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17 pages, 1783 KiB  
Article
Nature-Based Solutions in Sustainable Cities: Trace Metal Accumulation in Urban Forests of Vienna (Austria) and Krakow (Poland)
by Mateusz Jakubiak, Ewa Panek, Krzysztof Urbański, Sónia Silva Victória, Stanisław Lach, Kamil Maciuk and Marek Kopacz
Sustainability 2025, 17(15), 7042; https://doi.org/10.3390/su17157042 - 3 Aug 2025
Viewed by 204
Abstract
Forests are considered one of the most valuable natural areas in metropolitan region landscapes. Considering the sensitivity and ecosystem services provided by trees, the definition of urban forest ecosystems is nowadays based on a comprehensive understanding of the entire urban ecosystem. The effective [...] Read more.
Forests are considered one of the most valuable natural areas in metropolitan region landscapes. Considering the sensitivity and ecosystem services provided by trees, the definition of urban forest ecosystems is nowadays based on a comprehensive understanding of the entire urban ecosystem. The effective capturing of particulate matter is one of the ecosystem services provided by urban forests. These ecosystems function as efficient biological filters. Plants accumulate pollutants passively via their leaves. Therefore, another ecosystem service provided by city forests could be the use of tree organs as bioindicators of pollution. This paper aims to estimate differences in trace metal pollution between the wooded urban areas of Vienna and Krakow using leaves of evergreen and deciduous trees as biomonitors. An additional objective of the research was to assess the ability of the applied tree species to act as biomonitors. Plant samples of five species—Norway spruce, Scots pine, European larch, common white birch, and common beech—were collected within both areas, in seven locations: four in the “Wienerwald” Vienna forest (Austria) and three in the “Las Wolski” forest in Krakow (Poland). Concentrations of Cr, Cu, Cd, Pb, and Zn in plant material were determined. Biomonitoring studies with deciduous and coniferous tree leaves showed statistically higher heavy metal contamination in the “Las Wolski” forest compared to the “Wienerwald” forest. Based on the conducted analyses and the literature study, it can be concluded that among the analyzed tree species, only two: European beech and common white birch can be considered potential indicators in environmental studies. These species appear to be suitable bioindicators, as both are widespread in urban woodlands of Central Europe and have shown the highest accumulation levels of trace metals. Full article
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42 pages, 5770 KiB  
Review
Echoes from Below: A Systematic Review of Cement Bond Log Innovations Through Global Patent Analysis
by Lim Shing Wang, Muhammad Haarith Firdaous and Pg Emeroylariffion Abas
Inventions 2025, 10(4), 67; https://doi.org/10.3390/inventions10040067 - 2 Aug 2025
Viewed by 227
Abstract
Maintaining well integrity is essential in the oil and gas industry to prevent environmental hazards, operational risks, and economic losses. Cement bond log (CBL) tools are essential in evaluating cement bonding and ensuring wellbore stability. This study presents a patent landscape review of [...] Read more.
Maintaining well integrity is essential in the oil and gas industry to prevent environmental hazards, operational risks, and economic losses. Cement bond log (CBL) tools are essential in evaluating cement bonding and ensuring wellbore stability. This study presents a patent landscape review of CBL technologies, based on 3473 patent documents from the Lens.org database. After eliminating duplicates and irrelevant entries, 167 granted patents were selected for in-depth analysis. These were categorized by technology type (wave, electrical, radiation, neutron, and other tools) and by material focus (formation, casing, cement, and borehole fluid). The findings reveal a dominant focus on formation evaluation (59.9%) and a growing reliance on wave-based (22.2%) and other advanced tools (25.1%), indicating a shift toward high-precision diagnostics. Geographically, 75% of granted patents were filed through the U.S. Patent and Trademark Office, and 97.6% were held by companies, underscoring the dominance of corporate innovation and the minimal presence of academia and individuals. The review also identifies notable patents that reflect significant technical innovations and discusses their role in advancing diagnostic capabilities. These insights emphasize the need for broader collaboration and targeted research to advance well integrity technologies in line with industry goals for operational performance and safety. Full article
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18 pages, 4332 KiB  
Article
Soils of the Settlements of the Yamal Region (Russia): Morphology, Diversity, and Their Environmental Role
by Evgeny Abakumov, Alexandr Pechkin, Sergey Kouzov and Anna Kravchuk
Appl. Sci. 2025, 15(15), 8569; https://doi.org/10.3390/app15158569 (registering DOI) - 1 Aug 2025
Viewed by 113
Abstract
The landscapes of the Arctic seem endless. But they are also subject to anthropogenic impact, especially in urbanized and industrial ecosystems. The population of the Arctic zone of Russia is extremely urbanized, and up to 84% of the population lives in cities and [...] Read more.
