Search Results (91)

In most African countries, supplementary cementitious materials (SCMs), such as silica fume, slag, and fly ash, are scarce, creating a need for alternative low-clinker cement that utilises locally abundant resources. Given the limited availability of SCMs, the development of Limestone Calcined Clay Cement (LC³) has emerged as an attractive solution. LC³ is a blended binder composed of ground limestone, calcined kaolinite clay, and ordinary Portland cement clinker. This research assessed the mechanical and durability properties of LC³ binders formulated using raw materials obtained from selected deposits in Tanzania. Two samples of clay from the Pugu deposit were selected: Pugu hard clay (PH) and Pugu soft clay (PS). Limestone and gypsum were sourced from Dar es Salaam. LC³ mixes containing 58% CEM I/42.5N were produced and used to make concrete with a water/binder ratio of 0.4. Two control mixes were made, a mix with 100% Portland cement CEM I/42.5 N and a mix with 100% Portland pozzolana CEM II/P-B 42.5 N. In addition, four concrete mixes were designed for the study: LC³-PH, LC³-PS, CEM I + PH (CC-PH), and CEM I + PS (CC-PS). The mechanical properties evaluated included compressive strength, splitting tensile strength, and flexural strength, whilst durability performance was assessed through sulfuric acid resistance, water sorptivity, and absorption. The results demonstrated the superiority of LC³ concrete compared to CEM I and CEM II concretes. For instance, the LC³-PS mix achieved a 90-day compressive strength of 63 ± 2.1 MPa, compared with 62 ± 1.8 MPa for CEM I. Similarly, water absorption was 1.35% and 1.1% for CEM I and LC³ concretes, respectively. Under sulfuric acid exposure, LC³ concrete exhibited the lowest mass loss (1.6%) and strength loss (17.9%) compared with 2.4% and 23% for CEM I and 2.1% and 21% for CEM II, respectively. The enhanced performance of LC³ concrete was attributed to its denser and more refined microstructure, which reduced pore connectivity and improved resistance to the ingress of aggressive agents. Full article

Lithium is an essential material for lightweight batteries. Traditional mining of soluble salts expanded to include the extraction of hard rocks, which requires their solubilization through roasting. Among hard lithium rocks, spodumene has recently received attention from the scientific community. Its metallurgical processing can be classified according to the type of reagents, as well as the operating temperature and pressure. The use of calcium carbonate as a natural alkali avoids aggressive chemicals such as sulfuric acid or caustic soda. In this article, 0.5 g of jewelry-grade spodumene was loaded into a ceramic crucible with 2.5 g of reducing agent in a tandem of roasting at 1050 °C-1 bar-30 min and leaching with neutral water at 90 °C-1 bar-20 min at a water/clinker mass ratio of 25. Measurements by XRD, ICP-OES, and SEM-EDX suggest a pathway of spodumene cracking because of poor contact with the reductant. Potassium present in the crucible acts as a flux and encapsulates spodumene crystals, causing lithium to end up bound to silica. While lithium metasilicate is barely soluble in water, leaching potassium aluminate hoards in the liquid. The empirical observations were supported with thermodynamic spontaneity studies, which required compiling the mineral properties based on open reference tabulations. Full article

The decomposition of silicates in sulfuric acid to extract rare earth elements (REE) is typically characterized by the formation of an amorphous silica layer surrounding the receding crystal that may act as a passivation barrier limiting the rate of mineral dissolution. In this context, sulfuric acid treatment experiments coupled with detailed characterization of the evolution of the decomposition reaction were performed on natural allanite (CaREEAl₂Fe²⁺Si₃O₁₁O[OH]), as well as synthetic neodymium disilicate (Nd₂Si₂O₇), orthosilicate (Ca₂Nd₈(SiO₄)₆O₂), and orthophosphate (NdPO₄) phases in order to investigate if there are key factors, operating on a wide range of silicates, that negatively impact REE recovery. While, as expected, the acid strength is the driver in promoting the decomposition of the orthophosphate, for the silicates investigated, no matter their crystalline structure and chemical resistance, there is a severe passivation mechanism at play in concentrated H₂SO₄. However, in all cases, this effect can be minimized by water dilution, which strongly enhances sulfate-forming cation transfer across the produced amorphous silica layer. Taking into consideration this distinct characteristic of the mode of decomposition of silicates in sulfuric acid should help in defining optimal extraction strategies. Full article

