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15 pages, 6688 KiB  
Article
Integrated Additive Manufacturing of TGV Interconnects and High-Frequency Circuits via Bipolar-Controlled EHD Jetting
by Dongqiao Bai, Jin Huang, Hongxiao Gong, Jianjun Wang, Yunna Pu, Jiaying Zhang, Peng Sun, Zihan Zhu, Pan Li, Huagui Wang, Pengbing Zhao and Chaoyu Liang
Micromachines 2025, 16(8), 907; https://doi.org/10.3390/mi16080907 - 2 Aug 2025
Viewed by 183
Abstract
Electrohydrodynamic (EHD) printing offers mask-free, high-resolution deposition across a broad range of ink viscosities, yet combining void-free filling of high-aspect-ratio through-glass vias (TGVs) with ultrafine drop-on-demand (DOD) line printing on the same platform requires balancing conflicting requirements: for example, high field strengths to [...] Read more.
Electrohydrodynamic (EHD) printing offers mask-free, high-resolution deposition across a broad range of ink viscosities, yet combining void-free filling of high-aspect-ratio through-glass vias (TGVs) with ultrafine drop-on-demand (DOD) line printing on the same platform requires balancing conflicting requirements: for example, high field strengths to drive ink into deep and narrow vias; sufficiently high ink viscosity to prevent gravity-induced leakage; and stable meniscus dynamics to avoid satellite droplets and charge accumulation on the glass surface. By coupling electrostatic field analysis with transient level-set simulations, we establish a dimensionless regime map that delineates stable cone-jetting regime; these predictions are validated by high-speed imaging and surface profilometry. Operating within this window, the platform achieves complete, void-free filling of 200 µm × 1.52 mm TGVs and continuous 10 µm-wide traces in a single print pass. Demonstrating its capabilities, we fabricate transparent Ku-band substrate-integrated waveguide antennas on borosilicate glass: the printed vias and arc feed elements exhibit a reflection coefficient minimum of −18 dB at 14.2 GHz, a −10 dB bandwidth of 12.8–16.2 GHz, and an 8 dBi peak gain with 37° beam tilt, closely matching full-wave predictions. This physics-driven, all-in-one EHD approach provides a scalable route to high-performance, glass-integrated RF devices and transparent electronics. Full article
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10 pages, 1357 KiB  
Article
Design of Balanced Wide Gap No-Hit Zone Sequences with Optimal Auto-Correlation
by Duehee Lee, Seho Lee and Jin-Ho Chung
Mathematics 2025, 13(15), 2454; https://doi.org/10.3390/math13152454 - 30 Jul 2025
Viewed by 172
Abstract
Frequency-hopping multiple access is widely adopted to blunt narrow-band jamming and limit spectral disclosure in cyber–physical systems, yet its practical resilience depends on three sequence-level properties. First, balancedness guarantees that every carrier is occupied equally often, removing spectral peaks that a jammer or [...] Read more.
Frequency-hopping multiple access is widely adopted to blunt narrow-band jamming and limit spectral disclosure in cyber–physical systems, yet its practical resilience depends on three sequence-level properties. First, balancedness guarantees that every carrier is occupied equally often, removing spectral peaks that a jammer or energy detector could exploit. Second, a wide gap between successive hops forces any interferer to re-tune after corrupting at most one symbol, thereby containing error bursts. Third, a no-hit zone (NHZ) window with a zero pairwise Hamming correlation eliminates user collisions and self-interference when chip-level timing offsets fall inside the window. This work introduces an algebraic construction that meets the full set of requirements in a single framework. By threading a permutation over an integer ring and partitioning the period into congruent sub-blocks tied to the desired NHZ width, we generate balanced wide gap no-hit zone frequency-hopping (WG-NHZ FH) sequence sets. Analytical proofs show that (i) each sequence achieves the Lempel–Greenberger bound for auto-correlation, (ii) the family and zone sizes satisfy the Ye–Fan bound with equality, (iii) the hop-to-hop distance satisfies a provable WG condition, and (iv) balancedness holds exactly for every carrier frequency. Full article
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13 pages, 1017 KiB  
Article
Elevated Serum TNF-α/IL-1β Levels and Under-Nutrition Predict Early Mortality and Hospital Stay Burden in Pulmonary Tuberculosis
by Ionut-Valentin Stanciu, Ariadna-Petronela Fildan, Adrian Cosmin Ilie, Cristian Oancea, Livia Stanga, Emanuela Tudorache, Felix Bratosin, Ovidiu Rosca, Iulia Bogdan, Doina-Ecaterina Tofolean, Ionela Preotesoiu, Viorica Zamfir and Elena Dantes
J. Clin. Med. 2025, 14(15), 5327; https://doi.org/10.3390/jcm14155327 - 28 Jul 2025
Viewed by 294
Abstract
Background/Objectives: Romania remains a tuberculosis (TB) hotspot in the European Union, yet host-derived factors of poor outcomes are poorly characterised. We quantified circulating pro-inflammatory cytokines and examined their interplay with behavioural risk factors, the nutritional status, and the clinical course in adults hospitalised [...] Read more.
