Search Results (5,460)

This study examines the through-thickness microstructure and crystallographic texture evolution in friction-stir-welded (FSWed) AA5052-H32 and AA6061-T651 aluminum alloys using a tri-flats threaded pin tool. Optical microscopy and electron backscatter diffraction (EBSD) were employed to characterize grain morphology, boundary misorientation, and texture components across the weld thickness. Both alloys exhibited progressive grain refinement and increased high-angle grain boundary fractions from the top to the bottom of the stir zone due to combined thermal and strain gradients. The FSWed AA5052 displayed dominant {111}<110> and Y + γ fiber components at the upper and mid regions, whereas AA6061 showed more randomized textures. At the bottom region, both alloys developed rotated Goss {011}<01-1> and weak A ({112}<110>) and α fiber components. These results clarify how alloy strengthening mechanisms—solid-solution versus precipitation hardening—govern texture evolution under different strain-path and heat input conditions. The findings contribute to optimizing process parameters and material selection for structural-scale FSW aluminum joints in industrial applications such as bridge decks, transportation panels, and marine structures. Full article

The incorporation of carbon nanostructures into polymer composites is of significant importance for the development of novel sensor materials, due to the excellent mechanical strength and variable electrical conductivity that these structures provide. It is evident that the significance of polylactide (PLA) and carbon nanotube (CNT) systems is attributable to two key factors. Firstly, these systems are notable for their environmental sustainability. Secondly, they exhibit enhanced functional properties. Despite the fact that a considerable number of studies have been conducted on conductive PLA/CNT composites, there has been limited research focusing on the supramolecular ordering of the polymer matrix and its impact on electromechanical properties. This factor, however, has been demonstrated in this study to significantly influence their response to applied stress and, consequently, their potential application as stress sensors. The present study has demonstrated that the precipitation method is an effective means of producing conductive PLA/MWNTs nanocomposites. This method is effective in ensuring the uniform dispersion of the filler in the polymer matrix, which creates an interesting prospect for mechanical sensors. It is evident that the durability of the nanocomposites is a key factor in ensuring the ordering of the supramolecular structure of the PLA matrix into the α form. The materials obtained were found to have a low percolation threshold of 0.2 wt.%. Furthermore, the practical application of these sensors, in the form of resistive strain sensors, was demonstrated for materials containing 5 wt.% of carbon nanotubes. The results presented here demonstrate that this methodology provides a novel perspective on the production of sensor materials, with the supramolecular ordering of the PLA matrix being a key factor. Full article

Cadmium sulfide is an important II-VI semiconductor known for its valuable photocatalytic properties ascribable to its band gap energy, which allows light absorption in the visible domain. Nonetheless, the application of cadmium sulfide in wastewater organic pollutant degradation is restricted due to its high toxicity to humans, soil, and marine life. To address this issue, we developed new composite materials by depositing CdS on a bentonite support in a 1:9 mass ratio to develop a photocatalyst with lower toxicity. In the first step, bentonite was activated using an aqueous HCl solution; for the deposition of CdS powder, we proposed the trituration method and compared it with chemical precipitation and hydrothermal synthesis, using thioacetamide as a sulfide ion source. The modified bentonite underwent characterization using X-ray diffraction, scanning electron microscopy, X-ray fluorescence, UV-Vis, and FTIR spectroscopy. The photocatalytic activity was tested in the degradation of Congo red (CR), a persistent diazo dye. The efficiency of removing CR with CdS–bentonite composites depended on the deposition method of CdS, and it was higher than that of pristine CdS and of only adsorption onto acid-activated bentonite. The photocatalytic degradation mechanism was estimated by the scavenger test using ethylenediaminetetraacetic acid disodium salt, ascorbic acid, ethanol, and silver nitrate as radical scavengers. Full article

