Search Results (603)

Sandstone-hosted uranium deposits in the western Qaidam Basin are spatially associated with hydrocarbon-bearing structures, yet the specific roles of different sulfur sources in uranium mineralization remain poorly constrained. This study aims to distinguish the contributions of bacterial sulfate reduction and hydrocarbon-associated sulfate reduction to uranium precipitation by integrating detailed petrography, in situ trace element analyses, and sulfur isotope measurements of chalcopyrite from the Yuejin Ⅱ deposit. Chalcopyrite is restricted to high-grade uranium ores and occurs intergrown with uranium minerals, pyrite, baryte, and carbonate cements. Trace element patterns indicate that oxidizing brines acted as the main transport medium for both uranium and copper, as evidenced by positive correlations between U and brine-related elements (Ba, Sr, Na, K). Positive U-Th correlations with relatively constant Th/U ratios (0.027–0.225) reflect a combination of source composition, fluid transport capacity, and limited thorium remobilization in this near-source, hydrocarbon-rich environment. Correlations between U and high field strength elements (Sn, W) point to a highly evolved granitic origin, with Altyn granitoids likely supplying the copper. Sulfur isotopes show a clear bimodal distribution: one group exhibits heavy δ³⁴S values (+6.9‰ to +18.5‰), while the other shows extremely light values (–36.0‰ to –44.6‰). The light group reflects bacterial sulfate reduction in shallow strata, supported by framboidal pyrite textures, whereas the heavy group corresponds to surface-derived sulfate reduced at hydrocarbon-associated redox fronts, rather than direct incorporation of deep H₂S. The lack of intermediate δ³⁴S values indicates that two discrete sulfur reduction mechanisms coexisted within the same deposit, refining genetic models for uranium mineralization in petroliferous basins and challenging frameworks that invoke a single dominant sulfur source. Full article

The hornblende gabbro investigated in this study crops out in northwestern Elazığ, eastern Türkiye, within the Southeastern Anatolian Orogenic Belt (SAOB), where Late Cretaceous ophiolitic, volcanic, plutonic, and metamorphic units are widely exposed. This study examines the petrology, whole-rock geochemistry, Sr–Nd isotopic composition, mineral chemistry, and crystallisation conditions of these gabbroic bodies to constrain their petrogenesis and tectonomagmatic significance. Field observations show that the rock occurs as rounded to sub-rounded blocks with fresh inner cores and altered outer rims. Petrographic and XRD data indicate that the fresh gabbro mainly consists of plagioclase and amphibole, whereas the altered outer rims contain quartz and minor secondary phases. Whole-rock geochemical data classify the samples as low- to medium-K, tholeiitic, and predominantly metaluminous gabbro. Primitive mantle-normalised trace-element patterns display enrichment in large-ion lithophile elements and depletion in high-field-strength elements, whereas chondrite-normalised REE patterns show slight LREE enrichment, relatively flat HREE patterns, and weak Eu anomalies. Sr–Nd isotopic compositions are characterised by positive εNd_(T) values (+4.4 to +5.3) and moderately radiogenic initial ⁸⁷Sr/⁸⁶Sr ratios (0.704792–0.705344), indicating a predominantly mantle-derived magma source affected by subduction-related modification, with limited crustal contribution. Mineral chemistry data show that amphiboles belong to the calcic amphibole group and plot in the magnesio-hornblende field. Amphibole thermobarometric calculations yielded temperatures of 873–991 °C and pressures of 1.49–3.26 kbar, corresponding to crystallisation depths of 5.1–15.3 km. Overall, the results indicate that the hornblende gabbro was derived from a mafic magma generated from a spinel lherzolite mantle source and crystallised in a subduction-related tectonomagmatic setting. Full article