Background/Objectives: Romania remains a tuberculosis (TB) hotspot in the European Union, yet host-derived factors of poor outcomes are poorly characterised. We quantified circulating pro-inflammatory cytokines and examined their interplay with behavioural risk factors, the nutritional status, and the clinical course in adults hospitalised with pulmonary TB. We analysed 80 adults with microbiologically confirmed pulmonary TB and 40 respiratory symptom controls; four TB patients (5%) died during hospitalisation, all within 10 days of admission. Methods: A retrospective analytical case–control study was conducted at the Constanța regional TB referral centre (October 2020—October 2023). Patients with smear- or culture-confirmed TB were frequency-matched by sex, 10-year age band, and BMI class to culture-negative respiratory controls at a 2:1 ratio. The patients’ serum interferon-γ (IFN-γ), interleukin-1α (IL-1α), interleukin-1β (IL-1β), and tumour-necrosis-factor-α (TNF-α) were quantified within 24 h of admission; the neutrophil/lymphocyte ratio (NLR) was extracted from full blood counts. Independent predictors of in-hospital mortality were identified by multivariable logistic regression; factors associated with the length of stay (LOS) were modelled with quasi-Poisson regression. Results: The median TNF-α (24.1 pg mL−1 vs. 16.2 pg mL−1; p = 0.009) and IL-1β (5.34 pg mL−1 vs. 3.67 pg mL−1; p = 0.008) were significantly higher in the TB cases than in controls. TNF-α was strongly correlated with IL-1β (ρ = 0.80; p < 0.001), while NLR showed weak concordance with multiplex cytokine patterns. Among the patients with TB, four early deaths (5%) exhibited a tripling of TNF-α (71.4 pg mL−1) and a doubling of NLR (7.8) compared with the survivors. Each 10 pg mL−1 rise in TNF-α independently increased the odds of in-hospital death by 1.8-fold (95% CI 1.1–3.0; p = 0.02). The LOS (median 29 days) was unrelated to the smoking, alcohol, or comorbidity load, but varied across BMI strata: underweight, 27 days; normal weight, 30 days; overweight, 23 days (Kruskal–Wallis p = 0.03). In a multivariable analysis, under-nutrition (BMI < 18.5 kg m−2) prolonged the LOS by 19% (IRR 1.19; 95% CI 1.05–1.34; p = 0.004) independently of the disease severity. Conclusions: A hyper-TNF-α/IL-1β systemic signature correlates with early mortality in Romanian pulmonary TB, while under-nutrition is the dominant modifiable determinant of prolonged hospitalisation. Admission algorithms that pair rapid TNF-α testing with systematic nutritional assessment could enable targeted host-directed therapy trials and optimise bed utilisation in high-burden settings. Full article
(This article belongs to the Section Infectious Diseases)
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20 pages, 4256 KiB  
Review
Recent Progress and Future Perspectives of MNb2O6 Nanomaterials for Photocatalytic Water Splitting
by Parnapalle Ravi and Jin-Seo Noh
Materials 2025, 18(15), 3516; https://doi.org/10.3390/ma18153516 - 27 Jul 2025
Viewed by 229
Abstract
The transition to clean and renewable energy sources is critically dependent on efficient hydrogen production technologies. This review surveys recent advances in photocatalytic water splitting, focusing on MNb2O6 nanomaterials, which have emerged as promising photocatalysts due to their tunable band [...] Read more.
