Search Results (60)

The surface decoration techniques, such as incising-filling, glaze spraying, wood firing, and secondary low-temperature refiring, etc., have been widely used for traditional potteries, such as Jianshui purple pottery. These surface modifications are mainly for artistic expression, whereas functional surface modification has barely been reported. The development of novel coating materials and processes is an alternative path for the innovation of traditional pottery. However, the surface functional materials often peel or detach from the pottery body after high-temperature sintering. It is thus imperative to develop coating materials and processes with robust adhesion and accommodation for secondary functional materials. Through the screening of different ZrO(OH)₂ sols and coating processes, the coating of ZrO(OH)₂ sol on the 800 °C baked Jianshui purple pottery achieved uniform and tight surface coating. Reducing the colloidal particle size and particle concentration in the sol, as well as Y³⁺ doping, is also conductive to the structural stability of the coatings. Additional loading of silver nanoparticles onto the ZrO₂ coating layer effectively endows the pottery with antibacterial performance. The coated samples loaded with silver nanoparticles exhibited an antibacterial rate of 32.7% after accelerated desorption, demonstrating potential for functional pottery applications. Full article

Glazed tiles are a common component of ancient buildings, typically used for roofs and walls, serving decorative, protective, and waterproofing purposes. Currently, they are severely damaged and urgently require protection. This study investigated the preservation and damage status of glazed tile components in ancient buildings throughout Shanxi Province. Temperature and humidity variations and acid rain corrosion simulation experiments were conducted to investigate the causes of glazed tile damage. By characterizing morphological changes and corrosion products, the damage process of glazed tiles under the influence of external temperature, moisture, and acid rain was explained. For damage phenomena such as powdering of the tile body, hydroxyl-terminated PDMS–OH/TEOS was selected as the coating materials, and ethanol was used as the solvent to reinforce the glazed tile body. By characterizing indicators such as color difference, water resistance, and mechanical properties, a suitable coating materials formulation was selected. The reinforcement mechanism was investigated using infrared spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. For glazed tiles with extremely severe damage, new glazed tiles with superior mechanical properties were fired by reducing the particle size of the raw material in the tile body to replace them. Full article

This study investigates the application of the Positive Energy District paradigm to two existing and morphologically diverse urban districts in Rome: Testaccio and Valco San Paolo. The research aims to evaluate the feasibility and effectiveness of district-scale energy retrofitting strategies, integrating dynamic simulation tools to model current energy behavior and assess future scenarios. The methodology combines a range of interventions including envelope insulation, high-performance glazing, HVAC system upgrades, efficient lighting solutions, and large-scale photovoltaic deployment. Additionally, the study explores the potential benefits of energy storage systems, with particular focus on the optimal sizing of lithium-ion battery solutions to enhance local self-consumption and reduce grid dependency. Key performance indicators are used to analyze the alignment between renewable energy generation and district demand, as well as the interaction with the electrical grid. By calibrating simulation models with real thermophysical and consumption data, the research ensures methodological robustness and enables the replicability of the proposed approach in other urban contexts. The study offers a comprehensive framework for planners and policymakers seeking to support the decarbonization and resilience of urban districts through the implementation of PEDs. Future developments will focus on optimizing storage management, assessing the environmental impact of battery life cycles, and integrating PEDs within broader urban energy ecosystems. Full article