The landscapes of the Arctic seem endless. But they are also subject to anthropogenic impact, especially in urbanized and industrial ecosystems. The population of the Arctic zone of Russia is extremely urbanized, and up to 84% of the population lives in cities and industrial settlements. In this regard, we studied the background soils of forests and tundras and the soils of settlements. The main signs of the urbanogenic morphogenesis of soils associated with the transportation of material for urban construction are revealed. The peculiarities of soils of recreational, residential, and industrial zones of urbanized ecosystems are described. The questions of diversity and the classification of soils are discussed. The specificity of bulk soils used in the construction of industrial structures in the context of the initial stage of soil formation is considered. For the first time, soils and soil cover of settlements in the central and southern parts of the Yamal region are described in the context of traditional pedology. It is shown that the construction of new soils and grounds can lead to both decreases and increases in biodiversity, including the appearance of protected species. Surprisingly, the forms of urban soil formation in the Arctic are very diversified in terms of morphology, as well as in the ecological functions performed by soils. The urbanization of past decades has drastically changed the local soil cover. Full article
(This article belongs to the Section Environmental Sciences)
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21 pages, 16495 KiB  
Article
Regenerating Landscape Through Slow Tourism: Insights from a Mediterranean Case Study
by Luca Barbarossa and Viviana Pappalardo
Sustainability 2025, 17(15), 7005; https://doi.org/10.3390/su17157005 - 1 Aug 2025
Viewed by 160
Abstract
The implementation of the trans-European tourist cycle route network “EuroVelo” is fostering new strategic importance for non-motorized mobility and the associated practice of cycling tourism. Indeed, slow tourism offers a pathway for the development of inland areas. The infrastructure supporting it, such as [...] Read more.
The implementation of the trans-European tourist cycle route network “EuroVelo” is fostering new strategic importance for non-motorized mobility and the associated practice of cycling tourism. Indeed, slow tourism offers a pathway for the development of inland areas. The infrastructure supporting it, such as long-distance cycling and walking paths, can act as a vital connection, stimulating regeneration in peripheral territories by enhancing environmental and landscape assets, as well as preserving heritage, local identity, and culture. The regeneration of peri-urban landscapes through soft mobility is recognized as the cornerstone for accessibility to material and immaterial resources (including ecosystem services) for multiple categories of users, including the most vulnerable, especially following the restoration of green-area systems and non-urbanized areas with degraded ecosystems. Considering the forthcoming implementation of the Magna Grecia cycling route, the southernmost segment of the “EuroVelo” network traversing three regions in southern Italy, this contribution briefly examines the necessity of defining new development policies to effectively integrate sustainable slow tourism with the enhancement of environmental and landscape values in the coastal areas along the route. Specifically, this case study focuses on a coastal stretch characterized by significant morphological and environmental features and notable landscapes interwoven with densely built environments. In this area, environmental and landscape values face considerable threats from scattered, irregular, low-density settlements, abandoned sites, and other inappropriate constructions along the coastline. Full article
(This article belongs to the Special Issue A Systems Approach to Urban Greenspace System and Climate Change)
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40 pages, 585 KiB  
Article
Finite-Time Thermodynamics and Complex Energy Landscapes: A Perspective
by Johann Christian Schön
Entropy 2025, 27(8), 819; https://doi.org/10.3390/e27080819 - 1 Aug 2025
Viewed by 115
Abstract
Finite-time thermodynamics (FTT) describes the study of thermodynamic processes that take place in finite time. Due to the finite-time requirement, in general the system cannot move from equilibrium state to equilibrium state. As a consequence, excess entropy is generated, available work is reduced, [...] Read more.
