Search Results (194)

This paper reviews selected biofuels that are currently in use, as well as fuels considered promising, for powering compression-ignition (CI) engines, including Common Rail systems. The review focuses on fuel properties, production pathways, operational compatibility, and the effects on engine performance and exhaust emissions. The objective is to systematize the current state of knowledge on biodiesel, hydrotreated vegetable oil (HVO), biomass-to-liquid (BtL), F-34, and sustainable aviation fuel (SAF), and to identify their key advantages, implementation constraints, and research gaps relevant to transport and power-generation applications. The paper compiles and compares published studies on fuel production routes and on the consequences of fuel use in CI engines with respect to performance and pollutant emissions. As an outcome, the available evidence is synthesized, fuels with the highest implementation potential are indicated in the context of emission reduction while maintaining required operational functionality, and priority areas for further research are highlighted, including the still insufficiently characterized effects of SAF on CI engine operation and emissions. Full article

Utah State University has developed a high-performance “green” hybrid propulsion technology based on the unique electrical breakdown properties of 3D-printed acrylonitrile butadiene styrene. Using 3D-printed ABS as fuel, typical startup sequences require approximately 5–15 joules and, once started, the system can be sequentially fired with no additional energy inputs required. The number of possible ignitions is limited only by the amount of fuel. The most technologically mature version uses gaseous oxygen (GOX) as oxidizer and 3D-printed ABS as fuel. While GOX is mass-efficient, it lacks volumetric efficiency unless highly pressurized. Nytrox, a blend of GOX and nitrous oxide, improves propellant density and volumetric efficiency, while maintaining acceptable levels of mass efficiency (specific impulse). Nytrox can safely self-pressurize, eliminating the need for a separate oxidizer pressurization system and reducing overall complexity. However, employing Nytrox as a direct substitute for GOX results in reduced ignition reliability and considerably increases cold-start ignition latency. This paper quantifies the latency, explores its sources, and analyzes expected behaviors. Solutions include raising combustion and storage pressures to boost oxygen content in Nitrox’s liquid phase and increasing combustion chamber pressure to reduce ignition delays. Full article

Liquefied petroleum gas (LPG) is a widely available alternative fuel, easily stored in liquid form, capable of displacing diesel fuel in compression-ignition engines. Bio-LPG extends this pathway because it is a renewable drop-in form of LPG; its distinguishing advantage is not a different in-cylinder combustion chemistry, but a lower life-cycle greenhouse-gas intensity that depends on feedstock and production route. This review, therefore, combines a systematic synthesis of CI-engine LPG combustion evidence with a Bio-LPG transition perspective. A PRISMA-guided search of major databases (2000–2025) yielded 47 studies with matched diesel baseline. Evidence was categorized by LPG utilization pathway, distinguishing between fumigation, gaseous port injection, and in-cylinder LPG direct injection (gaseous or liquid), alongside engine class, pilot fuel fraction, and key operating parameters (injection timing/quantity, intake conditioning, exhaust gas recirculation (EGR), and boost). Data were normalized as percentage deviations relative to diesel and synthesized across standardized load bins (25/50/75/100%). Among studies reporting nitrogen oxides (NO_x), 20 of 37 showed net reductions, while results in 12 studies were load-dependent; particulate matter (PM), smoke, and soot indicators decreased in 17 of 27 cases. While intake-path strategies generally reduced NO_x and smoke, they often increased CO and HC emissions at low loads. The limited emerging liquid-phase direct-injection evidence shows the closest diesel-like efficiency response, although the evidence base remains limited. Overall, the engine-level findings identify the most promising LPG/Bio-LPG deployment pathways, while the specific additional climate benefit of Bio-LPG lies in its lower well-to-wheel greenhouse-gas intensity. Full article

Nitrous oxide (N₂O) has attracted increasing attention as an oxidizer for space propulsion systems due to its non-toxic nature and favorable handling characteristics. Its relatively high vapor pressure allows self-pressurization, while its wide storage temperature range makes it attractive for a range of space applications. In parallel with broader efforts to identify alternatives to conventional toxic propellants, numerous studies have investigated liquid propulsion systems based on N₂O combined with hydrocarbon fuels, spanning both premixed fuel blends and non-premixed bipropellant configurations. This review summarizes experimental and system-level studies on N₂O–hydrocarbon propellant combinations, including ethylene, ethane, ethanol, propane, acetylene, methane, dimethyl ether, and propylene. Results reported by different research groups reveal clear differences among propellant combinations in terms of vapor pressure, thermal stability, chemical reactivity, and ignition delay. These differences have direct implications for injector design, mixing strategies, ignition mechanism, and system safety. By bringing together recent results from the literature, this paper aims to clarify the practical trade-offs associated with fuel selection in N₂O-based premixed and bipropellant systems and to provide a useful reference for the design and development of future space propulsion concepts. Full article