SiO₂ is a versatile inorganic substance with a wide spectrum of applications in areas such as fuel cells. In this study, pristine (p-SiO₂) and sulfonated silica (s-SiO₂) particles were synthesised using the sol–gel and Stober methods. Furthermore, this study investigated the impact of calcination time and surface changes on the morphology, and hence functionality, of silica particles synthesised as potential fuel cell membrane additives. Tetraethyl orthosilicate (TEOS) was used as a silica precursor dissolved in water, with sulfuric acid serving as the sulfonation agent. Parametric data on particle morphology, such as particle size, porosity, total surface area, and agglomeration, were measured and evaluated using BET, Fourier-transform infrared (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The amorphous nature of silica particles was confirmed by XRD analysis. The BET outcome data acquired for the synthesised silica particles were a surface area ranging from 271 to 487 m²/g, a pore diameter of 12.10–21.02 nm, and a total pore volume of 0.76–1.58 cm³/g. These data give crucial characteristics for designing appropriate silica nanofillers for hybrid fuel cell membranes. As a result, the data gathered can be used to make future decisions about silica synthesis methods for various specific applications, such as fuel cell applications. Full article

The booming new energy industry has fueled a surge in global lithium demand, with the annual demand for lithium carbonate (Li₂CO₃) equivalent (LCE) projected to reach 11.2 million tons by 2050. As a key raw material for lithium extraction, spodumene generates approximately 10–15 tons of lithium slag per ton of lithium carbonate (Li₂CO₃) produced. However, the comprehensive utilization rate of lithium slag in China remains below 30%, and most of it is disposed of through landfilling, posing soil pollution risks. This review summarizes the main lithium extraction processes from spodumene: the sulfuric acid method (with a lithium recovery rate of over 96% but high acid consumption); alkali processes (achieving 96%–99% lithium recovery and featuring low equipment corrosion, yet with untested applicability to low-grade ores); salt roasting (simplifying purification processes but only achieving ~60% sulfate recovery); and chlorination roasting (with a lithium recovery rate of over 95% but requiring strict safety controls). Additionally, this review covers the resource utilization of lithium slag: 8–10 million tons of gypsum can be recovered annually (filling 16%–20% of China’s industrial by-product gypsum supply gap); the silica–alumina micro-powder can enhance concrete strength and reduce glass fiber production costs; and over 94% of tantalum (Ta) and niobium (Nb) can be recovered from fine tantalite concentrate slag. Key research gaps and future development directions are also identified to support the low-carbon development of the lithium industry. Full article

Serpentinite rocks and their processing waste represent a valuable source of magnesium and silicon; however, their complex composition complicates the efficient recovery of individual components. This study investigates the combined acid–alkali processing of serpentinite waste from the Zhitikara deposit (Kazakhstan). In the acid leaching stage, sulfuric acid enables magnesium extraction, while subsequent treatment with sodium hydroxide (NaOH) facilitates the selective recovery of silica gel formed during acid attack. At the final neutralization step, amorphous silica is precipitated with a yield exceeding 60% of its initial content. The obtained silica was characterized using FTIR spectroscopy, X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive spectroscopy (SEM-EDS), inductively coupled plasma mass spectrometry (ICP-MS, Thermo iCAP-Q), and nitrogen adsorption measurements via the BET method. It was established that the synthesized silica gel, according to the IUPAC classification, belongs to mesoporous materials, possesses a well-developed specific surface area (400 m²·g⁻¹), and is suitable for adsorption and catalytic applications. Full article