Finite-time thermodynamics (FTT) describes the study of thermodynamic processes that take place in finite time. Due to the finite-time requirement, in general the system cannot move from equilibrium state to equilibrium state. As a consequence, excess entropy is generated, available work is reduced, and/or the maximally achievable efficiency is not achieved; minimizing these negative side-effects constitutes an optimal control problem. Particularly challenging are processes and cycles that involve phase transitions of the working fluid material or the target material of a synthesis process, especially since most materials reside on a highly complex energy landscape exhibiting alternative metastable phases or glassy states. In this perspective, we discuss the issues and challenges involved in dealing with such materials when performing thermodynamic processes that include phase transitions in finite time. We focus on thermodynamic cycles with one back-and-forth transition and the generation of new materials via a phase transition; other systems discussed concern the computation of free energy differences and the general applicability of FTT to systems outside the realm of chemistry and physics that exhibit cost function landscapes with phase transition-like dynamics. Full article
(This article belongs to the Special Issue The First Half Century of Finite-Time Thermodynamics)
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48 pages, 8533 KiB  
Systematic Review
Eco-Efficient Retrofitting of Rural Heritage: A Systematic Review of Sustainable Strategies
by Stefano Bigiotti, Mariangela Ludovica Santarsiero, Anna Irene Del Monaco and Alvaro Marucci
Energies 2025, 18(15), 4065; https://doi.org/10.3390/en18154065 - 31 Jul 2025
Viewed by 177
Abstract
Through a systematic review of sustainable rural dwelling recovery, this study offers a broader reflection on retrofitting practices, viewing eco-efficiency as a means to enhance both cultural heritage and agricultural landscapes. The work is based on the assumption that vernacular architecture in rural [...] Read more.
Through a systematic review of sustainable rural dwelling recovery, this study offers a broader reflection on retrofitting practices, viewing eco-efficiency as a means to enhance both cultural heritage and agricultural landscapes. The work is based on the assumption that vernacular architecture in rural contexts embodies historical, cultural, and typological values worthy of preservation, while remaining adaptable to reuse through eco-efficient solutions and technological innovation. Using the PRISMA protocol, 115 scientific contributions were selected from 1711 initial records and classified into four macro-groups: landscape relationships; seismic and energy retrofitting; construction techniques and innovative materials; and morphological–typological analysis. Results show a predominance (over 50%) of passive design strategies, compatible materials, and low-impact techniques, while active systems are applied more selectively to protect cultural integrity. The study identifies replicable methodological models combining sustainability, cultural continuity, and functional adaptation, offering recommendations for future operational guidelines. Conscious eco-efficient retrofitting thus emerges as a strategic tool for the integrated valorization of rural landscapes and heritage. Full article
(This article belongs to the Special Issue Sustainable Building Energy and Environment: 2nd Edition)
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50 pages, 8673 KiB  
Article
Challenges of Integrating Assistive Technologies and Robots with Embodied Intelligence in the Homes of Older People Living with Frailty
by Abdel-Karim Al-Tamimi, Lantana Hewitt, David Cameron, Maher Salem and Armaghan Moemeni
Appl. Sci. 2025, 15(15), 8415; https://doi.org/10.3390/app15158415 - 29 Jul 2025
Viewed by 235
Abstract
The rapid increase in the global population of older adults presents a significant challenge, but also a unique opportunity to leverage technological advancements for promoting independent living and well-being. This study introduces the CIREI framework, which is a comprehensive model designed to enhance [...] Read more.
The rapid increase in the global population of older adults presents a significant challenge, but also a unique opportunity to leverage technological advancements for promoting independent living and well-being. This study introduces the CIREI framework, which is a comprehensive model designed to enhance the integration of smart home and assistive technologies specifically for pre-frail older adults. Developed through a systematic literature review and innovative and comprehensive co-design activities, the CIREI framework captures the nuanced needs, preferences, and challenges faced by older adults, caregivers, and experts. Key findings from the co-design workshop highlight critical factors such as usability, privacy, and personalised learning preferences, which directly influence technology adoption. These insights informed the creation of an intelligent middleware prototype named WISE-WARE, which seamlessly integrates commercial off-the-shelf (COTS) devices to support health management and improve the quality of life for older adults. The CIREI framework’s adaptability ensures it can be extended and refined to meet the ever-changing needs of the ageing population, providing a robust foundation for future research and development in user-centred technology design. All workshop materials, including tools and methodologies, are made available to encourage the further exploration and adaptation of the CIREI framework, ensuring its relevance and effectiveness in the dynamic landscape of ageing and technology. This research contributes significantly to the discourse on ageing in place, digital inclusion, and the role of technology in empowering older adults to maintain independence. Full article
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35 pages, 3995 KiB  
Review
Recent Advancements in Latent Thermal Energy Storage and Their Applications for HVAC Systems in Commercial and Residential Buildings in Europe—Analysis of Different EU Countries’ Scenarios
by Belayneh Semahegn Ayalew and Rafał Andrzejczyk
Energies 2025, 18(15), 4000; https://doi.org/10.3390/en18154000 - 27 Jul 2025
Viewed by 609
Abstract
Heating, ventilation, and air-conditioning (HVAC) systems account for the largest share of energy consumption in European Union (EU) buildings, representing approximately 40% of the final energy use and contributing significantly to carbon emissions. Latent thermal energy storage (LTES) using phase change materials (PCMs) [...] Read more.
