Search Results (1,621)

Aviation hydraulic systems operate under high pressure and large flow rates, which induce significant fluid pressure pulsations and hydraulic shocks in pipelines. These pulsations, exacerbated by complex external loads, can lead to excessive vibration stress, component damage, oil leakage, and compromised system safety. While existing methods—such as pump structure optimization, pipeline layout adjustment, and active control—can reduce pulsations to some extent, they are limited by cost, reliability, and adaptability, particularly under high-pressure and multi-excitation conditions. Passive control, using pressure pulsation damping devices, has proven to be more practical; however, conventional designs typically focus on low-load systems and have limited frequency adaptability. This paper proposes a multi-hole parallel pressure pulsation damping device that offers high vibration attenuation, broad adaptability, and easy installation. A combined simulation–experiment approach is employed to investigate its damping mechanism and performance. The results indicate that the damping device effectively reduces vibrations in the 200–500 Hz range, with minimal impact from changes in load pressure and rotational speed. Under a high pressure of 21 MPa and a speed of 1500 rpm, the maximum insertion loss can reach 15.82 dB, significantly reducing the pressure pulsation in the hydraulic pipeline. Full article

How to economically and effectively mobilize remaining oil and achieve carbon sequestration after water flooding in low-permeability, high-water-cut reservoirs is an urgent challenge. This study, focusing on Block Y of the Daqing Oilfield, employs numerical simulation to systematically reveal the synergistic influencing mechanisms of CO₂ flooding and geological storage. A three-dimensional compositional model characterizing this reservoir was constructed, with a focus on analyzing the controlling effects of key geological (depth, heterogeneity, physical properties) and engineering (gas injection rate, gas injection volume, bottom-hole flowing pressure) parameters on the displacement and storage processes. Simulation results indicate that the low-permeability characteristics of Block Y effectively suppress gas channeling, enabling a CO₂ flooding enhanced oil recovery (EOR) increment of 15.65%. Increasing reservoir depth significantly improves both oil recovery and storage efficiency by improving the mobility ratio and enhancing gravity segregation. Parameter optimization is key to achieving synergistic benefits: the optimal gas injection rate is 700–900 m³/d, the economically reasonable gas injection volume is 0.4–0.5 PV, and the optimal bottom-hole flowing pressure is 9–10 MPa. This study confirms that for Block Y and similar high-water-cut, low-permeability reservoirs, CO₂ flooding is a highly promising replacement technology; through optimized design, it can simultaneously achieve significant crude oil production increase and efficient CO₂ storage. Full article

Carbon fiber reinforced silicon carbide (C/SiC) composite material exhibits exceptional properties, including high strength, high stiffness, low density, outstanding high-temperature performance, and corrosion resistance. Consequently, they are widely used in aerospace, defense, and automotive engineering. However, their anisotropic, high hardness, and brittle characteristics make them a typical difficult-to-machine material. This paper focuses on achieving high-quality micro hole machining of C/SiC composite material via electrical discharge machining. It systematically investigates electrical discharge machining characteristics and innovatively develops a hollow internal flow helical electrode reaming process. Experimental results reveal four typical chip morphologies: spherical, columnar, blocky, and molten. The study uncovers a multi-mechanism cutting process: the EDM ablation of the composite involves material melting and explosive vaporization, the intact extraction and fracture of carbon fibers, and the brittle fracture and spalling of the SiC matrix. Discharge energy correlates closely with surface roughness: higher energy removes more SiC, resulting in greater roughness, while lower energy concentrates on m fibers, yielding higher vaporization rates. C fiber orientation significantly impacts removal rates: processing time is shortest at θ = 90°, longest at θ = 0°, and increases as θ decreases. Typical defects such as delamination were observed between alternating 0° and 90° fiber bundles or at hole entrances. Cracks were also detected at the SiC matrix–C fiber interface. The proposed hole-enlargement process enhances chip removal efficiency through its helical structure and internal flushing, reduces abnormal discharges, mitigates micro hole taper, and thereby improves forming quality. This study provides practical references for the EDM of C/SiC composite material. Full article

