Search Results (488)

Bulk metallic glasses exhibit unique viscoplastic flow behavior within their supercooled liquid region. Their high-temperature deformation mechanisms diverge markedly from the highly localized deformation at room temperature. This contrast offers a critical window for investigating their compressive flow models and assessing their forming potential. This study aims to systematically reveal the high-temperature compressive flow behavior of bulk metallic glasses within the supercooled liquid region and to establish a corresponding flow model. Through constant strain rate high-temperature compression experiments conducted on Zr₅₆Co₂₈Al₁₆ bulk metallic glass within its supercooled liquid region, the variations in flow stress, crystallinity, and surface deformation characteristics with temperature were systematically investigated. The results indicate that the compressive behavior of the bulk metallic glass exhibits significant temperature dependence within this temperature range. The compressive strength decreased from 689 MPa at 487 °C to 330 MPa at 507 °C, and then increased to 435 MPa at 527 °C. The angle between the fracture/bulging direction and the loading direction increased from 45° at 487 °C to 88° at 507 °C, and then decreased to 60° at 527 °C. The shear band average spacing increased from 1.797 μm at 487 °C to 2.060 μm at 507 °C, and then decreased to 1.189 μm at 527 °C. These results consistently indicate that the plastic deformability is optimal at a compression temperature of around 510 °C. By integrating the analysis of mechanical curves and morphological characteristics, the applicability of three deformation mechanisms was evaluated: highly localized shear banding, homogeneous viscoplastic flow, and dynamic structural relaxation hardening. A constitutive relationship between compressive strength and temperature was established, which accurately describes their correlation. Simultaneously, it reveals that the dominant deformation mechanism evolves through highly localized shear banding and homogeneous viscoplastic flow, ultimately transforming into dynamic structural relaxation hardening as the temperature increases. This study provides theoretical guidance for predicting the compressive flow behavior of bulk metallic glasses in the supercooled liquid region and offers critical model support for precisely controlling their thermoplastic forming processes. Full article

Cold tolerance of natural enemy insects is a critical determinant of their overwintering survival and efficacy in biological control. The green lacewing (Chrysoperla nipponensis) is an important natural enemy insect that overwinters as adults in nature; however, its high overwintering mortality severely limits its effective application in spring. To investigate the molecular mechanisms underlying low-temperature adaptation, this study focuses on the temperature-sensitive Transient Receptor Potential (TRP) channels and their roles in the cold tolerance of C. nipponensis. The TRPA subfamily gene, Pyrexia-1, was identified and found to be significantly downregulated upon cold exposure. A functional analysis indicates RNAi-mediated knockdown of Pyrexia-1 significantly lowered both the supercooling point and the freezing point of C. nipponensis adults, enhancing their survival rate at −10 °C. These results indicate Pyrexia-1 as a negative regulator of cold tolerance. Further mechanistic investigation revealed that inhibition of Pyrexia-1 function specifically down regulates the expression of trehalase (TRE1) genes, resulting in a marked accumulation of the cryoprotectant trehalose in adults. This metabolic adjustment was accompanied by the upregulation of heat shock protein Hsp70. Overall, these findings establish Pyrexia-1 as a critical molecular switch linking temperature-sensing signals to the metabolic pathways governing freeze resistance, thereby orchestrating the systemic cold adaptation in C. nipponensis. This discovery provides novel insights into the molecular basis of insect low-temperature adaptation and suggests a potential strategy for enhancing the overwintering capacity of natural enemy insects by targeting this regulatory node. Full article

Fresh fish is a highly nutritious and widely consumed product that remains highly perishable due to its chemical composition. Conventional preservation methods, such as chilling and freezing, are effective at inhibiting microbial growth but often compromise nutritional and organoleptic quality. Advanced thermal techniques, including supercooling and cryogenic storage, can extend shelf life to approximately 180 days but involve high infrastructure costs and potential sensory alterations. In response, non-thermal technologies have emerged as promising alternatives capable of minimizing microbial and enzymatic deterioration while reducing oxidative and sensory damage. These include high-pressure processing, cold plasma, gamma irradiation, advanced packaging systems (e.g., modified atmospheres, edible coatings), and natural antioxidants. However, such methods face limitations such as lipid oxidation, flavor changes, and scalability issues, highlighting the need for integrated preservation strategies. This study addresses a critical gap in the application of synergistic, multi-hurdle approaches that combine non-thermal technologies to enhance shelf life without compromising nutritional or sensory quality. It is essential to propose tailored and scalable solutions specific to fishery products to advance the development of sustainable and effective preservation systems that meet the practical needs of the seafood industry. Full article

