Search Results (6,034)

Pseudo-persistent organic pollutants, such as pharmaceuticals, personal care products (PPCPs), and organic dyes, are a major issue in current environmental engineering. Considering the limitations of traditional wastewater treatment plant methods and degradation technologies for organic pollutants, the search for new technologies more suitable for treating these new types of pollutants has become a research hotspot in recent years. Membrane filtration, adsorption, advanced oxidation, and electrochemical advanced oxidation technologies can effectively treat new organic pollutants. The electro-advanced oxidation process based on sulfate radicals is renowned for its non-selectivity, high efficiency, and environmental friendliness, and it can improve the dewatering performance of sludge after wastewater treatment. Therefore, in this study, octyl methoxycinnamate (OMC) was selected as the target pollutant. A new type of electrochemical filtration device based on the advanced oxidation process of sulfate radicals was designed, and a new type of modified carbon nanotube material electrode was synthesized to enhance its degradation effect. In a mixed system of water and acetonitrile, the efficiency of the electrochemical filtration device loaded with the modified electrode for degrading OMC is 1.54 times that at room temperature. The experimental results confirmed the superiority and application prospects of the self-designed treatment scheme for organic pollutants, providing experience and a reference for the future treatment of PPCP pollution. Full article

The discharge of oily wastewater threatens the ecosystem and human health, and the efficient treatment of oily wastewater is confronted with problems of high mass transfer resistance at the oil-water-solid multiphase interface, significant light shielding effect, and easy deactivation of photocatalysts. Although traditional physical separation methods avoid secondary pollution by chemicals and can effectively separate floating oil and dispersed oil, they are ineffective in removing emulsified oil with small particle sizes. To address these complex challenges, photocatalytic technology and photocatalysis-based improved technologies have emerged, offering significant application prospects in degrading organic pollutants in oily wastewater as an environmentally friendly oxidation technology. In this paper, the degradation mechanism, kinetic mechanism, and limitations of conventional photocatalysis technology are briefly discussed. Subsequently, the surface interface modulation functions of metal doping and heterojunction energy band engineering, along with their applications in enhancing the light absorption range and carrier separation efficiency, are reviewed. Focus on typical studies on the separation and degradation of aqueous and oily phases using photocatalytic membrane technology, and illustrate the advantages and mechanisms of photocatalysts loaded on the membranes. Finally, other new approaches and converging technologies in the field are outlined, and the challenges and prospects for the future treatment of oily wastewater are presented. Full article

Traditional ecotoxicology primarily investigates pollutant toxicity through physiological, biochemical, and single-molecular indicators. However, the limited data obtained through this approach constrain its application in the mechanistic analysis of pollutant toxicity. Omics technologies have emerged as a major research focus in recent years, enabling the comprehensive and accurate analysis of biomolecular-level changes. The integration of multi-omics technologies can holistically reveal the molecular toxicity mechanisms of pollutants, representing a primary emphasis in current toxicological research. This paper introduces the fundamental concepts of genomics, transcriptomics, proteomics, and metabolomics, while reviewing recent advancements in integrated omics approaches within aquatic toxicology. Furthermore, it provides a reference framework for the implementation of multi-omics strategies in ecotoxicological investigations. While multi-omics integration enables the unprecedented reconstruction of pollutant-induced molecular cascades and earlier biomarker discovery (notably through microbiome–metabolome linkages), its full potential requires experimental designs, machine learning-enhanced data integration, and validation against traditional toxicological endpoints within environmentally relevant models. Full article

The gut microbiota plays an essential role in the host’s metabolism. Its composition and structure depend on biological and environmental factors. This work was designed to identify the composition and structure of the wild and captive red grouper (Epinephelus morio) microbiota and make predictions regarding its metabolic functions. Our hypothesis stated that wild and captive individuals would share the most abundant taxonomic groups, forming a core microbiota, and individuals in captivity might have exclusive taxonomic groups. Metagenomic DNA was extracted from the intestinal contents of wild and captive individuals. The 16S rRNA gene was amplified and sequenced using Illumina pair-end technology. QIIME2 pipeline was used for sequence analysis and alpha and beta diversity assessment. PICRUSt was used to infer metabolic functions. Twenty-nine phyla were identified; the most abundant were Pseudomonadota, Bacillota, Fusobacteriota, and Actinomycetota. The dominant genera were Photobacterium, Vibrio, Cetobacterium, and Escherichia-Shigella. The metabolic prediction analysis suggested that the Epinephelus morio gut microbiota is related to food digestion, the immune system, antioxidant enzymes, antibiotic resistance, and vitamin B12 transport. We concluded that the microbiota of E. morio established in captivity is sensitive to environmental changes such as water pollution, which can cause a decrease in diversity. Full article

