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21 pages, 2588 KB  
Article
Petrogenesis and Geological Significance of the Jasacuo Monzogranite, Western Gangdese Belt, Southern Tibet: SIMS Zircon U-Pb Chronological and Whole-Rock Geochemical Constraints
by Wenwen Han, Qin Qin, Zhipen Liu, Yu Wu, Yunhe Liu and Wei Xu
Minerals 2026, 16(6), 644; https://doi.org/10.3390/min16060644 (registering DOI) - 18 Jun 2026
Viewed by 76
Abstract
Early Cretaceous magmatism in the western segment of the Gangdese belt is less well constrained than that in the central and eastern segments. This study presents petrography, whole-rock geochemistry, and SIMS zircon U–Pb geochronology for the Jasacuo monzogranite in Zhongba County, southern Tibet. [...] Read more.
Early Cretaceous magmatism in the western segment of the Gangdese belt is less well constrained than that in the central and eastern segments. This study presents petrography, whole-rock geochemistry, and SIMS zircon U–Pb geochronology for the Jasacuo monzogranite in Zhongba County, southern Tibet. Zircons are euhedral and show oscillatory zoning; 17 concordant analyses yield a weighted mean 206Pb/238U age of 101.4 ± 0.8 Ma (MSWD = 1.01), indicating crystallization in the late Early Cretaceous. The rocks are characterized by high SiO2 (63.73–77.11 wt.%), high K2O, low MgO, TiO2, and P2O5, and A/CNK values of 0.92–1.08, indicating metaluminous to weakly peraluminous, high-K calc-alkaline compositions with I-type affinity. Chondrite-normalized REE patterns show LREE enrichment and negative Eu anomalies, whereas primitive-mantle-normalized trace-element patterns display enrichment in Rb, U, Th, and Pb and depletion in Ba, Nb, Sr, Zr, and Ti. These features indicate that the Jasacuo monzogranite is an evolved felsic intrusion generated in a subduction-related continental-arc setting associated with northward subduction of the Neo-Tethyan oceanic lithosphere. The magma was dominated by crustal components and underwent significant fractional crystallization, mainly involving feldspar, with minor biotite and amphibole. Full article
14 pages, 3931 KB  
Article
Fractal Characteristics and Controlling Factors of Pore Structure in Different Lithofacies of Longmaxi Formation Shale
by Yi Sun, Xingyu Hu, Mengdi Liu and Fulin Meng
Fractal Fract. 2026, 10(6), 416; https://doi.org/10.3390/fractalfract10060416 - 18 Jun 2026
Viewed by 116
Abstract
Using 48 shale samples from the lower member of the Longmaxi Formation in Well YL, in the Middle Yangtze region, we investigate the fractal characteristics of pore structures across different shale lithofacies based on total organic carbon (TOC), X-ray diffraction (XRD), and low-pressure [...] Read more.
Using 48 shale samples from the lower member of the Longmaxi Formation in Well YL, in the Middle Yangtze region, we investigate the fractal characteristics of pore structures across different shale lithofacies based on total organic carbon (TOC), X-ray diffraction (XRD), and low-pressure N2 adsorption analyses. The shale succession is dominated by three lithofacies—clayey shale, mixed shale, and felsic shale—with mesopores and micropores forming the principal pore systems. N2 adsorption–desorption isotherms exhibit pronounced hysteresis loops, and ln(V) versus ln(ln(P0/P)) plots show distinct two-segment behaviour, indicating dual fractal dimensions within the pore network. The fractal dimension of small pores (Df1 = 2.75–2.87) is consistently higher than that of large pores (Df2 = 2.01–2.39), suggesting stronger structural heterogeneity in micropore–mesopore systems. Felsic shale exhibits the highest fractal dimensions, followed by mixed shale, whereas clayey shale shows the lowest values. Fractal dimensions correlate positively with TOC, clay minerals, and pyrite content, but negatively with quartz, feldspar, and carbonate minerals. Lithofacies therefore exert a first-order control on pore fractal characteristics through their influence on mineralogical composition and organic matter abundance. These results demonstrate that fractal dimensions provide a robust quantitative metric for evaluating reservoir heterogeneity in Longmaxi Formation shales. Unlike previous studies that examined pore complexity at the bulk-rock scale, this study adopts a lithofacies-resolved dual-fractal framework to quantify multiscale pore heterogeneity and explicitly elucidate the roles of mineralogy and organic matter in controlling pore complexity. Full article
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18 pages, 9934 KB  
Article
Genesis and Geological Significance of Tuff in the Wujiaping Formation, Upper Permian, Northern Sichuan Basin, China
by Jia Wang, Xiaoqin Liu, Pengfei Zhang, Jichang Yang and Fengjie Li
Geosciences 2026, 16(6), 234; https://doi.org/10.3390/geosciences16060234 - 13 Jun 2026
Viewed by 152
Abstract
In the northern Sichuan Basin, distant from the main body of the Emeishan Large Igneous Province (ELIP), marine deposits of the Wujiaping Formation from the Permian period contain widely distributed tuffs of varying thicknesses. To clarify the genesis of these tuffs and their [...] Read more.