With the development of polar regions and the deepening utilization of cold region resources, a large number of infrastructure projects are continuously being carried out. The freezing temperature of unsaturated soil is a critical factor governing the freezing depth and stability of foundations in cold regions or seasons. Concurrently, the supercooling state of soil significantly influences the assessment of its phase composition and physico-mechanical properties. This study employed physical experiments, theoretical formulas, and numerical simulations to reveal the influencing factors and underlying mechanisms of supercooling characteristics in unsaturated soils under controlled low-rate continuous cooling conditions. The results demonstrate that a reduced temperature gradient between the sample surface and the ambient environment correlates with a lower supercooling limit temperature and an extended supercooling duration. An excessively high cooling rate suppresses the supercooling phenomenon in the sample core due to boundary effects. In contrast, neither the temperature difference nor the external cooling rate exhibit a negligible influence on the freezing temperature. Analysis of the temperature–time curves reveals that the freezing process of silty clay is more stable, exhibiting fewer stepwise temperature declines during the phase change plateau, whereas mudstone shows heightened sensitivity to variations in the thermal gradient. Compared to conventional thermocouple measurements, the proposed methodology achieves an optimal balance between temporal efficiency and measurement accuracy. It not only enhances experimental controllability and data reliability, but also provides more scientific theoretical support and technical pathways for predicting freezing depth, designing foundation thermal systems, and preventing frozen ground disasters in cold region engineering. Full article

Centorus rufipes (Gebler, 1833) is the only tenebrionid beetle commonly found in late Pleistocene deposits of southern western Siberia. It is assumed that the reasons for its success during the Last Glacial Maximum could have been its cold resistance and/or the relatively mild conditions of its habitat, the shores of salt lakes. The cold resistance parameters of C. rufipes and their overwintering conditions were studied near Kusgan Lake (Novosibirsk Oblast, Russia). Adults and larvae of this species used a supercooling mechanism to protect themselves from sub-zero temperatures and did not tolerate freezing, just like other steppe species of Tenebrionidae. The supercooling point (SCP) for most of the individuals was around −31 °C. Measurements of low lethal temperatures (LLT) showed that 50% of individuals died after 2 days of exposure to −27 °C. The measured SCP and LLT were at least 5 °C lower than darkling beetle species from the Chuya Depression of the Altai, which is known for its extreme winter temperatures. Thus, the hypothesis of increased cold resistance of C. rufipes was confirmed. No warming effect of its salt lakeside habitats was detected. Full article

Ice-jam formation during winter low-flow conditions represents a persistent hydrotechnical hazard in small and medium-sized rivers of Central Europe. Despite extensive monitoring efforts, preventive structural measures remain insufficiently developed and rarely evaluated under real geomorphological constraints. This study proposes and hydraulically verifies a low-profile riverbed sill designed to suppress the initiation and stabilization of frazil and anchor ice during critical winter discharges. The analysis integrates 20 years of hydrological and water-temperature data (2004–2024), 26 detailed cross-sectional surveys, a high-resolution longitudinal profile derived from DMR 3.0, and a newly formulated Ice-Jam Risk Index (Iice) combining flow velocity, depth-to-width ratio and thermal deficit. Application to the Torysa River (rkm 42.8–43.6) revealed a clearly defined high-risk zone (rkm 43.20–43.38), where hydraulic conditions frequently fall below the critical thresholds for ice accumulation (U < 0.35 m·s⁻¹; h/B < (h/B)_crit; ΔT > 0.5 °C), indicating shallow and laterally widened channel sections prone to anchor-ice stabilization. Model simulations demonstrated that the proposed sill increases mean velocity by 22–35% during Q₆₅–Q₈₅ conditions, reducing the local I(ice) by 61%, while preserving the conveyance capacity for discharges above Q₅₀ and avoiding measurable backwater impacts upstream. Field-based morphology, risk index interpolation and hydraulic modeling all confirm that the structure effectively disrupts the formation of stable anchor-ice nuclei, which have historically triggered severe ice-jam floods in this reach (2011/12, 2016/17, 2021/22). The results show that a properly dimensioned low-profile sill provides a passive, low-cost, and transferable engineering solution for winter flood risk mitigation, outperforming reactive ice-management techniques while maintaining ecological and hydraulic compatibility with small natural rivers. The methodology is replicable for other rivers where supercooling, low-flow hydraulics and channel morphology jointly control ice-jam initiation. Full article