Natural sand extraction for concrete manufacturing is a global issue for ecological balance and environmental concerns. This study introduced three mixes with three newly developed sand types to replace natural sand in concrete manufacturing. Additionally, three more mixes were made by incorporating optimized 10% silica fume. The durability of the prepared mixes was evaluated at high temperatures of (150–750 °C) at the interval of 150 °C and against immersion in a 5% sulfuric acid solution for 28, 56, 91, and 182 days, respectively. The study’s results reported the stability of the samples up to 300 °C, and then the fall of the samples started at 450 °C. Severe damage in the samples was formed at about 600 °C, and finally, a total collapse was seen at 750 °C. From (150 to 750 °C), the mix TYPE-3SSFC with a sustainable sand combination (50% recycled sand + 45% desert sand + 5% crumb rubber) and 10% silica fume showed better resistance than the other mixes. The compressive strength in the mix TYPE-3SSFC was 20.6%, 16.3%, 14.7%, 21.3%, 26.5%, and 43.2% higher than the mix TYPE-3SC with 10% silica fume. The mix TYPE-3SSFC with optimized 10% silica fume content showed better resistance against 5% sulfuric acid solution than those without silica fume. By morphological analysis, the mix TYPE-3SSFC showed that the interface improved due to the dense interconnectivity of the concrete mix between the crumb rubber paste and silica fume content. A dense calcite crystal was also seen in the mixture, which confirmed the study’s results. The mix with TYPE 2-Sand (100% recycled sand) revealed inferior results, low stability, and high damage. Thus, 100% recycled sand is not recommended for structural concrete. Full article

Modified sulfur cake is a by-product of sulfuric acid and hydrometallurgical processes, and presents an underutilized resource in sustainable infrastructure with significant potential. This review evaluates the current technological innovations as pertaining to the use of modified sulfur cake in the manufacture of sulfur concrete and sulfur-modified bitumen. The processing strategies (thermal, chemical, and mechano-chemical processing, and effects of organic and inorganic additives to promote mechanical, chemical, and thermal behaviors) are discussed systematically. The effect of the modified sulfur cake on the workability, compressive strength, corrosion resistance, and environmental resistance of construction materials, in particular, is tested, with compression strengths beyond 40 MPa being reported, alongside the improved rutting resistance up to 40%. The most critical limitations associated with phase instability, toxic gas release during processing, compositional variability, and the absence of standardization are identified. Correspondingly, to alleviate them, new developments such as blends with sulfur, nano-reinforcements (e.g., carbon nanotubes (CNT), nano-silica), and the incorporation of formulation optimization by machine-learning are considered. The review particularly focuses on the life cycle performance, reduction in volatile organic compounds (VOC) emissions, and circular economy advantages, highlighting modified sulfur cake as an economical and low-carbon alternative to conventional concrete and bitumen. This review mainly aims to bridge the gap between waste valorization and green construction technologies, offering a roadmap for future research and industrial implementation in line with global climate and sustainability goals. Full article

Compared with vanadium extraction by sodium roasting followed by water leaching, the calcification roasting–sulfuric acid leaching method is considered a promising approach for the comprehensive utilization of vanadium titanomagnetite, as it avoids the introduction of alkali metals. However, during vanadium extraction by sulfuric acid heap leaching, the diffusion of leaching reagents and leaching products was hindered by the deposition of leaching solid products. To address this issue, this study systematically investigated the leaching kinetics and the mechanisms underlying the deposition of leaching solid products. The results indicated that vanadium leaching was governed by a combination of liquid film diffusion and internal diffusion through solid-phase products during days 0–2, and by internal diffusion alone from day 2 to day 9. The primary solid products formed during leaching were calcium sulfate and silica gel. Calcium sulfate precipitated and grew within the pore via two-dimensional nucleation, while silicates formed silica gel through dehydration. By optimizing the sulfuric acid leaching conditions—specifically, maintaining an H⁺ concentration of 2 mol/L, a leaching temperature of 40 °C, and a liquid-to-solid ratio of 5:1—the formation of calcium sulfate and silica gel was effectively suppressed. Under these conditions, the vanadium leaching efficiency reached 75.82%. Full article

