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Search Results (3,559)

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Keywords = model field theory

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33 pages, 3543 KiB  
Article
Shallow Sliding Failure of Slope Induced by Rainfall in Highly Expansive Soils Based on Model Test
by Shuangping Li, Bin Zhang, Shanxiong Chen, Zuqiang Liu, Junxing Zheng, Min Zhao and Lin Gao
Water 2025, 17(14), 2144; https://doi.org/10.3390/w17142144 - 18 Jul 2025
Abstract
Expansive soils, characterized by the presence of surface and subsurface cracks, over-consolidation, and swell-shrink properties, present significant challenges to slope stability in geotechnical engineering. Despite extensive research, preventing geohazards associated with expansive soils remains unresolved. This study investigates shallow sliding failures in slopes [...] Read more.
Expansive soils, characterized by the presence of surface and subsurface cracks, over-consolidation, and swell-shrink properties, present significant challenges to slope stability in geotechnical engineering. Despite extensive research, preventing geohazards associated with expansive soils remains unresolved. This study investigates shallow sliding failures in slopes of highly expansive soils induced by rainfall, using model tests to explore deformation and mechanical behavior under cyclic wetting and drying conditions, focusing on the interaction between soil properties and environmental factors. Model tests were conducted in a wedge-shaped box filled with Nanyang expansive clay from Henan, China, which is classified as high-plasticity clay (CH) according to the Unified Soil Classification System (USCS). The soil was compacted in four layers to maintain a 1:2 slope ratio (i.e., 1 vertical to 2 horizontal), which reflects typical expansive soil slope configurations observed in the field. Monitoring devices, including moisture sensors, pressure transducers, and displacement sensors, recorded changes in soil moisture, stress, and deformation. A static treatment phase allowed natural crack development to simulate real-world conditions. Key findings revealed that shear failure propagated along pre-existing cracks and weak structural discontinuities, supporting the progressive failure theory in shallow sliding. Cracks significantly influenced water infiltration, creating localized stress concentrations and deformation. Atmospheric conditions and wet-dry cycles were crucial, as increased moisture content reduced soil suction and weakened the slope’s strength. These results enhance understanding of expansive soil slope failure mechanisms and provide a theoretical foundation for developing improved stabilization techniques. Full article
(This article belongs to the Topic Hydraulic Engineering and Modelling)
17 pages, 2027 KiB  
Article
Coordinating the Redundant DOFs of Humanoid Robots
by Pietro Morasso
Actuators 2025, 14(7), 354; https://doi.org/10.3390/act14070354 - 18 Jul 2025
Abstract
The new generation of robots (Industry 5.0 and beyond) is expected to be accompanied by the massive introduction of autonomous and cooperative agents in our society, both in the industrial and service sectors. Cooperation with humans will be simplified by humanoid robots with [...] Read more.
The new generation of robots (Industry 5.0 and beyond) is expected to be accompanied by the massive introduction of autonomous and cooperative agents in our society, both in the industrial and service sectors. Cooperation with humans will be simplified by humanoid robots with a similar kinematic outline and a similar kinematic redundancy, which is required by the diversity of tasks that will be performed. A bio-inspired approach is proposed for coordinating the redundant DOFs of such agents. This approach is based on the ideomotor theory of action, combined with the passive motion paradigm, to implicitly address the degrees of freedom problem, without any kinematic inversion, while producing coordinated motor patterns structured according to the typical features of biological motion. At the same time, since the approach is force-field-based, it allows us to integrate the computational loop parallel modules that exploit the redundancy of the system for satisfying geometric or kinematic constraints implemented by appropriate repulsive force fields. Moreover, the model is expanded to include dynamic constraints associated with the Lagrangian dynamics of the humanoid robot to improve the energetic efficiency of the generated actions. Full article
14 pages, 1614 KiB  
Article
Neural Networks and Markov Categories
by Sebastian Pardo-Guerra, Johnny Jingze Li, Kalyan Basu and Gabriel A. Silva
AppliedMath 2025, 5(3), 93; https://doi.org/10.3390/appliedmath5030093 - 18 Jul 2025
Abstract
We present a formal framework for modeling neural network dynamics using Category Theory, specifically through Markov categories. In this setting, neural states are represented as objects and state transitions as Markov kernels, i.e., morphisms in the category. This categorical perspective offers an algebraic [...] Read more.