This paper analyzes the potential application of Physics-Informed Neural Networks (PINNs) in solving equations that describe thermal–electrical processes in thermoelectric systems. Combining machine learning with the laws of physics, the PINN method can serve as an alternative to traditional numerical methods, particularly in the context of the miniaturization of cooling systems, heat pumps, and systems that convert thermal energy (heat flow) into electrical energy (e.g., heat recovery), as well as the implementation of models in embedded systems. The article presents a model of thermoelectric equations, explains how PINNs work, provides numerical results, and assesses the advantages and disadvantages of the proposed approach. Full article

The water thermodynamics is characterized by polydispersity, which determines its structural and dynamic properties. This is due to the specifics of its characteristic bond: the hydrogen bond (HB). The isobars of the two fundamental thermodynamic functions, the isothermal compressibility ($K_T(P.T)$) and the isobaric expansivity (${\alpha }_P(P,T)$), show the presence of a temperature $T^{*}\simeq 315\pm 5$ K where both have a singular behavior. In this work, by carefully considering the thermal properties of the isobars of density $\rho$, specific heat $C_P$ and the self-diffusion $D_S$, we suggest the universality characteristics of this temperature. In addition, by analyzing the average intermolecular distance $d_{OO}$, in the same area of the P-T phase diagram, we demonstrate that such realities are due in the supercooled liquid state to the ratio between its two characteristic phases: the low-density liquid (LDL due to HB) and the HDL (which entirely characterizes the remaining parts of the phase diagram). Full article

Mixed-phase clouds, in which liquid droplets and ice crystals coexist at temperatures between $-38 °$C and $0 °$C, play a critical role in Earth’s radiation budget. Here, we assess the ability of climate and storm-resolving models to represent mixed-phase cloud properties and their hemispheric contrasts as inferred from satellite observations. We compare observations from the Advanced Very High Resolution Radiometer (AVHRR) and the Moderate Resolution Imaging Spectroradiometer (MODIS) with one global climate model, the Community Atmosphere Model version 6, Oslo configuration (CAM6-Oslo), and three storm-resolving models: the ICOsahedral Non-hydrostatic model (ICON), the Simple Cloud-Resolving E3SM Atmosphere Model (SCREAM), and the Goddard Earth Observing System model (GEOS). Our results show that all models reproduce the geographic distribution of mixed-phase clouds but differ significantly in detail. CAM6-Oslo yields the closest agreement in hemispheric contrasts of supercooled liquid fraction and its relationship with the liquid effective radius. Our results highlight the role of aerosol–cloud interactions and microphysics schemes in determining model performance and demonstrate that storm-resolving models still do not overcome the challenge of representing mixed-phase clouds at global scales. Full article

