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41 pages, 13170 KB  
Article
EA-TD3: An Energy-Aware Autonomous Trajectory Planning Method for Unmanned Electric Vertical Takeoff and Landing Aircraft
by Jinxu Cai, Juanzhang Xie, Lanxin Zhang, Ziyi Wang, Xueshun Li and Yongjun Zhao
Drones 2026, 10(5), 325; https://doi.org/10.3390/drones10050325 (registering DOI) - 26 Apr 2026
Abstract
Autonomous trajectory planning for electric Vertical Takeoff and Landing (eVTOL) Unmanned Aerial Vehicles (UAVs) faces the dual challenges of low-altitude environmental interference and limited onboard energy, which affects the reliability and safety of unmanned missions. To address these challenges, this paper develops the [...] Read more.
Autonomous trajectory planning for electric Vertical Takeoff and Landing (eVTOL) Unmanned Aerial Vehicles (UAVs) faces the dual challenges of low-altitude environmental interference and limited onboard energy, which affects the reliability and safety of unmanned missions. To address these challenges, this paper develops the EA-TD3 autonomous trajectory planning framework for eVTOL UAV systems. First, a stochastic urban wind field model is established to simulate low-altitude interference. Then, by integrating eVTOL UAV battery discharge data from Carnegie Mellon University (CMU), a mapping relationship between maneuvers and energy consumption is identified to construct a nonlinear energy consumption model. Finally, an energy boundary penalty function is introduced into the TD3 algorithm to ensure that trajectory planning remains within battery safety margins. Experiments based on the parameters of the EH216-S platform show that EA-TD3 achieves a near 100.00% success rate under ideal conditions and outperforms benchmark algorithms while reducing average energy consumption by 11.6%. Under an energy constraint of 120 J, its success rate remains at 87.80%, which exceeds the performance of the DDPG, SAC, and standard TD3 algorithms. This study optimizes the autonomous trajectory planning of eVTOL UAV platforms in urban air mobility (UAM) to improve the energy perception and power management of the autonomous system. Full article
13 pages, 10652 KB  
Article
Synergistic Design of ZnCo-MnO@NPC Cathode and ZIF-8@Zn Anode for High-Performance Aqueous Zinc-Ion Batteries
by Rui Zhang, Xinhuan Zhang, Jialiang Li, Wenting Li and Huan Pang
Molecules 2026, 31(9), 1429; https://doi.org/10.3390/molecules31091429 (registering DOI) - 26 Apr 2026
Abstract
Manganese-based cathodes offer high capacity, low cost, and safety for aqueous zinc-ion batteries (AZIBs), yet suffer from Mn dissolution, Jahn–Teller distortion, and sluggish Zn2+ kinetics. Herein, a Zn/Co co-doped MnO nanoporous carbon composite (denoted as ZnCo-MnO@NPC) derived from a bimetallic ZnCoMn metal–organic [...] Read more.
Manganese-based cathodes offer high capacity, low cost, and safety for aqueous zinc-ion batteries (AZIBs), yet suffer from Mn dissolution, Jahn–Teller distortion, and sluggish Zn2+ kinetics. Herein, a Zn/Co co-doped MnO nanoporous carbon composite (denoted as ZnCo-MnO@NPC) derived from a bimetallic ZnCoMn metal–organic framework (ZnCoMn-MOF-74) is successfully synthesized and proposed as a high-performance cathode to address these challenges. The introduction of Zn2+ increases the initial specific capacity of MnO, while Co doping effectively suppresses the Jahn–Teller distortion and improves the integrity of the structure. Furthermore, the nanoporous carbon matrix facilitates electrolyte infiltration and accelerates ionic transport. To further suppress dendrite growth and enhance cycling stability, a zeolitic imidazolate framework (ZIF-8) protective layer is engineered on the zinc anode (denoted as ZIF-8@Zn), effectively mitigating dendrite formation. The ZnCo-MnO@NPC//ZIF-8@Zn full cell demonstrates superior electrochemical performance, delivering 281.3 mAh g−1 at 0.1 A g−1 and retaining 98.7% of this value after 3500 long-term cycles at 2.0 A g−1, a remarkable finding that underscores its potential for high-performance energy storage. Collectively, this work highlights that transition metal ion doping represents an effective way to design efficient high-performance MOF-derived cathodes of AZIBs. Full article
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16 pages, 39362 KB  
Article
Aluminum–Calcium Alloy for Laser Powder Bed Fusion
by Nikolay V. Letyagin, Torgom K. Akopyan, Pavel A. Palkin, Ivan S. Solovev, Leonid V. Fedorenko, Stanislav V. Chernyshikhin, Ekaterina O. Babenko and Ruslan Yu. Barkov
J. Manuf. Mater. Process. 2026, 10(5), 148; https://doi.org/10.3390/jmmp10050148 (registering DOI) - 26 Apr 2026
Abstract
Developing specialized aluminum alloys for additive processes is a strategic approach to achieve both strength and mass reduction in high-performance products. The prospects of the new metallic powder composition of Al3Ca2La2Mn0.4Zr alloy for laser powder bed fusion (LPBF) have been studied. It has [...] Read more.