Accurately and efficiently predicting bottomhole pressure (BHP) is of great importance for safe drilling in complex formations. Many researchers have conducted extensive investigations into intelligent BHP prediction techniques. However, the current intelligent models mostly focus on the data-driven relationship between logging parameters and BHP, and less on the influence of the correlation between the logging parameters on the BHP. This paper proposes a real-time prediction framework based on graph neural networks. Our model selects input features based on drilling mechanisms and statistical analyses, and utilizes adaptive learning of the graph based on multivariate time-series parameters to capture the relationship between multivariate logging parameters and BHP. Finally, the model performance is thoroughly analyzed based on field drilling datasets after optimizing model hyperparameters using the Bayesian optimization method. Results indicate that the proposed method performs better in terms of prediction accuracy, captures the inflection points of curve changes better, and is more robust under the new well section. The mean absolute percentage error of the method reaches 1.28% which is reduced by 25% compared with other traditional intelligent models. This study provides a solution for achieving accurate real-time predictions of bottom hole pressure, establishing a solid foundation for the realization of precise pressure control during drilling operations. Full article

In this study, we systematically investigated the piezoelectric and carrier transport properties of two-dimensional (2D) Bi-based chalcohalide monolayers (BiXY, X = Se, Te; Y = Br, I) using first-principles calculations. The phonon dispersion and elastic properties proved that BiXY monolayers are dynamically and mechanically stable. Our results reveal that the stereochemically active 6s² lone-pair electrons of Bi³⁺ play a crucial role in determining the structural and electronic characteristics of these systems. The simultaneous enhancement of Born effective charges and the strong sensitivity of atomic positions to external strain give rise to pronounced piezoelectric responses in BiXY monolayers. Specifically, the calculated piezoelectric coefficients (d₁₁) reached 13.16 and 17.76 pm/V for BiSeBr and BiSeI, respectively. The carrier transport properties were estimated using the deformation potential (DP) theory, which yielded upper-bound values under idealized conditions. For instance, in BiTeBr, the effective masses of electrons and holes were 0.15 and 0.40 m₀, respectively, leading to high carrier mobilities of 2736.1 and 2689.9 cm² V⁻¹ s⁻¹. These findings highlight the potential of Bi-based chalcohalide monolayers as promising candidates for next-generation multi-functional nanoelectronic and piezoelectric devices. Full article

Background/Objectives: Although upper extremity dexterity problems are frequently reported in people with Parkinson’s disease (PwPD), valid and reliable scales for assessing upper extremity function and dexterity are limited. The objective of this study was to investigate the reliability and validity of the Action Research Arm Test (ARAT) and the Jebsen–Taylor Hand Function Test (JTHFT) in PwPD. Methods: Seventy PwPD and thirty HC were recruited. The test–retest reliability was evaluated by determining the intraclass correlation coefficient (ICC). MDC₉₅ was calculated by using ICC results. The concurrent validities of JTHFT and ARAT were determined by investigating their relationship with the Nine-Hole Peg Test (9-HPT), Hoehn and Yahr scale (H & Y), Unified Parkinson’s Disease Rating Scale (UPDRS), and motor symptoms (UPDRS-III). The cut-off times that best discriminated between PwPD and HC were investigated by plotting receiver operating characteristic (ROC) curves. Results: The ARAT and JTHFT showed excellent test–retest reliability (ICC = 0.937 to 0.995). The MDC₉₅ values for the ARAT were 0.38 for the dominant hand and 0.58 for the non-dominant hand. MDC₉₅ values for the JTHFT subtests and total scores ranged from 0.38 to 4.71. The ARAT, JTHFT subtests, and total scores demonstrated a fair-to-strong correlation with other outcomes (p < 0.05). The cut-off times that best differentiated JTHFT subtests and total scores ranged from 3.56 to 64.23. Conclusions: The JTHFT is a reliable and valid measurement tool for the assessment of manual dexterity in PwPD, while the ARAT is a reliable assessment tool in PwPD but does not have discriminant validity. Full article