To reveal the physical evolution of methanol spray under different environmental conditions and injection strategies, this study focuses on the atomization and evaporation behavior of low-pressure methanol spray. The coupled effects of temperature, pressure, and injection parameters are systematically investigated based on constant-volume combustion chamber experiments and three-dimensional CFD simulations. The formation, evolution, and interaction mechanisms of the liquid column core and cooling core are revealed. The results indicate that temperature is the dominant factor influencing methanol spray atomization. When the temperature increases from 255 K to 333 K, the spray penetration distance increases by approximately 70%, accompanied by a pronounced shortening of the liquid-core length and enhanced evaporation and air entrainment. Under low-temperature conditions, a stable liquid-core structure and a strong cooling core are formed, characterized by a high-density, long-axis morphology and an extensive low-temperature region, which suppress fuel–air mixing and ignition. Increasing the ambient pressure improves spray–air mixing but reduces penetration; at 255 K, increasing the ambient pressure from 0.05 MPa to 0.2 MPa increases the spray cone angle by approximately 10% while reducing the penetration distance by about 50%. Furthermore, optimizing the injection pressure or shortening the injection pulse width effectively enhances atomization performance: increasing the injection pressure from 0.4 MPa to 0.6 MPa and reducing the pulse width from 5 ms to 2 ms increases the penetration distance by approximately 30% and reduces the mean droplet diameter by about 20%. Full article

Hydrogen, a promising alternative to conventional fuels, presents significant combustion hazards due to its low minimum ignition energy (MIE) and wide flammability range (4–75 vol.%). The risks are amplified with liquid hydrogen (LH₂), which has an extremely low boiling point (20.3 K) and high diffusivity. Once released, LH₂ vaporizes rapidly and mixes with ambient air. This process forms a cryogenic and highly flammable cloud, which significantly increases ignition and explosion hazards. Therefore, a comprehensive understanding of the MIE of cryogenic hydrogen–air mixtures is crucial for quantitative risk assessment. This work develops and validates a numerical algorithm for predicting the MIE of hydrogen–air mixtures at cryogenic temperatures (down to 93 K) across a wide range of hydrogen concentrations (10~50 vol.%) and oxygen concentration ratios [O₂/(O₂ + N₂) = 21~52%]. By coupling a detailed H₂/O₂ reaction mechanism with a large eddy simulation (LES) turbulence model, this algorithm demonstrates high reliability and accuracy. The results indicate (1) an exponential increase in MIE with decreasing initial temperature; (2) a U-shaped dependence of MIE on hydrogen concentration, with the minimum occurring near 25% hydrogen concentration; (3) an asymptotic dependence of MIE on oxygen concentration ratio, particularly at 40% hydrogen concentration. The initial temperature has the greatest influence on MIE; hydrogen concentration is the second; and the oxygen concentration ratio has the weakest influence. This study provides a theoretical framework and a practical computational tool for assessing and mitigating cryogenic ignition associated with LH₂ leakage, thereby enabling safer application of liquid hydrogen technologies. Full article

To investigate the influence of injector recess depth on the combustion characteristics of air heaters, high-speed shadowgraph imaging technology combined with numerical simulation was employed. Targeting a tripropellant coaxial direct-flow single injector, three test cases with recess depths of 0 mm, 5 mm, and 10 mm were designed to systematically study the ignition process, flame propagation characteristics, quasi-steady combustion, and flow field evolution mechanisms. Experimental results indicate that the recessed structure can expand the liquid mist distribution range before ignition: the dimensionless spray width ratios of the 5 mm and 10 mm recess cases are increased by 57.5% and 64.9% respectively compared to the non-recessed case, with an obvious “saturation effect” observed. Injectors with recess exhibit the characteristic of “jet head priority ignition”, which shortens the ignition time and improves ignition efficiency. The 5 mm shallow recess case achieves the optimal combustion stability with the smallest chamber pressure fluctuation (±0.1 MPa). Although the 10 mm deep recess enhances near-field mixing and combustion intensity, it tends to induce flame oscillation and combustion instability. Simulation results verify the experimental observations: the recess depth regulates droplet atomization, component mixing, and combustion heat release processes by altering the recirculation zone range, velocity gradient, and gas–liquid momentum exchange efficiency. This research provides experimental and theoretical support for the structural optimization of injectors in combustion-type air heaters. Full article

To address the issues of narrow ignition limits and low combustion efficiency in ramjet combustors under low-temperature and low-pressure conditions, caused by low reactivity of liquid fuel and slow chemical reaction rates, a multi-channel gliding arc plasma excitation activation method for fuel–air mixtures is proposed. This method generates gaseous small molecules and highly active radicals. Focusing on the vaporizing flame holder of a subsonic ramjet combustor, this study investigates the fuel–air activation characteristics under different carrier gas flow rates, fuel flow rates, and numbers of discharge channels. The mechanism by which multi-channel gliding arc discharge plasma enhances fuel–air activation, ignition, and combustion performance is revealed. Full article