We present a formal framework for modeling neural network dynamics using Category Theory, specifically through Markov categories. In this setting, neural states are represented as objects and state transitions as Markov kernels, i.e., morphisms in the category. This categorical perspective offers an algebraic alternative to traditional approaches based on stochastic differential equations, enabling a rigorous and structured approach to studying neural dynamics as a stochastic process with topological insights. By abstracting neural states as submeasurable spaces and transitions as kernels, our framework bridges biological complexity with formal mathematical structure, providing a foundation for analyzing emergent behavior. As part of this approach, we incorporate concepts from Interacting Particle Systems and employ mean-field approximations to construct Markov kernels, which are then used to simulate neural dynamics via the Ising model. Our simulations reveal a shift from unimodal to multimodal transition distributions near critical temperatures, reinforcing the connection between emergent behavior and abrupt changes in system dynamics. Full article
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21 pages, 6787 KiB  
Article
Fast Calculation of Thermal-Fluid Coupled Transient Multi-Physics Field in Transformer Based on Extended Dynamic Mode Decomposition
by Yanming Cao, Kanghang He, Wenyuan Shangguan, Yuqi Wang and Chunjia Gao
Processes 2025, 13(7), 2282; https://doi.org/10.3390/pr13072282 - 17 Jul 2025
Abstract
With the development of digital power systems, the establishment of digital twin models for transformers is of great significance in enhancing power system stability. Consequently, greater demands are placed on the real-time performance and accuracy of thermal-fluid-coupled transient multi-physics field calculations for transformers. [...] Read more.
With the development of digital power systems, the establishment of digital twin models for transformers is of great significance in enhancing power system stability. Consequently, greater demands are placed on the real-time performance and accuracy of thermal-fluid-coupled transient multi-physics field calculations for transformers. However, traditional numerical methods, such as finite element or computational fluid dynamics techniques, often require days or even weeks to simulate full-scale high-fidelity transformer models containing millions of grid nodes. The high computational cost and long runtime make them impractical for real-time simulations in digital twin applications. To address this, this paper employs the dynamic mode decomposition (DMD) method in conjunction with Koopman operator theory to perform data-driven reduced-order modeling of the transformer’s thermal–fluid-coupled multi-physics field. A fast computational approach based on extended dynamic mode decomposition (EDMD) is proposed to enhance the modal decomposition capability of nonlinear systems and improve prediction accuracy. The results show that this method greatly improves computational efficiency while preserving accuracy in high-fidelity models with millions of grids. The errors in the thermal and flow field calculations remain below 3.06% and 3.01%, respectively. Furthermore, the computation time is reduced from hours to minutes, with the thermal field achieving a 97-fold speed-up and the flow field an 83-fold speed-up, yielding an average speed-up factor of 90. This enables fast computation of the transformer’s thermal–fluid-coupled field and provides effective support for the application of digital twin technology in multi-physics field simulations of power equipment. Full article
(This article belongs to the Section Chemical Processes and Systems)
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26 pages, 2989 KiB  
Article
Studying Homoclinic Chaos in a Class of Piecewise Smooth Oscillators: Melnikov’s Approach, Symmetry Results, Simulations and Applications to Generating Antenna Factors Using Approximation and Optimization Techniques
by Nikolay Kyurkchiev, Tsvetelin Zaevski, Anton Iliev, Vesselin Kyurkchiev and Asen Rahnev
Symmetry 2025, 17(7), 1144; https://doi.org/10.3390/sym17071144 - 17 Jul 2025
Abstract
In this paper, we provide a novel extended mixed differential model that is appealing to users because of its numerous free parameters. The motivation of this research arises from the opportunity for a general investigation of some outstanding classical and novel dynamical models. [...] Read more.
