Search Results (720)

Analysis of changes in TVOC and VOCs chemical composition or odor characteristics of particleboard before and after decoration treatment with resin-impregnated paper (RIP), polypropylene (PP) film and polyvinyl chloride (PVC) film were studied. The effects of these three decoration treatments on masking or suppressing the release of VOCs and odorants from particleboard were explored. The substances that were covered or suppressed and newly introduced before and after processing were identified to provide a basis for reducing the odor emissions of PVC-, PP- and RIP-decorated particleboard. Taking undecorated particleboard and particleboard treated by three types of decorative materials as research subjects, the air permeability of the three decorative materials was tested using the Gurley Permeability Tester. TVOC emissions from the boards were evaluated using the 1 m³ environmental chamber method. Qualitative and quantitative analyses of the samples were conducted via thermal desorption–gas chromatography–mass spectrometry (TD-GCMS). The contribution of odor substances was determined using odor activity value (OAV). The results indicated that the permeability from high to low was PVC film, PP film and RIP. Compared with undecorated particleboard, the TVOC emissions of PVC-decorated boards decreased by 93%, PP-decorated particleboard by 83% but the TVOC emissions of RIP-decorated particleboard increased by 67%. PP decoration treatment masked or suppressed the release of 20 odor substances but introduced xylene, which can increase potentially the health risks for PP-decorated particleboard. PVC decoration treatment masked or suppressed 19 odor substances, but it introduced 12 new compounds, resulting in an overall increase in TVOC emissions. RIP treatment did not introduce new odor substances. After PP film and RIP treatments, both the variety of VOCs released and the number of key odor-contributing compounds and modifying odorants decreased. In contrast, the number of modifying odorants and potential odorants increased after PVC treatment. VOC emissions were effectively masked or suppressed by three decoration treatments, same as the release of substances contributing to overall odor of particleboard was reduced. Among them, PP and RIP decorative materials demonstrate better effects. Full article

Agriculture is one of the most important sectors of the global economy, but it increasingly faces sustainability challenges in meeting rising food demands. The intensive use of mineral fertilizers not only improves yields, but also causes negative environmental impacts such as increasing greenhouse gas emissions, water eutrophication, and soil degradation. To develop more sustainable solutions, the focus is on organic fertilizers, which are produced using waste and biostimulants such as amino acids. The aim of this study was to develop and characterize liquid nitrogen–calcium–magnesium fertilizers produced by decomposing dolomite with nitric acid followed by further processing and to enrich them with a powdered amino acid concentrate Naturamin-WSP and liquid extracts from digestate, a by-product of biogas production. Nutrient-rich extracts were obtained using water and potassium hydroxide solutions, with the latter proving more effective by yielding a higher organic carbon content (4495 ± 0.52 mg/L) and humic substances, which can improve soil structure. The produced fertilizers demonstrated favourable physical properties, including appropriate viscosity and density, as well as low crystallization temperatures (eutectic points from –3 to –34 °C), which are essential for storage and application in cold climates. These properties were achieved by adjusting the content of nitrogenous compounds and bioactive extracts. The results of the study show that liquid fertilizers enriched with organic matter can be an effective and more environmentally friendly alternative to mineral fertilizers, contributing to the development of the circular economy and sustainable agriculture. Full article