Hypergolic propellants are easy to start and restart, stay liquid at normal temperatures, and avoid storage issues, making them ideal for spacecraft propulsion systems. However, conventional hypergolic propellants are toxic, prompting the need to find safer alternatives and/or reduce their toxicity. The growing demand for propulsion in advancing space technology has driven research into high-performance, sustainable, and environmentally safe hypergolic propellant types. At this point, research into new hypergolic fuels that can replace traditional rocket propellant designs is highly significant. In this study, the current status of hypergolic fuels is discussed, and new technological developments and future projections are examined. Several approaches have been studied in an effort to create a high-performance hypergolic propellant system. These include modifications such as changing the structure of propulsion systems, altering propellant constituents, and adding additives. All these conditions were found to bear a profound effect on the specific impulse, density impulse, heat energy, and ignition delay of the propellants. Full article

The global transition toward low-carbon energy and transportation systems positions hydrogen as a key clean and versatile energy carrier. However, ensuring the safe handling and storage of hydrogen—particularly in its liquid form LH₂)—remains a critical challenge to large-scale deployment. Accidental releases of LH₂ can lead to rapid dispersion, cryogenic hazards, and increased risks of ignition or detonation due to hydrogen’s low ignition energy and wide flammability limits. This review synthesizes recent advances in the understanding and modelling of LH₂ safety scenarios, emphasizing the complementary roles of Computational Fluid Dynamics (CFD) and Machine Learning (ML). The paper first outlines the fundamental physical processes governing cryogenic hydrogen leaks, spills, and jet releases, followed by an overview of current storage and sensing technologies. Special consideration is given to safety implications arising from the differences between open and enclosed environments and the fact that existent sensing technologies present deficiencies at low temperatures. CFD-based studies are reviewed to illustrate how these methods capture complex flow and dispersion dynamics under diverse operational and environmental conditions, supported by a summary of existing experimental investigations used for model validation. The emerging role of ML is then examined, focusing on its integration with CFD simulations and sensor networks for predictive risk assessment, real-time leak detection, and the development of digital twins. Finally, integrated CFD–ML-sensor systems are discussed as a pathway toward a physics-informed, data-driven framework for advancing hydrogen safety and reliability. Full article

Minimum Ignition Energy (MIE) is a critical parameter for assessing the combustion and explosion risks of liquid fuels under specific conditions. However, systematic testing methods for long-chain alkanes remain underdeveloped. In this study, an experimental apparatus was developed based on American Society for Testing and Materials Standard ASTM E582-21 to measure the MIE of liquid fuel vapors. Through systematic measurements of the minimum ignition energy (MIE) of alkane vapors, this study examines the influence of vapor concentration on MIE and elucidates the dependence of ignition energy on carbon chain length. System sensitivity parameters were calibrated using propane/air mixtures, establishing optimal testing conditions as a 2.0 mm electrode gap and a 14.0 pF capacitance. The measured minimum ignition energy (MIE) values for C₅–C₈ alkane vapors at their respective sensitive volume fractions were 0.197 mJ (at 3.4 vol%), 0.253 mJ (at 3.3 vol%), 0.303 mJ (at 3.0 vol%), and 0.323 mJ (at 2.8 vol%). The experimentally determined MIE values for C₅–C₈ alkane vapors demonstrate close agreement with literature data, confirming the reliability of the experimental system and methodology for MIE determination of liquid fuel vapors. Furthermore, the study reveals a characteristic V-shaped correlation between MIE and vapor concentration, along with a consistent shift in the sensitive concentration toward fuel-rich conditions relative to stoichiometric proportions. Extended measurements of C₉–C₁₁ alkanes revealed MIE values of 0.523 mJ (at 2.8 vol%) for n-nonane, 0.857 mJ (at 2.5 vol%) for n-decane, and 1.127 mJ (at 2.0 vol%) for n-undecane. Notably, the results demonstrate a substantial increase in MIE with carbon chain length, showing a 471% rise from C₅ to C₁₁. A nonlinear regression analysis confirmed a strong correlation between MIE and carbon chain length (R² = 0.98). Full article