Polyethylene waxes (PEWs) are considered promising mid-temperature phase change materials (PCMs). However, their low thermal conductivity limits both applicability and efficiency. One of the more interesting inorganic additives for PCMs is boron nitride (BN), which exhibits high thermal conductivity while remaining electrically insulating, excellent chemical and thermal stability, and good oxidation resistance. In this study, PEW was modified with hexagonal boron nitride (h-BN) in the range of 0.025 to 0.5 wt.%. Differential scanning calorimetry (DSC) results revealed that the addition of h-BN significantly alters the phase-transition behavior of polyethylene wax, broadens the melting and solidification temperature ranges, and reduces supercooling from 11 °C to 9 °C. Thermogravimetric analysis (TGA) showed that the incorporation of h-BN improves the thermal stability of the material. The temperature corresponding to 5% mass loss increased by about 50 °C after incorporation of more than 0.025% h-BN. The temperature of maximum mass-loss rate (T_DTGmax) was shifted about 8 °C toward higher temperatures. FTIR results indicate that h-BN does not change the chemical structure of polyethylene waxes, but does affect their morphology and physical properties by increasing the thermal conductivity from 0.30 to 0.40 mW/K. These effects enable the design of composites with tunable properties for energy-storage applications. Full article

Nanoparticle-mediated photothermal conversion exploits the unique light-to-heat transduction properties of engineered nanomaterials to address challenges in energy, water, and healthcare. This review first examines fundamental mechanisms—localized surface plasmon resonance (LSPR) in plasmonic metals and broadband interband transitions in semiconductors—demonstrating how tailored nanoparticle compositions can achieve >96% absorption across 250–2500 nm and photothermal efficiencies exceeding 98% under one-sun illumination (1000 W·m⁻², AM 1.5G). Next, we highlight advances in solar steam generation and desalination: floating photothermal receivers on carbonized wood or hydrogels reach >95% efficiency in solar-to-vapor conversion and >2 kg·m⁻²·h⁻¹ evaporation rates; three-dimensional architectures recapture diffuse flux and ambient heat; and full-spectrum nanofluids (LaB₆, Au colloids) extend photothermal harvesting into portable, scalable designs. We then survey photothermal-enhanced thermal energy storage: metal-oxide–paraffin composites, core–shell phase-change material (PCM) nanocapsules, and MXene– polyethylene glycol—PEG—aerogels deliver >85% solar charging efficiencies, reduce supercooling, and improve thermal conductivity. In biomedicine, gold nanoshells, nanorods, and transition-metal dichalcogenide (TMDC) nanosheets enable deep-tissue photothermal therapy (PTT) with imaging guidance, achieving >94% tumor ablation in preclinical and pilot clinical studies. Multifunctional constructs combine PTT with chemotherapy, immunotherapy, or gene regulation, yielding synergistic tumor eradication and durable immune responses. Finally, we explore emerging opto-thermal nanobiosystems—light-triggered gene silencing in microalgae and poly(N-isopropylacrylamide) (PNIPAM)–gold nanoparticle (AuNP) membranes for microfluidic photothermal filtration and control—demonstrating how nanoscale heating enables remote, reversible biological and fluidic functions. We conclude by discussing challenges in scalable nanoparticle synthesis, stability, and integration, and outline future directions: multicomponent high-entropy alloys, modular photothermal–PCM devices, and opto-thermal control in synthetic biology. These interdisciplinary innovations promise sustainable solutions for global energy, water, and healthcare demands. Full article

Supercooled liquid water (SLW) in mixed-phase clouds significantly influences precipitation efficiency and aviation safety. However, a comprehensive understanding of its vertical structure has been hampered by a lack of sustained, vertically resolved observations over the North China Plain. This study presents the first systematic analysis of SLW vertical distribution and microphysics in this region, utilizing a year-long dataset (2022) from synergistic ground-based instruments in Beijing. Our retrieval approach integrates Ka-band cloud radar, microwave radiometer, ceilometer, and radiosonde data, combining fuzzy-logic phase classification with a liquid water content inversion constrained by column liquid water path. Key findings reveal a distinct bimodal seasonality: SLW primarily occurs at mid-to-upper levels (4–7.5 km) during spring and summer, driven by convective lofting, while winter SLW is confined to lower altitudes (1–2 km) under stable atmospheric conditions. The temperature-dependent occurrence probability of SLW clouds has an annual maximum at −12 °C. The diurnal variation in SLW in summer shows peaks in the afternoon and at night, corresponding to convective cloud activity. Spring, autumn, and winter do not exhibit strong diurnal variations. Retrieved microphysical properties, including liquid water content and droplet effective radius, are consistent with in situ aircraft measurements, validating our methodology. This analysis provides a critical observational benchmark and offers actionable insights for improving cloud microphysics parameterizations in models and optimizing weather modification strategies, such as seeding altitude and timing, in this water-stressed region. Full article

