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Search Results (1,487)

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Keywords = safe transportation

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21 pages, 2608 KiB  
Review
Recent Progress on the Research of 3D Printing in Aqueous Zinc-Ion Batteries
by Yating Liu, Haokai Ding, Honglin Chen, Haoxuan Gao, Jixin Yu, Funian Mo and Ning Wang
Polymers 2025, 17(15), 2136; https://doi.org/10.3390/polym17152136 - 4 Aug 2025
Viewed by 265
Abstract
The global transition towards a low-carbon energy system urgently demands efficient and safe energy storage solutions. Aqueous zinc-ion batteries (AZIBs) are considered a promising alternative to lithium-ion batteries due to their inherent safety and environmental friendliness. However, conventional manufacturing methods are costly and [...] Read more.
The global transition towards a low-carbon energy system urgently demands efficient and safe energy storage solutions. Aqueous zinc-ion batteries (AZIBs) are considered a promising alternative to lithium-ion batteries due to their inherent safety and environmental friendliness. However, conventional manufacturing methods are costly and labor-intensive, hindering their large-scale production. Recent advances in 3D printing technology offer innovative pathways to address these challenges. By combining design flexibility with material optimization, 3D printing holds the potential to enhance battery performance and enable customized structures. This review systematically examines the application of 3D printing technology in fabricating key AZIB components, including electrodes, electrolytes, and integrated battery designs. We critically compare the advantages and disadvantages of different 3D printing techniques for these components, discuss the potential and mechanisms by which 3D-printed structures enhance ion transport and electrochemical stability, highlight critical existing scientific questions and research gaps, and explore potential strategies for optimizing the manufacturing process. Full article
(This article belongs to the Special Issue Polymeric Materials for Next-Generation Energy Storage)
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21 pages, 2799 KiB  
Article
Structural Integrity Assessments of an IMO Type C LCO2 Cargo Tank
by Joon Kim, Kyu-Sik Park, Inhwan Cha and Joonmo Choung
J. Mar. Sci. Eng. 2025, 13(8), 1479; https://doi.org/10.3390/jmse13081479 - 31 Jul 2025
Viewed by 130
Abstract
With the rise of carbon capture and storage, liquefied carbon dioxide (LCO2) has emerged as a promising medium for large-scale marine transport. This study evaluates the structural integrity of an IMO Type C cargo tank for a medium-range LCO2 carrier [...] Read more.
With the rise of carbon capture and storage, liquefied carbon dioxide (LCO2) has emerged as a promising medium for large-scale marine transport. This study evaluates the structural integrity of an IMO Type C cargo tank for a medium-range LCO2 carrier under four conditions: ultimate limit state, accidental limit state, hydrostatic pressure test, and fatigue limit state, based on IGC Code and classification rules. Seventeen load cases were analyzed using finite element methods with multi-step loading to ensure stability. The highest stress occurred at the pump dome–shell junction due to geometric discontinuities, but all stress and buckling criteria were satisfied. The fatigue damage from wave-induced loads was negligible, with low-cycle fatigue from loading/unloading operations governing the fatigue life, which exceeded 31,000 years. The findings confirm the tank’s structural robustness and its suitability for safe, efficient medium-pressure LCO2 transport. Full article
(This article belongs to the Special Issue New Advances in the Analysis and Design of Marine Structures)
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20 pages, 10603 KiB  
Article
A Safety-Based Approach for the Design of an Innovative Microvehicle
by Michelangelo-Santo Gulino, Susanna Papini, Giovanni Zonfrillo, Thomas Unger, Peter Miklis and Dario Vangi
Designs 2025, 9(4), 90; https://doi.org/10.3390/designs9040090 (registering DOI) - 31 Jul 2025
Viewed by 168
Abstract
The growing popularity of Personal Light Electric Vehicles (PLEVs), such as e-scooters, has revolutionized urban mobility by offering compact, cost-effective, and environmentally friendly transportation solutions. However, safety concerns, including inadequate infrastructure, poor protective measures, and high accident rates, remain critical challenges. This paper [...] Read more.