Ammonia (NH₃) is a promising zero-carbon fuel to eliminate carbon footprint while the high autoignition temperature and low combustion rate of NH₃ remain challenging for practical implementation. Using dimethyl ether (DME) as pilot ignition fuel can substantially promote the reactivity of NH₃, thus paving the way for a widespread application of NH₃. In this study, the ignition process and nitrogen oxides (NO_x) emissions of the NH₃ liquid spray ignited by liquid DME spray were numerically investigated using Converge software. The ambient temperatures (T_amb) ranging from 900 K to 1100 K were used to mimic the in-cylinder temperature typically encountered in turbocharger engines. The effect of ammonia energy ratio (AER) and fuel injection timing was examined as well. It is found that only half of NH₃ is consumed at T_amb = 900 K while 97.4% of NH₃ is burned at T_amb = 1100 K. Nitric oxide (NO) and nitrogen dioxide (NO₂) formation also have strong correlation with T_amb and NO₂ is usually formed around the periphery of NO through these two channels HO₂ + NO = NO₂ + OH and NO + O(+M) = NO₂(+M). Extremely high nitrous oxide (N₂O, formed by NH + NO = H + N₂O) and carbon monoxide (CO) are produced with the presence of abundant unburned NH₃ at T_amb = 900 K. Additionally, increasing AER from 60% to 90% results in slightly declined combustion efficiency of NH₃ from 98.7% to 94%. NO emission has a non-monotonical relationship with AER owing to the ‘trade-off’ relationship between HNO concentration and radical pool at varying AERs. A higher AER of 95% leads to failed ignition of NH₃. Advancing DME injection not only increases combustion efficiency, but also reduces NO_x and CO emissions. Full article

This article discusses the potential of using the double-Wiebe function to model combustion in a compression-ignition engine fueled by diesel fuel or its substitutes, such as hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME), and hydrogen injected into the engine intake manifold. The hydrogen amount ranged from 0 to 35% of the total energy content of the fuels burned. It was found that co-combustion of liquid fuel with hydrogen is characterized by two distinct combustion phases: premixed and diffusion combustion. The premixed phase, occurring just after ignition, is characterized by a rapid combustion rate, which increases with an increase in hydrogen injected. The novelty in this work is the modified formula for a double-Wiebe function and the proposed parameters of this function depending on the amount of hydrogen added for co-combustion with liquid fuel. To model this combustion process, the modified double-Wiebe function was proposed, which can model two phases with different combustion rates. For this purpose, a normalized HRR was calculated, and based on this curve, coefficients for the double-Wiebe function were proposed. Satisfactory consistency with the experiment was achieved at a level determined by the coefficient of determination (R-squared) of above 0.98. It was concluded that the presented double-Wiebe function can be used to model combustion in 0-D and 1-D models for fuels: RME and HVO with hydrogen addition. Full article

Lithium-ion batteries, widely used in phones and electric vehicles, pose safety concerns due to the flammability of conventional liquid electrolytes, which are prone to ignition under elevated temperatures and mechanical stress, increasing the risk of fire. Polymer electrolytes have been employed as a safer solution thanks to their superior thermal stability and mechanical strength. However, despite these advantages, many polymer matrices pose a fire hazard, limiting their potential. This review assesses recent advances in enhancing the flame retardancy of polymer electrolytes through a variety of strategies, namely the incorporation of flame-retardant additives, the addition of nanoscale fillers to improve thermal resistance, and the design of layered or hybrid polymer membrane structures that function as thermal barriers. This review evaluates the effectiveness of these methods, examining their flame-retardancy as well as their influences on ionic conductivity and overall battery performance. By highlighting recent progress and enduring safety challenges in solid-state batteries, it aims to offer insights for developing lithium batteries with enhanced safety and high performance. Full article

Utilization of waste tires via pyrolysis is a promising solution. The liquid hydrocarbons generated during this process could be used for enhancing low-reactivity coals for energy application. Current study investigates oxidation and combustion characteristics (including composition of gaseous combustion products) of low-reactivity coal mixed with liquid hydrocarbons from pyrolysis of waste tires with a concentration up to 20%wt at 700 °C. The oxidation tests via TG-analyzer revealed that at heating rates up to 10 °C/min, the process had one stage, associated with combined oxidation of coal-liquid hydrocarbons mixture. Starting from 10 °C/min the second stage occurred at temperature ~400 °C due to evaporation of light components of the mixture. Combustion tests at experimental setup at 700 °C revealed almost linear increase in fuel reactivity, expressed into decline in ignition delay time of mixtures (up to 71.6%) with increasing concentration of liquid hydrocarbons, while flame and diffusion combustion times were, in contrast, increasing (by up to 69.5%). Increasing concentration of additives from 2.5 to 20%wt resulted not only in change in the form of obtained mixture but also changed the combustion mechanism from predominantly heterogeneous smoldering to majorly homogeneous gas-phase ignition and combustion. Gas-phase combustion products concentration curves generally complimented previously observed peculiarities of combustion. Increased CO and NO_x concentrations in combustion products of coal mixed with liquid hydrocarbons revealed necessity in additional tailoring of burner characteristics for mitigating these effects. The compromise composition of mixture was found to include 10%wt of liquid hydrocarbons for enabling quick gas-phase ignition while maintaining moderate level of combustion products emissions. Full article