Developing specialized aluminum alloys for additive processes is a strategic approach to achieve both strength and mass reduction in high-performance products. The prospects of the new metallic powder composition of Al3Ca2La2Mn0.4Zr alloy for laser powder bed fusion (LPBF) have been studied. It has been found that the best printing mode, providing a more than 99.0% density of the specimens, includes substrate heating to 150 °C and printing with a 350 W laser power, a 1500 mm/s printing speed, a 0.08 mm hatch distance and a 0.03 mm layer thickness (energy density 97.2 J/mm2). The optimal printing mode provides for the following strength parameters: UTS 366 ± 5 MPa, yield strength 223 ± 8 MPa, and relative elongation 30 ± 3%. The alloy exhibits high thermal stability for the structure and its properties. Annealing temperatures below 300 °C have no critical effect on the alloy hardness: the hardness decreases by less than 10% of the initial 110 ± 3 HV. At 350 °C, the hardness decreases by 25.5% (82 ± 2 HV); 100 h exposure at 350 °C reduces the UTS to 265 ± 2 MPa and the yield strength to 178 ± 10 MPa, while maintaining the relative elongation of 29 ± 2%. Full article
(This article belongs to the Special Issue Advances in Powder Bed Fusion Technologies)
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31 pages, 7149 KB  
Article
Nationwide Solar Radiation Zoning and Performance Comparison of Empirical and Deep Learning Models
by Bing Hui, Qian Zhang, Lei Hou, Yan Zhang, Qinghua Shi, Guoqing Chen and Junhui Wang
Appl. Sci. 2026, 16(9), 4229; https://doi.org/10.3390/app16094229 (registering DOI) - 26 Apr 2026
Abstract
Accurate solar radiation estimation is critical for optimizing solar energy applications. This study divided 819 meteorological stations in China into six solar radiation zones using k-means, hierarchical, and bisecting k-means clustering based on daily relative sunshine duration. Correlation analysis and feature importance evaluation [...] Read more.