The transition to clean and renewable energy sources is critically dependent on efficient hydrogen production technologies. This review surveys recent advances in photocatalytic water splitting, focusing on MNb2O6 nanomaterials, which have emerged as promising photocatalysts due to their tunable band structures, chemical robustness, and tailored morphologies. The objectives of this work are to (i) encompass the current synthesis strategies for MNb2O6 compounds; (ii) assess their structural, electronic, and optical properties in relation to photocatalytic performance; and (iii) elucidate the mechanisms underpinning enhanced hydrogen evolution. Main data collection methods include a literature review of experimental studies reporting bandgap measurements, structural analyses, and hydrogen production metrics for various MNb2O6 compositions—especially those incorporating transition metals such as Mn, Cu, Ni, and Co. Novelty stems from systematically detailing the relationships between synthesis routes (hydrothermal, solvothermal, electrospinning, etc.), crystallographic features, conductivity type, and bandgap tuning in these materials, as well as by benchmarking their performance against more conventional photocatalyst systems. Key findings indicate that MnNb2O6, CuNb2O6, and certain engineered heterostructures (e.g., with g-C3N4 or TiO2) display significant visible-light-driven hydrogen evolution, achieving hydrogen production rates up to 146 mmol h−1 g−1 in composite systems. The review spotlights trends in heterojunction design, defect engineering, co-catalyst integration, and the extension of light absorption into the visible range, all contributing to improved charge separation and catalytic longevity. However, significant challenges remain in realizing the full potential of the broader MNb2O6 family, particularly regarding efficiency, scalability, and long-term stability. The insights synthesized here serve as a guide for future experimental investigations and materials design, advancing the deployment of MNb2O6-based photocatalysts for large-scale, sustainable hydrogen production. Full article
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32 pages, 7179 KiB  
Article
Effects of an Integrated Infrared Suppressor on the Infrared and Acoustic Characteristics of Helicopters
by Zongyao Yang, Xinqian Zheng and Jingzhou Zhang
Aerospace 2025, 12(8), 665; https://doi.org/10.3390/aerospace12080665 - 26 Jul 2025
Viewed by 212
Abstract
To enhance the survivability of armed helicopters in high-threat environments, integrated infrared (IR) suppressors are increasingly adopted to reduce thermal signatures. However, such integration significantly alters the exhaust flow field, which may in turn affect both the infrared and acoustic characteristics of the [...] Read more.
To enhance the survivability of armed helicopters in high-threat environments, integrated infrared (IR) suppressors are increasingly adopted to reduce thermal signatures. However, such integration significantly alters the exhaust flow field, which may in turn affect both the infrared and acoustic characteristics of the helicopter. This study investigates the aerodynamic, infrared, and acoustic impacts of an integrated IR suppressor through the comparative analysis of two helicopter configurations: a conventional design and a design equipped with an integrated IR suppressor. Full-scale models are used to analyze flow field and IR radiation characteristics, while scaled models are employed for aeroacoustic simulations. The results show that although the integrated IR suppressor increases flow resistance and reduces entrainment performance within the exhaust mixing duct, it significantly improves the thermal dissipation efficiency of the exhaust plume. The infrared radiation analysis reveals that the integrated suppressor effectively reduces radiation intensity in both the 3~5 μm and 8~14 μm bands, especially under cruise conditions where the exhaust is more efficiently cooled by ambient airflow. Equivalent radiation temperatures calculated along principal axes confirm lower IR signatures for the integrated configuration. Preliminary acoustic analyses suggest that the slit-type nozzle and integrated suppressor layout may also offer potential benefits in jet noise reduction. Overall, the integrated IR suppressor provides a clear advantage in lowering the infrared observability of armed helicopters, with acceptable aerodynamic and acoustic trade-offs. These findings offer valuable guidance for the future development of low-observable helicopter platforms. Full article
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31 pages, 14609 KiB  
Article
Reservoir Properties and Gas Potential of the Carboniferous Deep Coal Seam in the Yulin Area of Ordos Basin, North China
by Xianglong Fang, Feng Qiu, Longyong Shu, Zhonggang Huo, Zhentao Li and Yidong Cai
Energies 2025, 18(15), 3987; https://doi.org/10.3390/en18153987 - 25 Jul 2025
Viewed by 249
Abstract
In comparison to shallow coal seams, deep coal seams exhibit characteristics of high temperature, pressure, and in-situ stress, leading to significant differences in reservoir properties that constrain the effective development of deep coalbed methane (CBM). This study takes the Carboniferous deep 8# coal [...] Read more.