In the northern Sichuan Basin, distant from the main body of the Emeishan Large Igneous Province (ELIP), marine deposits of the Wujiaping Formation from the Permian period contain widely distributed tuffs of varying thicknesses. To clarify the genesis of these tuffs and their relationship with the ELIP, this study conducted field measurements and sample collection at the Daliang Section, Wangcang County, and the Qiaoting Section, Nanjiang County, of the northern Sichuan Basin and compared them with basalts and tuffs from Well DY1 in a minor basaltic eruption zone in the northern Sichuan Basin. The results indicate that tuffs from the Daliang and Qiaoting Sections of the northern Sichuan Basin exhibit high Al2O3/TiO2 ratios (23.65–39.55) and significant depletion of Eu, Ba, and Sr elements. These characteristics suggest that their origin is linked to multiphase felsic volcanic activity within the ELIP and formation in an intraplate extensional setting. The basalts and tuffs developed at Well DY1 share the same low Al2O3/TiO2 ratios (4.02–4.97), similar to the Emeishan basalts. In the Zr-Ti, Zr/Sc-Th/Sc, Nb/Y-Zr/TiO2, and Zr/TiO2-SiO2 diagram plots, they fall within the basalt range, indicating that the tuffs at Well DY1 originated from the mid-ELIP eruption of basic basalt. In contrast to the felsic nature of the tuffs at Well DY1, the northern Sichuan Basin lacks records of such basic–alkaline igneous eruptions, suggesting that the influence of basalt eruptions in the northeastern Sichuan Basin is limited and does not affect the Wujiaping Formation in the northern Sichuan Basin. There is a positive correlation between volcanic activity and the total organic carbon (TOC) content of black siliceous rocks and siliceous shales in the Wujiaping Formation of northern Sichuan. The acid volcanic eruptions from Emeishan likely also played a key role in the formation of high-quality hydrocarbon source rocks in the deep-water continental shelf areas of the Wujiaping Formation in the northern Sichuan Basin. Full article
(This article belongs to the Special Issue Sedimentary Basins and Energy Resources)
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25 pages, 4146 KB  
Article
Geochemical Characterisation of Late Neolithic Penha-Type Pottery from NW Spain
by Antonio Martínez Cortizas, Olalla López-Costas, Ainé Francos-Golán and Pilar Prieto Martínez
Minerals 2026, 16(6), 623; https://doi.org/10.3390/min16060623 - 10 Jun 2026
Viewed by 203
Abstract
This paper presents the geochemical characterisation of Penha-type ceramics, one of the most iconic prehistoric ceramics in Western Iberia. Penha pottery was a widespread material expression in Late Neolithic communities who displayed significant socio-cultural transformation before the advent of the Metal Ages. Samples [...] Read more.
This paper presents the geochemical characterisation of Penha-type ceramics, one of the most iconic prehistoric ceramics in Western Iberia. Penha pottery was a widespread material expression in Late Neolithic communities who displayed significant socio-cultural transformation before the advent of the Metal Ages. Samples (108) from seven archaeological sites in Galicia (NW Spain) were analysed by XRD, FTIR-ATR and ICP-MS to determine their mineral, molecular and elemental composition, respectively. The results indicate that most vessels are compositionally consistent with local geological sources, whether mafic or felsic, pointing to strong intra-site production. The use of raw materials seems to have been selective, and there are minor discordances and mixed compositions in almost all sites. The selected methods were effective in determining temper composition, while FTIR-ATR was also informative of clay transformations due to firing. The firing conditions were generally low-temperature (600–900 °C) with relatively short times (<5 h), compatible with simple kiln technology. Archaeometric evidence suggests two scales of mobility: predominant local mobility and limited long-distance exchange (coastal/inland). The geochemical characterisation reveals that individual communities seem to have developed their own customised recipes for pottery production using a profound knowledge of available local resources. Full article
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25 pages, 17224 KB  
Article
Mesozoic Dykes in the Xingcheng Area, Western Liaoning Province, NE China: Phases, Petrogenesis, and Tectonic Setting
by Zhixiong Tan, Deyou Sun, Wenqing Li, Weimin Li, Yujie Hao, Jun Gou and Changqing Zheng
Minerals 2026, 16(6), 586; https://doi.org/10.3390/min16060586 - 30 May 2026
Viewed by 282
Abstract
The Mesozoic dykes in the Xingcheng area of western Liaoning Province in China were investigated through an integrated study involving zircon U–Pb geochronology, whole-rock geochemistry, and zircon Hf isotopic compositions to elucidate their emplacement phases, petrogenesis, and tectonic setting. The dykes are classified [...] Read more.