The Western Liao River Basin is one of the cradles of Chinese civilization and is recognized as China’s third mother river, following the Yellow River and the Yangtze River. This study focuses on traditional settlements in the Western Liao River Basin and evaluates their spatial perception elements using the IPA (Importance–Satisfaction Analysis) method. By enriching research on the spatial perception evaluation of traditional settlements, this work provides guidance for the protection and inheritance of traditional settlements in the Western Liao River Basin. Based on a field survey of the current spatial conditions of these traditional settlements, an evaluation system for spatial perception elements is proposed. Using SPSS software, the importance and satisfaction scores of each evaluated element are determined. Using the IPA method, this study classified 18 spatial perception factors of traditional settlements in the West Liao River Basin into four categories: strengths, potential overkill, low priority, and urgent improvement. Differentiated conservation and optimization strategies were proposed based on these findings. The study also reveals that local residents’ spatial perception is an active construction process rooted in daily life and cultural practices, exhibiting characteristics of “place dependence” and “path orientation.” Elements rated as high in importance but low in satisfaction reflect residents’ cultural anxiety and sense of spatial loss. The study emphasizes that the conservation of traditional settlements should shift from expert-led approaches to local collaboration, fully incorporating residents’ cognitive patterns to construct a dynamic pathway for heritage transmission grounded in daily practices and cultural memory. Full article

Utilizing excavated waste soil to level gullies offers significant advantages in terms of engineering economy and construction efficiency. However, the stability and deformation risks of high-fill embankments in mountainous gullies under rainfall conditions have attracted significant attention, particularly when such structures are located adjacent to residential areas. This study compares two design schemes for highway high-fill embankments, Scheme 1: high-fill slope supported by stabilizing piles and prestressed anchors, and Scheme 2: ordinary waste soil as the core, foamed lightweight soil (EPS) as the edge band, and reinforcement by a micro-pile retaining wall system. Finite element analysis was used to evaluate the Factor of Safety (FOS), displacements of retaining structures, and characteristic slope points under three conditions (no rainfall, heavy rainfall, and heavy rainfall with soil strength deterioration). The results show that Scheme 2 reduces total costs by 3.5%, shortens the construction period by 14%, and cuts maintenance costs by 65%, with a minimum FOS of 1.56 under extreme rainfall. Further parametric analysis of Scheme 2 optimized key design parameters, and field monitoring data over 6 months verified the reliability of the numerical simulation. This study provides a transferable design-verification pathway for combining lightweight and conventional fills in high embankments, offering technical support for similar projects in complex mountainous areas. Full article

Biopolymer-based packaging films possess outstanding performances and are being developed as the alternatives to traditional petroleum-based plastic packaging films with many non-ignorable shortcomings. In this study, chitosan, succinylated pullulan (SP), and berberine (BBR) were combined to fabricate novel biopolymer-based composite films (CSSPB) via the layer-by-layer assembly method. The effects of the incorporation of BBR on the physicochemical properties of the film were investigated. It was found that after BBR was added, the tensile strength (TS), elongation at break (EAB), hydrophobicity, and antioxidant capacities of the film were enhanced. The chemical bonding, crystalline properties, elemental composition, and thermal stability of the films were also characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA), respectively. The in vitro antifungal tests revealed the antifungal activities of the films with a relatively high BBR content against Colletotrichum gloeosporioides (CG). In the preservation experiments, the CSSPB films exhibited preservation effects on fresh-cut apples, which manifested as delaying browning, weight loss, an increase in the soluble solids content, and a decrease in hardness. The new CSSPB composite films were opined to hold application potential in the field of food packaging. Full article

The recovery of oxygen-affine elements such as tantalum (Ta) using pyrometallurgical routes is difficult because this element cannot easily be enriched in a metal alloy, as is the case with battery recycling for the more noble metals Co, Ni, and Cu. A promising procedure, on the other hand, is to enrich this element in simple oxide compounds formed in a silicate melt. This enrichment in tailored mineral compounds is also known as the “Engineered Artificial Minerals” (EnAM) approach. Currently, the Technological Readiness Level (TRL) of this approach is relatively low and limited to understanding the mechanisms involved in the incorporation of target elements and the search for suitable compounds with a high enrichment factor, favorable morphology, and early crystallization during solidification in order to achieve maximum recovery yield of the selected compound (element). Due to its high ion charge (high field strength) and small ion radius for a heavy element, it is plausible that Ta behaves similarly to the abundant element titanium (Ti), whose chemistry is much better known. Ti minerals such as ulvospinel, perovskite, ilmenite, and pseudobrookite are therefore suitable candidates in the search for a suitable tantalum EnAM. A comparison of the solidification of synthetic silicate melts dominated by iron and calcium with Ti as an additive show that Ta is not incorporated into ulvospinel formed in olivine-containing Fe-rich silicate melts (base composition with 57 wt.% FeO). In contrast, the perovskites formed in silicate melts dominated by calcium-alumosilicate (max. 10 wt.% FeO addition) do incorporate Ta. Crystal size and Ta content increase with increasing iron content (up to a maximum of about 10 wt.%). The results indicate a possible solid solution with the well-known compounds CaTiO₃ and FeTiO₃ and the virtual compounds Ca_0.8TiO₃ and Fe_0.8TiO₃. Full article