The Yangtze River Delta urban agglomeration, characterized by high population density, an advanced transportation system, and a concentration of industrial activity, is one of the regions severely affected by O₃ pollution in central and eastern China. Using data collected from 251 monitoring stations between 2015 and 2025, this paper analyzed the spatio-temporal variation of 8 h O₃ concentrations and instances of exceedance. On the basis of exploring the influence of meteorological factors on regional 8 h O₃ concentration, the potential source contribution areas of pollutants under the exceedance condition were investigated using the HYSPLIT model. The results indicate a rapid increase in the 8 h O₃ concentration at a rate of 0.91 ± 0.98 μg·m⁻³·a⁻¹, with the average number of days exceeding concentration standards reaching 41.05 in the Yangtze River Delta urban agglomeration. Spatially, the 8 h O₃ concentrations were higher in coastal areas and lower in inland regions, as well as elevated in plains compared to hilly terrains. This distribution was significantly distinct from the concentration growth trend characterized by higher levels in the northwest and lower levels in the southeast. Furthermore, it diverged from the spatial characteristics where exceedances primarily occurred in the heavily industrialized northeastern region and the lightly industrialized central region, indicating that the growth and exceedance of 8 h O₃ concentrations were influenced by disparate factors. Local human activities have intensified the emissions of ozone precursor substances, which could be the key driving factor for the significant increase in regional 8 h O₃ concentrations. In the context of high temperatures and low humidity, this has contributed to elevated levels of 8 h O₃ concentrations. When wind speeds were below 2.5 m·s⁻¹, the proportion of 8 h O₃ concentrations exceeding the standards was nearly 0 under almost calm wind conditions, and it showed an increasing trend with rising wind speeds, indicating that the potential precursor sources that caused high O₃ concentrations originated occasionally from inland regions, with very limited presence within the study area. This observation implies that the main cause of exceedances was the transport effect of pollution from outside the region. Therefore, it is recommended that the Yangtze River Delta urban agglomeration adopt economic and technological compensation mechanisms within and between regions to reduce the emission intensity of precursor substances in potential source areas, thereby effectively controlling O₃ concentrations and improving public living conditions and quality of life. Full article

Restricting the use of chemical pesticides in forestry requires the search for alternative solutions. These could be volatile organic compounds produced by three investigated species of bacteria (Bacillus amyloliquefaciens (ex Fukumoto) Priest, B. subtilis (Ehrenberg) Cohn and B. thuringiensis Berliner), which inhibit the growth of the pathogen F. oxysporum Schltdl. emend. Snyder & Hansen in forest nurseries. The highest inhibition of fungal growth (70%) was observed with B. amyloliquefaciens after 24 h of antagonism test, which had a higher content of carbonyl compounds (46.83 ± 8.41%) than B. subtilis (41.50 ± 6.45%) or B. thuringiensis (34.62 ± 4.77%). Only in the volatile emissions of B. amyloliquefaciens were 3-hydroxybutan-2-one, undecan-2-one, dodecan-5-one and tetradecan-5-one found. In contrast, the main components of the volatile emissions of F. oxysporum were chlorinated derivatives of benzaldehyde (e.g., 3,5-dichloro-4-methoxybenzaldehyde) and chlorinated derivatives of benzene (e.g., 1,4-dichloro-2,5-dimethoxybenzene), as well as carbonyl compounds (e.g., benzaldehyde) and alcohols (e.g., benzyl alcohol). Further compounds were found in the interactions between B. amyloliquefaciens and F. oxysporum (e.g., $\alpha$-cubebene, linalool, undecan-2-ol, decan-2-one and 2,6-dichloroanisole). Specific substances were found for B. amyloliquefaciens (limonene, nonan-2-ol, phenethyl alcohol, heptan-2-one and tridecan-2-one) and for F. oxysporum (propan-1-ol, propan-2-ol, heptan-2-one and tridecan-2-one). The amounts of volatile chemical compounds found in B. amyloliquefaciens or in the bacterium–fungus interaction can be used for further research to limit the pathogenic fungus. In the future, one should focus on the compounds that were found exclusively in interactions and whose content was higher than in isolated bacteria. In order to conquer an ecological niche, bacteria increase the production of secondary metabolites, including specific chemical compounds. The results presented are a prerequisite for creating an alternative solution or supplementing the currently used methods of plant protection against F. oxysporum. Understanding and applying the volatile organic compounds produced by bacteria can complement chemical plant protection against the pathogen, especially in greenhouses or tunnels where plants grow in conditions that favour fungal growth. Full article

The search for substances that increase the immunity of bees is becoming a necessity in the era of various environmental threats and the declining immunocompetence of these insects. Therefore, we tested the biological and physicochemical properties of 7-diethylamino-4-hydroxycoumarin (7DOC). In a cage test, two groups of bees were created: a control group fed with sugar syrup and an experimental group fed with sugar syrup with the addition of 7DOC. In each group, the longevity of the bees was determined and the protein concentrations and antioxidant activities in the bees’ hemolymph were determined. The bees fed with 7DOC lived 2.7 times longer than those in the control group. The protein concentrations and activities of SOD, CAT, GPx and GST, as well as the TAC levels, were significantly higher in the hemolymph of the supplemented workers. To confirm these potent biological properties of 7DOC, the UV-Vis spectra, emission and excitation of fluorescence, synchronous spectra and finally the fluorescence lifetimes of this compound were measured using the time-correlated single photon counting method, in various environments differing in polarity and in the environment applied in bee research. This compound was shown to be sensitive to changes in solvent polarity. The spectroscopic assays were complemented with crystallographic tests of the obtained monocrystals of the aforementioned compounds, which attested to the aggregation effects observed in the spectra measurements for the selected coumarin. The research results confirm that this compound has the potential to be implemented in apiary management, which will be our application goal, but further research into apiary conditions is required. Full article

