Search Results (509)

This study focuses on the analysis of soliton solutions within the framework of the time-fractional cubic–quintic nonlinear Schrödinger equation (TFCQ-NLSE), a powerful model with broad applications in complex physical phenomena such as fiber optic communications, nonlinear optics, optical signal processing, and laser–tissue interactions in medical science. The nonlinear effects exhibited by the model—such as self-focusing, self-phase modulation, and wave mixing—are influenced by the combined impact of the cubic and quintic nonlinear terms. To explore the dynamics of this model, we apply a robust analytical technique known as the sub-ODE method, which reveals a diverse range of soliton structures and offers deep insight into laser pulse interactions. The investigation yields a rich set of explicit soliton solutions, including hyperbolic, rational, singular, bright, Jacobian elliptic, Weierstrass elliptic, and periodic solutions. These waveforms have significant real-world relevance: bright solitons are employed in fiber optic communications for distortion-free long-distance data transmission, while both bright and dark solitons are used in nonlinear optics to study light behavior in media with intensity-dependent refractive indices. Solitons also contribute to advancements in quantum technologies, precision measurement, and fiber laser systems, where hyperbolic and periodic solitons facilitate stable, high-intensity pulse generation. Additionally, in nonlinear acoustics, solitons describe wave propagation in media where amplitude influences wave speed. Overall, this work highlights the theoretical depth and practical utility of soliton dynamics in fractional nonlinear systems. Full article

The increasing demand for high-speed, energy-efficient computing has propelled the development of integrated photonic logic gates, which utilize the speed of light to surpass the limitations of traditional electronic circuits. These gates enable ultrafast, parallel data processing with minimal power consumption, making them ideal for next-generation computing, telecommunications, and quantum applications. Recent advancements in nanofabrication, nonlinear optics, and phase-change materials have facilitated the seamless integration of all-optical logic gates onto compact photonic chips, significantly enhancing performance and scalability. This paper explores the latest breakthroughs in photonic logic gate design, key material innovations, and their transformative applications. While challenges such as fabrication precision and electronic–photonic integration remain, integrated photonic logic gates hold immense promise for revolutionizing optical computing, artificial intelligence, and secure communication. Full article

This work presents the synthesis, characterization and evaluation of physicochemical and biological properties of two new aminoporphyrazine derivatives bearing magnesium(II) cations in their cores and peripheral pyrrolyl groups. The synthesis was carried out in several stages, using classical methods and the Microwave-Assisted Organic Synthesis (MAOS) approach. The obtained compounds were characterized using spectral techniques: UV-Vis spectrophotometry, mass spectrometry, ¹H and ¹³C NMR spectroscopy. The porphyrazine derivatives were tested for their electrochemical properties (CV and DPV), which revealed four redox processes, of which in compound 7 positive shifts of oxidation potentials were observed, resulting from the presence of free phenolic hydroxyl groups. In spectroelectrochemical measurements, changes in UV-Vis spectra associated with the formation of positive-charged states were noted. Photophysical studies revealed the presence of characteristic absorption Q and Soret bands, low fluorescence quantum yields and small Stokes shifts. The efficiency of singlet oxygen generation (Φ_Δ) was higher for compound 6 (up to 0.06), but compound 7, despite its lower efficiency (0.02), was distinguished by a better biological activity profile. Toxicity tests using the Aliivibrio fischeri bacteria indicated the lower toxicity of 7 compared to 6. The most promising result was the strong photodynamic activity of porphyrazine 7 against the Methicillin-resistant Stapylococcus aureus (MRSA) strain, leading to a more-than-5.6-log decrease in viable counts after the colony forming units (CFU) after light irradiation. Compound 6 did not show any significant antibacterial activity. The obtained data indicate that porphyrazine 7 is a promising candidate for applications in photodynamic therapy of bacterial infections. Full article