The Jiangnan Orogenic Belt is a world-renowned metallogenic region for Au-W-Sb mineralization, with the Wangu deposit being a representative one. Previous research has demonstrated that tungsten in this Au-W-Sb deposit is sourced from the hosting metasedimentary rocks, but the specific mineral that provides tungsten is still unclear. This study evaluates the tungsten source by conducting petrographic observations and geochemical and geochronological analyses on the rutile from the host slate the Wangu deposit. The results show that rutile from wall rocks of the Wangu deposit yields an age of 955 ± 13 Ma, which is older than both the ore-forming age of the deposit and the age of the host strata. Electron microprobe analyses (EMPA) and laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) elemental analyses show that detrital rutile is enriched in elements such as Fe, Cr, V, and W, as well as high-field-strength elements (HFSE) including Nb, Ta, Zr, and Hf. The total rare earth element (ΣREE) ranges from 3.37 ppm to 156.85 ppm. The samples are generally enriched in light rare earth elements (LREEs) and exhibit distinct negative Eu anomalies. These geochemical features and a geochronological age of 955 ± 13 Ma suggest that the rutile is of detrital origin and they are possibly derived from the Grenvillian rocks. It is concluded that the detrital rutile in the metasediments could be an important source for hydrothermal tungsten enrichment. Full article

High nitrogen austenitic stainless steels are an important engineering structural material. Under annealing conditions, the addition of interstitial solid solution element nitrogen can improve the yield strength and tensile strength of the alloy without reducing its plasticity. In addition, nitrogen can partly or completely replace the more expensive nickel element at a relatively cheap element cost to improve economic benefits, while maintaining or even enhancing the excellent corrosion resistance of stainless steels. However, the cracks and defects caused by high nitrogen austenitic stainless steels during hot working in high temperature ranges have always been the pain points in the engineering field. High nitrogen elements bring high temperature strength, but also narrow the hot working temperature range, the possibility of nitride precipitation and the tendency of heat induced cracking, which limit the further engineering application of high nitrogen austenitic stainless steels. It is urgent to analyze and study the hot deformation law of high nitrogen austenitic stainless steels in engineering. This article commences with an examination of the developmental trajectory of high nitrogen austenitic stainless steel, elucidates the role and strengthening mechanism of nitrogen, and delineates the factors influencing the mechanical behavior of high nitrogen austenitic stainless steel during hot working. These factors include the impact of nitrogen content and manufacturing processes, hot-working parameters, grain size distribution, and the presence of precipitated phases. This article synthesizes various studies, analyzes the causes of thermal cracking, and proposes potential solutions. Ultimately, it summarizes the practical applications and future prospects of high nitrogen austenitic stainless steel, highlighting its substantial potential. Full article

With the shift of oil and gas exploitation to deep seas, the 35 kV high-voltage electric slip ring in Single-Point Mooring (SPM) systems faces critical challenges of insulation failure and thermal failure, threatening operational safety. This study aims to investigate its insulation strength and temperature rise characteristics. A three-dimensional electric field model and a magnetic–thermal coupling model considering the skin effect were established using the finite element method (FEM). Simulations were conducted under four high-voltage configurations and various high-current operating conditions, followed by AC breakdown tests and high-current temperature rise experiments for validation. The results show that the maximum electric field (up to 19.53 kV/mm) concentrates at the inlet polytetrafluoroethylene (PTFE) bushing, which is the insulation weak point. The maximum temperature rise at the center ring can be predicted by a power-law model. Moreover, simulation results agree well with experimental data, confirming the reliability of the computational studies. This work provides a theoretical and experimental basis for the optimal design and safe operation of high-voltage slip rings in offshore SPM systems. Full article