Accurate solar radiation estimation is critical for optimizing solar energy applications. This study divided 819 meteorological stations in China into six solar radiation zones using k-means, hierarchical, and bisecting k-means clustering based on daily relative sunshine duration. Correlation analysis and feature importance evaluation were conducted to quantify the contributions of key meteorological variables. A comparison of models considering regional heterogeneity was performed. Six sunshine-based empirical models, three machine learning models (Random Forest, Support Vector Machine, and Extreme Gradient Boosting), and two deep learning models (Long Short-Term Memory and Gated Recurrent Unit) were systematically evaluated across 98 stations with observed solar radiation data. Model performance was assessed using the coefficient of determination (R2), mean absolute error (MAE), root mean square error (RMSE), and normalized RMSE (NRMSE). Results showed that k-means clustering outperformed the other two methods and was adopted for final zoning. The correlation analysis identified sunshine duration (S), extraterrestrial radiation (Ra), temperature difference (ΔT), and maximum temperature (Tmax) as the dominant influencing factors, with clear regional heterogeneity. The deep learning models, particularly LSTM (R2 = 0.939, RMSE = 1.702 MJ/m/2/d1, MAE = 1.319 MJ/m/2/d1, NRMSE = 0.046), achieved the highest accuracy, followed by GRU, XGB, SVM, and RF. Among the empirical models, Model 5 performed best in Zones 1, 3, 4, and 5, while Model 6 was optimal in Zones 2 and 6. The key novelty of the study is an integrated zoning–prediction framework for regional solar radiation estimation, combining clustering validation, correlation analysis, empirical model calibration, and deep learning benchmarking, with enhanced physical interpretability and prediction accuracy. Full article
16 pages, 17008 KB  
Article
Effect of Different Adhesives on the Bonding Performance of the CFRP–Steel Interface
by Qin Wang, Wenhao Guo, Li Gao, Luchang Li, Mengda Zhao, Mei-Ling Zhuang, Chuanzhi Sun and Fuhe Ge
Buildings 2026, 16(9), 1697; https://doi.org/10.3390/buildings16091697 (registering DOI) - 26 Apr 2026
Abstract
This study investigates the influence of adhesive type on the bond performance between CFRP plates and steel interfaces through static tensile double-shear tests. Three types of adhesives (Araldite 420A/B, 2015-1, Sikadur-30CN) were tested under four bond lengths. The results indicate that adhesive strength [...] Read more.
This study investigates the influence of adhesive type on the bond performance between CFRP plates and steel interfaces through static tensile double-shear tests. Three types of adhesives (Araldite 420A/B, 2015-1, Sikadur-30CN) were tested under four bond lengths. The results indicate that adhesive strength significantly affects failure characteristics, with distinct material performance differences observed. Bond length influences the stress distribution, enhancing dispersion while potentially altering damage progression. High-performance adhesives exhibit superior shear resistance and fracture energy due to improved viscous properties, whereas moderately plastic adhesives achieve adaptive deformation and durable bonding by enhancing the flow and substrate contact. These findings provide a theoretical basis for material selection in CFRP-strengthened steel structures and offer actionable guidance for structural repair engineering applications. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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19 pages, 4995 KB  
Article
A Low-Order Thermodynamic Chamber Model for Multiphase Compressible Flow in a Profiled-Rotor Rotary Compressor
by Mihaela Constantin, Antonios Detzortzis and Cătălina Dobre
Thermo 2026, 6(2), 30; https://doi.org/10.3390/thermo6020030 (registering DOI) - 26 Apr 2026
Abstract
This study presents a combined numerical and experimental investigation of transient multiphase compressible flow inside a profiled-rotor rotary volumetric compressor. While most existing studies rely on high-fidelity CFD approaches, a low-order thermodynamic chamber-based model implemented in MATLAB Release 2023a is proposed to predict [...] Read more.
This study presents a combined numerical and experimental investigation of transient multiphase compressible flow inside a profiled-rotor rotary volumetric compressor. While most existing studies rely on high-fidelity CFD approaches, a low-order thermodynamic chamber-based model implemented in MATLAB Release 2023a is proposed to predict the temporal evolution of pressure, temperature, and vapor volume fraction during the compression cycle. The model is based on mass and energy conservation applied to variable-volume control chambers and incorporates a simplified cavitation criterion derived from local pressure relative to saturation vapor pressure. An open-loop experimental test bench was developed to measure air mass flow rate, suction and discharge pressures, temperatures, torque, and shaft power under controlled operating conditions. These measurements are used to validate the numerical predictions. The results show good agreement between measured and simulated pressure levels and global performance indicators, with deviations quantified using mean absolute percentage error values remaining below 5% over the investigated operating range. The numerical analysis further reveals the occurrence of localized low-pressure zones during the suction phase, indicating incipient cavitation or microbubble formation at specific rotor positions. The proposed modeling approach provides a computationally efficient alternative to full CFD simulations and enables rapid parametric analysis of rotor geometry and operating conditions. The cavitation formulation does not aim to resolve detailed bubble dynamics or erosion mechanisms, but rather to identify cavitation tendency based on thermodynamic pressure thresholds. Full article
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27 pages, 10444 KB  
Article
Fracture Mechanics and Strata Pressure Responses in Underground Mining Excavations Induced by Prefabricated Cracks
by Rui Gao, Chenxi Zhang, Weichen Gao, Guorui Feng, Xiao Huang, Xueming Zhang and Hong Guan
Geosciences 2026, 16(5), 172; https://doi.org/10.3390/geosciences16050172 (registering DOI) - 26 Apr 2026
Abstract
Rock fracture mechanics and the associated energy-release behavior play a key role in ensuring safe extraction in underground coal mining. Hydraulic fracturing generates prefabricated fracture networks in competent rock strata, thereby modifying fracture propagation patterns and reducing the failure resistance of the strata. [...] Read more.