In this paper, we provide a novel extended mixed differential model that is appealing to users because of its numerous free parameters. The motivation of this research arises from the opportunity for a general investigation of some outstanding classical and novel dynamical models. The higher energy levels known in the literature can be governed by appropriately added correction factors. Furthermore, the different applications of the considered model can be achieved only after a proper parameter calibration. All these necessitate the use of diverse optimization and approximation techniques. The proposed extended model is especially useful in the important field of decision making, namely the antenna array theory. This is due to the possibility of generating high-order Melnikov polynomials. The work is a natural continuation of the authors’ previous research on the topic of chaos generation via the term x|x|a1. Some specialized modules for investigating the dynamics of the proposed oscillators are provided. Last but not least, the so-defined dynamical model can be of interest for scientists and practitioners in the area of antenna array theory, which is an important part of the decision-making field. The stochastic control of oscillations is also the subject of our consideration. The underlying distributions we use may be symmetric, asymmetric or strongly asymmetric. The same is true for the mass in the tails, too. As a result, the stochastic control of the oscillations we purpose may exhibit a variety of possible behaviors. In the final section, we raise some important issues related to the methodology of teaching Master’s and PhD students. Full article
(This article belongs to the Section Mathematics)
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23 pages, 4585 KiB  
Article
Power Losses in the Multi-Turn Windings of High-Speed PMSM Electric Machine Armatures
by Oleksandr Makarchuk and Dariusz Całus
Energies 2025, 18(14), 3761; https://doi.org/10.3390/en18143761 - 16 Jul 2025
Viewed by 120
Abstract
This paper investigates the dependencies between the design parameters of the armature (stator) winding of a high-speed PMSM machine and the electrical losses in its windings resulting from eddy currents. In addition, the factors accounting for the occurrence of parasitic circulating currents, whose [...] Read more.
This paper investigates the dependencies between the design parameters of the armature (stator) winding of a high-speed PMSM machine and the electrical losses in its windings resulting from eddy currents. In addition, the factors accounting for the occurrence of parasitic circulating currents, whose presence in the phase windings is associated with the design specificity, are analyzed. Quantitative analysis is carried out by the application of a newly developed mathematical model for the calculation of fundamental and additional losses in a multi-turn coil enclosed in the slots of a ferromagnetic core. The analysis takes into account the actual design of the slot and the conductor, the variable arrangement of individual conductors in the slot, the core saturation and the presence of the excitation field—to represent the main factors that affect the process of additional losses in the slot of the electric machine. The verification of the mathematical model developed in this study was carried out by comparing the distribution of power losses in the slot section of the coil, consisting of several elementary conductors connected in parallel and located in a rectangular open slot, with an identical distribution derived on the basis of an analytical method from the classical circuit theory. For the purpose of confirming the results and conclusions derived from simulation studies, a number of physical experiments were carried out, consisting in determining the power losses in multi-turn coils of different designs. Recommendations have been developed to minimize additional losses by optimizing the arrangement of conductors within the slot, selecting the appropriate cross-sectional size of a single conductor and the saturation level of the tooth zone. Full article
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41 pages, 1006 KiB  
Article
A Max-Flow Approach to Random Tensor Networks
by Khurshed Fitter, Faedi Loulidi and Ion Nechita
Entropy 2025, 27(7), 756; https://doi.org/10.3390/e27070756 - 15 Jul 2025
Viewed by 60
Abstract
The entanglement entropy of a random tensor network (RTN) is studied using tools from free probability theory. Random tensor networks are simple toy models that help in understanding the entanglement behavior of a boundary region in the anti-de Sitter/conformal field theory (AdS/CFT) context. [...] Read more.