The Mesozoic dykes in the Xingcheng area of western Liaoning Province in China were investigated through an integrated study involving zircon U–Pb geochronology, whole-rock geochemistry, and zircon Hf isotopic compositions to elucidate their emplacement phases, petrogenesis, and tectonic setting. The dykes are classified into two groups: felsic (granite porphyry, granite aplite) and mafic (diabase, lamprophyre). Emplacement occurred in four discrete phases: Late Triassic (229–212 Ma), Early Jurassic (ca. 179 Ma), Late Jurassic (162–152 Ma), and Early Cretaceous (133–102 Ma). The felsic dykes are characterized by high SiO2 and alkali contents, low TFeO and MgO abundances, and belong to the high-K calc-alkaline I-type granite series. The mafic dykes exhibit low SiO2, elevated MgO, and high Na2O contents, displaying both alkaline and calc-alkaline affinities. Both dyke suites are consistently enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs), and depleted in heavy rare earth elements (HREEs) and high field-strength elements (HFSEs). Zircon εHf(t) values for the felsic dykes range from −22.3 to −7.4, corresponding to two-stage model ages (TDM2) of 2613–1729 Ma, indicating derivation from partial melting of Neoarchean to Paleoproterozoic crustal material. Late Jurassic mafic dykes yield εHf(t) values between −27.8 and −20.2, consistent with an origin from partial melting of enriched lithospheric mantle. In contrast, Early Cretaceous mafic dykes display a bimodal εHf(t) distribution (−12.9 to −9.5 and +4.3 to +8.4), suggesting a predominant enriched mantle source with variable inputs from depleted mantle components. Integrated with regional tectonic reconstructions, the data indicate that the Xingcheng area evolved within a post-collisional extensional regime following the amalgamation of the North China Craton and the Central Asian Orogenic Belt during the Late Triassic. The Jurassic magmatic pulses are attributed to an active continental margin setting associated with subduction of the Paleo-Pacific Plate, whereas the Early Cretaceous phase reflects regional extension triggered by rollback of the subducting Paleo-Pacific slab. Full article
(This article belongs to the Special Issue Advances in Granite Geochronology and Geochemistry)
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26 pages, 14233 KB  
Article
Petrographic and Geochemical Evidence from the Jatunyacu River Outcrop, Central Abitagua Batholith, Ecuadorian Amazon: Preliminary Constraints on Magmatic Evolution and Arc Affinity
by Cindy Vera-Jaramillo, Oswaldo Guzmán, Dayana Vera, Carlos Correa-Jaramillo, Christian Coral, Renato Gonzalez, Corina Campos and John E. Soto Luzuriaga
Geosciences 2026, 16(6), 215; https://doi.org/10.3390/geosciences16060215 - 29 May 2026
Viewed by 456
Abstract
The Abitagua batholith is a 120 km long plutonic body located in the northern sub-Andean zone of Ecuador. Despite its size, previous studies have focused on its northern and southern sectors, leaving the central sector uncharacterized. This study presents the first petrographic and [...] Read more.
The Abitagua batholith is a 120 km long plutonic body located in the northern sub-Andean zone of Ecuador. Despite its size, previous studies have focused on its northern and southern sectors, leaving the central sector uncharacterized. This study presents the first petrographic and geochemical evidence from a single outcrop exposed along the Jatunyacu River, in the central part of the Abitagua Batholith, in order to understand its magmatic evolution and tectonic affinity. Petrographically, the dominant lithology is an equigranular monzogranite. The fractured zones show localized hydrothermal alteration, including epidote, sericitization of plagioclase, and chloritization of biotite. Subordinate bodies include tonalitic enclaves, felsic dikes, and an andesitic dike. Geochemically, the studied sector shows a calc-alkaline affinity, peraluminous character, and a volcanic arc granite (VAG) signature broadly consistent with I-type granitoids formed in a continental arc related to subduction. Samples from fractured zones show small shifts toward the S-type field in the K2O vs. Na2O diagram, attributed to hydrothermal alkali mobility rather than primary magmatic variation, as supported by petrographic evidence. Multi-element normalized diagrams reveal distinct signatures among subordinate bodies: tonalitic enclaves show strong enrichment in mafic components and Nb, suggesting a primitive mafic source; felsic dikes display enrichment in incompatible elements (Nb, Rb) consistent with evolved residual melts; and the andesitic dike exhibits the most primitive composition with apparent minimal interaction with the felsic host. These are interpreted as evidence of a complex magmatic evolution involving mafic recharge, magma mixing, late injection of residual melts, and localized hydrothermal alteration. Comparison with previous studies suggest that the studied outcrop records an arc signature similar to that reported for the northern and southern sectors, although further work is needed to confirm the extent of this affinity across the central sector. Full article
(This article belongs to the Section Geochemistry)
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15 pages, 4760 KB  
Article
Geochemical Response of Thermally Altered Coal to Igneous Intrusion in the Juji Coal Mine of Yongxia Coalfield, Henan, North China
by Hanjing Zhu, Yixuan Peng, Yuhang Zhang and Shangbin Chen
Minerals 2026, 16(6), 585; https://doi.org/10.3390/min16060585 - 29 May 2026
Viewed by 387
Abstract
Igneous intrusions significantly modify the distribution and mobility of elements in coal. In order to explore the influence of igneous intrusions on the elements in coals, the No. 2-2 coal seam of the Shanxi Formation of Juji Coal Mine was selected as the [...] Read more.