Group IV element-based topological semimetals (TSMs) are pivotal for next-generation quantum devices due to their ultra-high carrier mobility and low-energy consumption. However, germanium (Ge)-based TSMs remain underexplored despite their compatibility with existing semiconductor technologies. Here, we propose a novel I229-Ge₄₈ allotrope constructed via bottom-up cluster assembly that exhibits a unique porous spherical Fermi surface and strain-tunable topological robustness. First-principles calculations reveal that I229-Ge₄₈ is a topological nodal line semimetal with exceptional mechanical anisotropy (Young’s modulus ratio: 2.27) and ductility (B/G = 2.21, ν = 0.30). Remarkably, the topological property persists under spin-orbit coupling (SOC) and tensile strain, while compressive strain induces a semiconductor transition (bandgap: 0.29 eV). Furthermore, I229-Ge₄₈ demonstrates strong visible-light absorption (10⁵ cm⁻¹) and a strong strain-modulated infrared response, surpassing conventional Ge allotropes. These findings establish I229-Ge₄₈ as a multifunctional platform for strain-engineered nanoelectronics and optoelectronic devices. Full article

In this work, we undertake a comprehensive study of the functional measure of gravitational path integrals within a general framework involving non-trivial configuration spaces. As in Riemannian geometry, the integration over non-trival configuration spaces requires a metric. We examine the interplay between the functional measure and the dynamics of spacetime for general configuration-space metrics. The functional measure gives an exact contribution to the effective action at the one-loop level. We discuss the implications and phenomenological consequences of this correction, shedding light on the role of the functional measure in quantum gravity theories. In particular, we describe a mechanism in which the graviton acquires a mass from the functional measure without violating the diffeomorphism symmetry nor including Stückelberg fields. Since gauge invariance is not violated, the number of degrees of freedom goes as in general relativity. For the same reason, Boulware–Deser ghosts and the vDVZ discontinuity do not show up. The graviton thus becomes massive at the quantum level while avoiding the usual issues of massive gravity. Full article

Near-unstable cavities hold promise for reducing thermal noise in next-generation gravitational wave detectors and for enhancing light–matter interactions in quantum electrodynamics. However, operating close to the edge of geometrical stability presents significant challenges, including increased coupling to higher-order modes and heightened sensitivity to small cavity length changes and mirror imperfections. This study employs Finesse v3 simulations to systematically investigate the modal behavior of a plano-concave cavity as it approaches instability, incorporating measured mirror surface defects and anisotropic curvature to replicate realistic conditions. The simulations highlight the degradation of beam purity and control signals as the cavity approaches instability. By validating the simulations against experimental data, we confirm Finesse’s reliability for modeling cavities while identifying critical limitations in regimes close to the edge of stability. These findings provide essential guidance for optimizing cavity designs in future gravitational wave detectors, balancing performance gains against the challenges of operating at the stability edge. Full article

We present an analytical framework for describing light propagation in infinite waveguide arrays, incorporating a generalized long-range coupling to achieve a more realistic model. We demonstrate that the resulting solution can be expressed in terms of generalized Bessel-like functions. Additionally, by applying the concept of eigenstates, we borrow from quantum mechanics a basis given in terms of phase states that allows the analysis of the transition from the discrete to the continuum limit, obtaining a relationship between the field amplitudes and the Fourier series coefficients of a given function. We apply our findings to different coupling functions, providing new insights into the propagation dynamics of these systems. Full article

Recent advancements in thermally activated delayed fluorescence (TADF) materials and mechanochromic materials have significantly enhanced the efficiency and versatility of light-emitting electrochemical cells (LECs) and organic light-emitting diodes (OLEDs). TADF materials have enabled efficiency improvements, achieving an internal quantum efficiency (IQE) of nearly 100% by utilizing both singlet and triplet excitons. Meanwhile, mechanochromic materials exhibit reversible optical changes upon mechanical stimuli, making them promising for stress sensing, encryption, and flexible electronics. The synergistic integration of TADF and mechanochromic materials in OLEDs and LECs has led to enhanced efficiency, stability, and multifunctionality in next-generation lighting and display technologies. This narrative review explores recent breakthroughs in devices that incorporate both TADF and mechanochromic materials as emitters. Particular attention is given to the molecular design that enable both TADF and mechanochromic properties, as well as optimal device structures and performance parameters. Moreover, this review discusses the only LEC fabricated so far using a TADF-mechanochromic emitter, highlighting its performance and potential. Finally, the report concludes with an outlook on the future commercial applications of these materials, particularly in wearable electronics and smart display technologies. Full article