Heating, ventilation, and air-conditioning (HVAC) systems account for the largest share of energy consumption in European Union (EU) buildings, representing approximately 40% of the final energy use and contributing significantly to carbon emissions. Latent thermal energy storage (LTES) using phase change materials (PCMs) has emerged as a promising strategy to enhance HVAC efficiency. This review systematically examines the role of latent thermal energy storage using phase change materials (PCMs) in optimizing HVAC performance to align with EU climate targets, including the Energy Performance of Buildings Directive (EPBD) and the Energy Efficiency Directive (EED). By analyzing advancements in PCM-enhanced HVAC systems across residential and commercial sectors, this study identifies critical pathways for reducing energy demand, enhancing grid flexibility, and accelerating the transition to nearly zero-energy buildings (NZEBs). The review categorizes PCM technologies into organic, inorganic, and eutectic systems, evaluating their integration into thermal storage tanks, airside free cooling units, heat pumps, and building envelopes. Empirical data from case studies demonstrate consistent energy savings of 10–30% and peak load reductions of 20–50%, with Mediterranean climates achieving superior cooling load management through paraffin-based PCMs (melting range: 18–28 °C) compared to continental regions. Policy-driven initiatives, such as Germany’s renewable integration mandates for public buildings, are shown to amplify PCM adoption rates by 40% compared to regions lacking regulatory incentives. Despite these benefits, barriers persist, including fragmented EU standards, life cycle cost uncertainties, and insufficient training. This work bridges critical gaps between PCM research and EU policy implementation, offering a roadmap for scalable deployment. By contextualizing technical improvement within regulatory and economic landscapes, the review provides strategic recommendations to achieve the EU’s 2030 emissions reduction targets and 2050 climate neutrality goals. Full article
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23 pages, 1154 KiB  
Article
Impact of Paintings Made from Waste Materials from a Particular Region on Viewers’ Behavioral Intention Regarding Social and Environmental Issues
by Ryuzo Furukawa and Ayami Tamura
Sustainability 2025, 17(15), 6822; https://doi.org/10.3390/su17156822 - 27 Jul 2025
Viewed by 308
Abstract
The purpose of this study is to analyze how future landscape paintings using paints and binders made from the waste materials of a particular region and the background information of these artworks affect viewers’ behavioral intentions regarding social and environmental issues. First, 30 [...] Read more.
The purpose of this study is to analyze how future landscape paintings using paints and binders made from the waste materials of a particular region and the background information of these artworks affect viewers’ behavioral intentions regarding social and environmental issues. First, 30 beauty evaluation items were extracted by a repertory grid analysis. Then, we asked participants to view the artworks at an exhibition in order to determine the impact of the background information behind the painting and the painting itself on participants’ imagination of the future, reconsidering themselves, social and environmental issues, and their behavioral intentions. The results showed that viewing paintings with their background information and using paints made of waste materials from a particular region improved participants’ behavioral intentions to imagine the future, to reconsider themselves, and to reconsider social and environmental issues. The elements of beauty of the paintings were found to have the potential to trigger the first step toward lifestyle change for sustainability. Full article
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36 pages, 22778 KiB  
Review
Enzyme-Based Single Solid-State Nanochannel Biosensors
by L. Miguel Hernández Parra, Omar Azzaroni and Waldemar A. Marmisollé
Chemosensors 2025, 13(8), 275; https://doi.org/10.3390/chemosensors13080275 - 25 Jul 2025
Viewed by 213
Abstract
Sensing technologies play a critical role in healthcare, not only for diagnosis and treatment but especially for prevention and early intervention. Recent advances in biology, medicine, and materials science have expanded the landscape of measurable biological markers and enabled the development of nanotechnology-based [...] Read more.