In this study, bulk metallic glasses (BMGs) of Zr₅₆Cu₂₃Al₁₀Ni_11-xTa_x (x = 0, 0.5, 1, 1.5, 2, and 2.5 at.%) were prepared by copper mold suction-casting. The glass-forming ability, mechanical properties, crystallization kinetics, and corrosion resistance of the as-obtained amorphous alloys were all investigated. Experimental results showed enhanced forming ability of amorphous alloys in the presence of small amounts of Ta element. By adding appropriate amounts of Ta, the supercooled liquid region of bulk metallic glass increased from 64 K to 73 K. The critical diameter of the alloy rod at x = 1, 1.5 rose from 5 mm to 6 mm. The addition of Ta also reduced the sensitivity coefficients of the amorphous alloys to the heating rate during crystallization, while other quantities, like Eg, Ex, and Ep, all incremented. Thus, the addition of Ta declined the temperature sensitivity of amorphous alloy systems. This also increased the energy barrier required for atom rearrangement, nucleation and growth, as well as greatly enhancing the stability of the systems. At 2% Ta content, the plastic strain of the amorphous alloy exceeded 2.6%, and yield strength reached 1900 MPa. In sum, the mechanical properties of the amorphous alloys after the addition of Ta element obviously improved when compared to the original alloy. As Ta content raised, the corrosion current densities of BMGs in different corrosion solutions gradually decreased, while the corrosion potential gradually increased. Full article

Organic phase change materials (OPCMs) show immense application potential in solar energy storages owing to high energy storage capacity and latent heat efficiency. However, it is difficult to achieve prolonged energy storage due to the sensitivity of phase change to environmental temperature, and adding other substances will lead to a decrease in total energy density. Herein, azobenzene organic phase change composite (C₁₄Azo-MA) was designed and prepared by doping myristic acid (MA) with an azobenzene derivative (C₁₄Azo) featuring a carbon chain identical to that of the MA matrix. C₁₄Azo-MA was systematically characterized by UV–Visible absorption spectroscopy and differential scanning calorimetry. The results showed that the C₁₄Azo-MA retains the same isomerization properties as the C₁₄Azo dopant. C₁₄Azo-MA, due to its molecular photoisomerization and enhanced intermolecular interactions, establishes a new energy barrier and forms supercooling within C₁₄Azo-MA, thereby allowing the storage of thermal energy below the crystallization temperature of MA. Notably, the C₁₄Azo-MA exhibits a high energy density of 225.08 J g⁻¹, surpassing that of pure MA by 14.42%. This work holds significant potential for solar energy storage applications. Full article

Phase change materials (PCMs) are widely used for thermal energy storage; however, improving their thermal stability and minimizing supercooling effects remain important challenges. This study addresses these issues by synthesizing and characterizing new microencapsulated MCPs (microPCMs) that incorporate beeswax (BW), a sustainable biological source derived from animals, thus reducing the use of paraffins from petroleum resources, as the main material and calcium carbonate (CaCO₃) as the shell to improve overall performance. MicroPCMs with variable shell contents (20%, 40%, 60%, and 80%) were prepared and analyzed using Fourier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), particle size distribution analysis (PES), and differential scanning calorimetry (DSC) to evaluate their structural, morphological, and thermal properties. The results reveal that microPCMs exhibit a spherical morphology and robust core–envelope integrity, with thermal energy storage capacities ranging from 121.39 to 122.22 J/g, compared to 137.62 J/g for pure beeswax. In addition, the composites demonstrated reduced supercooling and stable thermal performance during repeated cyclic tests. This work introduces the use of calcium carbonate shells combined with a natural beeswax core to create environmentally friendly microPCMs with enhanced thermal stability and reduced supercooling, offering a sustainable alternative for efficient thermal energy storage. Full article