Coupling organic light-harvesting materials with lead halide perovskite quantum dots (LHP QDs) is an attractive approach that could provide great potential in optoelectronic applications owing to the diversity of organic materials available and the intriguing optical and electronic properties of LHP QDs. Here, we demonstrate energy collection by CsPbI₃ QDs from a near-infrared (NIR) light-harvesting upconversion system. The upconversion system consists of Pd-tetrakis-5,10,15,20-(p-methoxycarbonylphenyl)-tetraanthraporphyrin (PdTAP) as the sensitizer to harvest NIR photons and rubrene as the annihilator to generate upconverted photons via triplet fusion. Steady-state and time-resolved photoluminescence spectra reveal that CsPbI₃ QDs are energized via radiative energy transfer from the singlet excited rubrene with photophysics fidelity of respective components. In addition, a volumetric display demo incorporating CsPbI₃ QDs as light emitters employing triplet fusion upconversion was developed, showing bright luminescent images from CsPbI₃ QDs. These results present the feasibility of integrating organic light-harvesting systems and perovskite QDs, enabling diverse light harvesting and activation of perovskite materials for optoelectronic applications. Full article

Opto-spintronics is an emerging field that focuses on harnessing light to manipulate and analyze electron spins to develop next-generation electronic devices. This paper explores recent progress and the role of solid-state materials in opto-spintronics by focusing on key classes of materials, such as ferromagnetic semiconductors, two-dimensional (2D) transition metal dichalcogenides (TMDCs), and topological insulators. It examines the unique properties of ferromagnetic and antiferromagnetic materials and their ability to interact with light to affect spin dynamics, offering potential for improved sensing and quantum computing. By combining opto-spintronics with solid-state systems, spintronic devices could become faster and more efficient, leading to new technological advancements and scalable technologies. Full article

We review quantum architectures for engineering the N00N state, a bipartite maximally entangled state essential in quantum metrology. These schemes transform the initial state $|N⟩\otimes |0⟩$ into the N00N state, ${\displaystyle \frac{1}{\sqrt{2}}}\left(\right|N⟩\otimes |0⟩+|0⟩\otimes |N⟩),$ where $|N⟩$ and $|0⟩$ are Fock states with N and 0 excitations, respectively. We demonstrate that this state can be generated through superpositions of quantum light modes, hybrid light–matter interactions, or spin ensembles. Our approach also enables the creation of mesoscopic and macroscopic entangled states, including entangled coherent and squeezed states. Furthermore, we show that a broad class of maximally entangled states can be realized within this framework. Extensions to multi-mode state engineering are also explored. Full article

We pose and address the radical question of whether quantum mechanics, known for its firm internal structure and enormous empirical success, carries in itself the genomes of larger quantum theories that have higher internal intricacy and phenomenological versatility. In other words, we consider, at the basic level of closed quantum systems and regardless of interpretational aspects, whether standard quantum theory (SQT) harbors quantum theories with context-based deformed principles or structures, having definite predictive power within much broader scopes. We answer this question in the affirmative following complementary evidence and reasoning arising from quantum-computation-based quantum simulation and fundamental, general, and abstract rationales within the frameworks of information theory, fundamental or functional emergence, and participatory agency. In this light, as we show, one is led to the recently proposed experience-centric quantum theory (ECQT), which is a larger and richer theory of quantum behaviors with drastically generalized quantum dynamics. ECQT allows the quantum information of the closed quantum system’s developed state history to continually contribute to defining and updating the many-body interactions, the Hamiltonians, and even the internal elements and “particles” of the total system. Hence, the unitary evolutions are continually impacted and become guidable by the agent system’s experience. The intrinsic interplay of unitarity and non-Markovianity in ECQT brings about a host of diverse behavioral phases, which concurrently infuse closed and open quantum system characteristics, and it even surpasses the theory of open systems in SQT. From a broader perspective, a focus of our investigation is the existence of the quantum interactome—the interactive landscape of all coexisting, independent, context-based quantum theories that emerge from inferential participatory agencies—and its predictive phenomenological utility. Full article