In comparison to shallow coal seams, deep coal seams exhibit characteristics of high temperature, pressure, and in-situ stress, leading to significant differences in reservoir properties that constrain the effective development of deep coalbed methane (CBM). This study takes the Carboniferous deep 8# coal seam in the Yulin area of Ordos basin as the research subject. Based on the test results from core drilling wells, a comprehensive analysis of the characteristics and variation patterns of coal reservoir properties and a comparative analysis of the exploration and development potential of deep CBM are conducted, aiming to provide guidance for the development of deep CBM in the Ordos basin. The research results indicate that the coal seams are primarily composed of primary structure coal, with semi-bright to bright being the dominant macroscopic coal types. The maximum vitrinite reflectance (Ro,max) ranges between 1.99% and 2.24%, the organic is type III, and the high Vitrinite content provides a substantial material basis for the generation of CBM. Longitudinally, influenced by sedimentary environment and plant types, the lower part of the coal seam exhibits higher Vitrinite content and fixed carbon (FCad). The pore morphology is mainly characterized by wedge-shaped/parallel plate-shaped pores and open ventilation pores, with good connectivity, which is favorable for the storage and output of CBM. Micropores (<2 nm) have the highest volume proportion, showing an increasing trend with burial depth, and due to interlayer sliding and capillary condensation, the pore size (<2 nm) distribution follows an N shape. The full-scale pore heterogeneity (fractal dimension) gradually increases with increasing buried depth. Macroscopic fractures are mostly found in bright coal bands, while microscopic fractures are more developed in Vitrinite, showing a positive correlation between fracture density and Vitrinite content. The porosity and permeability conditions of reservoirs are comparable to the Daning–Jixian block, mostly constituting oversaturated gas reservoirs with a critical depth of 2400–2600 m and a high proportion of free gas, exhibiting promising development prospects, and the middle and upper coal seams are favorable intervals. In terms of resource conditions, preservation conditions, and reservoir alterability, the development potential of CBM from the Carboniferous deep 8# coal seam is comparable to the Linxing block but inferior to the Daning–Jixian block and Baijiahai uplift. Full article
(This article belongs to the Section H: Geo-Energy)
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30 pages, 13059 KiB  
Article
Verifying the Effects of the Grey Level Co-Occurrence Matrix and Topographic–Hydrologic Features on Automatic Gully Extraction in Dexiang Town, Bayan County, China
by Zhuo Chen and Tao Liu
Remote Sens. 2025, 17(15), 2563; https://doi.org/10.3390/rs17152563 - 23 Jul 2025
Viewed by 360
Abstract
Erosion gullies can reduce arable land area and decrease agricultural machinery efficiency; therefore, automatic gully extraction on a regional scale should be one of the preconditions of gully control and land management. The purpose of this study is to compare the effects of [...] Read more.
Erosion gullies can reduce arable land area and decrease agricultural machinery efficiency; therefore, automatic gully extraction on a regional scale should be one of the preconditions of gully control and land management. The purpose of this study is to compare the effects of the grey level co-occurrence matrix (GLCM) and topographic–hydrologic features on automatic gully extraction and guide future practices in adjacent regions. To accomplish this, GaoFen-2 (GF-2) satellite imagery and high-resolution digital elevation model (DEM) data were first collected. The GLCM and topographic–hydrologic features were generated, and then, a gully label dataset was built via visual interpretation. Second, the study area was divided into training, testing, and validation areas, and four practices using different feature combinations were conducted. The DeepLabV3+ and ResNet50 architectures were applied to train five models in each practice. Thirdly, the trainset gully intersection over union (IOU), test set gully IOU, receiver operating characteristic curve (ROC), area under the curve (AUC), user’s accuracy, producer’s accuracy, Kappa coefficient, and gully IOU in the validation area were used to assess the performance of the models in each practice. The results show that the validated gully IOU was 0.4299 (±0.0082) when only the red (R), green (G), blue (B), and near-infrared (NIR) bands were applied, and solely combining the topographic–hydrologic features with the RGB and NIR bands significantly improved the performance of the models, which boosted the validated gully IOU to 0.4796 (±0.0146). Nevertheless, solely combining GLCM features with RGB and NIR bands decreased the accuracy, which resulted in the lowest validated gully IOU of 0.3755 (±0.0229). Finally, by employing the full set of RGB and NIR bands, the GLCM and topographic–hydrologic features obtained a validated gully IOU of 0.4762 (±0.0163) and tended to show an equivalent improvement with the combination of topographic–hydrologic features and RGB and NIR bands. A preliminary explanation is that the GLCM captures the local textures of gullies and their backgrounds, and thus introduces ambiguity and noise into the convolutional neural network (CNN). Therefore, the GLCM tends to provide no benefit to automatic gully extraction with CNN-type algorithms, while topographic–hydrologic features, which are also original drivers of gullies, help determine the possible presence of water-origin gullies when optical bands fail to tell the difference between a gully and its confusing background. Full article
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9 pages, 902 KiB  
Article
Flat Top Non-Polarizing Optical Bandpass Filtering in Form of Planar Optical Waveguide
by Jianhua Liu and Ping Jiang
Photonics 2025, 12(7), 724; https://doi.org/10.3390/photonics12070724 - 17 Jul 2025
Viewed by 249
Abstract
To obtain a flat top shaped passband in a conventional thin-film-based optical bandpass filter (OBF), it needs a large number of constitutional layers of thin films, which makes the film deposition systems more complicated and accumulates errors in film growth. A flat top [...] Read more.