Climate change and irregular precipitation patterns have increasingly threatened groundwater sustainability in semi-arid regions like the Eastern Mediterranean. Specifically, in coastal Syria, the lack of quantitative understanding regarding aquifer recharge mechanisms hinders effective water resource management. To address this, this study investigates the dynamic relationship between rainfall and groundwater levels in the Al-Hsain Basin coastal plain using 48 months of monitoring data (2020–2024) from 35 wells. We employed a unified analytical framework combining statistical methods (correlation, regression) with advanced time–frequency techniques (Wavelet Coherence) to capture recharge behavior across diverse Quaternary, Neogene, and Cretaceous strata. The results indicate strong climatic control on groundwater dynamics, particularly in shallow Quaternary wells, which exhibit rapid recharge responses (lag < 1 month). In contrast, deeper aquifers showed delayed and buffered responses. A dual-variable model incorporating temperature significantly improved prediction accuracy (R² = 0.97), highlighting the role of evapotranspiration. These findings provide a transferable diagnostic framework for identifying recharge zones and supporting adaptive groundwater governance in data-scarce semi-arid environments. Full article

Shiqian County, located within a key geothermal fluids belt in Guizhou Province, China, has abundant underground hot water resources. Therefore, elucidating the hydrogeochemical characteristics and formation mechanisms of thermal mineral water in this area is essential for evaluating and sustainably utilizing regional geothermal fluids. This study focuses on the Shiqian Hot Spring Group and employs integrated analytical techniques, including rock geochemistry, hydrogeochemistry, isotope hydrology, digital elevation model (DEM) data analysis, remote sensing interpretation, geological surveys, mineral saturation index calculations, and PHREEQC-based inverse hydrogeochemical modeling, to elucidate its hydrogeochemical characteristics and formation mechanisms. The results show that strontium concentrations range from 0.06 to 7.17 mg/L (average 1.65 mg/L) and metasilicic acid concentrations range from 19.46 to 65.51 mg/L (average 33.64 mg/L). Most samples meet the national standards for natural mineral water and are classified as Sr-metasilicic acid type. Isotope analysis indicates that the geothermal water is recharged by meteoric precipitation at elevations between 911 m and 1833 m, mainly from carbonate outcrops and fracture zones on the southwestern slope of Fanjingshan, and discharges south of Shiqian County. The dominant hydrochemical types are HCO₃·SO₄-Ca·Mg and HCO₃-Ca·Mg. Strontium is primarily derived from carbonate rocks and celestite-bearing evaporites, whereas metasilicic acid mainly originates from quartz dissolution along the upstream groundwater flow path. PHREEQC-based inverse modeling indicates that, during localized thermal mineral water runoff in the middle-lower reaches or discharge areas, calcite dissolves while dolomite and quartz tend to precipitate, reflecting calcite dissolution-dominated water–rock interactions and near-saturation conditions for some minerals at late runoff stages. Full article

Aeolian sand in arid mining regions is highly susceptible to wind erosion, posing serious threats to ecological stability and surface engineering safety. To enhance its resistance, this study applied the microbially induced carbonate precipitation (MICP) technique and conducted wind tunnel experiments combined with SEM and XRD analyses to examine the effects of cementing solution type and concentration, bacteria-to-cementation-solution ratio (B/C ratio), and spraying volume on the wind erosion behavior of MICP-treated aeolian sand. Results show that the cementing solution type and concentration jointly control erosion resistance. The MgO-based system exhibited the best performance at a B/C ratio of 1:2, reducing erosion loss by 47.2% compared with the CaCl₂ system, while a 1.0 mol/L concentration further decreased loss by 97.4% relative to 0.5 mol/L. Increasing the spraying volume from 0.6 to 1.2 L/m² reduced erosion loss by 70–99%, and a moderate B/C ratio (1:2) ensured balanced microbial activity and uniform CaCO₃ deposition. Microstructural observations confirmed that MICP strengthened the sand through CaCO₃ crystal attachment, pore filling, and interparticle bridging, forming a dense surface crust with enhanced integrity. From a symmetry perspective, the microbially induced mineralization process promotes a more symmetric and spatially uniform distribution of carbonate precipitates at particle contacts and within pore networks. This symmetry-enhanced microstructural organization plays a key role in improving the macroscopic stability and wind erosion resistance of aeolian sand. Overall, MICP improved wind erosion resistance through a coupled biological induction–chemical precipitation–structural reconstruction mechanism, providing a sustainable approach for eco-friendly sand stabilization and wind erosion control in arid mining regions. Full article