The growing popularity of Personal Light Electric Vehicles (PLEVs), such as e-scooters, has revolutionized urban mobility by offering compact, cost-effective, and environmentally friendly transportation solutions. However, safety concerns, including inadequate infrastructure, poor protective measures, and high accident rates, remain critical challenges. This paper presents the design and development of an innovative self-balancing microvehicle under the H2020 LEONARDO project, which aims to address these challenges through advanced engineering and user-centric design. The vehicle combines features of monowheels and e-scooters, integrating cutting-edge technologies to enhance safety, stability, and usability. The design adheres to European regulations, including Germany’s eKFV standards, and incorporates user preferences identified through representative online surveys of 1500 PLEV users. These preferences include improved handling on uneven surfaces, enhanced signaling capabilities, and reduced instability during maneuvers. The prototype features a lightweight composite structure reinforced with carbon fibers, a high-torque motorized front wheel, and multiple speed modes tailored to different conditions, such as travel in pedestrian areas, use by novice riders, and advanced users. Braking tests demonstrate deceleration values of up to 3.5 m/s2, comparable to PLEV market standards and exceeding regulatory minimums, while smooth acceleration ramps ensure rider stability and safety. Additional features, such as identification plates and weight-dependent motor control, enhance compliance with local traffic rules and prevent misuse. The vehicle’s design also addresses common safety concerns, such as curb navigation and signaling, by incorporating large-diameter wheels, increased ground clearance, and electrically operated direction indicators. Future upgrades include the addition of a second rear wheel for enhanced stability, skateboard-like rear axle modifications for improved maneuverability, and hybrid supercapacitors to minimize fire risks and extend battery life. With its focus on safety, regulatory compliance, and rider-friendly innovations, this microvehicle represents a significant advancement in promoting safe and sustainable urban mobility. Full article
(This article belongs to the Section Vehicle Engineering Design)
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21 pages, 2854 KiB  
Article
Unseen Threats at Sea: Awareness of Plastic Pellets Pollution Among Maritime Professionals and Students
by Špiro Grgurević, Zaloa Sanchez Varela, Merica Slišković and Helena Ukić Boljat
Sustainability 2025, 17(15), 6875; https://doi.org/10.3390/su17156875 - 29 Jul 2025
Viewed by 214
Abstract
Marine pollution from plastic pellets, small granules used as a raw material for plastic production, is a growing environmental problem with grave consequences for marine ecosystems, biodiversity, and human health. This form of primary microplastic is increasingly becoming the focus of environmental policies, [...] Read more.
Marine pollution from plastic pellets, small granules used as a raw material for plastic production, is a growing environmental problem with grave consequences for marine ecosystems, biodiversity, and human health. This form of primary microplastic is increasingly becoming the focus of environmental policies, owing to its frequent release into the marine environment during handling, storage, and marine transportation, all of which play a crucial role in global trade. The aim of this paper is to contribute to the ongoing discussions by highlighting the environmental risks associated with plastic pellets, which are recognized as a significant source of microplastics in the marine environment. It will also explore how targeted education and awareness-raising within the maritime sector can serve as key tools to address this environmental challenge. The study is based on a survey conducted among seafarers and maritime students to raise their awareness and assess their knowledge of the issue. Given their operational role in ensuring safe and responsible shipping, seafarers and maritime students are in a key position to prevent the release of plastic pellets into the marine environment through increased awareness and initiative-taking practices. The results show that awareness is moderate, but there is a significant lack of knowledge, particularly in relation to the environmental impact and regulatory aspects of plastic pellet pollution. These results underline the need for improved education and training in this area, especially among future and active maritime professionals. Full article
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41 pages, 3023 KiB  
Article
Enhanced Scalability and Security in Blockchain-Based Transportation Systems for Mass Gatherings
by Ahmad Mutahhar, Tariq J. S. Khanzada and Muhammad Farrukh Shahid
Information 2025, 16(8), 641; https://doi.org/10.3390/info16080641 - 28 Jul 2025
Viewed by 422
Abstract
Large-scale events, such as festivals and public gatherings, pose serious problems in terms of traffic congestion, slow transaction processing, and security risks to transportation planning. This study proposes a blockchain-based solution for enhancing the efficiency and security of intelligent transport systems (ITS) by [...] Read more.