Rock fracture mechanics and the associated energy-release behavior play a key role in ensuring safe extraction in underground coal mining. Hydraulic fracturing generates prefabricated fracture networks in competent rock strata, thereby modifying fracture propagation patterns and reducing the failure resistance of the strata. In this study, standardized three-point bending tests were conducted to investigate the fracture behavior of pre-cracked sandstone specimens with different crack morphologies, quantities, and spacings. New crack initiation occurred mainly at the midspan in specimens containing horizontal prefabricated cracks, whereas inclined prefabricated cracks promoted crack initiation from the crack tips. Although horizontal crack length did not exhibit a clear monotonic effect on load-bearing capacity, the overall capacity decreased with increasing crack density or decreasing crack spacing. Vertical cracks further reduced load-bearing performance, particularly at relatively small crack spacings. The strain response exhibited a non-monotonic relationship with horizontal crack parameters, increasing first and then decreasing with increasing crack length and spacing, while showing a positive correlation with vertical crack spacing. Dissipated energy was negatively correlated with prefabricated crack angle, accounting for 92.65%, 89.10%, and 94.03% of the total input energy. With increasing crack length, the proportion of dissipated energy first increased and then decreased, with values of 92.65%, 90.77%, 92.52%, and 96.13%. Energy dissipation decreased with increasing horizontal crack spacing but increased with vertical crack spacing. Numerical simulations further showed that both horizontal and vertical fractures generated by ground fracturing promoted timely strata failure, while vertical fractures were more effective in facilitating overburden fracture propagation and reducing the bearing capacity of the rock strata and advance coal body by more than 13%. These findings provide a mechanistic basis for the control of thick and competent hard-roof strata. Full article
(This article belongs to the Topic Advances in Mining and Geotechnical Engineering)
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25 pages, 3546 KB  
Article
Study and Development of High-Capacity Electrical ESS for RES
by Aizhan Zhanpeiissova, Yerlan Sarsenbayev, Askar Abdykadyrov, Dildash Uzbekova, Ardak Omarova, Seitzhan Orynbayev and Nurlan Kystaubayev
Energies 2026, 19(9), 2088; https://doi.org/10.3390/en19092088 (registering DOI) - 25 Apr 2026
Abstract
The increasing penetration of renewable energy sources (RES) introduces significant variability and instability in modern power systems, creating a growing need for advanced and coordinated energy storage solutions. However, a key unresolved challenge remains the integrated modeling and optimal sizing of hybrid energy [...] Read more.