Agricultural nonpoint source pollution is emerging as one of the increasingly serious environmental concerns all over the world. This study conducted field experiments in Zengcheng District, Guangzhou City, from 2019 to 2023 to explore the mechanisms by which different crop types, fertilization modes, and meteorological conditions affect the loss of nitrogen and phosphorus in agricultural nonpoint source pollution. In rice and corn, the CK and PK treatment groups showed significant fitting advantages, such as the R² of rice-CK reaching 0.309. MAE was 0.395, and the R² of corn-PK was as high as 0.415. For compound fertilization groups such as NPK and OF, the model fitting ability decreased, such as the R² of rice-NPK dropping to 0.193 and the R² of corn-OF being only 0.168. In addition, the overall performance of the model was limited in the modeling of total phosphorus. A relatively good fit was achieved in corn (such as NPK group R² = 0.272) and in vegetables and citrus. R² was mostly below 0.25. The results indicated that fertilization management, crop types, and meteorological conditions affected nitrogen and phosphorus losses in agricultural runoff. Cornfields under conventional nitrogen, phosphorus, and potassium fertilizer (NPK) and conventional nitrogen and potassium fertilizer treatment without phosphorus fertilizer (NK) treatments exhibited the highest nitrogen losses, while citrus fields showed elevated phosphorus concentrations under NPK and PK treatments. Organic fertilizer treatments led to moderate nutrient losses but greater variability. Organic fertilizer treatments resulted in moderate nutrient losses but showed greater interannual variability. Meteorological drivers differed among crop types. Nitrogen enrichment was mainly associated with high temperature and precipitation, whereas phosphorus loss was primarily triggered by short-term extreme weather events. Linear regression models performed well under simple fertilization scenarios but struggled with complex nutrient dynamics. Crop-specific traits such as flooding in rice fields, irrigation in corn, and canopy coverage in citrus significantly influenced nutrient migration. The findings of this study highlight that nutrient losses are jointly regulated by crop systems, fertilization practices, and meteorological variability, particularly under extreme weather conditions. These findings underscore the necessity of crop-specific and climate-adaptive nutrient management strategies to reduce agricultural nonpoint source pollution. By integrating long-term field observations with machine learning–based analysis, this study provides scientific evidence to support sustainable fertilizer management, protection of water resources, and environmentally responsible agricultural development in subtropical regions. The proposed approaches contribute to sustainable land and water resource utilization and climate-resilient agricultural systems, aligning with the goals of sustainable development in rapidly urbanizing river basins. Full article

The dissimilar joining of solid-solution-strengthened superalloys and precipitation-strengthened superalloys enables complementary performance synergy, holding significant application potential in the aerospace industry. This study investigated the transient liquid phase bonding of Hastelloy X and IN738 using a BNi-2 interlayer, focusing on the effects of bonding temperature and time on interfacial microstructure evolution and mechanical properties. The results demonstrated that achieving complete isothermal solidification is paramount for joint properties, a process governed by the synergistic control of bonding temperature and time. At lower temperatures (e.g., 1050 °C), the joint centerline contained an athermal solidification zone (ASZ) rich in hard and brittle Cr-rich (∼15.9 GPa) and Ni-rich borides, which served as the failure initiation site. As the ASZ was progressively eliminated with increasing temperature, a fully isothermal solidified zone (ISZ, ∼52 μm wide) consisting of γ-Ni formed at 1100 °C. Concurrently, Cr-Mo borides (∼9.8 GPa) precipitated within the diffusion-affected zone (DAZ) on the Hastelloy X side, becoming the new potential sites for crack initiation. Prolonging the holding time at 1100 °C not only ensured complete isothermal solidification but also promoted Mo diffusion, which improved the plasticity of the Cr-Mo borides and their interfacial bonding with the γ-Ni matrix (∼5.9 GPa). This synergistic optimization resulted in a significant increase in joint shear strength, achieving a maximum value of 587 MPa under the optimal condition of 1100 °C/40 min. Full article