Large-scale events, such as festivals and public gatherings, pose serious problems in terms of traffic congestion, slow transaction processing, and security risks to transportation planning. This study proposes a blockchain-based solution for enhancing the efficiency and security of intelligent transport systems (ITS) by utilizing state channels and rollups. Throughput is optimized, enabling transaction speeds of 800 to 3500 transactions per second (TPS) and delays of 5 to 1.5 s. Prevent data tampering, strengthen security, and enhance data integrity from 89% to 99.999%, as well as encryption efficacy from 90% to 98%. Furthermore, our system reduces congestion, optimizes vehicle movement, and shares real-time, secure data with stakeholders. Practical applications include fast and safe road toll payments, faster public transit ticketing, improved emergency response coordination, and enhanced urban mobility. The decentralized blockchain helps maintain trust among users, transportation authorities, and event organizers. Our approach extends beyond large-scale events and proposes a path toward ubiquitous, Artificial Intelligence (AI)-driven decision-making in a broader urban transit network, informing future operations in dynamic traffic optimization. This study demonstrates the potential of blockchain to create more intelligent, more secure, and scalable transportation systems, which will help reduce urban mobility inefficiencies and contribute to the development of resilient smart cities. Full article
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28 pages, 2976 KiB  
Review
Catalytic Combustion Hydrogen Sensors for Vehicles: Hydrogen-Sensitive Performance Optimization Strategies and Key Technical Challenges
by Biyi Huang, Yi Wang, Chao Wang, Lijian Wang and Shubin Yan
Processes 2025, 13(8), 2384; https://doi.org/10.3390/pr13082384 - 27 Jul 2025
Viewed by 405
Abstract
As an efficient and low-carbon renewable energy source, hydrogen plays a strategic role in the global energy transition, particularly in the transportation sector. However, the flammable and explosive nature of hydrogen makes leakage risks in enclosed environments a core challenge for the safe [...] Read more.
As an efficient and low-carbon renewable energy source, hydrogen plays a strategic role in the global energy transition, particularly in the transportation sector. However, the flammable and explosive nature of hydrogen makes leakage risks in enclosed environments a core challenge for the safe promotion of hydrogen fuel cell vehicles. Catalytic combustion sensors are ideal choices due to their high sensitivity and long lifespan. Nevertheless, they face technical bottlenecks under vehicle operational conditions, such as high-power consumption caused by elevated working temperatures, slow response rates, weak anti-interference capabilities, and catalyst poisoning. This paper systematically reviews the research status of catalytic combustion hydrogen sensors for vehicle applications, summarizes technical difficulties and development strategies from the perspectives of hydrogen-sensitive material design and integration processes, and provides theoretical references and technical guidance for the development of catalytic combustion hydrogen sensors suitable for vehicle use. Full article
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16 pages, 2523 KiB  
Article
Application of Machine Learning Algorithms for Predicting the Dynamic Stiffness of Rail Pads Based on Static Stiffness and Operating Conditions
by Isaac Rivas, Jose A. Sainz-Aja, Diego Ferreño, Víctor Calzada, Isidro Carrascal, Jose Casado and Soraya Diego
Appl. Sci. 2025, 15(15), 8310; https://doi.org/10.3390/app15158310 - 25 Jul 2025
Viewed by 207
Abstract
The vertical stiffness of railway tracks is crucial for ensuring safe and efficient rail transport. Rail-pad dynamic stiffness is a key component influencing track performance. Determining the dynamic stiffness of rail pads poses a challenge because it depends not only on the material [...] Read more.