This study investigates the effects of sodium sulfate (Na₂SO₄) dosage, reaction temperature, and processing time on the structural decomposition of complex compounds in copper slag. Experimental results demonstrated that applying 20% Na₂SO₄ achieves an impressive decomposition rate of 89%, highlighting its effectiveness in liberating valuable metals from the slag matrix. The optimal temperature for maximizing fayalite decomposition is determined to be 900 °C, which significantly enhances reaction kinetics and efficiency. Furthermore, extending the reaction time to 90 min resulted in the highest observed decomposition efficiency. Subsequent leaching experiments in sulfuric acid confirmed that the liberated metal transitioned into the solution phase was very effective, ensuring high metal recovery rates. The treated samples demonstrated metal recovery rates of 97% for copper (Cu), 96% for iron (Fe), and 93% for zinc (Zn). In contrast, the untreated samples exhibited considerably lower recovery rates, with copper at 61%, iron at 59%, and zinc at 65%. Additionally, this approach mitigates filtration challenges by preventing the formation of silica gel. These findings provide key operational parameters for optimizing metal recovery from copper slag and establish a solid foundation for advancing sustainable and efficient resource extraction research. Full article

Although 3D-printed concrete (3DPC) offers advantages such as faster construction, reduced labour costs, and minimized material waste, concerns remain about its long-term durability. This review examines these challenges by assessing how the unique layer-by-layer manufacturing process of 3DPC influences key material properties and overall durability. The formation of interfacial porosity and anisotropic microstructures can compromise structural integrity over time, increasing susceptibility to environmental degradation. Increased porosity at layer interfaces and the presence of shrinkage-induced cracking, including both plastic and autogenous shrinkage, contribute to reduced durability. Studies on freeze–thaw performance indicate that 3DPC can achieve durability comparable to cast concrete when proper mix designs and air-entraining agents are used. Chemical resistance, particularly under sulfuric acid exposure, remains a challenge, but improvements have been observed with the inclusion of supplementary cementitious materials such as silica fume. In addition, tests for chloride ingress and carbonation reveal that permeability and resistance are highly sensitive to printing parameters, material composition, and curing conditions. Carbonation resistance, in particular, appears to be lower in 3DPC than in traditional concrete. This review highlights the need for further research and emphasizes that optimizing mix designs and printing processes is critical to improving the long-term performance of 3D-printed concrete structures. Full article

This study evaluated the odor mitigation potential of rice husk biochar in a simulated dairy bedded pack over 21 days. Biochar was incorporated into a dairy manure–sawdust mixture at 5% and 10% dry weight. Emissions of key odorous compounds—ammonia (NH₃), sulfur compounds, volatile fatty acids, phenol, p-cresol, and indole—were evaluated. Odor units were assessed to determine perceived odor reduction. Biochar significantly reduced NH₃ and dimethyl sulfide (DMS) emissions: NH₃ by 27% and 43%, and DMS by 53% and 75%, at 5% and 10% application, respectively. The NH₃ reduction was attributed to ammoniacal nitrogen adsorption, while the DMS reduction likely resulted from enhanced air permeability suppressing anaerobic bacterial activity. The 5% biochar treatment, achieving 63% and 70% of the NH₃ and DMS reductions attained by the 10% treatment, respectively, offers a more practical and cost-effective option. Other odorous compounds were not significantly affected. A temporary reduction in odor units was observed on day 7. Rice husk biochar contains 14.5% atomic Si, primarily as silica, which supports structural stability but hinders pore development, reducing adsorption efficiency. These findings demonstrate the importance of biochar’s physicochemical properties in odor mitigation. Future research should evaluate long-term field performance, microbial interactions, and silica modification strategies. Full article

