Search Results (1,132)

In the present work, six biochars were produced from the pyrolysis of poultry manure at 400 °C and 600 °C (PM-B-400 and PM-B-600), and their post-modification with, respectively, iron chloride (PM-B-400-Fe and PM-B-600-Fe) and potassium permanganate (PM-B-400-Mn and PM-B-600-Mn). First, these biochars were deeply characterized through the assessment of their particle size distribution, pH, electrical conductivity, pH at point-zero charge, mineral composition, morphological structure, and surface functionality and crystallinity, and then valorized as biofertilizer to grow spring barley at pot-scale for 40 days. Characterization results showed that Fe- and Mn-based nanoparticles were successfully loaded onto the surface of the post-modified biochars, which significantly enhanced their structural and surface chemical properties. Moreover, compared to the control treatment, both raw and post-modified biochars significantly improved the growth parameters of spring barley plants (shoot and root length, biomass weight, and nutrient content). The highest biomass production was obtained for the treatment with PM-B-400-Fe, owing to its enhanced physico-chemical properties and its higher ability in releasing nutrients and immobilizing heavy metals. These results highlight the potential use of Fe-modified poultry manure-derived biochar produced at low temperatures as a sustainable biofertilizer for soil enhancement and crop yield improvement, while addressing manure management issues. Full article

Oxybenzone (OBZ), an organic ultraviolet filter, is an emerging contaminant posing severe threats to ecosystem health. Using tobacco (Nicotiana tabacum) as a model plant, this study investigated the alleviation mechanisms of exogenous silicon (Na₂SiO₃, Si) and bamboo-based biochar (Bc) under OBZ stress. We systematically analyzed physiological and biochemical responses, including phenotypic parameters, reactive oxygen species metabolism, photosynthetic function, chlorophyll synthesis, and endogenous hormone levels. Results reveal that OBZ significantly inhibited tobacco growth and triggered a reactive oxygen species (ROS) burst. Additionally, OBZ disrupted antioxidant enzyme activities and hormonal balance. Exogenous Bc mitigated OBZ toxicity by adsorbing OBZ, directly scavenging ROS, and restoring the ascorbate-glutathione (AsA-GSH) cycle, thereby enhancing photosynthetic efficiency, while Si alleviated stress via cell wall silicification, preferential regulation of root development and hormonal signaling, and repair of chlorophyll biosynthesis precursor metabolism and PSII function. The mechanisms of the two stress mitigators were complementary, Bc primarily relied on physical adsorption and ROS scavenging, whereas Si emphasized metabolic regulation and structural reinforcement. These findings provide practical strategies for simultaneously mitigating organic UV filter pollution and enhancing plant resilience in contaminated soils. Full article

Climate change negatively affects agriculture, causing desertification, salinisation, and drought. The biochar hydroinfiltrator (ES Patent No.: ES2793448 B2) is a device that increases the capture of rainwater or irrigation water for crops by increasing infiltration rates. Biochar, produced via biomass pyrolysis, has emerged as a promising agricultural amendment, as it helps to optimise moisture retention and improve soil structure, key aspects for boosting crop yields. There is growing interest in microorganisms’ plant-growth-promoting activity (PGP) by carrying out different activities considered growth promoters. The aim of the present study is to evaluate the use of a biochar hydroinfiltrator as a promoter of microbial activity when it is used in soil. Metagenomic analysis of soils with and without the device reveals that genera Bacillus and Sphingomonas became particularly enriched in soils with hydroinfiltrators. Also, in order to understand the interaction between the uses of biochar together with bacteria PGP, an in vitro test was carried out. Two microorganisms, previously selected for their characteristics as plant growth promoters, were inoculated in soils with and without biochar and they grew better after 15 to 30 days of inoculation, showing major CFU counts. This combined strategy—biochar hydroinfiltrator and PGP bacteria—offers an innovative, eco-friendly approach to sustainable agriculture, particularly under drought stress. Full article