The vertical stiffness of railway tracks is crucial for ensuring safe and efficient rail transport. Rail-pad dynamic stiffness is a key component influencing track performance. Determining the dynamic stiffness of rail pads poses a challenge because it depends not only on the material and geometry of the rail pad but also on the testing conditions, due to the non-linear material response. To address this issue, a methodology is proposed in this paper to estimate dynamic stiffness using static stiffness measurements. This approach enables the prediction of dynamic stiffness for different situations from a single laboratory test. This study further examines whether this correlation remains valid for different types of rail pads, even when their mechanical behavior has been degraded by temperature, wear, or chemical agents. Experiments were conducted under varying temperatures and on rail pads that underwent mechanical and chemical degradation. The analysis assesses the validity of the static-to-dynamic stiffness correlation under degraded conditions and investigates the influence of each testing condition on the ability to estimate dynamic stiffness from static stiffness and operational parameters. The findings provide insights into the reliability of this predictive model and highlight the impact of degradation mechanisms on the dynamic behavior of rail pads. This research enhances the understanding of rail pad performance and offers a practical approach for evaluating dynamic stiffness. By considering all of the variables used in the analysis, the approach achieves R2 values of up to 0.99, which carries significant implications for track design and maintenance. Full article
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23 pages, 8212 KiB  
Review
Recent Developments in the Nonlinear Hydroelastic Modeling of Sea Ice Interaction with Marine Structures
by Sarat Chandra Mohapatra, Pouria Amouzadrad and C. Guedes Soares
J. Mar. Sci. Eng. 2025, 13(8), 1410; https://doi.org/10.3390/jmse13081410 - 24 Jul 2025
Viewed by 356
Abstract
This review provides the recent advancements in nonlinear sea ice modeling for hydroelastic analysis of ice-covered channels and their interaction with floating structures. It surveys theoretical, experimental, and numerical methodologies used to analyze complex coupled sea ice–structure interactions. The paper discusses governing fluid [...] Read more.
This review provides the recent advancements in nonlinear sea ice modeling for hydroelastic analysis of ice-covered channels and their interaction with floating structures. It surveys theoretical, experimental, and numerical methodologies used to analyze complex coupled sea ice–structure interactions. The paper discusses governing fluid domain solutions, fluid–ice interaction mechanisms, and ice–structure (ship) contact models, alongside experimental techniques and various numerical models. While significant progress has been made, particularly with coupled approaches validated by experimental data, challenges remain in full-scale validation and accurately representing ice properties and dynamic interactions. Findings highlight the increasing importance of understanding sea ice interactions, particularly in the context of climate change, Arctic transportation, and the development of very large floating structures. This review serves as a crucial resource for advancing safe and sustainable Arctic and offshore engineering. Full article
(This article belongs to the Section Ocean Engineering)
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25 pages, 31775 KiB  
Article
Machine Learning-Based Binary Classification Models for Low Ice-Class Vessels Navigation Risk Assessment
by Yuanyuan Zhang, Guangyu Li, Jianfeng Zhu and Xiao Cheng
J. Mar. Sci. Eng. 2025, 13(8), 1408; https://doi.org/10.3390/jmse13081408 - 24 Jul 2025
Viewed by 255
Abstract
The presence of sea ice threatens low ice-class vessels’ navigation safety in the Arctic, and traditional Navigation Risk Assessment Models based on sea ice parameters have been widely used to guide safe passages for ships operating in ice regions. However, these models mainly [...] Read more.