We present a corrosion-resistant quadrupole ion trap mass spectrometer (QIT-MS) for the direct detection of biosignature gasses in chemically reactive planetary atmospheres, such as Venusian clouds. The system employs a Paul trap with hyperbolic titanium alloy electrodes and alumina spacers for chemical durability and precise ion confinement. An yttria-coated iridium filament serves as the thermionic emitter within a modular electron gun capable of axial and radial ionization. Analytes are introduced through fused silica capillaries and crescent inlets into a miniature pressure cell. The testbed integrates high-voltage RF electronics, pressure-regulated sample delivery, and FPGA-based control for real-time tuning. Continuous operation in 98% sulfuric acid vapor for over three months demonstrated no degradation in emitter or sensor performance. Mass spectra revealed H₂SO₄ fragmentation and thermally induced decomposition up to 425 K. Spectral variations with filament current and electron energy highlight thermal and electron-induced dissociation dynamics. Operational modes include high-resolution scans and selective ion ejection (e.g., CO₂⁺, N₂⁺) to enhance the detection of PH₃⁺, H₂S⁺, and daughter ions. The compact QIT-MS platform is validated for future missions targeting corrosive atmospheres, enabling in situ astrobiological investigations through the detection of biosignature gasses such as phosphine and hydrogen sulfide. Full article

This study explores both pyrometallurgical and hydrometallurgical methods for decarbonizing and recovering valuable metals from bauxite residue, with hydrogen plasma reduction and direct acid leaching as the primary approaches. The goal is to offer innovative techniques for extracting metals from bauxite residue, a by-product of the Bayer process, which cannot be disposed of in an environmentally sustainable manner. Additionally, reducing the volume of bauxite residue through combined treatments is a key objective. In contrast to traditional carbon-based reductive melting, which generated significant CO₂ emissions, hydrogen is now being investigated as a cleaner alternative. Through hydrogen plasma reduction, approximately 99.9% of iron is recovered as crude metallic iron, which can be easily separated from the slag containing other valuable metals. Thermochemical analysis was used to predict slag formation and chemical analysis of slag during hydrogen reduction. To further recover metals like aluminum and titanium, the slag is subjected to sulfuric acid leaching under high-pressure of oxygen in an autoclave avoiding silica gel formation. The results demonstrated a leaching efficiency of 93.21% for aluminum and 84.56% for titanium, using 5 mol/L sulfuric acid at 150 °C, with almost complete iron recovery. Assisted ultrasound leaching of slag with sulphuric acid under atmospheric pressure leads to 54% leaching efficiency of titanium. Full article

The siliceous precursor was hydrolyzed from tetraethylorthosilicate (TEOS) under acidic conditions, followed by the addition of sodium aluminate and sodium hydroxide. Y zeolite was subsequently obtained through hydrothermal crystallization under alkaline conditions. Key synthesis parameters, including reactant molar ratios, crystallization temperature, and time, were systematically varied to optimize the synthesis conditions. The synthesized products were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), nitrogen adsorption analysis, and inductively coupled plasma (ICP) elemental analysis. Well-crystallized Y zeolite with a silica-alumina ratio (SAR) of 5.55 was successfully synthesized via TEOS hydrolysis catalyzed by sulfuric acid at a low crystallization temperature of 85 °C. The catalytic performance of benzyl phenyl ether, a lignin model compound, over NiY catalyst was evaluated in a high-pressure reactor. The results indicate that the catalytic efficiency of Y zeolite synthesized using TEOS as the silicon source under acidic hydrolysis conditions is significantly superior to Y zeolite prepared using alkaline silica sol as the silicon source. Full article