The entanglement entropy of a random tensor network (RTN) is studied using tools from free probability theory. Random tensor networks are simple toy models that help in understanding the entanglement behavior of a boundary region in the anti-de Sitter/conformal field theory (AdS/CFT) context. These can be regarded as specific probabilistic models for tensors with particular geometry dictated by a graph (or network) structure. First, we introduce a model of RTN obtained by contracting maximally entangled states (corresponding to the edges of the graph) on the tensor product of Gaussian tensors (corresponding to the vertices of the graph). The entanglement spectrum of the resulting random state is analyzed along a given bipartition of the local Hilbert spaces. The limiting eigenvalue distribution of the reduced density operator of the RTN state is provided in the limit of large local dimension. This limiting value is described through a maximum flow optimization problem in a new graph corresponding to the geometry of the RTN and the given bipartition. In the case of series-parallel graphs, an explicit formula for the limiting eigenvalue distribution is provided using classical and free multiplicative convolutions. The physical implications of these results are discussed, allowing the analysis to move beyond the semiclassical regime without any cut assumption, specifically in terms of finite corrections to the average entanglement entropy of the RTN. Full article
(This article belongs to the Section Quantum Information)
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18 pages, 2200 KiB  
Article
A Self-Supervised Adversarial Deblurring Face Recognition Network for Edge Devices
by Hanwen Zhang, Myun Kim, Baitong Li and Yanping Lu
J. Imaging 2025, 11(7), 241; https://doi.org/10.3390/jimaging11070241 - 15 Jul 2025
Viewed by 158
Abstract
With the advancement of information technology, human activity recognition (HAR) has been widely applied in fields such as intelligent surveillance, health monitoring, and human–computer interaction. As a crucial component of HAR, facial recognition plays a key role, especially in vision-based activity recognition. However, [...] Read more.
With the advancement of information technology, human activity recognition (HAR) has been widely applied in fields such as intelligent surveillance, health monitoring, and human–computer interaction. As a crucial component of HAR, facial recognition plays a key role, especially in vision-based activity recognition. However, current facial recognition models on the market perform poorly in handling blurry images and dynamic scenarios, limiting their effectiveness in real-world HAR applications. This study aims to construct a fast and accurate facial recognition model based on novel adversarial learning and deblurring theory to enhance its performance in human activity recognition. The model employs a generative adversarial network (GAN) as the core algorithm, optimizing its generation and recognition modules by decomposing the global loss function and incorporating a feature pyramid, thereby solving the balance challenge in GAN training. Additionally, deblurring techniques are introduced to improve the model’s ability to handle blurry and dynamic images. Experimental results show that the proposed model achieves high accuracy and recall rates across multiple facial recognition datasets, with an average recall rate of 87.40% and accuracy rates of 81.06% and 79.77% on the YTF, IMDB-WIKI, and WiderFace datasets, respectively. These findings confirm that the model effectively addresses the challenges of recognizing faces in dynamic and blurry conditions in human activity recognition, demonstrating significant application potential. Full article
(This article belongs to the Special Issue Techniques and Applications in Face Image Analysis)
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13 pages, 890 KiB  
Hypothesis
Beyond Classical Multipoles: The Magnetic Metapole as an Extended Field Source
by Angelo De Santis and Roberto Dini
Foundations 2025, 5(3), 25; https://doi.org/10.3390/foundations5030025 - 14 Jul 2025
Viewed by 92
Abstract
We introduce the concept of the magnetic metapole—a theoretical extension of classical multipole theory involving a fractional j pole count (related to the harmonic degree n as j = 2n). Defined by a scalar potential with colatitudinal dependence and no radial [...] Read more.
