposition (LP-DED) to investigate the effects of laser input energy and WC content on crack formation, compositional distribution, and hardness. Two-layer structures were formed, with the first layer containing either 30.5 wt.% or 42.9 wt.% WC and the second layer containing 63.7 wt.% WC. Crack formation was evaluated in situ using acoustic emission (AE) sensors, and elemental composition and Vickers hardness were measured across the cross-section of the deposited layers. The results showed that crack formation increased with higher laser power and higher WC content in the first layer. Elemental analysis revealed that higher laser input led to greater Co enrichment and reduced W content near the surface. Additionally, the formation of brittle structures was observed under high-energy conditions, contributing to increased hardness but decreased toughness. These findings indicate that both WC content and laser energy strongly influence the microstructural evolution and mechanical properties of graded cemented carbide layers. Optimizing the balance between WC content and laser parameters is essential for improving the crack resistance and performance of cemented carbide layers in additive manufacturing applications. Full article
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