The presence of sea ice threatens low ice-class vessels’ navigation safety in the Arctic, and traditional Navigation Risk Assessment Models based on sea ice parameters have been widely used to guide safe passages for ships operating in ice regions. However, these models mainly rely on empirical coefficients, and the accuracy of these models in identifying sea ice navigation risk remains insufficiently validated. Therefore, under the binary classification framework, this study used Automatic Identification System (AIS) data along the Northeast Passage (NEP) as positive samples, manual interpretation non-navigable data as negative samples, a total of 10 machine learning (ML) models were employed to capture the complex relationships between ice conditions and navigation risk for Polar Class (PC) 6 and Open Water (OW) vessels. The results showed that compared to traditional Navigation Risk Assessment Models, most of the 10 ML models exhibited significantly improved classification accuracy, which was especially pronounced when classifying samples of PC6 vessel. This study also revealed that the navigability of the East Siberian Sea (ESS) and the Vilkitsky Strait along the NEP is relatively poor, particularly during the month when sea ice melts and reforms, requiring special attention. The navigation risk output by ML models is strongly determined by sea ice thickness. These findings offer valuable insights for enhancing the safety and efficiency of Arctic maritime transport. Full article
(This article belongs to the Special Issue Remote Sensing for Maritime Monitoring and Ship Surveillance)
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19 pages, 1040 KiB  
Systematic Review
A Systematic Review on Risk Management and Enhancing Reliability in Autonomous Vehicles
by Ali Mahmood and Róbert Szabolcsi
Machines 2025, 13(8), 646; https://doi.org/10.3390/machines13080646 - 24 Jul 2025
Viewed by 344
Abstract
Autonomous vehicles (AVs) hold the potential to revolutionize transportation by improving safety, operational efficiency, and environmental impact. However, ensuring reliability and safety in real-world conditions remains a major challenge. Based on an in-depth examination of 33 peer-reviewed studies (2015–2025), this systematic review organizes [...] Read more.
Autonomous vehicles (AVs) hold the potential to revolutionize transportation by improving safety, operational efficiency, and environmental impact. However, ensuring reliability and safety in real-world conditions remains a major challenge. Based on an in-depth examination of 33 peer-reviewed studies (2015–2025), this systematic review organizes advancements across five key domains: fault detection and diagnosis (FDD), collision avoidance and decision making, system reliability and resilience, validation and verification (V&V), and safety evaluation. It integrates both hardware- and software-level perspectives, with a focus on emerging techniques such as Bayesian behavior prediction, uncertainty-aware control, and set-based fault detection to enhance operational robustness. Despite these advances, this review identifies persistent challenges, including limited cross-layer fault modeling, lack of formal verification for learning-based components, and the scarcity of scenario-driven validation datasets. To address these gaps, this paper proposes future directions such as verifiable machine learning, unified fault propagation models, digital twin-based reliability frameworks, and cyber-physical threat modeling. This review offers a comprehensive reference for developing certifiable, context-aware, and fail-operational autonomous driving systems, contributing to the broader goal of ensuring safe and trustworthy AV deployment. Full article
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17 pages, 5257 KiB  
Article
Research on Draft Control Optimization of Ship Passing a Lock Based on CFD Method
by Yuan Zhuang, Yu Ding, Jialun Liu and Song Zhang
J. Mar. Sci. Eng. 2025, 13(8), 1406; https://doi.org/10.3390/jmse13081406 - 23 Jul 2025
Viewed by 207
Abstract
Waterborne transportation serves as a critical pillar of trunk-line freight systems, offering unparalleled advantages in transport capacity, energy efficiency, and cost-effectiveness. As cargo throughput demands escalate, optimizing lock capacity becomes imperative. This study investigates ship sinkage dynamics through computational fluid dynamics (CFD) simulations [...] Read more.
Waterborne transportation serves as a critical pillar of trunk-line freight systems, offering unparalleled advantages in transport capacity, energy efficiency, and cost-effectiveness. As cargo throughput demands escalate, optimizing lock capacity becomes imperative. This study investigates ship sinkage dynamics through computational fluid dynamics (CFD) simulations for a representative inland cargo vessel navigating the Three Gorges on the Yangtze River. We develop a predictive sinkage model that integrates four key hydrodynamic parameters: ship velocity, draft, water depth, and bank clearance, applicable to both open shallow water and lockage conditions. The model enables determination of maximum safe drafts for lock transit by analyzing upstream/downstream water levels and corresponding chamber depths. Our results demonstrate the technical feasibility of enhancing single-lock cargo capacity while maintaining safety margins. These findings provide (1) a scientifically grounded framework for draft control optimization, and (2) actionable insights for lock operation management. The study establishes a methodological foundation for balancing navigational safety with growing throughput requirements in constrained waterways. Full article
(This article belongs to the Section Ocean Engineering)
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15 pages, 2004 KiB  
Article
Impact of Aquifer Heterogeneity on the Migration and Natural Attenuation of Multicomponent Heavy Dense Nonaqueous Phase Liquids (DNAPLs) in a Retired Chemically Polluted Site
by Wenyi Xie, Mei Li, Dengdeng Jiang, Lingya Kong, Mengjie Wang, Shaopo Deng and Xuwei Li
Processes 2025, 13(8), 2338; https://doi.org/10.3390/pr13082338 - 23 Jul 2025
Viewed by 269
Abstract
Retired chemically polluted sites in southern Jiangsu Province, China, are characterized by dense nonaqueous phase liquids (DNAPLs) and extremely thick aquifers (>30 m), which pose substantial challenges for determining investigation and remediation depths during redevelopment and exploitation. This study constructed a 2D groundwater [...] Read more.