Particulate matter (PM), polycyclic aromatic hydrocarbons (PAHs), and heavy metals (HMs) present in polluted air are strongly associated with an increased risk of respiratory diseases. In our study, we grouped cities based on their pollution levels using a method called Ward’s cluster analysis and looked at the increased cancer risk from PM₁₀-bound harmful substances for adult men and women living in Polish cities. The analysis was based on data from 8 monitoring stations where concentrations of PM₁₀, PAHs, and HMs were measured simultaneously between 2018 and 2022. The cluster analysis made it possible to distinguish three separate agglomeration clusters: cluster I (Upper Silesia, Wroclaw) with the highest concentrations of heavy metals and PAHs, with mean levels of lead 14.97 ± 7.27 ng·m⁻³, arsenic 1.73 ± 0.60 ng·m⁻³, nickel 1.77 ± 0.95 ng·m⁻³, cadmium 0.49 ± 0.28 ng·m⁻³, and ∑PAHs 15.53 ± 6.44 ng·m⁻³, cluster II (Warsaw, Łódź, Lublin, Cracow) with dominant road traffic emissions and low emissions, with average levels of lead 8.00 ± 3.14 ng·m⁻³, arsenic 0.70 ± 0.17 ng·m⁻³, nickel 1.64 ± 0.96 ng·m⁻³, and cadmium 0.49 ± 0.28 ng·m⁻³, and cluster III (Szczecin, Tricity) with the lowest concentration levels with favourable ventilation conditions. All calculated ILCR values were in the range of 1.20 × 10⁻⁶ to 1.11 × 10⁻⁵, indicating a potential cancer risk associated with long-term exposure. The highest ILCR values were reached in Upper Silesia and Wroclaw (cluster I), and the lowest in Tricity, which was classified in cluster III. Our findings suggest that there are continued preventive actions and stricter air quality control. The results confirm that PM₁₀ is a significant carrier of airborne carcinogens and should remain a priority in both environmental and public health policy. Full article

Mathematical modeling and computer visualization of hazardous zones of toxic substance cloud spread that occur during different accidents at industrial enterprises located near residential areas are in high demand to support the operational planning of evacuation measures and accident response. The possible chain-like nature of fires and explosions of containers with toxic substances inside increases the importance of predicting changes in hazardous zone parameters in real time. The objective of this study is to develop algorithms for the development of a mathematical model of a hazardous zone during an explosion and fire at an enterprise. The subject of this study is a software tool created for the visualization of hazardous substance emission zones in real time, superimposed onto a development map to determine potential damage to human health and for the operational planning of evacuation measures. The proposed model takes into account variables such as the air temperature, wind speed and direction, the mass of the substance at each explosion and fire site, etc. C# and Visual Studio 2022 languages and an SQL database were used to create a software tool for visualizing the hazardous area. The testing of the calculation model and software used for the visualization of the hazardous zones of toxic substance cloud spread are presented on the basis of explosion cases involving a railway tank containing ammonia and the combustion of polyvinyl chloride at a chemical industry enterprise. The results confirmed the operability of the software and the prospects of its use in regard to the mitigation of the consequences of human-made accidents. Full article

The cement industry, a foundation of global infrastructure development, significantly contributes to environmental pollution. Key sources of pollution include dust emissions; greenhouse gases, particularly carbon dioxide; and the release of toxic substances such as heavy metals and particulate matter. These pollutants contribute to air, water, and soil degradation and are linked to severe health conditions in nearby populations, including respiratory disorders, cardiovascular diseases, and increased mortality rates. Noise pollution is also a significant issue, inducing auditory diseases that affect most workers in cement plants, and disturbing the population living in the neighborhoods and fauna behavior. This review explores the pollution paths and the multifaceted impacts of cement production on the environment. It also highlights the social challenges faced by communities, underscoring the urgent need for stricter environmental policies and the adoption of greener technologies to mitigate the adverse effects of cement production on both the environment and human health. Full article