Igneous intrusions significantly modify the distribution and mobility of elements in coal. In order to explore the influence of igneous intrusions on the elements in coals, the No. 2-2 coal seam of the Shanxi Formation of Juji Coal Mine was selected as the research focus. The No. 2-2 coal was investigated using X-ray fluorescence spectrometry and a high-resolution inductively coupled plasma mass spectrometer. The results show that the volatile gases accompanying the igneous intrusion, together with CO2 generated by reaction between the intrusion and the coal seam, led to marginally higher MnO and MgO in the thermally altered coals compared to unaltered coal, and also promoted reprecipitation of carbonate and silicate minerals, which increased loss on ignition. The content of P2O5 initially rises with increasing distance from the intrusion, indicating that contact metamorphism can lead to a depletion of major elements in thermally altered coals. Meanwhile, the igneous intrusion caused reprecipitation of silicate minerals, but the high temperatures from the intrusion pyrolyzed some of these minerals, resulting in Li, Sb, and U contents that increase with distance from the intrusion. In contrast, Ge, Mo, Ba, Eu, and Pb, together with hydrothermal fluids, entered the thermally metamorphosed coal via fractures and migrated downward, gradually accumulating within it; their contents therefore decrease with increasing distance. Additionally, the intrusion and associated hydrothermal fluids also induced positive Eu, Gd, and Y anomalies and negative Ce anomalies in the thermally altered coals, whereas intermediate-felsic source rocks and oxidizing conditions produced negative Eu, positive Ce, and weakly negative Y anomalies in coals farther from the intrusion. Contact metamorphism results in a significant element depletion, exerting negative effects. Conversely, hydrothermal fluids and fluids from the host rocks promote the redistribution and enrichment of elements in coal, producing positive effects. Overall, the negative effects outweigh the positive ones. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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35 pages, 9033 KB  
Article
Geochemical and Mineralogical Evolution of a Hydrologically Dynamic Mixed Carbonate–Siliciclastic Lacustrine System: Insights from the Late Miocene–Pliocene Alagöz Formation (Central Anatolia)
by Elif Akiska
Minerals 2026, 16(6), 580; https://doi.org/10.3390/min16060580 - 27 May 2026
Viewed by 561
Abstract
Marginal lacustrine systems are highly sensitive archives of hydrological fluctuations, climatic variability, and changes in sediment supply in continental basins. The Alagöz Formation (Late Miocene–Pliocene) exposed in the Haymana–Polatlı Basin, Central Anatolia, was investigated through integrated sedimentological, mineralogical, geochemical, and stable isotope analyses [...] Read more.