Retired chemically polluted sites in southern Jiangsu Province, China, are characterized by dense nonaqueous phase liquids (DNAPLs) and extremely thick aquifers (>30 m), which pose substantial challenges for determining investigation and remediation depths during redevelopment and exploitation. This study constructed a 2D groundwater transport model using TMVOC to systematically investigate the migration, diffusion, and natural attenuation processes of two typical DNAPLs—1,2-dichloroethane (DCE) and carbon tetrachloride (CTC)—under three scenarios: individual transport, mixed transport, and heterogeneous aquifer conditions, with a simulation period of 35 years. In individual transport scenarios, DCE and CTC showed distinct migration behaviors. DCE achieved a maximum vertical transport distance of 14.01 m and a downstream migration distance of 459.58 m, while CTC reached 13.57 m vertically and 453.51 m downstream. When transported as a mixture, their migration was inhibited: DCE’s vertical and downstream distances decreased to 13.76 m and 440.46 m, respectively; and CTC’s to 13.23 m and 420.32 m, likely due to mutual solvent effects that altered their physicochemical properties such as viscosity and solubility. Under natural attenuation conditions, both DNAPLs ceased downstream transport by the end of the 6th year. DCE concentrations dropped below its risk control value (0.81 mg/L) by the 14th year, and CTC (with a risk control value of 0.23 mg/L) by the 11th year. By the 10th year, DCE’s downstream plume had retreated to 48.65 m, and CTC’s to 0.95 m. In heterogeneous aquifers, vertical upward transport of DCE and CTC increased to 14.82 m and 14.22 m, respectively, due to the partial absence of low-conductivity silt layers, while their downstream distances decreased to 397.99 m and 354.11 m, constrained by low-permeability lenses in the migration path. These quantitative results clarify the dynamic differences in DNAPL transport under varying conditions, highlighting the impacts of multicomponent interactions, natural attenuation, and aquifer heterogeneity. They provide critical references for risk management, scientific determination of remediation depths, and safe exploitation of retired chemically polluted sites with similar hydrogeological characteristics. Full article
(This article belongs to the Section Environmental and Green Processes)
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19 pages, 2452 KiB  
Article
Women’s Right to the City: The Case of Quito, Ecuador
by Maria Carolina Baca Calderón, Gloria Quattrone, Eufemia Sánchez Borja and Daniele Rocchio
Soc. Sci. 2025, 14(8), 448; https://doi.org/10.3390/socsci14080448 - 23 Jul 2025
Viewed by 263
Abstract
Henri Lefebvre’s “right to the city” has rarely been examined through an intersectional feminist lens, leaving unnoticed the uneven burdens that urban design and policy place on women. This article bridges that gap by combining constitutional analysis, survey data (n = 736), [...] Read more.