Rock-socketed piles are a common type of end-bearing pile, but when there is deep sediment or holes at the pile bottom, the load is primarily supported by side resistance. In this study, based on such conditions and considering the influence of pile shaft roughness, model tests were conducted to investigate the bearing characteristics of rock-socketed friction piles. The results show that the failure mode of rock-socketed friction piles is the formation of a penetrating cylinder in the rock layer, with the cylinder diameter directly approximating the pile diameter. The load–displacement curves of the test piles are steeply variable. After reaching the ultimate bearing capacity, the residual bearing capacity of rough test pile is approximately 60% of the ultimate bearing capacity, while that of smooth test pile is 72.4%. The maximum side resistance of the test pile is located within a depth range of 25 mm below the soil–rock interface, and the upper load of 41.0% to 48.9% on the test piles was born by the pile side resistance within this depth range. As the roughness factor (RF) increases gradually from 0.0 to 0.3, the ultimate bearing capacity of the test pile shows nearly linear growth, the ultimate displacement increases sharply first and then decreases slowly, and both the axial force attenuation and the percentage of side resistance within the depth range of 25 mm below the soil–rock interface gradually increase slightly. In this paper, two existing methods are employed to calculate the ultimate bearing capacity of friction piles under the conditions of this study. Based on a comparison of the results, the applicable conditions for each method are proposed. The findings of this study can serve as a reference for the design of rock-socketed piles in similar geological formations. Full article

Based on the characteristics and distribution patterns of collapsed holes in cast-in-place bored pile foundations in the typical coastal area of Guangdong Petrochemical Company, the deformation and collapse behavior of pile walls in the project zone were systematically monitored and measured using a specialized pore diameter detection system for cast-in-place bored pile quality assessment. A collapse rate parameter is proposed and established as an evaluation index for pile wall stability and collapse. Using the basic principles of Quantification Theory I and considering the collapse characteristics of pile walls in a cast-in-place bored pile project in Guangdong, the influencing factors and mechanisms of pile wall collapse are comprehensively analyzed and evaluated. A quantitative theoretical evaluation model for the influencing factors of pile wall collapse is then established. Focusing on the construction technology of cast-in-place bored piles, the proposed quantitative theoretical evaluation model is applied to quantitatively analyze and assess the factors contributing to pile wall collapse in the project area. The relationships between pile wall collapse rate in the Guangdong Petrochemical Company cast-in-place bored pile project and influencing factors such as stratum structure, soil properties, sand layer thickness, drilling depth, and drilling methods are systematically determined. The primary collapse factors and secondary influencing factors in the pile wall collapse of the cast-in-place bored pile engineering zone are identified, providing a theoretical basis for determining optimal prevention and control measures against pile wall collapse during the drilling process of cast-in-place bored piles. Full article

Regarding the cooling structure of gas turbine combustors, this paper employs numerical simulation methods to analyze the influence of structural parameters of a rectangular trench with inclined holes on flow and heat transfer characteristics at a coolant-side Reynolds number of 100,000. The results indicate that with a decrease in the width of the rectangular trench and an increase in the diameter of the inclined holes, the coolant-side friction factor gradually decreases. The coolant-side friction factor at a streamwise distance of Y/D = 30 is lower than that at Y/D = 20 and 40. With an increase in the diameter of the inclined holes, the average coolant-side Nusselt number exhibits a greater increase, indicating significantly enhanced heat transfer effectiveness. The average coolant-side Nusselt number at a streamwise distance of Y/D = 40 is higher than that at Y/D = 20 and 30. Furthermore, with an increase in the diameter of the inclined holes and a decrease in the streamwise distance, the average temperature of the solid wall on the hot-gas side gradually decreases, leading to a progressive improvement in cooling efficiency. Full article

The Cimabanshuo deposit, situated in the western Gangdese Belt, is a recently discovered porphyry Cu deposit formed in a post-collisional setting, approximately 10 km from the giant Zhunuo porphyry Cu deposit. Despite its proximity to Zhunuo, Cimabanshuo remains poorly studied, and the current exploration depth of 600 m leaves the potential for deeper resources uncertain. In this study, 840 samples from four drill holes along the NW-SE section (A-A′) were analyzed using portable X-ray fluorescence (pXRF). Based on the geochemical characteristics of primary halos, the deep mineralization potential of Cimabanshuo was evaluated. The results show that Co, Pb, and Ag are near-ore indicator elements; Zn, Cs, Hg, Sb, As, and Ba represent the frontal elements; and Te, Sn, and Bi occur as tail elements. Based on these distributions, a 14-element zoning sequence is defined along the A-A′ profile according to Gregorian’s zoning index, showing Mo-Co-Cu-Pb-Bi-Ag-Sn-Te-Sb-Hg-Cs-Zn-Ba-As from shallow to deep. This sequence shows a distinct reverse zonation pattern, in which tail elements occur in the middle and frontal elements appear at depth, suggesting the existence of a concealed ore body in the lower part of the deposit. Horizontally, the geochemical ratios Ag/Mo and Ag/Cu decrease from northwest to southeast along the profile, implying hydrothermal flow from southeast to northwest. Vertically, the ratios As/Bi, (As × Cs)/(Bi × Te), (As × Ba)/(Bi × Sn), and (As × Ba × Cs)/(Bi × Sn × Te) display a downward-decreasing then upward-increasing trend, further indicating hidden mineralization at depth. This inference is supported by the predominance of propylitic alteration and the deep polarization anomaly revealed by audio-magnetotelluric imaging. pXRF analysis provides a fast, efficient, and environmentally friendly approach, showing strong potential for rapid geochemical evaluation in porphyry Cu exploration. Full article