Marginal lacustrine systems are highly sensitive archives of hydrological fluctuations, climatic variability, and changes in sediment supply in continental basins. The Alagöz Formation (Late Miocene–Pliocene) exposed in the Haymana–Polatlı Basin, Central Anatolia, was investigated through integrated sedimentological, mineralogical, geochemical, and stable isotope analyses to constrain provenance, weathering history, and lacustrine hydrological variability. Facies analysis reveals a transition from alluvial–fluvial systems to a shallow marginal lacustrine environment subjected to short-term hydrological fluctuations. Mineralogical and geochemical data indicate that sedimentation occurred within a mixed carbonate–siliciclastic lacustrine system controlled by variable lake-water chemistry. Detrital mineral assemblages indicate contributions from metamorphic source rocks. Trace-element and REE signatures suggest derivation mainly from felsic-to-intermediate continental sources. Reworked carbonate fragments and fossil debris indicate recycling of older carbonate units. The occurrence of calcite, dolomite, and protodolomite reflects variable Mg/Ca ratios, whereas clay mineral assemblages record shifts between detrital input during relatively humid phases and chemically concentrated conditions. Palygorskite occurrence indicates localized and episodic alkaline conditions associated with short-lived evaporative concentration. Weathering indices (CIA, CIW, PIA, and ICV) suggest low-to-moderate chemical weathering and compositionally immature sediments, consistent with transitional humid to semi-arid climatic conditions. Trace-element systematics also indicate a minor mafic contribution to the detrital source. Stable isotope values (δ13C: −7.05‰ to +2.82‰; δ18O: −8.60‰ to −2.94‰ VPDB) and their weak correlation (r = 0.34) support a shallow, hydrologically dynamic lacustrine system dominated by freshwater input but episodically influenced by evaporative concentration. Taken together, the Alagöz Formation records a sensitive marginal lacustrine system shaped by short-term hydrological fluctuations. These findings provide a useful analog for understanding hydrologically sensitive marginal lacustrine systems developed in post-collisional continental basins under fluctuating semi-arid climatic conditions. Full article
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22 pages, 5570 KB  
Article
Quality and Genesis of Shale Reservoir Rich in Feldspar, Taking the Qiongzhusi Formation in the Sichuan Basin of China as an Example
by Majia Zheng, Ya Wu, Junyu Chen, Zeyun Wang, Xianglu Tang, Dadong Liu and Shitan Ning
Minerals 2026, 16(6), 564; https://doi.org/10.3390/min16060564 - 24 May 2026
Viewed by 449
Abstract
Shale gas will be the focus of global oil and gas exploration in the future. As a key mineral component in shale, the characteristics and genesis of feldspar are of great significance for reservoir quality. The feldspar in the Qiongzhusi Formation shale was [...] Read more.
Shale gas will be the focus of global oil and gas exploration in the future. As a key mineral component in shale, the characteristics and genesis of feldspar are of great significance for reservoir quality. The feldspar in the Qiongzhusi Formation shale was studied through core observation, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and major and trace elements analysis. The results show that the content of feldspar in the Qiongzhusi Formation shale is relatively high, with an average content of 27.3%, mainly sodium feldspar. The feldspar presents various forms, such as angular clastic particles and strongly altered particles. It exhibits localized dissolution and illitetization. The feldspar in the Qiongzhusi Formation shale is multi-source, mainly provided by the mixture of felsic sedimentary rocks and granites from the upper crust. The main source areas are the Western Sichuan Block, the Motianling Block, and the Hanyang Block. Rapid sedimentation leading to rapid burial is the primary sedimentary control factor for the high initial content of feldspar in the Qiongzhusi Formation shale. During the late burial and diagenetic stages, localized fluid action, comprising the synergy between micro-scale migration and chemical reactions driven by hydrocarbon generation, acts as a key factor influencing the minor variations in feldspar content. Under a stable tectonic background, the fluids in the Qiongzhusi Formation mainly come from organic acids produced by shale hydrocarbon generation, and the influence of formation water fluids is relatively limited, with a low degree of feldspar mineral transformation. Full article
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27 pages, 246529 KB  
Article
Quantitative Lithofacies Characterization and Log-Based Identification of Organic-Rich Shales from the First Member of the Upper Cretaceous Qingshankou Formation in the Southern Songliao Basin of Northeast China
by Haonan Chen, Guomiao Xu, Xin Tong, Yangxue Zhang, Hui Ban, Jia Xu, Yating Zhang and Yanhao Xiong
Minerals 2026, 16(5), 555; https://doi.org/10.3390/min16050555 - 21 May 2026
Viewed by 410
Abstract
Lithofacies characterization of organic-rich shales constitutes the essential foundation for sweet spot evaluation in lacustrine shale oil systems. This study targets the first member of the Upper Cretaceous Qingshankou Formation (K2qn1) in the southern Songliao Basin. Based on systematic [...] Read more.