We quantified the bioactive compounds of Ethiopian coffee (ETH), spent coffee grounds SCGs from ETH (SCG-ETH), and mixed SCGs (SCG-MIX) prepared by filtration methods and investigated the effect of SCG-ETH on ruminal fermentation as well as the anthelmintic activity of ETH. Three substrates, meadow hay (MH)-barley grain (MH-BG), MH-SCG-ETH, and BG-SCG-ETH (1:1 w/w), were fermented using an in vitro gas production technique. The bioactive compounds were quantitatively analyzed using ultra-high-resolution mass spectrometry. We performed an in vitro larval development test to determine the anthelmintic effect of an aqueous extract of ETH against the gastrointestinal nematode (GIN) Haemonchus contortus. The total content of bioactive compounds was highest in SCG-ETH, followed by SCG-MIX and ETH (35.2, 31.2, and 20.9 mg/g dry matter, respectively). Total gas and methane production (p < 0.001) were decreased by both MH-SCG-ETH and BG-SCG-ETH. The in vitro digestibility of dry matter was higher for MH-SCG-ETH and BG-SCG-ETH than for MH-BG. The aqueous ETH extract exhibited a strong larvicidal effect, with a mean lethal dose of 13.2 mg/mL for 50% mortality and 31.9 mg/L for 99% mortality. SCG substrates have the potential to modulate ruminal fermentation and serve as a source of anthelmintic bioactive compounds against GINs in ruminants. Full article

Environmental xenobiotics, including heavy metals, endocrine-disrupting chemicals (EDCs), pesticides, air pollutants, nano- and microplastics, mycotoxins, and phycotoxins, are widespread compounds that pose significant risks to human health. These substances, originating from industrial and agricultural activities, vehicle emissions, and household products, disrupt cellular homeostasis and contribute to a range of diseases, including cancer and neurodegenerative diseases, among others. Emerging evidence indicates that epigenetic alterations, such as abnormal deoxyribonucleic acid (DNA) methylation, aberrant histone modifications, and altered expression of non-coding ribonucleic acids (ncRNAs), may play a central role in mediating the toxic effects of environmental xenobiotics. Furthermore, exposure to these compounds during critical periods, such as embryogenesis and early postnatal stages, can induce long-lasting epigenetic alterations that increase susceptibility to diseases later in life. Moreover, modifications to the gamete epigenome can potentially lead to effects that persist across generations (transgenerational effects). Although these modifications represent significant health risks, many epigenetic alterations may be reversible through the removal of the xenobiotic trigger, offering potential for therapeutic intervention. This review explores the relationship between environmental xenobiotics and alterations in epigenetic signatures, focusing on how these changes impact human health, including their potential for transgenerational inheritance and their potential reversibility. Full article

Volcanic eruptions release gases and particulates that may adversely affect human health. The Tajogaite eruption on La Palma provided a unique opportunity to evaluate inorganic pollutant exposure in a directly affected population. As part of the ISVOLCAN study, blood samples from 393 adults residing in the island’s western region were analyzed for 43 inorganic elements using Inductively Coupled Plasma Mass Spectrometry (ICP-MS), including 20 toxic elements identified by the Agency for Toxic Substances and Disease Registry (ATSDR). The median age of participants was 51 years, and 56.7% were female. Higher levels of Hg and Mn were associated with long-term occupational exposure, while smoking was linked to elevated Cd, Pb, and Sr levels. Participants living within 6.5 km of the volcano had significantly higher concentrations of Al and Ti. Ash cleanup activities were associated with increased levels of Ni and Cu, and those spending over five hours outdoors daily showed elevated Se and Pb. This is the first biomonitoring study to assess blood concentrations of inorganic pollutants in a population exposed to volcanic emissions. The findings highlight key exposure factors and underscore the need for continued research to assess long-term health effects and inform public health measures. Full article