Heavy metal-contaminated soil poses a severe threat to environmental quality and human health, calling for eco-friendly and efficient remediation strategies. This study explored the use of biochar-immobilized copper-resistant Pseudomonas aeruginosa to remediate copper-contaminated soil and promote growth of Chinese milk vetch (Astragalus sinicus L.). Indoor pot experiments compared four groups: copper-contaminated soil (control), soil with biochar, soil with free bacteria, and soil with biochar-immobilized bacteria (IM). Results showed IM had the most significant effects on soil properties: it raised pH to 7.04, reduced bioavailable copper by 34.37%, and increased catalase (3.48%) and urease (78.95%) activities. IM also altered soil bacterial communities, decreasing their richness and evenness (alpha diversity) while shifting community composition. For Chinese milk vetch, IM reduced leaf malondialdehyde (a marker of oxidative stress) by 15%, increased total dry weight by 90%, and lowered copper accumulation in roots (18.62%) and shoots (60.33%). As a nitrogen-fixing plant, the vetch’s nitrogen fixation in roots and shoots rose by 82.70% and 57.08%, respectively, under IM. These findings demonstrate that biochar-immobilized Pseudomonas aeruginosa is a promising in situ amendment for remediating copper-contaminated soil and boosting plant growth. Full article

The low nitrogen-use efficiency (NUE) in sandy soils, due to high porosity and poor nutrient retention, necessitates proper management in fertilization. This study aims to evaluate the effect of biochar-coated urea (BCU) with different coating thicknesses and nitrogen doses on soil nitrogen content, nitrogen uptake, NUE, growth, and yield of sweet corn in sandy soil. The experiment used a factorial randomized block design with two factors, including biochar coating thicknesses (i.e., 14% and 29%) and fertilization doses (i.e., 50%, 100%, 150%, 200%, and 250%). The results showed that the 29% biochar coating thickness led to 9.9–21.3% higher plant height, N uptake, and N-use efficiency, but it led to 22.8% lower yield, as compared to the 14% biochar coating thickness. Additionally, the application of BCU doses of 100% and 150% (~161 and 241.5 kg N/ha) led to 9.2–97.3% higher maize growth, yield, N uptake, and NEU as compared to the other doses (i.e., 50%, 100%, 250%). This study confirmed that the combination of a 29% biochar coating thickness with 150% of the recommended BCU dose (~241.5 kg N/ha) was the best combination, resulting in the highest N uptake, growth, and yield of maize. Full article

Biochar, a porous carbonaceous material derived from the pyrolysis of biomass under oxygen-limited conditions, offers several advantages for environmental remediation, including a high specific surface area, ease of preparation, and abundant raw material sources. However, the application of pristine biochar is limited by its inherent physicochemical shortcomings, such as a lack of active functional groups and limited elemental compositions. To overcome these limitations, metal-modified biochars have garnered increasing attention. In particular, iron-manganese (Fe-Mn) modification significantly enhances the adsorption capacity, redox potential, and microbial activity of biochar, owing to the synergistic interactions between Fe and Mn. Iron-manganese-modified biochar (FM-BC) has demonstrated effective removal of heavy metals, organic matter, phosphate, and nitrate through mechanisms including mesoporous adsorption, redox reactions, complexation, electrostatic interactions, and precipitation. Moreover, FM-BC can improve soil physicochemical properties and support plant growth, highlighting its promising potential for broader environmental application. This review summarizes the preparation methods, environmental remediation mechanisms, and practical applications of FM-BC and discusses future directions in mechanism elucidation, biomass selection, and engineering implementation. Overall, FM-BC, with its tunable properties and multifunctional capabilities, emerges as a promising and efficient material for addressing complex environmental pollution challenges. Full article