Sensing technologies play a critical role in healthcare, not only for diagnosis and treatment but especially for prevention and early intervention. Recent advances in biology, medicine, and materials science have expanded the landscape of measurable biological markers and enabled the development of nanotechnology-based biosensing platforms. Among the most prominent strategies in biosensing are those that take inspiration from nature, particularly through the integration of biological components such as enzymes. This review focuses on the intersection between enzymatic catalysis and single solid-state nanochannel (SSN) technologies as a promising approach for the development of advanced biosensing devices. We provide an overview of the historical background, current state of the art, and major achievements in enzyme-based biosensors and artificial nanochannel platforms, highlighting their synergistic potential. Particular attention is given to the challenges associated with enzyme integration into artificial environments, including stability and functionality retention, and the strategies employed to overcome them. Finally, we discuss the prospects and limitations of combining enzymes with SSNs, aiming to inspire future research in this emerging and multidisciplinary field. Full article
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49 pages, 21554 KiB  
Article
A Disappearing Cultural Landscape: The Heritage of German-Style Land Use and Pug-And-Pine Architecture in Australia
by Dirk H. R. Spennemann
Land 2025, 14(8), 1517; https://doi.org/10.3390/land14081517 - 23 Jul 2025
Viewed by 272
Abstract
This paper investigates the cultural landscapes established by nineteenth-century German immigrants in South Australia and the southern Riverina of New South Wales, with particular attention to settlement patterns, architectural traditions and toponymic transformation. German immigration to Australia, though numerically modest compared to the [...] Read more.
This paper investigates the cultural landscapes established by nineteenth-century German immigrants in South Australia and the southern Riverina of New South Wales, with particular attention to settlement patterns, architectural traditions and toponymic transformation. German immigration to Australia, though numerically modest compared to the Americas, significantly shaped local communities, especially due to religious cohesion among Lutheran migrants. These settlers established distinct, enduring rural enclaves characterized by linguistic, religious and architectural continuity. The paper examines three manifestations of these cultural landscapes. A rich toponymic landscape was created by imposing on natural landscape features and newly founded settlements the names of the communities from which the German settlers originated. It discusses the erosion of German toponyms under wartime nationalist pressures, the subsequent partial reinstatement and the implications for cultural memory. The study traces the second manifestation of a cultural landscapes in the form of nucleated villages such as Hahndorf, Bethanien and Lobethal, which often followed the Hufendorf or Straßendorf layout, integrating Silesian land-use principles into the Australian context. Intensification of land use through housing subdivisions in two communities as well as agricultural intensification through broad acre farming has led to the fragmentation (town) and obliteration (rural) of the uniquely German form of land use. The final focus is the material expression of cultural identity through architecture, particularly the use of traditional Fachwerk (half-timbered) construction and adaptations such as pug-and-pine walling suited to local materials and climate. The paper examines domestic forms, including the distinctive black kitchen, and highlights how environmental and functional adaptation reshaped German building traditions in the antipodes. Despite a conservation movement and despite considerable documentation research in the late twentieth century, the paper shows that most German rural structures remain unlisted and vulnerable. Heritage neglect, rural depopulation, economic rationalization, lack of commercial relevance and local government policy have accelerated the decline of many of these vernacular buildings. The study concludes by problematizing the sustainability of conserving German Australian rural heritage in the face of regulatory, economic and demographic pressures. With its layering of intangible (toponymic), structural (buildings) and land use (cadastral) features, the examination of the cultural landscape established by nineteenth-century German immigrants adds to the body of literature on immigrant communities, settler colonialism and landscape research. Full article
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19 pages, 3031 KiB  
Article
Mutational Profiling Detection in FNAC Samples of Different Types of Thyroid Neoplasms Using Targeted NGS
by Riying Liang, Man Luo, Xinhua Yang, Baoming Luo and Rongbin Liu
Cancers 2025, 17(15), 2429; https://doi.org/10.3390/cancers17152429 - 23 Jul 2025
Viewed by 229
Abstract
Background: Thyroid neoplasms exhibit a diverse molecular landscape, and the 2022 WHO classification emphasizes the critical role of molecular profiling in thyroid cancer management; however, comprehensive mutational data from fine-needle aspiration cytology (FNAC) samples using targeted next-generation sequencing (NGS) are still limited, necessitating [...] Read more.