Many studies have examined normal impacts on glass, but data on oblique impacts are limited, and, in particular, there is very limited experimental data on oblique impacts at various angles under consistent experimental conditions. Therefore, this study investigated fracture patterns of 5 mm thick low-emissivity (low-e) glass impacted by a 10 mm steel ball at velocities of 40 to 50 m/s at various oblique impact angles from 0° to 80°. Results showed that fracture patterns varied clearly with impact angle. Truncated cone fractures occurred in all specimens at 0° to 60°, while three of six specimens did not fracture at 80° because the normal energy dropped to below damage limit energy. Damage parameters normalized by kinetic energy showed that C_max/KE and C_min/KE remained stable at 5.7–6.4 and 4.9–5.3 mm/J from 0° to 45°, but dropped sharply to 0.7 and 0.6 mm/J at 80°. The aspect ratio of cone cracks remained relatively constant (1.2–1.3) regardless of oblique impact angle, while the aspect ratio of perforated holes increased from 1.0 (0°) to 1.6 (60°) before decreasing at 80°. Steel ball size comparison confirmed that normalized damage patterns are not significantly affected by projectile size variations. Mechanism-based analysis revealed that cone cracks and perforated holes are governed by fundamentally different physical processes. Cone cracks form through axisymmetric stress fields following Hertzian contact theory, showing limited angular sensitivity (15.4% maximum eccentricity change). In contrast, perforated holes result from trajectory-dependent mechanical penetration, exhibiting extreme angular sensitivity with 338.9% eccentricity increase from 0° to 60°. This 22-fold difference demonstrates a dual damage mechanism framework that explains the pronounced angular dependence of hole geometry versus the relative stability of cone crack patterns. These findings provide essential data for forensic glass analysis and impact-resistant glazing design, while the dual mechanism concept offers new insights into angle-dependent fracture behavior of brittle materials. Full article

Glazed components in ancient Chinese architecture hold profound historical and cultural value. However, over time, environmental erosion, physical impacts, and human disturbances gradually lead to various forms of damage, severely impacting the durability and stability of the buildings. Therefore, preventive protection of glazed components is crucial. The key to preventive protection lies in the early detection and repair of damage, thereby extending the component’s service life and preventing significant structural damage. To address this challenge, this study proposes a Restoration-Scale Identification (RSI) method that integrates depth information. By combining RGB-D images acquired from a depth camera with intrinsic camera parameters, and embedding a Convolutional Block Attention Module (CBAM) into the backbone network, the method dynamically enhances critical feature regions. It then employs a scale restoration strategy to accurately identify damage areas and recover the physical dimensions of glazed components from a global perspective. In addition, we constructed a dedicated semantic segmentation dataset for glazed tile damage, focusing on cracks and spalling. Both qualitative and quantitative evaluation results demonstrate that, compared with various high-performance semantic segmentation methods, our approach significantly improves the accuracy and robustness of damage detection in glazed components. The achieved accuracy deviates by only ±10 mm from high-precision laser scanning, a level of precision that is essential for reliably identifying and assessing subtle damages in complex glazed architectural elements. By integrating depth information, real scale information can be effectively obtained during the intelligent recognition process, thereby efficiently and accurately identifying the type of damage and size information of glazed components, and realizing the conversion from two-dimensional (2D) pixel coordinates to local three-dimensional (3D) coordinates, providing a scientific basis for the protection and restoration of ancient buildings, and ensuring the long-term stability of cultural heritage and the inheritance of historical value. Full article

The building sector plays a key role in the transition toward climate neutrality, with national regulations across the EU requiring the construction of nearly zero-energy buildings (nZEBs). However, while energy performance has been extensively studied, less attention has been given to the problem of ensuring user comfort—both indoors and in the surrounding outdoor areas—under nZEB design constraints. This gap raises two key research objectives: (1) to evaluate whether a well-designed nZEB with extensive glazing maintains acceptable indoor thermal comfort and (2) to assess whether residents experience greater outdoor thermal comfort and satisfaction in small, sun-exposed private gardens or in larger, shaded communal green spaces. To address these objectives, a newly built residential estate near Kraków (Poland) was analyzed. The investigation included simulation-based assessments during the design phase and in situ measurements during building operation, complemented by a user survey on spatial preferences. Indoor comfort was evaluated for rooms with large glazed façades, as well as rooms with standard-sized windows, while outdoor comfort was assessed in both private gardens and a shared green courtyard. Results show that shading the southwest-oriented glazed façade with an overhanging terrace provided slightly lower temperatures in ground-floor rooms compared to rooms with standard unshaded windows. Outdoors, users experienced lower thermal comfort in small, unshaded gardens than in the larger, vegetated communal area (pocket park), which demonstrated greater capacity for temperature moderation and thermal stress reduction. Survey responses further indicate that potential future residents prefer the inclusion of a shared green–blue infrastructure area, even at the expense of building some housing units in semi-detached form, instead of maximizing the number of detached units with unshaded individual gardens. These findings emphasize the importance of addressing both indoor and outdoor comfort in residential nZEB design, showing that technological efficiency must be complemented by user-centered design strategies. This integrated approach can improve the well-being of residents while supporting climate change adaptation in the built environment. Full article