Nickel–Aluminum–Bronze (NAB) has gained significant attention in marine applications due to its excellent corrosion resistance and has shown growing potential for laser powder bed fusion (L-PBF) additive manufacturing. However, research on the fabrication of NAB alloys using L-PBF remains relatively limited. In this study, fully dense NAB samples were successfully fabricated through L-PBF process parameter optimization. The microstructural evolution and mechanical properties of both as-built and annealed L-PBF samples were systematically investigated and compared with those of traditionally cast NAB. The results reveal that the as-built L-PBF specimens primarily consist of columnar β′ grains, with the α phase distributed along the grain boundaries and a small amount of κ phase precipitated within the β′ matrix, distinctly different from the cast microstructure characterized by a columnar α-phase matrix with precipitated β′ and κ phases. After annealing at 675 °C for 6 h, the β′ phase in both methods decomposed into α + κ phases, and the original columnar structure in the L-PBF specimens transformed into a dendritic morphology. Compared to the cast samples, the L-PBF-produced NAB alloy exhibited significantly enhanced yield strength, tensile strength, and microhardness, attributable to rapid solidification during the L-PBF process. Following annealing, the yield strength and elongation increased by 12.8% and 184.4%, respectively, compared to the as-built condition, resulting from the decomposition of the martensitic phase into α + κ phases and further grain refinement. Full article

Improper disposal of granite sawdust from stone processing and heavy metal-containing tailings sand can pose severe threats to the environment and human health. Based on their physicochemical properties, granite sawdust was used to synthesize a zeolite-based stabilizer (GFAS) for immobilizing lead (Pb) and zinc (Zn) in tailings waste. The stabilizer was prepared through an alkali fusion–hydrothermal method, followed by phosphoric acid modification. Characterization by XRD, SEM-EDS, and BET revealed that GFAS possesses a Na-P1 zeolite structure (Na₆Al₆Si₁₀O₃₂) with a micro-mesoporous texture and a specific surface area of 35.00 m²/g, representing a 10-fold increase over raw sawdust. The cation exchange capacity (CEC) of GFAS reached 57.08 cmol⁺/kg, a 116-fold enhancement. The stabilization mechanism involved synergistic physical adsorption, chemical precipitation (e.g., Pb₃(PO₄)₂, Zn(OH)₂), and ion exchange. This study presents a sustainable “waste-treats-waste” strategy for effectively reducing the mobility of heavy metals in tailings waste, thereby contributing to the remediation of seepage from tailings pond foundations. Full article

Titanium compounds are an integral component for paint pigments, food additives (E171), catalysts, precursors for resistant structural materials, medicine, and water, and air purification and disinfection processes. A new and rather promising trend for titanium dioxide production is obtaining it from minerals with magnesium titanium structure. Magnesium titanates obtained by pyrometallurgical processing of quartz–leucoxene concentrate (oil sandstones). It was found that the optimal pyrometallurgical processing conditions were 4 h and a temperature of 1425–1450 °C, with TiO₂ → Mg_XTi_YO_Z conversion exceeding 95%, and that sulfation of the magnesium titanate mixture with 60–70% H₂SO₄ for 150–210 min allows a 95% extraction of titanium compounds into solution. Investigation of the mechanism of titanium compound precipitation from Mg-Ti-containing sulfuric acid solutions revealed that in the pH range from 3 to 6, only titanium compounds were extracted from solution, while coprecipitation of magnesium compounds begins only at pH above 6.5. The product obtained by precipitation is titanium dioxide with an anatase structure, with particle distribution ranging from 0.8 to 5.0 µm and a developed surface area over 250 m²/g with mesopores characteristic of sorption materials. Full article

This research systematically investigates the influence of multi-microalloying with Sn, Mn, Er, and Zr on the homogenized microstructure, aging behavior, and mechanical properties of a 6082 Al-Mg-Si alloy. The optimization of the homogenization treatment for the alloy was based on isochronal aging curves and conductivity measurements. The results show that the addition of Mn, Er, and Zr can precipitate thermally stable Al(Fe,Mn)Si dispersoids and Al(Er,Zr) dispersoids. The three-stage homogenization treatment resulted in the precipitation of more heat-resistant dispersoids, thereby achieving the best thermal stability. During direct artificial aging, the initial hardening rate of the Mn-containing alloy was slightly delayed, but its peak hardness was significantly increased. This is due to the dispersoids offering additional heterogeneous nucleation sites for the strengthening precipitates. Meanwhile, the Sn atoms release their trapped vacancies at the aging temperature, thereby promoting atomic diffusion. However, short-term natural aging before artificial aging accelerated the early-stage aging response of the Sn-containing alloy but resulted in a reduced peak hardness. Notably, the co-microalloying with Mn and Sn led to a higher peak hardness during direct artificial aging, while it caused a more significant hardness loss when a natural aging preceded artificial aging, revealing a distinct synergistic negative effect. The reason for the negative synergy effect might be related to the weakened ability of Sn to release vacancies after natural aging. This study clarifies the process dependence of microalloying effects, providing a theoretical basis for optimizing aluminum alloy properties through the synergistic design of composition and processing routes. Full article