Multistatic sonar provides enhanced target detection in complex underwater environments. The wide-angle bistatic scattering characteristics of targets, particularly the bistatic reflection coefficients, are important for evaluating system performance and designing acoustic absorbing coatings. However, obtaining full-angle experimental measurements is challenging, and conventional finite-element simulations become computationally prohibitive for large structures, high frequencies, or exhaustive angle sweeps. To overcome these challenges, a fast wide-angle scattering prediction method for acoustically coated plates is proposed. The method constructs a scattering transfer matrix from the surface mesh and retrieves the equivalent source density from a small subset of scattered-pressure samples, enabling reconstruction of the full-angle scattering field and rapid extraction of reflection coefficients. The approach is demonstrated on both rigid and coated plates, with predictions compared against finite-element calculations. The results demonstrate that the proposed method accurately reproduces the bistatic reflection coefficients, including non-linear dispersion effects and interference fringes, across a wide frequency band from 100 Hz to 5 kHz. Compared to traditional FEM sweeps, this method significantly reduces computational time while maintaining high accuracy, providing an efficient tool for the design of acoustic stealth materials and laying a foundation for rapid target strength prediction of complex targets using the Planar Element Method. Full article

Late Early Jurassic continental arc magmatism in the northern Greater Khingan Range enables the investigation of complicated tectonic processes associated with the subduction and closure of the Mongol–Okhotsk Ocean. To further clarify the timing, genesis, and geodynamic mechanisms driving the magmatic activity during this period, the present study addresses these critical questions by integrating zircon U–Pb geochronological, geochemical, and isotopic analyses of a wide variety of igneous rocks, including gabbro, gabbro-diorite, granodiorite, porphyritic monzogranite, and biotite-bearing monzogranite from the Fushan region. Zircon U–Pb geochronology constrains the timing of magmatic activity to 184–179 Ma, coinciding with active subduction phases. Geochemical data reveal arc-like signatures characterized by enrichment in light rare-earth elements (LREEs) and large-ion lithophile elements (LILEs), together with pronounced depletion in high field strength elements (HFSEs). A comprehensive analysis of geochemical and Sr–Nd–Hf isotopic signatures suggests that the mafic rocks originated from an enriched lithospheric mantle modified by subduction-related fluids and sediment-derived melts. By contrast, the granodiorite and porphyritic monzonite exhibit adakitic characteristics, indicating partial melting of the thickened Mesoproterozoic lower crust with contributions from mantle-derived or newly formed crustal material. The biotite-bearing monzogranite, with its pronounced Eu anomaly and lower zircon saturation temperatures, reflects advanced magmatic differentiation from a shallower source. These findings indicate extensive crust–mantle interactions during the southward subduction of the Mongol–Okhotsk Ocean, driven by high-angle subduction and slab rollback. Full article

Movable guardrail systems are increasingly used in work zones, reversible lanes, and temporary traffic operations; however, evidence on their crashworthiness, material performance, and operational reliability remains dispersed across multiple design typologies and regulatory frameworks. This PRISMA-compliant systematic review synthesizes 78 studies involving full-scale crash tests, validated finite-element simulations, field performance evaluations, and compliance evaluations under MASH, EN 1317, NCHRP 350, and AS/NZS 3845.1. The findings indicate that modular rigid barriers reliably achieve TL-3/TL-4 performance when joint alignment and foundation conditions are properly controlled; semi-rigid steel systems provide a practical balance between containment capacity and redeployability, but remain sensitive to post spacing and connector detailing; and flexible polymer systems are best suited for short-duration, low-speed applications. Material-focused research highlights the advantages of UHPC section refinement, high-strength steels, and hybrid FRP–metal configurations in enhancing energy absorption without exceeding occupant-risk thresholds. Across studies, connection integrity consistently emerges as the dominant factor governing redirection stability and working-width performance. Field evaluations confirm satisfactory operational performance in constrained environments, while life-cycle assessments identify refurbishment intervals and mass-related logistics as major cost contributors. This review provides an integrated, evidence-based synthesis and a structured engineering foundation for advancing next-generation movable barrier designs, testing protocols, and deployment strategies. Full article

