Search Results (25)

Horticultural substrates based on coconut fibre are among the most commonly used growing media, but with limited durability. This study presents methods for modifying coconut fibre through surface coating with biopolymers, where polymerisation was initiated in the applied solution. Additionally, the suitability of adding pelletised biochar was analysed. A biomonomer derived from wood processing was used both for fibre surface modification and for binding biochar into pellets. Surface modification through biopolymer coating resulted in changes to selected physicochemical properties. It was found that the coating significantly altered the porosity of the substrate. Depending on the type of coconut fibre, the differences in porosity compared to the unmodified substrate ranged from 12 to 24%. This directly influenced bulk density, which is a crucial parameter in the preparation of substrates for plant growth. The surface properties of the modified substrates also affected sorption and retention capacities. From the perspective of plant production, the supply of bioavailable forms of potassium and phosphorus is essential. Coating and the addition of pelletised biochar, regardless of the type of fibre used, significantly increased the release of PO₄³⁻ and K⁺ compared to unmodified substrates. The physiological parameters in plants confirmed the suitability of the modified substrates for plant production. Full article

The European Union (EU) advocates for a sustainable agricultural model with reduced synthetic fertiliser use. This study compares different high-P organo-mineral pellet fertilisers (OMFs) and their effects on crop yield. A trial was conducted under controlled conditions in ryegrass (Lollium perenne L.) pots with different organo-mineral fertilisation strategies at sowing with adjusted doses of P (120 kg P ha⁻¹) and N (200 kg N ha⁻¹). Pellets were developed from compost enriched with bone meal (OMF-BON), struvite (OMF-STR), and monoammonium phosphate (OMF-MAP). Conventional fertilisers (Complex15 and MAP) and alternative unpelletised/pelletised sources (STR and BON) were also tested. The experimental design included an unfertilised control (C), and treatments were carried out in triplicate (N = 24). Over 40 days, three cuttings (10, 25, and 40 days) were collected to determine fresh/dry biomass, nutrient content, and N, P, and K extraction efficiency. Soil labile parameters were influenced by the application of fertilisers especially OMF-MAP, OMF-STR, and MAP. MAP and STR yielded the highest nutrient extraction and biomass production, followed by their pelletised forms (OMF-MAP and OMF-STR). These results highlight the potential of pelletised organo-mineral fertilisers as sustainable alternatives to conventional sources. Full article

Novel Ni/SBA-15 catalysts were synthesised and their activity in the dry reforming of methane process was assessed. These materials were prepared into extrudates shaped like pellets and tested in a pyrolysis pilot plant fitted with a catalytic reactor for sewage sludge pyrolysis tar removal. The Ni/SBA-15 catalyst pellets remained highly active and stable throughout the test’s duration, converting 100% tar in the hot gas to smaller non-condensable gases, thereby increasing the pyrolysis gas fraction and eliminating the problematic tar in the vapour stream. Catalyst characterisation with Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray (EDX) analysis, Transmission Electron Microscopy (TEM), and Thermogravimetric Analysis (TGA) confirmed that both the Ni/SBA-15-powered catalyst and the pellets were resistant to sintering and carbon deposition and remained highly active even with relatively high-level sulphur in the feed stream. The Ni/SBA-15 catalyst extrudates were prepared by mixing the powdered catalyst with varied amounts of colloidal silica binder and fixed amounts of methyl cellulose and water. The highest mechanical strength of the extrudates was determined to be of those obtained with 36% of the inorganic binder. The physical properties and catalytic activity of Ni/SBA-15 pellets with 36% colloidal silica were compared with the original powdered Ni/SBA-15 catalyst to assess the binder inhibitory effect, if any. The results confirmed that colloidal silica binder did not inhibit the desired catalyst properties and performance in the reaction. Instead, enhanced catalytic performance was observed. Full article

Solid recovered fuel (SRF) is highly suited for thermal treatment, but its low bulk density and other physical properties limit the number of compatible energy systems that can effectively process it. This study presents the findings on SRF energy utilisation, focusing on mechanical treatment and a novel approach to its small-scale co-combustion with certified softwood (SW) pellets and catalytic flue gas control. In this study, the processes of certified SRF feedstock characterisation and mechanical treatment were thoroughly examined. Unique SRF pellets of proper mechanical properties were experimentally prepared for real-scale experiments. Mechanical and chemical properties, such as mechanical resilience, toughness, moisture and heating value, were examined and compared with standard SW A1 class pellets. The prepared SRF pellets possessed an energy density of 30.5 MJ∙kg⁻¹, meeting the strict requirements from multiple perspectives. The influence of pelletisation temperature on pellet quality was investigated. It was found that increased resilience and a water content of 1.59% were achieved at a process temperature equal to 75 °C. Moreover, the moisture resilience was found to be significantly better (0.5 vs. 14.23%) compared with commercial SW pellets, while the hardness and durability values were reasonably similar: 40.7 vs. 45.2 kg and 98.74 vs. 98.99%, respectively. This study demonstrates that SRF pellets, with their improved mechanical and energy properties, are a viable alternative fuel, from a technical standpoint, which can be fully utilised in existing combustion units. Full article

