Synthesis and Characterization of Peripherally Functionalized Porphyrazines and Phthalocyanines
A special issue of Molecules (ISSN 1420-3049). This special issue belongs to the section "Organic Chemistry".
Deadline for manuscript submissions: 31 December 2025 | Viewed by 462
Special Issue Editors
Interests: organic synthesis; electrochemistry; photocatalysis; nanomaterials; sensors; porphyrinoids
Special Issue Information
Dear Colleagues,
Porphyrazines and phthalocyanines, also known as tetraazaporphyrins, are synthetic members of the porphyrinoid family. They comprise pyrrole or isoindole moieties, respectively, linked by nitrogen bridges in the form of macrocyclic rings, able to bind metal cations at their center. This binding imparts unique physicochemical and electrochemical properties, tunable by substituting the central cation or functionalizing the heteroaromatic rings. Porphyrazines and phthalocyanines feature an extended aromatic system with 18 conjugated π-electrons, contributing to their stability and optical properties, including visible and ultraviolet light absorption. Their ability to absorb light and generate reactive oxygen species through energy transfer mechanisms is leveraged in photodynamic therapy (targeting cancer cells and microorganisms) and in photocatalysis. Additionally, tetraazaporphyrins' ability to emit fluorescence after light irradiation is employed in photodynamic diagnosis. Porphyrazines and phthalocyanines can also catalyze oxidation and reduction reactions, especially when coordinating d-block metal ions like iron and manganese, which enables them to serve as electrocatalysts.
In this Special Issue, entitled “Synthesis and Characterization of Peripherally Functionalized Porphyrazines and Phthalocyanines”, we invite researchers worldwide who contribute to the field and publish studies highlighting the diverse applicability of tetraazaporphyrins.
Dr. Tomasz Koczorowski
Dr. Dariusz T. Mlynarczyk
Guest Editors
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Keywords
- porphyrazine
- phthalocyanine
- organic synthesis
- photodynamic therapy
- photodynamic inactivation
- photocatalysis
- photodegradation
- electrocatalysis
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