This study investigates the adsorption and migration of sulfadiazine (SDZ) in soda saline–alkali soils under Cu/Zn co-pollution using equilibrium adsorption and soil column experiments. Freundlich and Langmuir isothermal models, combined with Hydrus-1D two-site modeling, revealed concentration-dependent interactions. Low Cu (10–100 mg kg⁻¹) and Zn (10–100 mg kg⁻¹) enhanced SDZ adsorption via charge regulation and complexation, while high concentrations (300 mg kg⁻¹) suppressed adsorption through competitive adsorption and hydroxide precipitation. Synergistic Cu-Zn coexistence further reduced adsorption to 3.035 mg kg⁻¹. Freundlich modeling (R² = 0.922–0.995) outperformed Langmuir, confirming adsorption site heterogeneity. Column experiments showed Cu (300 mg kg⁻¹) and Zn (300 mg kg⁻¹) accelerated SDZ migration (peaks 0.93–0.94), delaying breakthrough versus Br⁻. Hydrus-1D simulations (R² ≥ 0.915, RMSE < 0.1) effectively quantified nonlinear dynamics between instantaneous adsorption sites (f = 0.101–0.554) and metal concentrations. Results demonstrate heavy metals critically regulate antibiotic fate via concentration-dependent mechanisms in saline–alkali ecosystems. Full article

Magnetic filaments for fused deposition modeling, 3D printing, were produced by depositing polyamide 11 (PA11), by liquid–liquid phase separation and precipitation, onto exchange-coupled nanocomposite magnetic powders, SmCo₅ + 20 wt% Fe produced by mechanical milling and subsequent annealing. The produced filaments have good mechanical properties, a tensile strength of 32 MPa and a maximum elongation of slightly over 40%. The filaments also present good magnetic properties: a high coercive field of 1 T at 300 K and nearly double the saturation magnetization and remanence, compared to filaments made by depositing PA11 on commercial SmCo₅ and recycled SmCo₅ powders and four times the energy product. This work shows that magnetic filaments made by encapsulating exchange-coupled magnetic nanocomposite powders in PA11 may be a viable option for the production of 3D-printed isotropic bonded magnets, as the high energy product and remanence especially can lead to a reduction in both magnetic powder quantity and rare earth elements required for high performance magnetic filaments. This in turn may reduce costs and improve sustainability. Full article

Hunan Province from 2000 to 2023 is the study area. Based on NOAA precipitation data and county-level rice yield statistics in Hunan Province, the Mann–Kendall test, extreme precipitation indices, and wavelet analysis examine the spatial and temporal evolution characteristics of extreme precipitation and its multi-scale impact on rice yield. The results show that the extreme precipitation in Hunan Province showed a stable pattern of fluctuation, and the main extreme precipitation indexes had no significant change trend. The spatial distribution showed a pattern of “high value in central-northern Hunan and stable in southern Hunan”, and the precipitation was concentrated in June–August. The rice yield showed the characteristics of “stable increase in the core area, intensified fluctuation in the transition area, and continuous shrinkage in the marginal area”, and the Dongting Lake Plain was a high-yield and stable area. Multi-scale analysis shows significant coupling between extreme precipitation and yield: in the 4–8-year cycle, the peak value of precipitation lags behind the response of 1–2 years, and changes synchronously in a short period. The response of rice to extreme precipitation showed a threshold-type nonlinear characteristic. Moderate wetting was beneficial to stable yield, while the yield decreased significantly when the intensity or continuous precipitation exceeded the threshold. Hunan’s rice system has strong climate resilience but requires a multi-scale climate-adaptive agricultural system via engineering, technology, and policy for long-term stability and sustainable grain production. Full article