Biochar has emerged as a promising soil amendment for mitigating heavy metal contamination in agricultural systems. This study investigates the effects of biochar on cadmium (Cd) and copper (Cu) uptake, plant growth, oxidative stress, and physiological responses in lettuce (Lactuca sativa L.) plants exposed to different metal concentrations. Results indicate that biochar significantly influenced Cd bioavailability, reducing its accumulation in plant tissues by up to 31.9% and alleviating oxidative stress, with malondialdehyde and proline levels decreasing by up to 51.0% and 60.2%, particularly at higher application rates (5%). Cd-exposed plants treated with biochar exhibited an improved fresh weight (+22.6%), lower malondialdehyde and proline levels, and enhanced the chlorophyll content (+14.9% to 24.1%) compared to untreated plants. The bioaccumulation factor for Cd decreased (up to 31.8%) while the immobilization index (II) increased, confirming the role of biochar in limiting Cd mobility in soil. In contrast, Cu uptake remained consistently low across all treatments, with a significant reduction observed only at higher contamination levels (up to −34.2%). Biochar contributed to Cu immobilization, reflected in increased II values, and enhanced the plant biomass and chlorophyll content under Cu exposure (+15.4% and up to +24.1%, respectively), suggesting a partial alleviation of Cu toxicity. These findings highlight biochar’s potential in heavy metal remediation, particularly for Cd, by reducing bioavailability and improving plant resilience. However, its role in Cu-contaminated soils is mainly through immobilization rather than uptake reduction. Full article

Every year, a large amount of antibiotics enter aquatic environments globally through discharging of pharmaceutical wastewater and domestic sewage, emissions from agriculture, and livestock, posing a severe threat to ecosystems and human health. Therefore, it is essential to develop efficient adsorption materials for rapid removal of antibiotics in water. In this study, abundant and renewable wetland plants (lotus leaves, Arundo donax, and canna lilies) were utilized as raw materials to prepare biochar through slow pyrolysis combined with KOH chemical activation. The prepared biochar was employed to adsorb typical tetracycline (TC) antibiotics (TC-HCl, CTC-HCl, OTC-HCl) from water. The results showed that the optimum biochar (LBC-600 (1:3)) was prepared at a pyrolysis temperature of 600 °C with the mass ratio of KOH to lotus leaf of 1:3. The optimum pH for the adsorption of the three antibiotics were 5, 4, and 3, respectively. The highest adsorption rates reached 93.32%, 81.44%, and 83.76% for TC-HCl, CTC-HCl, and OTC-HCl with 0.6 g/L of biochar, respectively. At an initial antibiotic concentration of 80 mg·L⁻¹, the maximum adsorption capacities achieved 40.17, 27.76, and 24.6 mg·g⁻¹ for TC-HCl, CTC-HCl, and OTC-HCl, respectively. The adsorption process conformed to the pseudo-second-order kinetic and Langmuir isotherm models, indicating that it was a spontaneous endothermic process and primarily involved monolayer chemical adsorption. This study transformed wetland plant waste into adsorbent and applied it for antibiotic removal, providing a valuable resource utilization strategy and technical support for recycling wetland plant residues and antibiotic removal from water environments. Full article

Organic amendments provide a sustainable strategy to enhance soil quality in degraded environments while also helping to reduce greenhouse gas emissions, for example, by improving soil structure, minimizing the use of synthetic fertilizers, and promoting a green economy. This study assessed the comparative effects of two organic amendments—vermicompost leachate and biochar—on the performance of popcorn maize (Zea mays L. var. everta) cultivated in saline soil conditions. Four treatments were evaluated: T0 (Control), T1 (Vermicompost leachate), T2 (Biochar), and T3 (Vermicompost leachate + Biochar), each with 10 replicates arranged in a Completely Randomized Design (CRD). Although various soil physicochemical, microbiological, and agronomic parameters displayed no significant differences compared to the control, the application of biochar resulted in considerable improvements in soil total organic carbon, the microbial community (mesophilic aerobic bacteria, molds, and yeasts), and increased seed length and diameter. In contrast, vermicompost leachate alone negatively impacted plant growth, leading to decreases in leaf area, stem thickness, and grain yield. Specifically, grain yield declined by 46% with leachate alone and by 31% when combined with biochar, compared to the control. These findings emphasize the superior effectiveness of biochar over vermicompost leachate as a soil amendment under saline conditions and highlight the potential risks of widely applying compost teas in stressed soils. It is recommended to conduct site-specific assessments and screenings for phytotoxins and phytopathogens prior to use. Additionally, the combined application of leachate and biochar may not be advisable given the tested soil characteristics. Full article