Phenetole derivatives are widely used in various fields, and the presence of the ethoxy group, with its longer alkyl chain, suggests the possibility of multiple rotamers. In particular, diethoxybenzene derivatives, containing two ethoxy groups, exhibit an even greater number of rotameric forms. In this study, we report the first investigation of the stable structures, vibronic spectra, and cationic spectra of different rotamers of m-diethoxybenzene (MDEB). Resonance-enhanced multiphoton ionization (REMPI) spectra of the rotamers were identified via hole-burning (HB) experiments, while mass-analyzed threshold ionization (MATI) spectra provided precise adiabatic ionization energies (IEs) of the observed rotamers, as well as the active vibrations of their corresponding cations. Density functional theory (DFT) calculations predicted thirteen rotamers of MDEB, but only two rotamers were observed in the supersonic molecular beam. The band origins of the S₁ ← S₀ transition and the adiabatic IEs of the down–up and down–down rotamers of MDEB were determined to be 36,091 ± 2 cm⁻¹ and 36,165 ± 2 cm⁻¹ and 62,419 ± 5 cm⁻¹ and 63,378 ± 5 cm⁻¹, respectively. Franck–Condon spectral simulations for the S₁ ← S₀ and D₀ ← S₁ transitions were performed based on DFT calculations, and the theoretical results showed good agreement with the experimental data. Vibrational features observed in the S₁ and D₀ states were assigned by comparing the experimentally measured spectra with the simulated spectra as well as the previously reported vibrational spectra of structurally similar molecules. Finally, several key findings and molecular characteristics are discussed in detail. Full article

The problem of poor coupling and wheel breakage is a critical issue in the rapid inspection of rails using contact piezoelectric ultrasonic technology for trolleys and vehicles. To overcome this shortcoming, a non-contact unidirectional Shear Vertical Wave EMAT (USV-EMAT) for rapid rail flaw detection with a larger emission angle is proposed and optimized. First, the core characteristics of the USV-EMAT and the Unidirectional Line-Focusing Shear Vertical Wave EMAT (ULSV-EMAT) are compared and analyzed, including emission angle, directivity, intensity, and detection scan distance. The results confirmed that the USV-EMAT is more suitable for rapid rail flaw detection. Secondly, the orthogonal experimental analysis method was used to optimize the structural parameters of the probe. This study systematically identified the key factors influencing the directivity and intensity of acoustic waves excited by the probe, as well as the detection blind zones. Finally, the structural parameters of the integrated 37° USV-EMAT probe were determined by comparing and analyzing the received signal characteristics of the transmit–receive racetrack coil and the self-transmitting–receiving meander coil. The results show that the optimized probe achieves a 14.3 dB SNR for detecting a 5 mm diameter, 50 mm deep transverse hole in the rail, and a 14.0 dB SNR for a 3 mm diameter, 25 mm long, 50 mm deep flat-bottomed hole. Additionally, this study reveals that as the burial depth of the transverse holes increases, the detection scan distance for such defects exhibits an “N”-shaped trend, with the minimum occurring at a depth of 90 mm. Full article