Lithofacies characterization of organic-rich shales constitutes the essential foundation for sweet spot evaluation in lacustrine shale oil systems. This study targets the first member of the Upper Cretaceous Qingshankou Formation (K2qn1) in the southern Songliao Basin. Based on systematic core description of 908 m of core from eight cored wells, combined with 123 total organic carbon (TOC) measurements, 47 whole-rock X-ray diffraction (XRD) analyses, 29 major- and trace-element analyses, and six maceral identification datasets (≥500 organic particles counted per sample), together with conventional well log data from 75 wells (measured vitrinite reflectance Ro = 0.34%–1.38%, mean = 0.94%), we establish an integrated lithofacies classification scheme incorporating the TOC as a classification parameter and develop a log-based lithofacies identification workflow. Eight lithofacies are recognized within K2qn1 across the study area, of which three are organic-rich. The high-TOC clay-rich mudstone-grade laminated shale deposited in a deep lake setting (LF-A; mean TOC = 3.18%, clay minerals ≥50%, formed under saline and strongly anoxic-euxinic conditions; mean paleosalinity = 8.06‰, V/(V + Ni) = 0.75–0.97) and the high-to-moderate-TOC felsic mudstone-grade laminated shale deposited in a semi-deep lake setting (LF-B; mean TOC = 2.18%, felsic minerals ≥50%, formed under brackish-to-saline anoxic conditions; mean paleosalinity = 5.10‰, V/(V + Ni) = 0.70–0.84) constitute the dominant organic-rich lithofacies. From Y1 to Y3, the cumulative thickness of organic-rich lithofacies expands from approximately 10 m to approximately 25 m. Areally, the mean TOC increases systematically from 1.65% in the southern delta-front zone to 2.74% in the northern deep lake center, reflecting an enrichment pattern governed primarily by paleoproductivity and modulated jointly by preservation conditions and terrigenous dilution. The log-based identification workflow, established by integrating a modified ΔlogR method with multiple linear regression, achieves a TOC prediction coefficient of determination of R2=0.86 in the calibration well and lithofacies identification accuracies ranging from 64.6% to 94.0% in validation wells, with the highest performance observed in the delta-front facies zone. These results provide quantitative constraints for the genetic interpretation and log-based identification of organic-rich lacustrine shales. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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15 pages, 12540 KB  
Article
Development Characteristics and Reservoir Significance of Laminae in the Cambrian Qiongzhusi Formation Shale in the Southern Sichuan Basin
by Xin Chen, Hongzhi Yang, Bo Li, Shengxian Zhao, Chenglin Zhang, Shengyang Xie, Gaoxiang Wang, Yifu Luo and Lei Chen
Minerals 2026, 16(5), 552; https://doi.org/10.3390/min16050552 - 20 May 2026
Viewed by 315
Abstract
The Cambrian Qiongzhusi Formation shale in southern Sichuan is a promising new marine shale gas exploration target, often considered the next major potential source following the Silurian Longmaxi Formation. Clarifying its reservoir characteristics of shale is crucial for identifying shale gas sweet spots. [...] Read more.
The Cambrian Qiongzhusi Formation shale in southern Sichuan is a promising new marine shale gas exploration target, often considered the next major potential source following the Silurian Longmaxi Formation. Clarifying its reservoir characteristics of shale is crucial for identifying shale gas sweet spots. As the most distinctive structure feature in shale, laminae development plays a vital role in the formation and evolution of shale reservoirs. Based on core samples, thin sections, and a variety of test data, this study investigates the laminae development characteristics and reservoir significance of the Qiongzhusi Formation shale in the southern Sichuan Basin, yielding the following conclusions: (1) A three-level classification and nomenclature system for shale laminae in the Qiongzhusi Formation is proposed based on mineral composition and stacking patterns, dividing laminae into single laminae, lamina sets, and lamina series. The study area exhibits diverse lamina types, including four types of single laminae, three types of lamina sets, and seven types of lamina series. (2) The vertical heterogeneity in lamina series is pronounced. Within the organic-rich interval, the lithology transitions upward from organic-rich massive shale, through organic-rich argillaceous–felsic laminae, to organic-lean argillaceous–felsic laminae. In the low-TOC interval, increasing water depth corresponds to a transition from massive sandstone to predominantly organic-lean argillaceous–felsic–calcareous laminae and organic-lean argillaceous–felsic laminae. (3) Lamina development exerts a significant control over reservoir properties, with marked differences observed between various lamina series and massive shale. Among them, the organic-rich argillaceous–felsic lamina series exhibits the most favorable reservoir characteristics, including the highest total organic carbon (TOC) content, porosity, and gas content, representing the optimal shale reservoir type. Full article
(This article belongs to the Special Issue Element Enrichment and Gas Accumulation in Black Rock Series)
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31 pages, 21660 KB  
Article
Integration of Remote Sensing, Geochemistry, and Pb Isotopes to Unravel the Origin of Felsic Volcanism, Arabian Nubian Shield
by El Saeed R. Lasheen, Basma A. El-Badry, Samir Z. Kamh, Matthew Leybourne, Tamader Alhazani, Ioan V. Sanislav and Mabrouk Sami
Minerals 2026, 16(5), 545; https://doi.org/10.3390/min16050545 - 19 May 2026
Cited by 2 | Viewed by 386
Abstract
The Neoproterozoic Wadi Mahasin metavolcanics (WMVs) in the Central Eastern Desert, Egypt, were remapped using Landsat-8 and Sentinel-2 imagery and verified by field observations, and their petrogenesis was evaluated using petrography, whole-rock geochemistry, and Pb isotopes. The image processing techniques of decorrelation stretch [...] Read more.