We discuss an extension of the Single-Active-Electron (SAE) approximation in atoms by allowing the model potential to depend on the angular-momentum quantum number ℓ. We refer to this extension as the ℓ-SAE approximation. The main ideas behind ℓ-SAE are illustrated using the helium atom as a benchmark system. We show that introducing ℓ-dependent potentials improves the accuracy of key quantities in atomic structure computed from the Time-Independent Schrödinger Equation (TISE), including energies, oscillator strengths, and static and dynamic polarizabilities, compared to the standard SAE approach. Additionally, we demonstrate that the ℓ-SAE approximation is suitable for quantum simulations of light−atom interactions described by the Time-Dependent Schrödinger Equation (TDSE). As an illustration, we simulate High-order Harmonic Generation (HHG) and the three-sideband (3SB) version of the Reconstruction of Attosecond Beating by Interference of Two-photon Transitions (RABBITT) technique, achieving enhanced accuracy comparable to that obtained in all-electron calculations. One of the main advantages of the ℓ-SAE approach is that existing SAE codes can be easily adapted to handle ℓ-dependent potentials without any additional computational cost. Full article

In natural photosynthesis, solar energy is utilized to convert water and CO₂ into energy-rich compounds. However, in practice, the maximum quantum efficiency of natural photosynthesis is limited to 6.0%. Conversely, artificial photosynthesis (AP) systems utilize solar energy to convert CO₂ into biosynthetic solar fuels and value-added chemicals. To mimic natural photosystems, AP integrates light-harvesting chemical catalysts with the enzyme-mediated biological catalysis occurring in microorganisms. Similar to solar energy-based optoelectronic power sources, AP has also been recognized as a promising option for reducing carbon emissions generated by the fossil fuel-based power sector. Typical quantum efficiency of AP is 5–10%; in some cases, it exceeds 20%. Recent advancements have focused on nanomaterial biohybrids (NBHs), combining nanomaterial-based photocatalysts/photosensitizers with microorganisms/enzymes for enhanced oxidation/reduction reactions. The synergistic interaction between nanomaterials and microorganisms, facilitated by their comparable size and tunable surface properties, enables improved solar energy absorption, charge separation, and conversion. NBHs offer a versatile platform for sustainable solar energy harvesting and conversion, overcoming the limitations of natural and fully abiotic photosynthesis systems. This review highlights recent breakthroughs in diverse platforms of sunlight and visible light-driven NBH-based AP systems for CO₂ fixation, H₂ production, water splitting, and value-added chemical synthesis. The synthesis strategies, operating mechanisms, and challenges are highlighted. Full article

Two-dimensional materials have emerged as core components for next-generation optoelectronic devices due to their quantum confinement effects and tunable electronic properties. Indium selenide (InSe) demonstrates breakthrough photoelectric performance, with its remarkable light-responsive characteristics spanning from visible to near-infrared regions, offering application potential in high-speed imaging, optical communication, and biosensing. This study investigates the doping characteristics of InSe using first-principles calculations, focusing on the doping and adsorption behaviors of Argentum (Ag) and Bismuth (Bi) atoms in InSe and their effects on its electronic structure. The research reveals that Ag atoms preferentially adsorb at interlayer vacancies with a binding energy of −2.19 eV, forming polar covalent bonds. This reduces the band gap from the intrinsic 1.51 eV to 0.29–1.16 eV and induces an indirect-to-direct band gap transition. Bi atoms doped at the center of three Se atoms exhibit a binding energy of −2.06 eV, narrowing the band gap to 0.19 eV through strong ionic bonding, while inducing metallic transition at inter-In sites. The introduced intermediate energy levels significantly reduce electron transition barriers (by up to 60%) and enhance carrier separation efficiency. This study links doping sites, electronic structures, and photoelectric properties through computational simulations, offering a theoretical framework for designing high-performance InSe-based photodetectors. It opens new avenues for narrow-bandgap near-infrared detection and carrier transport optimization. Full article