In response to increasingly stringent emission regulations, low-carbon fuels have received significant attention as sustainable energy sources for internal combustion engines. This study investigates four representative low-carbon fuels, methane, methanol, hydrogen, and ammonia, by systematically summarizing their combustion characteristics and emission profiles, along with a review of existing after-treatment technologies tailored to each fuel type. For methane engines, unburned hydrocarbon (UHC) produced during low-temperature combustion exhibits poor oxidation reactivity, necessitating integration of oxidation strategies such as diesel oxidation catalyst (DOC), particulate oxidation catalyst (POC), ozone-assisted oxidation, and zoned catalyst coatings to improve purification efficiency. Methanol combustion under low-temperature conditions tends to produce formaldehyde and other UHCs. Due to the lack of dedicated after-treatment systems, pollutant control currently relies on general-purpose catalysts such as three-way catalyst (TWC), DOC, and POC. Although hydrogen combustion is carbon-free, its high combustion temperature often leads to elevated nitrogen oxide (NO_x) emissions, requiring a combination of optimized hydrogen supply strategies and selective catalytic reduction (SCR)-based denitrification systems. Similarly, while ammonia offers carbon-free combustion and benefits from easier storage and transportation, its practical application is hindered by several challenges, including low ignitability, high toxicity, and notable NO_x emissions compared to conventional fuels. Current exhaust treatment for ammonia-fueled engines primarily depends on SCR, selective catalytic reduction-coated diesel particulate filter (SDPF). Emerging NO_x purification technologies, such as integrated NO_x reduction via hydrogen or ammonia fuel utilization, still face challenges of stability and narrow effective temperatures. Full article

This review examines the research progress on non-noble-metal-based catalysts for formaldehyde (HCHO) oxidation at room temperature. It begins with an introduction to the hazards of HCHO as an indoor pollutant and the urgency of its removal, comparing several HCHO removal technologies and highlighting the advantages of room-temperature catalytic oxidation. It delves into the classification, preparation methods, and regulation strategies for non-precious metal catalysts, with a focus on manganese-based, cobalt-based, and other transition metal-based catalysts. The effects of catalyst preparation methods, morphological structure, and specific surface area on catalytic performance are discussed, and the catalytic oxidation mechanisms of HCHO, including the Eley–Rideal, Langmuir–Hinshelwood, and Mars–van Krevelen mechanisms, are analyzed. Finally, the challenges faced by non-precious metal catalysts are summarized, such as issues related to the powder form of catalysts in practical applications, lower catalytic activity at room temperature, and insufficient research in the presence of multiple VOC molecules. Suggestions for future research directions are also provided. Full article

Educational buildings, including schools, nurseries and universities, face stricter regulation and design control on indoor air quality (IAQ) and thermal conditions than other built environments, as these may affect children’s health and wellbeing. In this scoping review, wide-ranging health, performance, and absenteeism consequences of poor—and benefits of good—IAQ and thermal conditions are evaluated, focusing on source control, ventilation and air purification interventions. Economic impacts of interventions in educational buildings have been evaluated to enable the assessment of tangible building-related costs and savings, alongside less easily quantifiable improvements in educational attainment and reduced healthcare. Key recommendations are provided to assist decision makers in pathways to provide clean air, at an optimal temperature for students’ learning and health outcomes. Although the role of educational buildings can be challenging to isolate from other socio-economic confounders, secondary short- and long-term impacts on attainment and absenteeism have been demonstrated from the health effects associated with various pollutants. Sometimes overlooked, source control and repairing existing damage can be important cost-effective methods in minimising generation and preventing ingress of pollutants. Existing ventilation standards are often not met, even when mechanical and hybrid ventilation systems are already in place, but can often be achieved with a fraction of a typical school budget through operational and maintenance improvements, and small-scale air-cleaning and ventilation technologies, where necessary. Full article

This review critically examines the recent advancements in the development and application of electrospun molecularly imprinted polymer (MIP) nanofiber membranes for environmental remediation. Emphasizing the significance of these materials, the discussion highlights the mechanisms by which electrospun MIPs achieve high selectivity and efficiency in removing various pollutants, including dyes, heavy metals, and pharmaceutical residues such as NSAIDs and antiretroviral drugs. The synthesis methodologies are explored in detail, focusing on the choice of monomers, templates, and polymerization conditions that influence the structural and functional properties of the membranes. Characterization techniques used to assess morphology, surface area, porosity, and imprinting efficacy are also examined, providing insights into how these parameters affect adsorption performance. Furthermore, the review evaluates the performance metrics of electrospun MIPs, including adsorption capacities, selectivity, reusability, and stability in complex environmental matrices. Practical considerations, such as scalability, regeneration, and long-term operational stability, are discussed to assess their potential for real-world applications. The article concludes with an outline of future research directions, emphasizing the need for multi-template imprinting, integration with existing treatment technologies, and field-scale validation to address current limitations. Full article