Smart textiles provide a significant technological advancement, but their development must balance traditional textile properties with electronic features. To address this challenge, this study introduces a flexible, electrically conductive composite material that can be fabricated using a continuous bi-component extrusion process, making it ideal for sensor electrodes. The primary aim was to create a composite for the filament’s core, combining multi-walled carbon nanotubes (MWCNTs), polypropylene (PP), and thermoplastic elastomer (TPE), optimised for conductivity and flexibility. This blend, suitable for bi-component extrusion processes, exemplifies the role of advanced materials in combining electrical conductivity, mechanical flexibility, and processability, which are essential for wearable technology. The composite optimisation balanced MWCNT (2.5, 5, 7.5, and 10 wt.%) and TPE (0, 25, and 50 wt.%) in a PP matrix. There was a significant decrease in electrical resistivity between 2.5 and 5 wt.% MWCNT, with electrical resistivity ranging from (7.64 ± 4.03)10⁴ to (1.15 ± 0.10)10⁻¹ Ω·m. Combining the composite with 25 wt.% TPE improved the flexibility, while with 50 wt.% TPE decreased tensile strength and hindered the masterbatch pelletising process. The final stage involved laminating the composite filament electrodes, with a 5 wt.% MWCNT/PP/(25 wt.% TPE) core and a TPE sheath, into a textile triboelectric impact detection sensor. This sensor, responding to contact and separation, produced an output voltage of approximately 5 V peak-to-peak per filament and 15 V peak-to-peak with five filaments under a 100 N force over 78.54 cm². This preliminary study demonstrates an innovative approach to enhance the flexibility of conductive materials for smart textile applications, enabling the development of triboelectric sensor electrodes with potential applications in impact detection, fall monitoring, and motion tracking. Full article

This article presents a modular open chamber stand which simulates the densification process that occurs in a single channel of a pelletising die. The results of the verification tests confirmed the suitability of this stand for determining the optimal geometry of the channel. The test material was the biomass of Miscanthus × giganteus which is considered to be a difficult material for pressure densification; therefore, it was decided that it would be a good material for verifying the stand. The stand consists of four modules: an introductory section with a diameter of D = 12 and 10 mm, a conical part with an angle of α = 10°, 20°, 30°, 40°, a cylindrical part with lengths L = 5, 15, 25, 35, 45 mm and diameter d= 8 mm and a pellet receiving module. The stand is able to heat the densification channel. Individual modules can be assembled into test combinations; this results in a change in channel geometry without the necessity to manufacture many singular channels. The optimum geometry of the channel for miscanthus with a moisture content of 13%, densified at 100 °C was determined. It should be a channel with D = 10 mm, α = 40° and L = 18 mm. Full article

Biomass storage is an essential requirement in the supply chain of bio-refineries and power plants. This research aims to evaluate the influence of long-term outdoor storage (1 year) of baled rockrose (Cistus laurifolius L.) shrub biomass on biofuel’s quality, pre-treatment processes and on combustion emissions in an industrial boiler. The raw material was obtained from different rockrose shrublands in north central Spain. A total of 233 t_WM (tones of wet matter) of biomass were used to produce biofuels (30 mm of milled biomass and Ø 8 mm pellets) in the pre-treatment pilot plants at CEDER-CIEMAT. The combustion tests were conducted in an industrial moving grate boiler with a thermal power of 50 MWth, in a 17 MWe power plant. Outdoor storage improved some biofuel quality parameters, mainly the reduction in ash content, which allowed 30 mm of milled material to be classified as class I1 (ISO 17225-9:2022) and pellets as class I3 (ISO 17225-2-2021). No significant differences were observed in the total specific mass flow and energy consumption in the pre-treatment processes. The combustion tests had similar results, with the emissions being below the limits established in the directive (EU) 2015/2193. The results obtained indicated that the 1-year outdoor storage of rockrose-baled biomass, under Mediterranean conditions, was feasible for its subsequent use as biofuel. Full article