In this paper, we introduce graph machine learning to enhance the estimation of heating and cooling loads in buildings, a critical factor in building energy efficiency. Traditional methods often overlook the complex interaction between building topology and geometric characteristics, leading to less accurate predictions. This research bridges this gap by incorporating these elements into a graph-based machine learning framework. This study introduces a parametric generative workflow to create a synthetic dataset, which is central to this research. This dataset encompasses multiple building forms, each with unique topological connections and attributes, ensuring a thorough analysis across varied building scenarios. The research involves simulating diverse building shapes and glazing scenarios with different window sizes and orientations. The study primarily utilizes Deep Graph Learning (DGL) for training, with Random Forest (RF) serving as a baseline for validation. Both DGL and RF algorithms demonstrate high performance in predicting heating and cooling loads. Full article

The efficacy of indoor residual spray (IRS) products is affected by various factors, such as the substrate on which they are sprayed and the surface concentration and bioavailability of the insecticide. This study investigated the potential of bespoke silica particles (hereafter referred to as ‘X-tec silica’) as a unique carrier for insecticides to reduce the insecticide content in an IRS formulation by improving pickup by mosquitoes and optimising the physical state of the insecticide while maintaining its residual biological activity on a surface. Molecular computer modelling was used to define the critical crystallisation size of clothianidin, and silica particles were manufactured with pore diameters smaller than this length to maintain the insecticide in an amorphous state. Silica carriers were then formulated to incorporate clothianidin inside their pores, and a full material characterisation was conducted to assess the clothianidin coating position on/in the silica particles, their concentration, and their physical form. The clothianidin-formulated silica (10%) was sprayed at three different application rates (30, 60, and 90 mg active ingredient (a.i.)/m²) onto two surfaces: glazed and unglazed tiles. The tiles were tested for bioefficacy against the insecticide-susceptible Anopheles gambiae s.s. Kisumu mosquito strain at 1 week and 8 months post-spray application. At 1 week post-spray application, at 60 and 90 mg a.i./m² application rates, 100% mortality was observed on both surfaces within 48 h. For the lowest concentration (30 mg a.i./m²), 100% mortality was reached within 72 h on glazed tiles; however, for unglazed tiles, due to the surface irregularity and porosity, it remained below 60%. At 8 months post-spray application, on glazed tiles, 100% mortality was reached within 24 h at 60 and 90 mg a.i./m² application rates and within 48 h at 30 mg a.i./m². On unglazed tiles, 96 h mortality was not measured; however, 100% mortality was reached within 72 h (90 mg a.i./m²) and 120 h (60 mg a.i./m²) at higher concentrations. At the lowest concentration (30 mg a.i./m²) at 120 h, mortality only reached 25%. The lowest application rate tested (30 mg a.i./m²) is ten times lower than that of current products on the market and demonstrates the potential of this approach. Preliminary findings from this study suggest that X-tec silica particles may enhance the effectiveness of IRS using clothianidin. However, further extensive research is needed to confirm this. Full article

Laminated glass (LG) composite systems are increasingly being utilized in architectural and security applications due to their enhanced strength and safety features. Understanding the structural response of LG systems is crucial for optimizing their performance under blast loads. This paper presents a comprehensive study of an analytical model for predicting the static and dynamic resistance functions of various LG systems used in blast-resistant designs to advance engineering analysis and design methods. The proposed analytical model integrates the strain-rate-dependent interlayer behavior with the glass dynamic increase factors to generate a physically consistent post-fracture membrane resistance, offering a unified framework for deriving the static and dynamic resistance functions directly applicable to single-degree-of-freedom (SDOF) analyses across different LG layups. The developed models were validated statistically using full-scale water chamber results and dynamically against experimental blast field data and the results from shock tube testing. We validated the model’s accuracy for various LG layup configurations, including variations in the glass and interlayer sizes, types, and thicknesses. The established dynamic resistance model was developed by incorporating a strain-rate-dependent interlayer material model. The energy absorption of LG panels, influenced by factors like interlayer thickness and type, is critical for blast design, as it determines the panels’ ability to withstand and dissipate energy, thereby reducing the transmitted forces and deformations to a building’s structure. The dynamic model closely matched the dynamic deflection time histories, with a maximum difference of 6% for all the blast experiments. The static resistance validations across the various LG configurations consistently demonstrated reliable prediction results. The energy absorption comparisons between the analytical and quasi-static LG panel responses ranged from 1% to 17%. These advancements provide higher-fidelity SDOF predictions and clear guidance for selecting the interlayer type and thickness to optimize energy absorption. This will result in enhanced blast resistance and contribute to more effective blast mitigation in glazing system design. Full article