To obtain a flat top shaped passband in a conventional thin-film-based optical bandpass filter (OBF), it needs a large number of constitutional layers of thin films, which makes the film deposition systems more complicated and accumulates errors in film growth. A flat top and polarization-independent optical bandpass filter structure is proposed based on experimentally verified polarization independency in the form of a prism-pair coupled planar optical waveguide (POW). The POW is composed of two waveguide stacks, which consists of nine planar thin-film layers. Theoretical simulations show that the flat band top spans about 5 nm with transmittance over 97.8%. The passband is designed to be centered at 632.8 nm, the He-Ne laser wavelength, and the FWHM (full width at half maximum) bandwidth is about 35 nm. Within 0.5° tuning for the incident angle of the light, the passband could be shifted within 50 nm, while its transmittance fluctuates only less than 1% and the passband shape distorts only slightly. This type of OBF is potentially applicable in various fields of optical and laser spectroscopies. Full article
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17 pages, 7597 KiB  
Article
Screen-Printed 1 × 4 Quasi-Yagi-Uda Antenna Array on Highly Flexible Transparent Substrate for the Emerging 5G Applications
by Matthieu Egels, Anton Venouil, Chaouki Hannachi, Philippe Pannier, Mohammed Benwadih and Christophe Serbutoviez
Electronics 2025, 14(14), 2850; https://doi.org/10.3390/electronics14142850 - 16 Jul 2025
Viewed by 263
Abstract
In the Internet of Things (IoT) era, the demand for cost-effective, flexible, wearable antennas and circuits has been growing. Accordingly, screen-printing techniques are becoming more popular due to their lower costs and high-volume manufacturing. This paper presents and investigates a full-screen-printed 1 × [...] Read more.
In the Internet of Things (IoT) era, the demand for cost-effective, flexible, wearable antennas and circuits has been growing. Accordingly, screen-printing techniques are becoming more popular due to their lower costs and high-volume manufacturing. This paper presents and investigates a full-screen-printed 1 × 4 Quasi-Yagi-Uda antenna array on a high-transparency flexible Zeonor thin-film substrate for emerging 26 GHz band (24.25–27.55 GHz) 5G applications. As part of this study, screen-printing implementation rules are developed by properly managing ink layer thickness on a transparent flexible Zeonor thin-film dielectric to achieve a decent antenna array performance. In addition, a screen-printing repeatability study has been carried out through a performance comparison of 24 antenna array samples manufactured by our research partner from CEA-Liten Grenoble. Despite the challenging antenna array screen printing at higher frequencies, the measured results show a good antenna performance as anticipated from the traditional subtractive printed circuit board (PCB) manufacturing process using standard substrates. It shows a wide-band matched input impedance from 22–28 GHz (i.e., 23% of relative band-width) and a maximum realized gain of 12.8 dB at 27 GHz. Full article
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53 pages, 915 KiB  
Review
Neural Correlates of Huntington’s Disease Based on Electroencephalography (EEG): A Mechanistic Review and Discussion of Excitation and Inhibition (E/I) Imbalance
by James Chmiel, Jarosław Nadobnik, Szymon Smerdel and Mirela Niedzielska
J. Clin. Med. 2025, 14(14), 5010; https://doi.org/10.3390/jcm14145010 - 15 Jul 2025
Viewed by 474
Abstract
Introduction: Huntington’s disease (HD) disrupts cortico-striato-thalamocortical circuits decades before clinical onset. Electroencephalography (EEG) offers millisecond temporal resolution, low cost, and broad accessibility, yet its mechanistic and biomarker potential in HD remains underexplored. We conducted a mechanistic review to synthesize half a century [...] Read more.