The development in wastewater management has caused a shift towards a circular model that prioritises energy generation and waste reduction. Traditional unitary processes in wastewater treatment, such as screening, only allow for landfill disposal without energy recovery. However, producing solid recovered fuel (SRF) from waste screening may be a possibility. The economic and environmental viability of this alternative, as a fundamental requirement for its implementation at industrial level, was assessed through a multi-scenario analysis using Monte Carlo simulation. The cost and benefit streams were determined based on the financial net present value (NPV_f) and the social net present value (NPV_s), including monetised CO₂ emissions generated. The results showed that waste drying costs were found to be the most significant ones, with thermal drying being more financially advantageous than solar drying. The densification of SRF raises the costs by 7.88 to 8.48%, but its use as fuel would likely be profitable due to the economic benefits it provides. Current landfill disposal practices, which have an NPV_s of −1052.60 EUR/t, are not a feasible, particularly when compared to the other SRF production scenarios, with maximum NPV_s of −53.91 EUR/t. SRF production without densification using solar drying is the most acceptable scenario with the lowest NPV_s (38.39 EUR/t). Full article

Renewable active sludge is a smart material for wastewater treatment and the protection of surface water bodies. The generated pellets (dried and pelletised dehydrated anaerobically stabilised excess sludge) are produced in a quantity of 31.4 ± 5.6 g dry matter (DM) per one Population equivalent (PE) calculated to COD (PE_COD) in one day. As pellets are combustible material, their energy utilisation must reach the sustainable development goals (SDGs)—a bridge must be created between “treated sewage sludge as the tool to remove pollutants and nutrients from wastewater” and “preparation of the valuable material as a solid recovered fuel (SRF) that meets customer-specific requirements”. Technical Report CEN/TR 15508 and Technical Standard EN ISO 21640 set up methods for specifying and classifying pellets as an SRF. In the last eleven years (2010–2021), pellets’ net calorific value (NCV) is 13.0 ± 0.7 MJ kg⁻¹ as received (ar). In 2021, the 80th percentile of the Hg/NCV ratio was 0.079 mg Hg MJ⁻¹. In 2010–2021, the annual amount of Hg transferred to stakeholders reduced by 64.3% m/m—from 10.1 kg to 3.67 kg. The halogen contents of the pellets do not threaten corrosion to the incineration facility. Stable pellets’ energy potential and perspective ash composition for critical raw materials recovery qualify pellets as a specific waste stream and a renewable material for SRF production. Full article

This study investigated the influence of viscose fibre (VF) geometry on the microstructures and resulting properties of high-density polyethylene (HDPE) composites. Seven types of viscose fibres varying in cross-section shape, linear density, and length were pelletised, compounded into HDPE with a twin-screw extruder, and injection moulded. The microstructures of the composites were characterised by investigating their cross-sections and by extracting the fibres and measuring their lengths using optical microscopy (OM). The mechanical and thermal properties of the composites were characterised using differential scanning calorimetry (DSC), tensile tests, Charpy impact tests, and dynamic mechanical analysis (DMA). The composites prepared using cylindrical fibres with a linear density of 1.7 dtex exhibited the best fibre dispersion, highest orientation, and lowest fibre–fibre contact area. The decrease in the linear density of the cylindrical fibres resulted in increasingly worse dispersion and orientation, while composites containing non-cylindrical fibres exhibited a comparably larger fibre–fibre contact area. The initial fibre length of about 3 to 10 mm decreased to the mean values of 0.29 mm to 0.41 mm during processing, depending on the initial geometry. In general, cylindrical fibres exhibited a superior reinforcing effect in comparison to non-cylindrical fibres. The composites containing cylindrical fibres with a linear density of 1.7 dtex and a length of 5 mm exhibited the best reinforcing effect with an increase in tensile modulus and strength of 323% and 141%, respectively. Full article

This study establishes that processed zero valent iron can be pelletised and used to desalinate water. The pellets desalinate water using a zero-order reaction, where: product water salinity = −[a][Reaction Time] + Feed Water Salinity. Desalination using the pellets requires no onsite energy, no onsite infrastructure, and produces no reject brine. Potential applications for the pellets, include desalination of saline impoundments, desalination of agricultural water, desalination of irrigation water, desalination of irrigated salinized soils, and aquifer desalination. The examples demonstrate 30% to 60% desalination for saline feed water within the salinity range of 4 to 10 g L⁻¹. The product water has a low outcome variability for a specific pellet charge. The achievable desalination increases as the pellet weight: water volume ratio increases. The pellets can also be used for water purification, wastewater desalination, treatment of domestic wastewater, treatment of industrial wastewater, treatment of livestock feed water, treatment of oil field and mining wastewater, water purification to allow reuse, and the treatment of polluted soils. This study addresses the manufacture of the pellets, their effectiveness in desalinating water, and the outcome variability associated with desalination. Full article