This study addresses the challenge of optimizing envelope retrofit strategies for aged residential buildings across China’s five distinct climate zones. A simulation-based frame work is proposed, applying a standardized Taguchi L27 experimental design to ensure direct comparability across climates. Analysis of variance (ANOVA) and effect size (partial eta squared, η²) are used to identify and quantitatively rank the sensitivity of each retrofit parameter, while interaction analysis reveals the independence or synergy between measures. Technical results are linked with discounted payback period (DPP) analysis to evaluate economic feasibility. The findings show that insulation thickness is most influential in cold climates (η² > 0.95), whereas glazing system upgrades are dominant in warmer regions (η² > 0.97), with parameter interactions generally insignificant. The resulting climate-responsive retrofit priority matrix offers practical guidance for region-specific design and investment decisions. This scalable and replicable method enables policymakers and practitioners to tailor low-carbon, cost-effective retrofit solutions to diverse building and climate contexts, bridging the gap between technical performance and financial viability. Full article

This study investigates window renovation strategies for a detached building in Belper, UK, analyzing double- and triple-glazed, vacuum, and low-E vacuum windows with varying gas fillings, pillar radii, and spacing. The results reveal that increasing glass layers reduces energy consumption, while a larger pillar radius decreases efficiency. More pillars improve window performance. For windows with the same U-value, a higher SHGC enhances energy efficiency by maximizing solar heat gain, particularly in colder climates. Conversely, reducing the U-value while maintaining a constant SHGC enhances insulation and minimizes heat loss. The study emphasizes the necessity of balancing U-value and SHGC for optimal window performance in different climates. The most effective strategy involves using a low-E vacuum window with a 0.25 mm pillar radius and 40 mm spacing while doubling the south-facing window area, leading to a 7.01 GJ heating load reduction—a 27.9% improvement over modifying the window type alone. Additionally, a key ratio, SHGC/(U_window − U_wall), is introduced to assess window size modifications. The results indicate that enlarging windows is beneficial when solar heat gain surpasses additional heat loss, underscoring the importance of balancing heat conduction and solar energy utilization in energy-efficient building design. Full article

This paper summarizes the potential energy efficiency benefits of PV-integrated dynamic overhangs for housing units in Qatar. Specifically, the technology combines two energy benefits of shading effects of reducing air conditioning loads and generating on-site electricity generation. The analysis is performed for a prototypical dwelling unit in Doha, Qatar. Three adjustment frequencies for the positions of the PV-integrated dynamic overhangs are evaluated, including hourly, daily, and monthly. It is found that optimally operated PV-integrated overhangs can substantially reduce the annual electricity needs of the dwelling unit. For instance, southern-oriented PV-integrated dynamic overhangs can lower the annual net energy requirements for the dwelling unit by 69.7% relative to the case with no shading and by 32.2% relative to the case of deploying PV-integrated static overhangs. Higher energy use reductions can be achieved when the overhang depth and window size are increased and when more energy-efficient glazing types are installed. Full article