Henri Lefebvre’s “right to the city” has rarely been examined through an intersectional feminist lens, leaving unnoticed the uneven burdens that urban design and policy place on women. This article bridges that gap by combining constitutional analysis, survey data (n = 736), in-depth interviews, and participatory observation to assess how Quito’s public spaces affect women’s safety and mobility. Quantitative results show that 81% of respondents endured sexual or offensive remarks, 69.8% endured obscene gestures, and 38% endured severe harassment in the month before the survey; 43% of these incidents occurred only days or weeks beforehand, underscoring their routine nature. Qualitative narratives reveal behavioral adaptations—altered routes, self-policing dress codes, and distrust of authorities—and identify poorly lit corridors and weak institutional presence as spatial amplifiers of violence. Analysis of Quito’s “Safe City” program exposes a gulf between its ambitious rhetoric and its narrow, transport-centered implementation. We conclude that constitutional guarantees of participation, appropriation, and urban life will remain aspirational until urban planning mainstreams gender-sensitive design, secures intersectoral resources, and embeds women’s substantive participation throughout policy cycles. A feminist reimagining of Quito’s public realm is therefore indispensable to transform the right to the city from legal principle into lived reality. Full article
(This article belongs to the Section Gender Studies)
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14 pages, 1928 KiB  
Article
Thermal and Flammability Analysis of Polyurethane Foams with Solid and Liquid Flame Retardants: Comparative Study
by Dorota Głowacz-Czerwonka, Patrycja Zakrzewska, Beata Zygmunt-Kowalska and Iwona Zarzyka
Polymers 2025, 17(14), 1977; https://doi.org/10.3390/polym17141977 - 18 Jul 2025
Viewed by 280
Abstract
The thermal properties and flammability of rigid polyurethane foams (RPUFs) containing various flame retardants, including solid (melamine, expanded graphite (EG), Exolit OP 935, ammonium polyphosphate (APP)) and liquid (Roflam B7, Roflam PLO) types, added at 30 wt.% and 60 wt.% by weight have [...] Read more.
The thermal properties and flammability of rigid polyurethane foams (RPUFs) containing various flame retardants, including solid (melamine, expanded graphite (EG), Exolit OP 935, ammonium polyphosphate (APP)) and liquid (Roflam B7, Roflam PLO) types, added at 30 wt.% and 60 wt.% by weight have been evaluated. Thermogravimetric analysis (TGA) demonstrated enhanced thermal stability, with the maximum 10% weight loss temperature (292 °C, +34 °C vs. reference) observed for foams containing 60 wt.% Exolit OP 935 and APP. The limiting oxygen index (LOI) test demonstrated the optimal performance for 30 wt.% APP and melamine (26.4 vol.% vs. 18.7 vol.% reference). In the UL-94 test, Exolit OP 935 and APP achieved a V-0 rating. The 60 wt.% Exolit with an EG blend also demonstrated a substantial reduction in heat release rate. These findings underscore the cooperative effects of hybrid flame retardants, thereby supporting their utilization in fire-safe RPUFs for construction and transport. Full article
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28 pages, 3053 KiB  
Review
X-in-the-Loop Methodology for Proton Exchange Membrane Fuel Cell Systems Design: Review of Advances and Challenges
by Hugo Lambert, David Hernàndez-Torres, Clément Retière, Laurent Garnier and Jean-Philippe Poirot-Crouvezier
Energies 2025, 18(14), 3774; https://doi.org/10.3390/en18143774 - 16 Jul 2025
Viewed by 239
Abstract
Proton Exchange Membrane Fuel Cells (PEMFCs) are seen as an alternative for heavy-duty transportation electrification. Powered by a green hydrogen source, they can provide high efficiency and low carbon emissions compared to traditional fuels. However, to be competitive, these systems require high reliability [...] Read more.
Proton Exchange Membrane Fuel Cells (PEMFCs) are seen as an alternative for heavy-duty transportation electrification. Powered by a green hydrogen source, they can provide high efficiency and low carbon emissions compared to traditional fuels. However, to be competitive, these systems require high reliability when operated in real-life conditions, as well as safe and efficient operating management. In order to achieve these goals, the X-in-the-loop (also called model-based design) methodology is well suited. It has been largely adopted for PEMFC system development and optimisation, as they are complex multi-component systems. In this paper, a systematic analysis of the scientific literature is conducted to review the methodology implementation for the design and improvement of the PEMFC systems. It exposes a precise definition of each development step in the methodology. The analysis shows that it can be employed in different ways, depending on the subsystems considered and the objectives sought. Finally, gaps in the literature and technical challenges for fuel cell systems that should be addressed are identified. Full article
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