Introduction: Huntington’s disease (HD) disrupts cortico-striato-thalamocortical circuits decades before clinical onset. Electroencephalography (EEG) offers millisecond temporal resolution, low cost, and broad accessibility, yet its mechanistic and biomarker potential in HD remains underexplored. We conducted a mechanistic review to synthesize half a century of EEG findings, identify reproducible electrophysiological signatures, and outline translational next steps. Methods: Two independent reviewers searched PubMed, Scopus, Google Scholar, ResearchGate, and the Cochrane Library (January 1970–April 2025) using the terms “EEG” OR “electroencephalography” AND “Huntington’s disease”. Clinical trials published in English that reported raw EEG (not ERP-only) in human HD gene carriers were eligible. Abstract/title screening, full-text appraisal, and cross-reference mining yielded 22 studies (~700 HD recordings, ~600 controls). We extracted sample characteristics, acquisition protocols, spectral/connectivity metrics, and neuroclinical correlations. Results: Across diverse platforms, a consistent spectral trajectory emerged: (i) presymptomatic carriers show a focal 7–9 Hz (low-alpha) power loss that scales with CAG repeat length; (ii) early-manifest patients exhibit widespread alpha attenuation, delta–theta excess, and a flattened anterior-posterior gradient; (iii) advanced disease is characterized by global slow-wave dominance and low-voltage tracings. Source-resolved studies reveal early alpha hypocoherence and progressive delta/high-beta hypersynchrony, microstate shifts (A/B ↑, C/D ↓), and rising omega complexity. These electrophysiological changes correlate with motor burden, cognitive slowing, sleep fragmentation, and neurovascular uncoupling, and achieve 80–90% diagnostic accuracy in shallow machine-learning pipelines. Conclusions: EEG offers a coherent, stage-sensitive window on HD pathophysiology—from early thalamocortical disinhibition to late network fragmentation—and fulfills key biomarker criteria. Translation now depends on large, longitudinal, multi-center cohorts with harmonized high-density protocols, rigorous artifact control, and linkage to clinical milestones. Such infrastructure will enable the qualification of alpha-band restoration, delta-band hypersynchrony, and neurovascular coupling as pharmacodynamic readouts, fostering precision monitoring and network-targeted therapy in Huntington’s disease. Full article
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20 pages, 5288 KiB  
Article
Spectral Estimation of Nitrogen Content in Cotton Leaves Under Coupled Nitrogen and Phosphorus Conditions
by Shunyu Qiao, Wenjin Fu, Jiaqiang Wang, Xiaolong An, Fuqing Li, Weiyang Liu and Chongfa Cai
Agronomy 2025, 15(7), 1701; https://doi.org/10.3390/agronomy15071701 - 14 Jul 2025
Viewed by 310
Abstract
With the increasing application of hyperspectral technology, rapid and accurate monitoring of cotton leaf nitrogen concentrations (LNCs) has become an effective tool for large-scale areas. This study used Tahe No. 2 cotton seeds with four nitrogen levels (0, 200, 350, 500 kg ha [...] Read more.
With the increasing application of hyperspectral technology, rapid and accurate monitoring of cotton leaf nitrogen concentrations (LNCs) has become an effective tool for large-scale areas. This study used Tahe No. 2 cotton seeds with four nitrogen levels (0, 200, 350, 500 kg ha−1) and four phosphorus levels (0, 100, 200, 300 kg ha−1). Spectral data were acquired using an ASD FieldSpec HandHeld2 portable spectrometer, which measures spectral reflectance covering a band of 325–1075 nm with a spectral resolution of 1 nm. LNCs determination and spectral estimation were conducted at six growth stages: squaring, initial bloom, peak bloom, initial boll, peak boll, and boll opening. Thirty-seven spectral indices (SIs) were selected. First derivative (FD), standard normal variate (SNV), multiplicative scatter correction (MSC), and Savitzky–Golay (SG) were applied to preprocess the spectra. Feature bands were screened using partial least squares discriminant analysis (PLS–DA), and support vector machine (SVM) and random forest (RF) models were used for accuracy validation. The results revealed that (1) LNCs initially increased and then decreased with growth, peaking at the full-flowering stage before gradually declining. (2) The best LNC recognition models were SVM–MSC in the squaring stage, SVM–FD in the initial bloom stage, SVM–FD in the peak bloom stage, SVM–FD in the initial boll stage, RF–SNV in the peak boll Mstage, and SVM–FD in the boll opening stage. FD showed the best performance compared with the other three treatments, with SVM outperforming RF in terms of higher R2 and lower RMSE values. The SVM–FD model effectively improved the accuracy and robustness of LNCs prediction using hyperspectral leaf spectra, providing valuable guidance for large-scale information production in high-standard cotton fields. Full article
(This article belongs to the Section Precision and Digital Agriculture)
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23 pages, 3008 KiB  
Article
Quantitative Analysis of Sulfur Elements in Mars-like Rocks Based on Multimodal Data
by Yuhang Dong, Zhengfeng Shi, Junsheng Yao, Li Zhang, Yongkang Chen and Junyan Jia
Sensors 2025, 25(14), 4388; https://doi.org/10.3390/s25144388 - 14 Jul 2025
Viewed by 365
Abstract
The Zhurong rover of the Tianwen-1 mission has detected sulfates in its landing area. The analysis of these sulfates provides scientific evidence for exploring past hydration conditions and atmospheric evolution on Mars. As a non-contact technique with long-range detection capability, Laser-Induced Breakdown Spectroscopy [...] Read more.