The maritime sector is undergoing rapid transformation, driven by increasingly stringent international regulations targeting air pollution. While newly built vessels integrate advanced technologies for compliance, the global fleet averages 21.8 years of age and must meet emission requirements through retrofitting or operational changes. This study evaluates, at environmental and economic levels, two key sulphur abatement strategies for a 1998-built cruise vessel nearing the end of its service life: (i) the installation of open-loop scrubbers with fuel enhancement devices, and (ii) a switch to marine diesel oil as main fuel. The analysis was based on real operational data from a cruise vessel. For the environmental assessment, a Tier III hybrid emissions model was used. The results show that scrubbers reduce SO_x emissions by approximately 97% but increase fuel consumption by 3.6%, raising both CO₂ and NO_x emissions, while particulate matter decreases by only 6.7%. In contrast, switching to MDO achieves over 99% SO_x reduction, an 89% drop in particulate matter, and a nearly 5% reduction in CO₂ emissions. At an economic level, it was found that, despite a CAPEX of nearly USD 1.9 million, scrubber installation provides an average annual net saving exceeding USD 8.2 million. From the deterministic and probabilistic analyses performed, including Monte Carlo simulations under various fuel price correlation scenarios, scrubber installation consistently shows high profitability, with NPVs surpassing USD 70 million and payback periods under four months. Full article

As the most unstable crystalline form of calcium carbonate, vaterite is rarely found in nature due to being highly prone to phase transitions. However, its high specific surface area, excellent biocompatibility, and high solubility properties have led to a research boom and the following breakthroughs in the last two decades: (1) From primitive calculations and spectroscopic analyses to modern multidimensional research methods combining calculations and experiments, the crystal structure of vaterite has turned from early identifications in orthorhombic and hexagonal crystal systems to a complex polymorphic structure within the monoclinic crystal system. (2) The formation process of vaterite not only conforms to the classical crystal growth theory but also encompasses the nanoparticle aggregation theory, which incorporates the concepts of oriented nanoparticle assembly and mesoscale transformation. (3) Regardless of the conditions, the formation of vaterite depends on an excess of CO₃²⁻ relative to Ca²⁺, and its stability duration relates to preservation conditions. (4) Vaterite demonstrates significant value in biomedical applications—including bone repair scaffolds, targeted drug carriers, and antibacterial coating materials—leveraging its porous structure, high specific surface area, and exceptional biocompatibility. While it also shows utility in environmental pollutant adsorption and general coating technologies, the current research remains predominantly concentrated on its medical applications. Currently, the rapid transformation of vaterite presents the primary limitation for its industrial application. Future research should prioritize investigating its formation kinetics and stability. Full article

The improvement of environmental conditions has become a priority for governments and legislators. New electrified mobility systems are increasingly present in our environment, as they enable the reduction of polluting emissions. Electric vehicles (EVs) are one of the fastest-growing alternatives to date, with exponential growth expected over the next few years. In this article, the various charging modes for EVs are explored, and the risks associated with charging technologies are analysed, particularly for charging systems in high-power DC with Lithium battery energy storage, given their long market deployment and characteristic behaviour. In particular, the Arc Flash (AF) risk present in high-power DC chargers will be studied, involving numerous simulations of the charging process. Subsequently, the Incident Energy (IE) analysis is carried out at different specific points of a commercial high-power ‘Mode 4’ charger. For this purpose, different analysis methods of recognised prestige, such as Doan, Paukert, or Stokes and Oppenlander, are applied, using the latest version of the ETAP^® simulation tool version 22.5.0. This study focuses on quantifying the potential severity (consequences) of an AF event, assuming its occurrence, rather than performing a probabilistic risk assessment according to standard methodologies. The primary objective of this research is to comprehensively quantify the potential consequences for workers involved in the operation, maintenance, repair, and execution of tasks related to EV charging systems. This analysis makes it possible to provide safe working conditions and to choose the appropriate and necessary personal protective equipment (PPE) for each type of operation. It is essential to develop this novel process to quantify the consequences of AF and to protect the end users of EV charging systems. Full article