A new generation of fluorescent diamond nanoparticles synthesized from hydrocarbons at high pressure appears to be promising for the design of efficient single-photon diamond sources and nanometer-sized optical sensors. A characteristic feature of such nanodiamonds (NDs) is the termination of their surface with hydrogen. This hydrogen induces the formation of free holes at the diamond surface, thereby affecting the charge state of nearby fluorescent centers. In this study, the effect of the H-terminated ND surface on negatively charged silicon-vacancy (SiV⁻) fluorescence as a function of the ND size was investigated. Raman, photoluminescence and scanning electron microscopy techniques were used to characterize the NDs. Diamond nanoparticles of various sizes in the 50–300 nm range were analyzed before and after H desorption from their surface. It was shown that a significant increase in SiV⁻ fluorescence (>50%) upon hydrogen removal starts for particles smaller than 100 nm. The effective thickness of the diamond surface layer, within which charge neutralization of SiV⁻ centers occurs under the hydrogen influence, was determined to be 6 nm. Full article

The synthesis, phase behavior and semiconductor properties of two novel organosilicon tetramers with dialkyl-substituted [1]benzothieno[3,2-b]benzothiophene (BTBT) moieties, D4-Und-BTBT-Hex and D4-Hex-BTBT-Oct, are described. The synthesis of these molecules was carried out by sequential modification of the BTBT core by carbonyl-containing functional alkyl substituents using the Friedel–Crafts reaction, followed by the reduction in the keto group. The target tetramers, D4-Und-BTBT-Hex and D4-Hex-BTBT-Oct, were obtained by the hydrosilylation reaction between tetraallylsilane and corresponding 1,1,3,3-tetramethyl-1-(ω-(7-alkyl[1]benzothieno[3,2-b]benzothiophen-2-yl)alkyl)disiloxanes. The chemical structure of the compounds obtained was confirmed by NMR ¹H-, ¹³C- and ²⁹Si-spectroscopy, gel permeation chromatography and elemental analysis. Their phase behavior was investigated by differential scanning calorimetry, polarization optical microscopy and X-ray diffraction analysis. It was found that D4-Und-BTBT-Hex shows higher crystallinity at room temperature as compared to D4-Hex-BTBT-Oct, while both molecules possess smectic ordering favorable for active layer formation in organic field-effect transistors (OFETs). The active layers were applied by spin-coating under conditions of a homogeneous thin layer formation with a low content of defects. The devices obtained from D4-Und-BTBT-Hex have demonstrated good semiconductor characteristics in OFETs with a hole mobility up to 3.5 × 10⁻² cm² V⁻¹ s⁻¹, a low threshold voltage and an on/off ratio up to 10⁷. Full article

Against the backdrop of global water scarcity, utilizing sediment-laden river water for agricultural irrigation is a critical strategy for ensuring food security. However, the associated water and nitrogen transport processes are influenced by the coupled effects of multiple factors, and the governing mechanisms are not yet fully understood. To investigate the coupled effects of muddy water sediment concentration (ρ), physical clay content (d_0.01), applied nitrogen concentration (N), and pressure head (H) on infiltration characteristics during film hole irrigation, this study conducted an indoor soil-box experiment using an orthogonal design to analyze soil water and nitrogen transport dynamics. Results indicated that sediment properties were the dominant factors governing infiltration, with their relative influence on cumulative infiltration following the order ρ > d_0.01 > H > N. ρ and d_0.01 strongly inhibited infiltration; for instance, an increase in ρ from 3% to 9% reduced the initial infiltration rate by as much as 49.3%. Conversely, H and N exhibited a slight promoting effect. High muddy water sediment concentration and physical clay content significantly restricted water and nitrogen transport, causing substantial amounts of ammonium nitrogen (NH₄⁺-N) to be retained within the surface soil layer adjacent to the irrigation hole. Paradoxically, the same factors that reduced infiltration (ρ and d_0.01) led to a significant increase in the average change in volumetric water content (Δθ) within the wetted soil volume. Based on these findings, multivariate power function models were developed to predict key parameters. The models demonstrated high predictive accuracy, with coefficients of determination (R²) of 0.9715 for cumulative infiltration, 0.94 for wetting front migration, and 0.9758 for Δθ, and validation errors were within acceptable limits. In conclusion, the film hole irrigation process is predominantly governed by physical clogging from sediment particles, a mechanism that decisively controls the spatial distribution of water and nitrogen. Furthermore, the slight enhancement of infiltration by nitrogen fertilizer suggests a potential physicochemical mechanism, possibly involving ion-induced flocculation of clay particles. The models developed in this study provide a quantitative basis for precision fertigation management in China’s Yellow River irrigation district and other regions with similar conditions. Full article