The Neoproterozoic Wadi Mahasin metavolcanics (WMVs) in the Central Eastern Desert, Egypt, were remapped using Landsat-8 and Sentinel-2 imagery and verified by field observations, and their petrogenesis was evaluated using petrography, whole-rock geochemistry, and Pb isotopes. The image processing techniques of decorrelation stretch (DS), band ratios (BR), principal component analysis (PCA), and Minimum Noise Fraction (MNF) were applied to three remotely sensed datasets from Landsat-8, Sentinel-2B, and Planet to produce an updated geologic map of the study area. Moreover, two robust supervised classification techniques, maximum likelihood (MLC) and the support vector machine (SVM), enhanced geological contacts, structural elements, and produced classified images by 95.68% and 96%, respectively. The WMV suite comprises metadacite and metarhyolite with SiO2 contents of 61.8–66.5 and 77.8–79.8 wt.%, respectively, and belongs to a subalkaline calc–alkaline series with a transitional medium- to high-K character at the felsic end. Primitive mantle-normalized patterns show enrichment in LILEs (Rb, U, K, and Pb) and depletion in Nb, Ta, Ti, and P, consistent with subduction-related felsic magmatism. Chondrite-normalized REE patterns are characterized by enriched LREEs, flat to weakly fractionated HREEs ((Gd/Yb)N ≈ 1.5), and negative Eu anomalies (Eu/Eu* = 0.30–0.81). The flat HREE segment suggests melting of a garnet-free source, most plausibly a plagioclase–amphibole-bearing crustal assemblage. Eu/Eu* correlates positively with Sr for the suite as a whole, indicating plagioclase control during differentiation. Metarhyolite samples form a tightly clustered evolved group, whereas metadacites show broader scatter that mainly reflects differentiation. Pb isotopes and crust-like trace-element ratios (high Y/Nb, low Ce/Pb, and low Nb/U) indicate strong crustal involvement. Although assimilation–fractional crystallization from a mantle-derived parent magma cannot be excluded completely, the available isotopic data do not define a simple mantle-to-crust differentiation trend, and the uniformly evolved major- and trace-element signatures favor direct partial melting of felsic continental crust, followed by limited fractional crystallization. The WMV suite is, therefore, interpreted as a mature continental-arc felsic assemblage within the Arabian–Nubian Shield. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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25 pages, 13921 KB  
Article
Petrogenesis of the Early Cretaceous Volcanic Rocks in the North Himalayan Longzi Area, Southern Tibet
by Jiacong Wu, Dian Luo, Yubin Li, Duo Ji, Hairui Yang, Suiliang Dong, Wei Li and Khin Ei Thu
Minerals 2026, 16(5), 510; https://doi.org/10.3390/min16050510 - 12 May 2026
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Abstract
Early Cretaceous volcanic rocks are widely developed in the Longzi area, southern Tibet. Their petrogenesis and tectonic setting are important for understanding the initial breakup of eastern Gondwana and its deep geodynamic mechanisms. This study integrates field observations, petrography, zircon U-Pb geochronology and [...] Read more.
Early Cretaceous volcanic rocks are widely developed in the Longzi area, southern Tibet. Their petrogenesis and tectonic setting are important for understanding the initial breakup of eastern Gondwana and its deep geodynamic mechanisms. This study integrates field observations, petrography, zircon U-Pb geochronology and trace elements, whole-rock major and trace element geochemistry, and Sr-Nd-Pb isotopes to investigate the origin and tectonic significance of these rocks. The analyzed suite comprises diabase and rhyolite, with no intermediate compositions in the studied samples, thus defining a mafic–felsic volcanic association. Zircon U-Pb ages indicate Early Cretaceous magmatism at 132–138 Ma for the diabase and 132–134 Ma for the rhyolite. Geochemically, the mafic rocks are enriched in LREEs and HFSEs and display OIB-like trace-element characteristics, with εNd(t) values ranging from −0.2 to +4.4, indicating derivation from low-degree partial melting of a spinel–garnet lherzolite source modified by limited interaction with the lithospheric mantle. The felsic rocks show pronounced negative Eu anomalies, A-type granite affinities, and εNd(t) values ranging from −12.2 to −11.9, indicating derivation mainly from partial melting of upper-crustal materials. The marked geochemical and isotopic contrast between the mafic and felsic rocks argues against simple fractional crystallization from a common parental magma. Combined with regional geological data, these results indicate that the Longzi mafic–felsic volcanic association formed in an intraplate extensional setting related to Kerguelen-plume thermal input during the initial breakup of eastern Gondwana. Full article
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17 pages, 12113 KB  
Article
Petrogenesis and Uranium Metallogenic Fertility of Triassic Peraluminous Granites from the Yangjiaonao Deposit, Lujing Ore Field, South China
by Shuang Gao, Jia-Hu Su, Qianlin Wang, Yong-Qin Ye, Hao-Jie Cao, Shuang Tan, Sheng Wang, Li Li, Xiao-Yong Li and Ping-Ning Ouyang
Minerals 2026, 16(5), 494; https://doi.org/10.3390/min16050494 - 8 May 2026
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Abstract
Granites associated with hydrothermal uranium deposits provide critical insights into the processes governing uranium enrichment and mobilization within the continental crust. The Yangjiaonao deposit, situated in the Lujing ore field within the Nanling Metallogenic Belt (South China), is a typical granite-related hydrothermal vein-type [...] Read more.