This study intends to portray how varying degrees of environmental policy stringency and the growing pressure of global competition reflect on high-tech (HT) sectors’ cost rationalization strategies and lead to environmental consequences in 15 G20 countries (1992–2019). Moreover, we center the pattern of cost rationalization management regarding the opportunity cost of ecosystem service consumption and propose to test the fundamental hypothesis stating the possible transmission of competition-induced technological innovations to green economic transformation. Our new methodology estimates quantile-specific effects with MM-QR, while identifying the main interaction effects between regulatory pressure and trade competition uses an extended STIRPAT model. The results reveal a paradoxical finding: despite higher environmental policy stringency and opportunity costs of ecosystem services, HT sectors persistently adopt environmentally detrimental cost-reduction approaches. These findings carry important policy implications: (1) environmental regulations for HT sectors require complementary innovation subsidies, (2) trade agreements should incorporate clean technology transfer clauses, and (3) governments must monitor sectoral emission leakage risks. Our dual machine learning–econometric approach provides policymakers with targeted insights for different emission scenarios, highlighting the need for differentiated strategies across clean and polluting HT subsectors. Full article

Coal gangue, a major by-product of coal mining, poses significant environmental challenges due to its large-scale accumulation, land occupation, and potential for air and water pollution. This manuscript presents a comprehensive overview of continuous chamber gangue storage technology as a sustainable mining solution for coal mines. The principles of this approach emphasize minimizing disturbance to overlying strata, enabling uninterrupted mining operations, and reducing both production costs and environmental risks. By storing the surface or underground gangue in continuous chambers, the proposed method ensures the roof stability, maximizes the waste storage, and prevents the interaction between mining and waste management processes. Detailed storage sequences and excavation methods are discussed, including continuous and jump-back excavation strategies tailored to varying roof conditions. The process flows for both underground and ground-based chamber storage are described, highlighting the integration of gangue crushing, paste preparation, and pipeline transport for efficient underground storage. In a case study with annual storage of 500,000 t gangue, the annual economic benefit reached CNY 1,111,425,000. This technology not only addresses the urgent need for sustainable coal gangue management, but also aligns with the goals of resource conservation, ecological protection, and the advancement of green mining practices in the coal industry. Full article

The contamination of drinking water sources with selenium (Se) oxyanions, including selenite (Se(IV)) and selenate (Se(VI)), contains serious health hazards with an oral intake exceeding 400 µg/day and therefore requires urgent attention. Various natural and anthropogenic sources are responsible for high Se concentrations in aquatic environments. In addition, the chemical behavior and speciation of selenium can vary noticeably depending on the origin of the source water. The Se(VI) oxyanion is more soluble and therefore more abundant in surface water. Se levels in contaminated waters often exceed 50 µg/L and may reach several hundred µg/L, well above drinking water limits set by the World Health Organization (40 µg/L) and Germany (10 µg/L), as well as typical industrial discharge limits (5–10 µg/L). Overall, Se is difficult to remove using conventionally available physical, chemical, and biological treatment technologies. The recent literature has therefore highlighted promising advancements in Se removal using emerging technologies. These include advanced physical separation methods such as membrane-based treatment systems and engineered nanomaterials for selective Se decontamination. Additionally, other integrated approaches incorporating photocatalysis coupled adsorption processes, and bio-electrochemical systems have also demonstrated high efficiency in redox transformation and capturing of Se from contaminated water bodies. These innovative strategies may offer enhanced selectivity, removal, and recovery potential for Se-containing species. Here, a current review outlines the sources, distribution, and chemical behavior of Se in natural waters, along with its toxicity and associated health risks. It also provides a broad and multi-perspective assessment of conventional as well as emerging physical, chemical, and biological approaches for Se removal and/or recovery with further prospects for integrated and sustainable strategies. Full article

With the rapid growth of energy demand, the development of efficient energy-conversion technologies (e.g., water splitting, fuel cells, metal-air batteries, etc.) becomes an important way to circumvent the problems of fossil fuel depletion and environmental pollution, which motivates the pursuit of high-performance electrocatalysts with controllable compositions and morphologies. Among them, two-dimensional (2D) Pt-group metallic electrocatalysts show a series of distinctive architectural merits, including a high surface-to-volume ratio, numerous unsaturated metal atoms, an ameliorative electronic structure, and abundant electron/ion transfers channels, thus holding great potential in realizing good selectivity, rapid kinetics, and high efficiency for various energy-conversion devices. Considering that great progress on this topic has been made in recent years, here we present a panoramic review of recent advancements in 2D Pt-group metallic nanocrystals, which covers diverse synthetic methods, structural analysis, and their applications as electrode catalysts for various energy-conversion technologies. At the end, the paper also outlines the research challenges and future opportunities in this emerging area. Full article