We introduce the concept of the magnetic metapole—a theoretical extension of classical multipole theory involving a fractional j pole count (related to the harmonic degree n as j = 2n). Defined by a scalar potential with colatitudinal dependence and no radial variation, the metapole yields a magnetic field that decays as 1/r and is oriented along spherical surfaces. Unlike classical multipoles, the metapole cannot be described as a point source; rather, it corresponds to an extended or filamentary magnetic distribution as derived from Maxwell’s equations. We demonstrate that pairs of oppositely oriented metapoles (up/down) can, at large distances, produce magnetic fields resembling those of classical monopoles. A regularized formulation of the potential resolves singularities for the potential and the field. When applied in a bounded region, it yields finite field energy, enabling practical modeling applications. We propose that the metapole can serve as a conceptual and computational framework for representing large-scale magnetic field structures particularly where standard dipole-based models fall short. This construct may have utility in both geophysical and astrophysical contexts, and it provides a new tool for equivalent source modeling and magnetic field decomposition. Full article
(This article belongs to the Section Physical Sciences)
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34 pages, 1456 KiB  
Project Report
On Control Synthesis of Hydraulic Servomechanisms in Flight Controls Applications
by Ioan Ursu, Daniela Enciu and Adrian Toader
Actuators 2025, 14(7), 346; https://doi.org/10.3390/act14070346 - 14 Jul 2025
Viewed by 61
Abstract
This paper presents some of the most significant findings in the design of a hydraulic servomechanism for flight controls, which were primarily achieved by the first author during his activity in an aviation institute. These results are grouped into four main topics. The [...] Read more.
This paper presents some of the most significant findings in the design of a hydraulic servomechanism for flight controls, which were primarily achieved by the first author during his activity in an aviation institute. These results are grouped into four main topics. The first one outlines a classical theory, from the 1950s–1970s, of the analysis of nonlinear automatic systems and namely the issue of absolute stability. The uninformed public may be misled by the adjective “absolute”. This is not a “maximalist” solution of stability but rather highlights in the system of equations a nonlinear function that describes, for the case of hydraulic servomechanisms, the flow-control dependence in the distributor spool. This function is odd, and it is therefore located in quadrants 1 and 3. The decision regarding stability is made within the so-called Lurie problem and is materialized by a matrix inequality, called the Lefschetz condition, which must be satisfied by the parameters of the electrohydraulic servomechanism and also by the components of the control feedback vector. Another approach starts from a classical theorem of V. M. Popov, extended in a stochastic framework by T. Morozan and I. Ursu, which ends with the description of the local and global spool valve flow-control characteristics that ensure stability in the large with respect to bounded perturbations for the mechano-hydraulic servomechanism. We add that a conjecture regarding the more pronounced flexibility of mathematical models in relation to mathematical instruments (theories) was used. Furthermore, the second topic concerns, the importance of the impedance characteristic of the mechano-hydraulic servomechanism in preventing flutter of the flight controls is emphasized. Impedance, also called dynamic stiffness, is defined as the ratio, in a dynamic regime, between the output exerted force (at the actuator rod of the servomechanism) and the displacement induced by this force under the assumption of a blocked input. It is demonstrated in the paper that there are two forms of the impedance function: one that favors the appearance of flutter and another that allows for flutter damping. It is interesting to note that these theoretical considerations were established in the institute’s reports some time before their introduction in the Aviation Regulation AvP.970. However, it was precisely the absence of the impedance criterion in the regulation at the appropriate time that ultimately led, by chance or not, to a disaster: the crash of a prototype due to tailplane flutter. A third topic shows how an important problem in the theory of automatic systems of the 1970s–1980s, namely the robust synthesis of the servomechanism, is formulated, applied and solved in the case of an electrohydraulic servomechanism. In general, the solution of a robust servomechanism problem consists of two distinct components: a servo-compensator, in fact an internal model of the exogenous dynamics, and a stabilizing compensator. These components are adapted in the case