In the current numerical simulation study of high-strength steel welding, ignoring the phase transformation plasticity effect in the coupling analysis led to a significant deviation between the simulated value of residual stress and the experimentally measured value. To investigate the influence mechanism of the Welding Residual Stresses (WRSs) of 30MnCrNiMo armor steel, the transformation plasticity (TP) coefficient (7.81 × 10⁻⁵ MPa⁻¹) was measured via a Gleeble 3500, and a Finite Element Model (FEM) of thermal–metallurgical–mechanical coupling considering yield strength, volumetric strain and TP behavior in Solid-State Phase Transformation (SSPT) was developed. The results show that the volume expansion during the SSPT is the main factor for the shift in WRS from tensile to compressive. In contrast, the TP effect reduces the peak longitudinal tensile stress in the Heat-Affected Zone (HAZ) by 51 MPa. It also ultimately neutralizes the compressive component in this region. When the martensite fraction ranges from 0.12 to 0.45, transformation plastic strain becomes the dominant factor, leading to a characteristic evolution of longitudinal stress that initially decreases and subsequently increases. The FEM incorporating the TP effect successfully captures the dual reversals of residual stress in the HAZ. The average relative error between the simulated longitudinal stress and the experimental data obtained via X-ray diffraction (cosα method) is 8.8%. The TP coefficient database and the developed multi-field coupling model markedly enhance the predictive accuracy for WRS in 30MnCrNiMo steel, offering a robust theoretical foundation for the design of stress corrosion resistance and the service life assessment of welded joints in armored vehicles. Full article

Large deformations in deep soft rock roadways primarily stem from low rock strength under high in situ stress and intense mining disturbance. This renders stability control a critical challenge in tunneling support engineering. Utilizing Xinhe Coal Mine’s deep soft rock tunnel as a representative case, this study integrates field monitoring, laboratory experimentation, and numerical simulation to investigate how excavation and grouted rock bolting influence surrounding rock stability. Building upon field-observed deformation mechanisms and support failure patterns, constitutive models for FLAC^3D’s embedded cable and beam elements were modified to achieve high-fidelity simulation of grouted support systems. Numerical models simulating diverse support schemes were established to analyze roadway displacement fields, plastic failure development, and structural behavior of support components, ultimately identifying the optimal rehabilitation solution. The research results indicate that the numerical simulation outcomes of the original support scheme exhibit good agreement with field observations in terms of roadway deformation patterns, deformation magnitudes, and occurrences of bolt/cable fractures. This demonstrates that the adopted refined numerical simulation methodology and parameters are reasonable and exhibit high reliability. Considering both surrounding rock stability and cost control, Roadway Rehabilitation Scheme S1 was identified as the optimal support solution. Its specific parameters are pre-grouting + full-section rock bolts (diameter 22 mm, length 2.4 m, spacing 0.8 m, row spacing 1.6 m) + full-section grouted cables (diameter 22 mm, length 6.2 m, spacing 1.0 m, row spacing 1.6 m). Full article

In this paper, high-strength high-nitrogen steel Cr₁₈Mn₁₅ was fabricated using centrifugal casting. High-temperature tensile tests were subsequently performed on the centrifugally cast material. Based on the dynamic material model (DMM), power dissipation and instability maps were constructed for the steel. The results revealed that the optimal processing conditions for Cr₁₈Mn₁₅ are within a temperature range of 940 °C to 980 °C and a strain rate range of 0.001 s⁻¹ to 0.01 s⁻¹. Flow instability was observed primarily under high strain rate conditions (1 s⁻¹) at a lower temperature of 900 °C. Four constitutive equation models were established based on the experimental results, and the prediction accuracy was assessed by calculating their average absolute relative errors (AAREs) and correlation coefficients (r). It was found that the Modified-JC constitutive model could simultaneously take care of both accuracy and simulation convergence with an AARE of 17.823 and Pearson’s correlation coefficient (PCC) of 0.968. For the practical application of Cr₁₈Mn₁₅ high-nitrogen steel, a three-layer composite tube forming and a continuous rolling equipment were developed. The rolling and spreading process was simulated using finite elements, and the stress field, strain field, and temperature field in the spreading process were analyzed to determine the following optimum process parameters of the alloy: a temperature of 950 °C, a processing line speed of 1 m/s, and a preheating temperature of 200 °C. Full article