Background: Thyroid neoplasms exhibit a diverse molecular landscape, and the 2022 WHO classification emphasizes the critical role of molecular profiling in thyroid cancer management; however, comprehensive mutational data from fine-needle aspiration cytology (FNAC) samples using targeted next-generation sequencing (NGS) are still limited, necessitating further investigation to guide clinical practice. Purpose: To characterize the mutational landscape of thyroid neoplasms using targeted NGS of FNAC samples and to assess the clinical implications of molecular profiling. Materials and Methods: This retrospective study included 952 patients with thyroid carcinomaneoplasms who underwent surgery at Sun Yat-sen Memorial Hospital from 2021 to 2023. Preoperative ultrasound, FNAC, and targeted NGS were performed. NGS panels covering 18, 88, and pan-cancer genes were used to analyze FNAC samples. Molecular alterations were correlated with clinical and pathological features. Results: The most frequent mutation was BRAFV600E (84.45%), followed by RET (6.41%), BRCA1/2 (4.41%) and RAS (4.41%). Patients were categorized into BRAF-like (830 cases), RAS-like (36 cases), high-risk mutations (25 cases), and other mutations (28 cases). High-risk mutations were associated with older age and larger tumor size. BRAF-like tumors had a higher lymph node metastasis rate (58.77%) compared to RAS-like tumors (33.33%). Tumor mutation burden varied significantly among different thyroid neoplasm subtypes. Conclusions: Molecular profiling using targeted NGS of FNAC samples provides valuable insights into the genetic landscape of thyroid neoplasms and has significant clinical implications for diagnosis and personalized treatment strategies. Further validation with paired tumor and plasma samples is warranted. Full article
(This article belongs to the Section Molecular Cancer Biology)
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27 pages, 12120 KiB  
Article
The Menhir as an Oral Tradition in Cattle-Raising Territories: First Geological Provenance Analyses at the Antequera Heritage Site, Spain
by Lidia Cabello-Ligero, Primitiva Bueno-Ramírez, María José Armenteros-Lojo, José Suarez Padilla, José L. Caro Herrero, Rodrigo de Balbín-Behrmann, Rosa Barroso-Bermejo, Alia Vázquez Martínez, Juan José Durán Valsero, Sergio Raúl Durán-Laforet, Rafael Jordá Bordehore, Raquel Morales García and Miguel Ángel Varo Sánchez-Garrido
Heritage 2025, 8(8), 291; https://doi.org/10.3390/heritage8080291 - 22 Jul 2025
Viewed by 1246
Abstract
The great megalithic sites reveal an extended use of their monuments. In Late Prehistory, in Protohistory, and even in historical times, dolmens remained visible references on the landscape and were central for navigating it. The megaliths of Menga, Viera, and Romeral provide quality [...] Read more.
The great megalithic sites reveal an extended use of their monuments. In Late Prehistory, in Protohistory, and even in historical times, dolmens remained visible references on the landscape and were central for navigating it. The megaliths of Menga, Viera, and Romeral provide quality data to confirm their continued relevance. Our aim here is to understand whether menhirs also played that role, using the area of Tierras de Antequera, which is connected to the sea, as a case study. With that goal in mind, a research project has been initiated through intensive archaeological field surveying, combined with the collection of testimonies from oral tradition and other archaeological tools such as GIS, geophysical prospection, photogrammetry and RTI, for the detection of engravings and paintings on some of the located landmarks. We present in this paper the first geological analyses in the megalithic territory of Antequera to determine the raw material of the menhirs that are studied and the geological outcrops from which they come. Full article
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40 pages, 1777 KiB  
Review
Nanomaterials for Direct Air Capture of CO2: Current State of the Art, Challenges and Future Perspectives
by Cataldo Simari
Molecules 2025, 30(14), 3048; https://doi.org/10.3390/molecules30143048 - 21 Jul 2025
Viewed by 415
Abstract
Direct Air Capture (DAC) is emerging as a critical climate change mitigation strategy, offering a pathway to actively remove atmospheric CO2. This comprehensive review synthesizes advancements in DAC technologies, with a particular emphasis on the pivotal role of nanostructured solid sorbent [...] Read more.