Woody biomass represents a sustainable type of fuel that is marketed directly as firewood or pre-treated by grinding, drying and compressing. Densified biomass fuels provide benefits in transport, storage and handling, and wood pellets in particular are one of the most commercially attractive products. With this in mind, the objective of the presented research was to evaluate the quality of various pellets obtained from different tree parts of five species (and various age): Eucalyptus spp., Fagus sylavtica L., Pinus eldarica Medw., Pinus radiata D.Don, and Robinia pseudoacacia L. In all the analysed cases, the wooden material was harvested according to the whole tree system (WTS), with their branches and leaves. The samples were chipped, refined by a shredder and dried. Pelletisation was finally carried out using a 4 kW Bianco line (Cuneo, Italy) pelletiser. Physical and chemical analyses were undertaken to determine the quality of the pellets as an energy source. Results of this classification showed that the best pellets, mostly due to better mechanical properties, were from plantation trees of Eucalyptus spp. (6- and 3-year-old) and from thinnings of Fagus sylavtica L. (70-year-old), whereas the least attractive types were made from 18-year-old, coppice Eucalyptus spp. and 3-year-old Robinia pseudoacacia L. Regarding the classification developed within this study, all the pellet types were found to be classifiable as none exceeded the toxic content limit. In terms of the influence of the species, management system and stem age on pellet quality, this study showed the presence of a link between cycle duration and pellet quality, with increasing stem age resulting in better pellet characteristics. Full article

The agricultural sector and its related production chains are good sources of residual biomass. Olive and vineyard pruning residues are present in high quantities in Italy. The limited bulk and energy densities of these biomass materials affect the harvesting and logistic costs, limiting energy and environmental sustainability. Pelletisation is the most efficient process for increasing bulk and energy densities. This study evaluates the pelletisation process of olive and vineyard prunings, pure, or blended with variable quantities of spruce sawdust. A 15 kW pelletisation system was chosen, in line with production at the farm level. The most important quality parameters of the produced agripellets were analyzed. The results of this investigation suggest that blending could valorize other biomass materials less suitable for pelletisation and reach the pellet quality required by Italian technical standards. The addition of pruning residues to spruce sawdust leads to an improvement in durability. Spruce sawdust pellets have a durability value of 78.4%. Adding 20% of olive prunings (S80O20) increases this value to 92.2, while adding 20% vineyard prunings (S80V20) increases this value up to 90.3. The addition of 20% of pruning residues significantly increased the length and decreased fines. Full article

Agricultural by-products have several disadvantages as fuel, such as low calorific values and high ash contents. To address these disadvantages, this study examined the mixing of agricultural by-products and spent coffee grounds, for use as a solid fuel, and the improvement of fuel characteristics through torrefaction. Pepper stems and spent coffee grounds were first dried to moisture contents of <15% and then combined, with mixing ratios varying from 9:1 to 6:4. Fuel pellets were produced from these mixtures using a commercial pelletiser, evaluated against various standards, and classified as grade A, B, or Bio-SRF. The optimal ratio of pepper stems to spent coffee grounds was determined to be 8:2. The pellets were torrefied to improve their fuel characteristics. Different torrefaction temperatures improved the mass yields of the pellets to between 50.87% and 88.27%. The calorific value increased from 19.9% to 26.8% at 290 °C. The optimal torrefaction temperature for coffee ground pellets was 230 °C, while for other pellets, it was 250 °C. This study provides basic information on the potential enhancement of agricultural by-products for fuel applications. Full article

Wood pellets are an important source of renewable energy. Their mechanical strength is a crucial property. In this study, the tensile strength of pellets made from oak, pine, and birch sawdust with moisture contents of 8% and 20% compacted at 60 and 120 MPa was determined in a diametral compression test. The highest tensile strength was noted for oak and the lowest for birch pellets. For all materials, the tensile strength was the highest for a moisture content of 8% and 120 MPa. All pellets exhibited a ductile breakage mode characterised by a smooth and round stress–deformation relationship without any sudden drops. Discrete element method (DEM) simulations were performed to check for the possibility of numerical reproduction of pelletisation of the sawdust and then of the pellet deformation in the diametral compression test. The pellet breakage process was successfully simulated using the DEM implemented with the bonded particle model. The simulations reproduced the results of laboratory testing well and provided deeper insight into particle–particle bonding mechanisms. Cracks were initiated close to the centre of the pellet and, as the deformation progressed, they further developed in the direction of loading. Full article