Biochar and seaweed fertilizers could improve soil quality and promote plant growth. However, the key soil factors and microbial mechanisms that drive maize growth in coastal saline–alkali soils remain unclear. A soil culture experiment was designed with four treatments—no organic fertilizer (CK), single seaweed fertilizer (F), single biochar (B), and combined application of seaweed fertilizer and biochar (BF)—to investigate the effects of biochar and seaweed fertilizer on maize growth and its mechanism. The results showed that B and BF significantly increased maize aboveground biomass by 8.86% and 17.28% compared to CK, respectively. The soil organic carbon, total nitrogen, available nitrogen, available phosphorus, available potassium content, and pH of B and BF were significantly increased. Bacterial diversity increased under B and BF, while fungal richness decreased under BF. The changes in the fungal community were mainly affected by soil available nitrogen, but there was no significant correlation between bacterial communities and these indicators. Pearson correlation analysis suggested that the bacterial Chao1 index was significantly positively correlated with maize growth indicators, soil available phosphorus, and available potassium, as well as the bacterial PD whole tree index with leaf area and available phosphorus. The fungal Shannon index was significantly negatively correlated with maize plant height, leaf area, SPAD, aboveground biomass, and soil total nitrogen and available nutrients. Overall, biochar and seaweed fertilization could significantly promote maize growth by improving soil chemical properties and microbial communities in coastal saline–alkali soils. Full article

The utilization of the widely distributed saline–alkali lands by planting forage grasses is a hot topic. However, the promotion of plant growth remains a great challenge during the exploration of this stressful soil. While halotolerant bacteria are beneficial for plants against saline–alkali stress, their stable colonization on plant roots should be further strengthened. In this study, we investigated the effect of moss biochar on the root colonization of the exogenous halotolerant Halomonas salifodinae isolated from saline lake sediments. During the incubation with the bacteria, the biochar strongly bound the bacterium and induced biofilm formation on the biochar surface. When the biochar and the bacterium were added into the culturing soil of the forage grass Medicago sativa, the biochar remarkably assisted the root binding and biofilm formation of this bacterium on the plant roots. Under the biochar–bacterium combined treatment, the numbers of total bacteria, halotolerant bacteria, and nitrogen-fixing bacteria increased from 10^5.5 CFU/g soil to 10^7.2 CFU/g soil, from 10^4.5 CFU/g soil to 10^6.1 CFU/g soil, and from 10^4.7 CFU/g soil to 10^6.3 CFU/g soil, respectively. After 30 days of culturing, the biochar and the bacterium in combination increased the plant height from 10.3 cm to 36 cm, and enhanced the accumulation of chlorophyll a, reducing sugars, soluble proteins, and superoxide dismutase in the leaves. Moreover, the combined treatment increased the activity of soil enzymes, including peroxidase, alkaline phosphatase, and urease. Meanwhile, the levels of various cations in the rhizosphere soil were reduced by the combined treatment, e.g., Na⁺, Cu²⁺, Fe²⁺, Mg²⁺, Mn²⁺, etc., indicating an improvement in the soil quality. This study developed the biochar–halotolerant bacterium joint strategy to improve the yield of forage grasses in saline–alkali soil. Full article