Direct Air Capture (DAC) is emerging as a critical climate change mitigation strategy, offering a pathway to actively remove atmospheric CO2. This comprehensive review synthesizes advancements in DAC technologies, with a particular emphasis on the pivotal role of nanostructured solid sorbent materials. The work critically evaluates the characteristics, performance, and limitations of key nanomaterial classes, including metal–organic frameworks (MOFs), covalent organic frameworks (COFs), zeolites, amine-functionalized polymers, porous carbons, and layered double hydroxides (LDHs), alongside solid-supported ionic liquids, highlighting their varied CO2 uptake capacities, regeneration energy requirements, and crucial water sensitivities. Beyond traditional temperature/pressure swing adsorption, the review delves into innovative DAC methodologies such as Moisture Swing Adsorption (MSA), Electro Swing Adsorption (ESA), Passive DAC, and CO2-Binding Organic Liquids (CO2 BOLs), detailing their unique mechanisms and potential for reduced energy footprints. Despite significant progress, the widespread deployment of DAC faces formidable challenges, notably high capital and operational costs (currently USD 300–USD 1000/tCO2), substantial energy demands (1500–2400 kWh/tCO2), water interference, scalability hurdles, and sorbent degradation. Furthermore, this review comprehensively examines the burgeoning global DAC market, its diverse applications, and the critical socio-economic barriers to adoption, particularly in developing countries. A comparative analysis of DAC within the broader carbon removal landscape (e.g., CCS, BECCS, afforestation) is also provided, alongside an address to the essential, often overlooked, environmental considerations for the sustainable production, regeneration, and disposal of spent nanomaterials, including insights from Life Cycle Assessments. The nuanced techno-economic landscape has been thoroughly summarized, highlighting that commercial viability is a multi-faceted challenge involving material performance, synthesis cost, regeneration energy, scalability, and long-term stability. It has been reiterated that no single ‘best’ material exists, but rather a portfolio of technologies will be necessary, with the ultimate success dependent on system-level integration and the availability of low-carbon energy. The review paper contributes to a holistic understanding of cutting-edge DAC technologies, bridging material science innovations with real-world implementation challenges and opportunities, thereby identifying critical knowledge gaps and pathways toward a net-zero carbon future. Full article
(This article belongs to the Special Issue Porous Carbon Materials: Preparation and Application)
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15 pages, 1238 KiB  
Article
Assessment of Environmental Dynamics and Ecosystem Services of Guadua amplexifolia J. Presl in San Jorge River Basin, Colombia
by Yiniva Camargo-Caicedo, Jorge Augusto Montoya Arango and Fredy Tovar-Bernal
Resources 2025, 14(7), 115; https://doi.org/10.3390/resources14070115 - 18 Jul 2025
Viewed by 374
Abstract
Guadua amplexifolia J. Presl is a Neotropical bamboo native to southern Mexico through Central America to Colombia, where it thrives in riparian zones of the San Jorge River basin. Despite its ecological and socio-economic importance, its environmental dynamics and provision of ecosystem services [...] Read more.
Guadua amplexifolia J. Presl is a Neotropical bamboo native to southern Mexico through Central America to Colombia, where it thrives in riparian zones of the San Jorge River basin. Despite its ecological and socio-economic importance, its environmental dynamics and provision of ecosystem services remain poorly understood. This study (1) quantifies spatial and temporal land use/cover changes in the municipality of Montelíbano between 2002 and 2022 and (2) evaluates the ecosystem services that local communities derive from in 2002, 2012, and 2022, and they were classified in QGIS using G. amplexifolia. We applied a supervised classification of Landsat imagery (2002, 2012, 2022) in QGIS, achieving 85% overall accuracy and a Cohen’s Kappa of 0.82 (n = 45 reference points). For the social assessment, we held participatory workshops and conducted semi-structured interviews with artisans, fishers, authorities, and NGO representatives; responses were manually coded to extract key themes. The results show a 12% decline in total vegetated area from 2002 to 2012, followed by an 8% recovery by 2022, with bamboo-dominated stands following a similar pattern. Communities identified raw material provision (87% of mentions), climate regulation (82%), and cultural–recreational benefits (58%) as the most important services provided by G. amplexifolia. This is the first integrated assessment of G. amplexifolia’s landscape dynamics and community-valued services in the San Jorge basin, highlighting its dual function as a renewable resource and a natural safeguard against environmental risks. Our findings offer targeted recommendations for management practices and land use policies to support the species’ conservation and sustainable utilization. Full article
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