of an electrohydraulic servomechanism. In addition to the classical case mentioned above, a synthesis problem of an anti-windup (anti-saturation) compensator is formulated and solved. The fourth topic, and the last one presented in detail, is the synthesis of a fuzzy supervised neurocontrol (FSNC) for the position tracking of an electrohydraulic servomechanism, with experimental validation, in the laboratory, of this control law. The neurocontrol module is designed using a single-layered perceptron architecture. Neurocontrol is in principle optimal, but it is not free from saturation. To this end, in order to counteract saturation, a Mamdani-type fuzzy logic was developed, which takes control when neurocontrol has saturated. It returns to neurocontrol when it returns to normal, respectively, when saturation is eliminated. What distinguishes this FSNC law is its simplicity and efficiency and especially the fact that against quite a few opponents in the field, it still works very well on quite complicated physical systems. Finally, a brief section reviews some recent works by the authors, in which current approaches to hydraulic servomechanisms are presented: the backstepping control synthesis technique, input delay treated with Lyapunov–Krasovskii functionals, and critical stability treated with Lyapunov–Malkin theory. Full article
(This article belongs to the Special Issue Advanced Technologies in Actuators for Control Systems)
25 pages, 2780 KiB  
Article
Motion of Magnetic Microcapsules Through Capillaries in the Presence of a Magnetic Field: From a Mathematical Model to an In Vivo Experiment
by Mikhail N. Zharkov, Mikhail A. Pyataev, Denis E. Yakobson, Valentin P. Ageev, Oleg A. Kulikov, Vasilisa I. Shlyapkina, Dmitry N. Khmelenin, Larisa A. Balykova, Gleb B. Sukhorukov and Nikolay A. Pyataev
Magnetochemistry 2025, 11(7), 60; https://doi.org/10.3390/magnetochemistry11070060 - 14 Jul 2025
Viewed by 189
Abstract
In this paper, we discuss the prediction of the delivery efficiency of magnetic carriers based on their properties and field parameters. We developed a theory describing the behavior of magnetic capsules in the capillaries of living systems. A partial differential equation for the [...] Read more.
In this paper, we discuss the prediction of the delivery efficiency of magnetic carriers based on their properties and field parameters. We developed a theory describing the behavior of magnetic capsules in the capillaries of living systems. A partial differential equation for the spatial distribution of magnetic capsules has been obtained. We propose to characterize the interaction between the magnetic field and the capsules using a single vector, which we call “specific magnetic force”. To test our theory, we performed experiments on a model of a capillary bed and on a living organism with two types of magnetic capsules that differ in size and amount of magnetic material. The experimental results show that the distribution of the capsules in the field correlated with the theory, but there were fewer actually accumulated capsules than predicted by the theory. In the weaker fields, the difference was more significant than in stronger ones. We proposed an explanation for this phenomenon based on the assumption that a certain level of magnetic force is needed to keep the capsules close to the capillary wall. We also suggested a formula for the relationship between the probability of capsule precipitation and the magnetic force. We found the effective value of a specific magnetic force at which all the capsules attracted by the magnet reach the capillary wall. This value can be considered as the minimum level for the field at which it is, in principle, possible to achieve a significant magnetic control effect. We demonstrated that for each type of capsule, there is a specific radius of magnet for which the effective magnetic force is achieved at the largest possible distance from the magnet’s surface. For the capsules examined in this study, the maximum distance where the effective field can be achieved does not exceed 1.5 cm. The results of the study contribute to our understanding of the behavior of magnetic particles in the capillaries of living organisms when exposed to a magnetic field. Full article
(This article belongs to the Special Issue Fundamentals and Applications of Novel Functional Magnetic Materials)
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20 pages, 6594 KiB  
Article
Intelligent Diagnosis Method for Early Weak Faults Based on Wave Intercorrelation–Convolutional Neural Networks
by Weiting Zhong and Bao Pang
Electronics 2025, 14(14), 2808; https://doi.org/10.3390/electronics14142808 - 12 Jul 2025
Viewed by 163
Abstract
Rolling bearings are widely used in rotating machinery, and their health status is crucial for the safe operation of the equipment. The research on relevant fault diagnosis algorithms is a hot topic in the field. As a leading deep learning paradigm, Convolutional Neural [...] Read more.