The Zhurong rover of the Tianwen-1 mission has detected sulfates in its landing area. The analysis of these sulfates provides scientific evidence for exploring past hydration conditions and atmospheric evolution on Mars. As a non-contact technique with long-range detection capability, Laser-Induced Breakdown Spectroscopy (LIBS) is widely used for elemental identification on Mars. However, quantitative analysis of anionic elements using LIBS remains challenging due to the weak characteristic spectral lines of evaporite salt elements, such as sulfur, in LIBS spectra, which provide limited quantitative information. This study proposes a quantitative analysis method for sulfur in sulfate-containing Martian analogs by leveraging spectral line correlations, full-spectrum information, and prior knowledge, aiming to address the challenges of sulfur identification and quantification in Martian exploration. To enhance the accuracy of sulfur quantification, two analytical models for high and low sulfur concentrations were developed. Samples were classified using infrared spectroscopy based on sulfur content levels. Subsequently, multimodal deep learning models were developed for quantitative analysis by integrating LIBS and infrared spectra, based on varying concentrations. Compared to traditional unimodal models, the multimodal method simultaneously utilizes elemental chemical information from LIBS spectra and molecular structural and vibrational characteristics from infrared spectroscopy. Considering that sulfur exhibits distinct absorption bands in infrared spectra but demonstrates weak characteristic lines in LIBS spectra due to its low ionization energy, the combination of both spectral techniques enables the model to capture complementary sample features, thereby effectively improving prediction accuracy and robustness. To validate the advantages of the multimodal approach, comparative analyses were conducted against unimodal methods. Furthermore, to optimize model performance, different feature selection algorithms were evaluated. Ultimately, an XGBoost-based feature selection method incorporating prior knowledge was employed to identify optimal LIBS spectral features, and the selected feature subsets were utilized in multimodal modeling to enhance stability. Experimental results demonstrate that, compared to the BPNN, SVR, and Inception unimodal methods, the proposed multimodal approach achieves at least a 92.36% reduction in RMSE and a 46.3% improvement in R2. Full article
(This article belongs to the Section Sensing and Imaging)
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21 pages, 15482 KiB  
Article
InSAR Detection of Slow Ground Deformation: Taking Advantage of Sentinel-1 Time Series Length in Reducing Error Sources
by Machel Higgins and Shimon Wdowinski
Remote Sens. 2025, 17(14), 2420; https://doi.org/10.3390/rs17142420 - 12 Jul 2025
Viewed by 378
Abstract
Using interferometric synthetic aperture radar (InSAR) to observe slow ground deformation can be challenging due to many sources of error, with tropospheric phase delay and unwrapping errors being the most significant. While analytical methods, weather models, and data exist to mitigate tropospheric error, [...] Read more.
Using interferometric synthetic aperture radar (InSAR) to observe slow ground deformation can be challenging due to many sources of error, with tropospheric phase delay and unwrapping errors being the most significant. While analytical methods, weather models, and data exist to mitigate tropospheric error, most of these techniques are unsuitable for all InSAR applications (e.g., complex tropospheric mixing in the tropics) or are deficient in spatial or temporal resolution. Likewise, there are methods for removing the unwrapping error, but they cannot resolve the true phase when there is a high prevalence (>40%) of unwrapping error in a set of interferograms. Applying tropospheric delay removal techniques is unnecessary for C-band Sentinel-1 InSAR time series studies, and the effect of unwrapping error can be minimized if the full dataset is utilized. We demonstrate that using interferograms with long temporal baselines (800 days to 1600 days) but very short perpendicular baselines (<5 m) (LTSPB) can lower the velocity detection threshold to 2 mm y−1 to 3 mm y−1 for long-term coherent permanent scatterers. The LTSPB interferograms can measure slow deformation rates because the expected differential phases are larger than those of small baselines and potentially exceed the typical noise amplitude while also reducing the sensitivity of the time series estimation to the noise sources. The method takes advantage of the Sentinel-1 mission length (2016 to present), which, for most regions, can yield up to 300 interferograms that meet the LTSPB baseline criteria. We demonstrate that low velocity detection can be achieved by comparing the expected LTSPB differential phase measurements to synthetic tests and tropospheric delay from the Global Navigation Satellite System. We then characterize the slow (~3 mm/y) ground deformation of the Socorro Magma Body, New Mexico, and the Tampa Bay Area using LTSPB InSAR analysis. The method we describe has implications for simplifying the InSAR time series processing chain and enhancing the velocity detection threshold. Full article
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16 pages, 4139 KiB  
Article
Engineering Hierarchical CuO/WO3 Hollow Spheres with Flower-like Morphology for Ultra-Sensitive H2S Detection at ppb Level
by Peishuo Wang and Xueli Yang
Chemosensors 2025, 13(7), 250; https://doi.org/10.3390/chemosensors13070250 - 11 Jul 2025
Viewed by 363
Abstract
Highly sensitive real-time detection of hydrogen sulfide (H2S) is important for human health and environmental protection due to its highly toxic properties. The development of high-performance H2S sensors remains challenging for poor selectivity, high limit detection and slow recovery [...] Read more.