Subsurface drainage and biochar application are conventional measures for improving saline–alkali soils. However, their combined effects on the fate of nitrogen (N) fertilizers remain unclear. This study investigated the combined effects of subsurface drainage and biochar amendment on the fate of nitrogen (N) in coastal saline–alkali soils, where these conventional remediation measures’ combined impacts on fertilizer N dynamics remain seldom studied. Using ¹⁵N-labeled urea tracing in an alfalfa–soil system, we examined how different drainage spacings (0, 6, 12, and 18 m) and biochar application rates (5, 10, and 15 t/ha) influenced N distribution patterns. Results demonstrated decreasing in drainage spacing and increasing in biochar application; these treatments enhanced ¹⁵N use efficiency on three harvested crops. Drainage showed more sustained effects than biochar. Notably, the combination of 6 m drainage spacing with 15 t/ha biochar application achieved optimal performance of ¹⁵N use, showing N utilization efficiency of 46.0% that significantly compared with most other treatments (p < 0.05). ¹⁵N mass balance analysis revealed that the plant absorption, the soil residual and the loss of applied N accounted for 21.6–46.0%, 38.6–67.5% and 8.5–18.1%, respectively. These findings provide important insights for optimizing nitrogen management in coastal saline–alkali agriculture, demonstrating that strategic integration of subsurface drainage (6 m spacing) with biochar amendment (15 t/ha) can maximize N use efficiency, although potential N losses warrant consideration in field applications. Full article

The aim of this work was to obtain biochar materials from plant biomass and to determine the changes occurring under the conditions of the pyrolysis process and physical activation, as well as to characterize the physicochemical characteristics of the produced products in terms of their practical use. The pyrolysis process was carried out at a temperature of 700 °C, under the flow of a protective gas, i.e., carbon dioxide, at a rate of 5.0 L/min. The pyrolysis processes were carried out in the absence and presence of an activating agent. For ecological safety, physical activation using water vapor was chosen. In the next stage of the work, biochars were produced and subjected to detailed physicochemical analysis. A scanning electron microscope with energy-dispersive SEM/EDS was used to determine the microstructure and changes in the chemical composition of the biochars. FTIR spectrophotometry was used to identify the functional groups present in the structures of biochars and to indicate changes occurring in the biomass during pyrolysis. Meanwhile, Raman spectroscopy was used to assess the ordering of the biochar structures based on the identification of spectral signals. The description of the specific surface areas of the biochars was made possible by studies conducted using a physical and chemical adsorption analyzer. Based on the obtained research results, the elementary structure, surface development, presence of functional groups on the surfaces of biochars and changes in the structure before and after activation with water vapor were determined. It was found that the biochars had functional groups, a well-developed specific surface area that increased after activation with water vapor, micropores and mesopores, as well as changes in structure under the influence of physical activation. It has been shown that the presence of functional groups influences the hydrogen sulfide sorption capacity. Full article

This perspective explores the use of biochar, a carbon-rich material derived from biomass, as a sustainable solution for mitigating volatile organic compounds (VOCs) emitted during asphalt production and use. VOCs from asphalt contribute to ozone formation and harmful secondary organic aerosols (SOAs), which negatively impact air quality and public health. Biochar, with its high surface area and capacity to adsorb VOCs, provides an effective means of addressing these challenges. By tailoring biochar’s surface chemistry, it can efficiently capture VOCs, while also offering long-term carbon sequestration benefits. Additionally, biochar enhances the durability of asphalt, extending road lifespan and reducing maintenance needs, making it a promising material for sustainable infrastructure. Despite these promising benefits, several challenges remain. Variations in biochar properties, driven by differences in feedstock and production methods, can affect its performance in asphalt. Moreover, the integration of biochar into existing plant operations requires the further development of methods to streamline the process and ensure consistency in biochar’s quality and cost-effectiveness. Standardizing production methods and addressing logistical hurdles will be crucial for biochar’s widespread adoption. Research into improving its long-term stability in asphalt is also needed to ensure sustained efficacy over time. Overcoming these challenges will be essential for fully realizing biochar’s potential in sustainable infrastructure development Full article