Rolling bearings are widely used in rotating machinery, and their health status is crucial for the safe operation of the equipment. The research on relevant fault diagnosis algorithms is a hot topic in the field. As a leading deep learning paradigm, Convolutional Neural Networks (CNNs) have demonstrated remarkable effectiveness in bearing fault diagnosis. However, conventional CNNs encounter significant limitations in accurately identifying and classifying early-stage bearing faults, primarily due to two challenges: (1) the diagnostic accuracy is highly susceptible to variations in the input signal length and segmentation strategies and (2) incipient faults are characterized by extremely low signal-to-noise ratios (SNRs), which obscure fault signatures. To address these challenges, we propose a Waveform Intersection-CNN (WI-CNN)-based intelligent diagnosis method for early faults. This approach integrates Gramian Angular Field theory to construct high-resolution fault signatures, enabling the CNN-based diagnosis of incipient bearing faults. Validation using the Case Western Reserve University dataset demonstrates an average diagnostic accuracy exceeding 98%. Furthermore, we established a custom test platform to develop a hybrid diagnosis strategy for 10 distinct fault types. Comparative studies against two conventional CNN diagnostic methods confirm that our approach delivers superior diagnostic precision, a faster iteration speed, and enhanced algorithmic robustness. The empirical findings demonstrate that the model achieves an accuracy of 99.67% during training and 98.167% in the testing phase. Crucially, the proposed method offers exceptional simplicity, computational efficiency, and practical applicability, facilitating its widespread implementation. Full article
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28 pages, 1706 KiB  
Article
Adaptive Grazing and Land Use Coupling in Arid Pastoral China: Insights from Sunan County
by Bo Lan, Yue Zhang, Zhaofan Wu and Haifei Wang
Land 2025, 14(7), 1451; https://doi.org/10.3390/land14071451 - 11 Jul 2025
Viewed by 286
Abstract
Driven by climate change and stringent ecological conservation policies, arid and semi-arid pastoral areas face acute grassland degradation and forage–livestock imbalances. In Sunan County (Gansu Province, China), herders have increasingly turned to off-site grazing—leasing crop fields in adjacent oases during autumn and winter—to [...] Read more.
Driven by climate change and stringent ecological conservation policies, arid and semi-arid pastoral areas face acute grassland degradation and forage–livestock imbalances. In Sunan County (Gansu Province, China), herders have increasingly turned to off-site grazing—leasing crop fields in adjacent oases during autumn and winter—to alleviate local grassland pressure and adapt their livelihoods. However, the interplay between the evolving land use system (L) and this emergent borrowed pasture system (B) remains under-explored. This study introduces a coupled analytical framework linking L and B. We employ multi-temporal remote sensing imagery (2018–2023) and official statistical data to derive land use dynamic degree (LUDD) metrics and 14 indicators for the borrowed pasture system. Through entropy weighting and a coupling coordination degree model (CCDM), we quantify subsystem performance, interaction intensity, and coordination over time. The results show that 2017 was a turning point in grassland–bare land dynamics: grassland trends shifted from positive to negative, whereas bare land trends turned from negative to positive; strong coupling but low early coordination (C > 0.95; D < 0.54) were present due to institutional lags, infrastructural gaps, and rising rental costs; resilient grassroots networks bolstered coordination during COVID-19 (D ≈ 0.78 in 2023); and institutional voids limited scalability, highlighting the need for integrated subsidy, insurance, and management frameworks. In addition, among those interviewed, 75% (15/20) observed significant grassland degradation before adopting off-site grazing, and 40% (8/20) perceived improvements afterward, indicating its potential role in ecological regulation under climate stress. By fusing remote sensing quantification with local stakeholder insights, this study advances social–ecological coupling theory and offers actionable guidance for optimizing cross-regional forage allocation and adaptive governance in arid pastoral zones. Full article
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36 pages, 3846 KiB  
Article
The Development of a Forest Tourism Attractiveness Model and a Foundational Framework for Forest Climatic Spa Resorts: An Attributive Theory Approach
by Darija Cvikl
Forests 2025, 16(7), 1149; https://doi.org/10.3390/f16071149 - 11 Jul 2025
Viewed by 107
Abstract
To date, there has been a noticeable lack of a systematic and structured approach to the development of forest therapy tourism. This study addresses this problem by introducing a forest tourism attractiveness model and an evidence-based framework for the conceptual development of Forest [...] Read more.