While natural grass has been a reliable recreational surface for decades, artificial turf has gained popularity due to its durability, supposed ability to save water, and lower associated costs for municipalities and schools. Growing environmental and health concerns associated with artificial turf have prompted a necessary comparison of the environmental impact, chemical exposure, injury rates, surface heat, and costs of turf with natural grass. The township of Verona, New Jersey, engaged the PSEG Institute for Sustainability Studies’ Green Teams Program interns to perform an environmental impact assessment, literature review, and cost–benefit analysis to determine if the township should restore an aging artificial turf field in the town to natural grass. The environmental impact assessment revealed concerns regarding artificial turf’s high emission profile, microplastic pollution, lack of permeability, and the presence of per- and polyfluoroalkyl substances (PFAS). Natural grass’ high water usage was also identified as a drawback. The literature review revealed safety concerns of artificial turf regarding temperature disparities and no conclusive results regarding differences in overall injury rates. The artificial turf field in this case study was 182% hotter than the natural grass field when measured by an infrared thermometer during mid-day readings in June. The cost–benefit analysis revealed that natural grass offers a lower long-term expense over a 25-year period. Artificial turf has many benefits; however, natural grass was the recommended option when considering environmental sustainability, reduced chemical exposure, lower surface temperatures, and overall cost. The conclusions may further inform policy decisions and support the adoption of environmentally responsible and health-centered practices for sports fields across municipalities in New Jersey and beyond. Full article

Transportation is a major contributor to air pollution, with vehicles emitting around 65% of manmade hydrocarbons, 64% of carbon monoxide, and 40% of nitrogen oxides. These pollutants harm the environment, human health, and materials. With vehicle populations expected to reach 1.3 billion by 2030, emissions will only worsen. This project focuses on enhancing the efficiency of catalytic converters, which help convert harmful tailpipe emissions like unburned hydrocarbons and CO into less harmful substances (CO₂ and H₂O). Using a selective catalyst alongside a catalytic converter, the study aims to significantly reduce toxic emissions from traditional IC engine vehicles. Full article

In this study, a large portion of data on the chemical composition of precipitation falling in the South Baikal region shows the main factors determining their formation in 2017–2024. Taking into account the high variability of meteorological conditions in the region, both in time and in space, a method of observing the chemical composition of atmospheric precipitation has been developed, which makes it possible to determine its composition depending on the conditions of air mass formation. Using statistical analysis, marker substances characterizing the main groups of sources influencing the composition of atmospheric precipitation were identified. Joint analysis of air mass trajectories and data on chemical composition of precipitation allowed for establishing the areas of location of potential sources of precipitation pollution. All precipitation events were categorized based on the similarity of air mass formation conditions and chemical composition. Precipitation composition data collected on the shores of Lake Baikal reflect the influence of different types of pollutants such as industrial emissions, motor vehicles, dust storms, and forest fires. The results of the study are relevant for air quality assessment in the region and demonstrate the potential of using precipitation chemistry data to understand the long-range transport of pollutants, which contributes to sustainable development by increasing the availability of air quality data in ecologically significant regions such as Lake Baikal. Full article

Pollen allergies represent a growing public health concern that necessitates enhancements to the network of instruments and modeling calculations in order to facilitate a more profound comprehension of pollen transportation. The Beenose instrument quantifies the light scattered by particles that traverse a laser beam at four angles. This methodology enables the differentiation of pollen particles from other particulate matter, predominantly mineral and carbonaceous in nature, thereby facilitating the retrieval of pollen concentrations. The Beenose instrument has been installed on the tourist balloon known as “Ballon de Paris” in a large park situated in the southwest of Paris, France. The measurement period is from April to November 2024, coinciding with the pollen seasons of trees and grasses. The balloon conducts numerous flights per day, reaching an altitude of 150 m when weather conditions are conducive, which occurs approximately 58% of the time during this period. The data are averaged to produce vertical profiles with a resolution of 30 m. Concentrations of the substance decrease with altitude, although a secondary layer is observed in spring. This phenomenon may be attributed to the presence of emissions from a proximate forest situated at a higher altitude. The average decrease in concentration of 11 ± 8% per 10 m is consistent with the findings of previous studies. The long-term implementation of Beenose measurements on this tourist balloon is intended to enhance the precision of the results and facilitate the differentiation of the various parameters that can influence the vertical transportation of pollen. Full article