Icing significantly reduces the electrical performance of insulators, and grid failures caused by insulator icing are common. Currently, most research on the flashover characteristics of insulators under icing conditions focuses on artificially iced suspension insulators, with limited studies on post insulators under natural icing conditions. The shed spacing of post insulators is smaller, making them more prone to bridging by icicles in the same icing environment, which exacerbates insulation problems. Therefore, investigating the icing characteristics of post insulators is crucial. In this study, natural icing growth was observed on seven different types of post insulators at the Xuefeng Mountain Energy Equipment Safety National Observation and Research Station. The icing morphology and characteristics of these insulators were examined. The main conclusions are as follows: (1) the icing type and morphology of post insulators are influenced by meteorological conditions, with more severe icing observed on the windward side. (2) The icing mass and icicle length of the insulator increase nonlinearly with icing time. Specifically, during the glaze icing period from 0 to 8 h, the ice mass on the Type V composite post insulator was 3.89 times greater than that during the 13-to-18 h period. (3) Within the same icing cycle, the icing growth rate on composite post insulators is faster than on porcelain post insulators. (4) Compared to suspension insulators, the sheds of post insulators are more easily bridged by icicles. Notably, when the sheds of post insulators are bridged by icicles, the length of icicles on suspension insulators is only half of the gap size. Full article

A flat-plate unglazed solar water heater (SWH) with a polymer thermal absorber was developed and experimented with. Polymer thermal absorbers could be a viable alternative to metal thermal absorbers for SWH systems. The performance of this polymer SWH system was measured based on inlet and outlet water temperature, water flow rate, ambient air temperature and solar irradiance. The polymer thermal absorbers were hollow Polyvinyl Chloride (PVC) tubes with a 20 mm external diameter and 3 mm thickness and were painted black to enhance radiation absorption. The pipes are arranged in a rectangular spiral inward–outward alternating-flow (RSioaf) pattern. The collector pipes were placed in a 1 m × 1 m enclosure with bottom insulation and a reflective surface for maximized radiation absorption. Water circulated through a closed loop with an uninsulated 16 L storage tank, driven by a pump and controlled by two valves to maintain a mass flow rate of 0.0031 to 0.0034 kg·s⁻¹. The test was conducted under a partially clouded sky from 9 a.m. to 5 p.m., with solar irradiance between 105 and 1003 W·m⁻² and an ambient air temperature of 27–36 °C. This SWH system produced outlet hot water at 65 °C by midday and maintained the storage temperature at 63 °C until the end of the test period. Photothermal energy conversion was recorded, showing a maximum value of 23%. Results indicate that a flat-plate solar water heater with a polymer thermal absorber in an RSioaf design can be an effective alternative to an SWH with a metal thermal absorber. Its performance can be improved with glazing and optimized tube sizing. Full article

The crystalline morphology and glaze color of Jian Kiln oil-spot glaze porcelain exhibit artistic beauty, making it one of the typical representatives of iron-based crystallized black porcelain from the Song Dynasty in China. This study sampled a series of specimens from key temperature points during simulation experiments, employing rapid air quenching to preserve the high-temperature state, capturing the formation process of oil-spot glaze crystals in Jian kiln ceramics. Key samples were subjected to microscopic structure and phase analysis using scanning electron microscopy (SEM), laser Raman spectroscopy (LRS), and X-ray photoelectron spectroscopy (XPS), revealing the formation mechanism of oil-spot glaze crystals in Jian kiln ceramics. The results indicate that the bubbles generated from the decomposition of iron oxide at high temperatures facilitate the migration and enrichment of iron-rich particles towards the glaze surface, laying a crucial material foundation for the subsequent crystallization process. The high-temperature reducing atmosphere accelerates the decomposition reaction of iron oxide, altering the concentration of Fe²⁺ in the glaze, the viscosity of the melt, and the surface tension, all of which are critical conditions that promote the formation of oil-spot glaze crystals. During the cooling phase, Fe₃O₄ nanocrystals oxidize into ε-Fe₂O₃ crystals, with external iron sources migrating inward to support ε-Fe₂O₃ crystal growth. This process gradually leads to the formation of micrometer-scale, leaf-shaped ε-Fe₂O₃ crystals that fully occupy the crystalline spots. The coloration of crystalline spots is closely tied to the size of the crystals. Thus, by adjusting the cooling regime, it is possible to create iron-based crystallization glazes with innovative color effects. Furthermore, this study offers significant insights for understanding the crystallization mechanisms of other ancient Chinese high-temperature iron-based crystallization glazes. Full article