Highly sensitive real-time detection of hydrogen sulfide (H2S) is important for human health and environmental protection due to its highly toxic properties. The development of high-performance H2S sensors remains challenging for poor selectivity, high limit detection and slow recovery from irreversible sulfidation. To solve these problems, we strategically prepared a layered structure of CuO-sensitized WO3 flower-like hollow spheres with CuO as the sensitizing component. A 15 wt% CuO/WO3 exhibits an ultra-high response (Ra/Rg = 571) to 10 ppm H2S (131-times of pure WO3), excellent selectivity (97-times higher than 100 ppm interference gas), and a low detection limit (100 ppb). Notably, its fast response (4 s) is accompanied by full recovery within 236 s. After 30 days of continuous testing, the response of 15 wt% CuO/WO3 decreased slightly but maintained the initial response of 90.5%. The improved performance is attributed to (1) the p-n heterojunction formed between CuO and WO3 optimizes the energy band structure and enriches the chemisorption sites for H2S; (2) the reaction of H2S with CuO generates highly conductive CuS, which significantly reduces the interfacial resistance; and (3) the hierarchical flowery hollow microsphere structure, heterojunction, and oxygen vacancy synergistically promote the desorption. This work provides a high-performance H2S gas sensor that balances response, selectivity, and response/recovery kinetics. Full article
(This article belongs to the Special Issue Recent Progress in Nano Material-Based Gas Sensors)
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60 pages, 2063 KiB  
Systematic Review
Advancements in Antenna and Rectifier Systems for RF Energy Harvesting: A Systematic Review and Meta-Analysis
by Luis Fernando Guerrero-Vásquez, Nathalia Alexandra Chacón-Reino, Segundo Darío Tenezaca-Angamarca, Paúl Andrés Chasi-Pesantez and Jorge Osmani Ordoñez-Ordoñez
Appl. Sci. 2025, 15(14), 7773; https://doi.org/10.3390/app15147773 - 10 Jul 2025
Viewed by 730
Abstract
This systematic review explores recent advancements in antenna and rectifier systems for radio frequency (RF) energy harvesting within the gigahertz frequency range, aiming to support the development of sustainable and efficient low-power electronic applications. Conducted under the PRISMA methodology, our review filtered 2465 [...] Read more.
This systematic review explores recent advancements in antenna and rectifier systems for radio frequency (RF) energy harvesting within the gigahertz frequency range, aiming to support the development of sustainable and efficient low-power electronic applications. Conducted under the PRISMA methodology, our review filtered 2465 initial records down to 80 relevant studies, addressing three research questions focused on antenna design, operating frequency bands, and rectifier configurations. Key variables such as antenna type, resonant frequency, gain, efficiency, bandwidth, and physical dimensions were examined. Antenna designs including fractal, spiral, bow-tie, slot, and rectangular structures were analyzed, with fractal antennas showing the highest efficiency, while array antennas exhibited lower performance despite their compact dimensions. Frequency band analysis indicated a predominance of 2.4 GHz and 5.8 GHz applications. Evaluation of substrate materials such as FR4, Rogers, RT Duroid, textiles, and unconventional composites highlighted their impact on performance optimization. Rectifier systems including Schottky, full-wave, half-wave, microwave, multi-step, and single-step designs were assessed, with Schottky rectifiers demonstrating the highest energy conversion efficiency. Additionally, correlation analyses using boxplots explored the relationships among antenna area, efficiency, operating frequency, and gain across design variables. The findings identify current trends and design considerations crucial for enhancing RF energy harvesting technologies. Full article
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