To date, there has been a noticeable lack of a systematic and structured approach to the development of forest therapy tourism. This study addresses this problem by introducing a forest tourism attractiveness model and an evidence-based framework for the conceptual development of Forest Climatic Spa Resorts. Based on an attributive theory approach, a comprehensive set of forest tourism attractiveness attributes is defined, a model of forest tourism attractiveness is developed, and theoretical and conceptual foundations to support the criteria for the development of Forest Climatic Spa Resorts are presented. This research contributes to the ongoing discourse on sustainable tourism practices and emphasises the role of forest environments in promoting health and well-being in therapeutic tourism activities. Ultimately, our findings offer valuable insights for policymakers, tourism developers, and practitioners in the field of forest therapy tourism, providing a foundation for future initiatives aimed at enhancing the appeal and sustainability of forest-based tourism experiences. Full article
(This article belongs to the Section Urban Forestry)
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26 pages, 5689 KiB  
Article
Insights into the Adsorption of Carbon Dioxide in Zeolites ITQ-29 and 5A Based on Kinetic Measurements and Molecular Simulations
by Magdy Abdelghany Elsayed, Shixue Zhou, Xiaohui Zhao, Gumawa Windu Manggada, Zhongyuan Chen, Fang Wang and Zhijuan Tang
Nanomaterials 2025, 15(14), 1077; https://doi.org/10.3390/nano15141077 - 11 Jul 2025
Viewed by 299
Abstract
Understanding the adsorption mechanism is essential for developing efficient technologies to capture carbon dioxide from industrial flue gases. In this work, laboratory measurements, density functional theory calculations, and molecular dynamics simulations were employed to study CO2 adsorption and diffusion behavior in LTA-type [...] Read more.
Understanding the adsorption mechanism is essential for developing efficient technologies to capture carbon dioxide from industrial flue gases. In this work, laboratory measurements, density functional theory calculations, and molecular dynamics simulations were employed to study CO2 adsorption and diffusion behavior in LTA-type zeolites. The CO2 adsorption isotherms measured in zeolite 5A are best described by the Toth model. Thermodynamic analysis indicates that the adsorption process is spontaneous and exothermic, with an enthalpy change of −44.04 kJ/mol, an entropy change of −115.23 J/(mol·K), and Gibbs free energy values ranging from −9.68 to −1.03 kJ/mol over the temperature range of 298–373 K. The isosteric heat of CO2 adsorption decreases from 40.35 to 21.75 kJ/mol with increasing coverage, reflecting heterogeneous interactions at Ca2+ and Na+ sites. The adsorption kinetics follow a pseudo-first-order model, with an activation energy of 2.24 kJ/mol, confirming a physisorption mechanism. The intraparticle diffusion model indicates that internal diffusion is the rate-limiting step, supported by a significant reduction in the diffusion rate. The DFT calculations demonstrated that CO2 exhibited a −35 kJ/mol more negative adsorption energy in zeolite 5A than in zeolite ITQ-29, attributable to strong interactions with Ca2+/Na+ cations in 5A that were absent in the pure silica ITQ-29 framework. The molecular dynamics simulations based on molecular force fields indicate that CO2 diffuses more rapidly in ITQ-29, with a diffusion coefficient measuring 2.54 × 10−9 m2/s at 298 K, whereas it was 1.02 × 10−9 m2/s in zeolite 5A under identical conditions. The activation energy for molecular diffusion reaches 5.54 kJ/mol in zeolite 5A, exceeding the 4.12 kJ/mol value in ITQ-29 by 33%, which accounts for the slower diffusion kinetics in zeolite 5A. There is good agreement between experimental measurements and molecular simulation results for zeolite 5A across the studied temperature and pressure ranges. This confirms the accuracy and reliability of the selected simulation parameters and allows for the study of zeolite ITQ under similar simulation conditions. This research provides insights into CO2 adsorption energetics and diffusion within LTA-type zeolite frameworks, supporting the rational design of high-performance adsorbents for industrial gas separation. Full article
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