Granites associated with hydrothermal uranium deposits provide critical insights into the processes governing uranium enrichment and mobilization within the continental crust. The Yangjiaonao deposit, situated in the Lujing ore field within the Nanling Metallogenic Belt (South China), is a typical granite-related hydrothermal vein-type uranium deposit. This study presents integrated zircon U-Pb geochronology, whole-rock geochemistry, whole-rock Nd isotopes and zircon Hf isotopes for the medium-to-coarse-grained porphyritic biotite (MCB) and medium-to-fine-grained two-mica (MFM) granites from the Yangjiaonao (YJN) granitic pluton. Both units yielded Triassic ages (~235–233 Ma), indicating synchronous emplacement during the Early Mesozoic period. However, they exhibit distinct metallogenic fertilities rooted in their petrogenesis. MCB granite, derived from greywacke-dominated sources, shows typical S-type characteristics, whereas uranium remained mineralogically sequestered in refractory accessory phases (e.g., zircon, monazite) during differentiation, evidenced by high and stable Th/U ratios. Conversely, MFM granite represents L-type peraluminous systems originated from felsic, arkose-like protoliths. Advanced fractionation in the MFM system triggered significant Th-U decoupling, driving Th/U ratios down to ~0.5 and promoting uranium enrichment in the residual melt. This differentiation-driven concentration of ‘leachable’ uranium identifies MFM granite as the primary fertile source for the Yangjiaonao hydrothermal mineralization. Full article
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36 pages, 15890 KB  
Article
Geochemistry and U-Pb-Hf Geochronology of Mesoarchean Granitoids from the Arco Verde Complex: Implications for the Crustal Evolution of the Rio Maria Domain, Carajás Province
by Bruna Karine Correa Nogueira, Jean-Michel Lafon, João Marinho Milhomem Neto, Fábio dos Santos Pereira, Regina Celia dos Santos Silva and Elton Luiz Dantas
Minerals 2026, 16(5), 483; https://doi.org/10.3390/min16050483 - 2 May 2026
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Abstract
The Arco Verde Complex, exposed in the Serra do Inajá region of the Rio Maria Domain (Carajás Province, Amazonian Craton), represents one of the oldest TTG granitoid association of the province (3.00–2.92 Ga). While TTG magmatism is well constrained in the northern domain, [...] Read more.
The Arco Verde Complex, exposed in the Serra do Inajá region of the Rio Maria Domain (Carajás Province, Amazonian Craton), represents one of the oldest TTG granitoid association of the province (3.00–2.92 Ga). While TTG magmatism is well constrained in the northern domain, its southern sector lacks precise geochronological data. This study integrates petrographic, geochemical, U–Pb zircon geochronology, and Nd–Hf isotopes to constrain the age, source, and crustal significance of these granitoids. Uranium–Pb zircon dating of two granodiorites yielded ages of 2979 ± 8 and 2979 ± 11 Ma, extending the 2.98 Ga TTG magmatic episode to the southern sector of the Rio Maria Domain. Geochemical data indicate dominant tonalites formed by partial melting of a similar mafic source at different crustal depths, whereas subordinate granodioritic and monzogranitic rocks show transitional TTG affinities. These features indicate coeval mafic and felsic crust rapidly reworked after formation. Hf and Nd model ages of 3.0–3.2 Ga, with positive εHf–Nd at 2.98 Ga, reinforce the Early Mesoarchean as the main crustal growth period in the province. In addition, we propose that the differentiation of the depleted mantle (DM) beneath the Carajás Province may have initiated around 3.8 Ga. Full article
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