The increasing penetration of renewable energy sources (RES) introduces significant variability and instability in modern power systems, creating a growing need for advanced and coordinated energy storage solutions. However, a key unresolved challenge remains the integrated modeling and optimal sizing of hybrid energy storage systems (ESS) that combine technologies with different temporal characteristics under high RES penetration. This study addresses this challenge by developing a unified techno-economic and physical–mathematical framework for hybrid ESS integrating lithium-ion (Li-ion), vanadium redox flow batteries (VRFB), and hydrogen (H2) technologies. Unlike conventional approaches that treat storage technologies independently or use simplified hybrid representations, the proposed framework jointly considers dynamic energy balance, degradation-aware lifecycle behavior, and multi-criteria cost optimization. The model was implemented using Python 3.10-based simulation tools and evaluated under renewable penetration scenarios of 30%, 50%, and 70%. The results indicate that increasing RES penetration leads to higher power fluctuations, reaching ±15–20% at 50% RES and ±20–25% at 70% RES. The optimized hybrid system achieves an overall efficiency of up to 92%, reduces total system cost to approximately 450 USD/kWh, and extends operational lifetime to 25 years, demonstrating a balanced techno-economic performance compared to standalone storage technologies. The proposed framework addresses this gap by coupling dynamic energy balance analysis with degradation-aware techno-economic optimization, enabling coordinated allocation of storage functions across short-, medium-, and long-duration timescales. In this way, the study not only evaluates hybrid storage performance, but also provides a practical decision-support framework for renewable-dominated power systems, particularly in the context of Kazakhstan’s energy transition. Full article
(This article belongs to the Section D: Energy Storage and Application)
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23 pages, 20194 KB  
Article
Experimental Assessment and Optimization of an Industrial Tunnel Pasteurizer for Bottled Liquid Products
by Alessia Di Giuseppe and Alberto Maria Gambelli
Processes 2026, 14(9), 1381; https://doi.org/10.3390/pr14091381 (registering DOI) - 25 Apr 2026
Abstract
Industrial tunnel pasteurizers are widely used for bottled liquid products because they provide a robust and continuous thermal treatment. However, operating conditions are often conservatively selected to ensure microbiological safety, which may result in excessive energy consumption and limited thermal efficiency. This study [...] Read more.
Industrial tunnel pasteurizers are widely used for bottled liquid products because they provide a robust and continuous thermal treatment. However, operating conditions are often conservatively selected to ensure microbiological safety, which may result in excessive energy consumption and limited thermal efficiency. This study experimentally investigates the thermal behavior and energy performance of an industrial tunnel pasteurizer used for a sealed bottled herbal-based high-viscosity liquid formulation under both nominal and modified operating conditions. An instrumented bottle was developed to measure temperature evolution at different locations inside the bottle, including the product core. In parallel, the overall heat capacity of the bottle–product system was determined by differential scanning calorimetry, enabling the estimation of the thermal energy absorbed by the bottles. Mass and energy balances were applied to quantify the heat exchanged in each process stage and to estimate phase-specific and overall heat-transfer efficiencies. Under nominal conditions, the pasteurization requirement, defined as a temperature above 72 °C for at least 12 min at the coldest point, was fully satisfied, with the temperature remaining above 72 °C for approximately 22 min near the bottle wall and 17–18 min at the product core. The energy analysis showed that overall process efficiency was limited, indicating room for improvement. Three additional experimental tests were therefore carried out under modified temperature and flow-rate conditions. In all cases, the pasteurization target was maintained. The results demonstrate that the process complies with the prescribed pasteurization target while offering significant opportunities for energy savings through optimization of the operating parameters. Full article
(This article belongs to the Section Food Process Engineering)
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13 pages, 5922 KB  
Article
Investigation of Rapid Non-Isothermal Crystallization Kinetics of Polyamide 66 Using a Fast-Scanning Chip-Based DSC
by Shaokui Tan, Ming Li, Zechun Li, Jun Yan, Zhihao Zhang, Pengcheng Xu, Peide Wu and Xinxin Li
Sensors 2026, 26(9), 2680; https://doi.org/10.3390/s26092680 (registering DOI) - 25 Apr 2026
Abstract
Understanding the rapid non-isothermal crystallization behavior of polymers is crucial for tailoring and optimizing their performance. However, conventional techniques are limited in achieving rapid heating and cooling rates, which hinders in-depth investigation of the crystallization kinetics of fast-crystallizing polymers. In this study, a [...] Read more.
Understanding the rapid non-isothermal crystallization behavior of polymers is crucial for tailoring and optimizing their performance. However, conventional techniques are limited in achieving rapid heating and cooling rates, which hinders in-depth investigation of the crystallization kinetics of fast-crystallizing polymers. In this study, a high-scan-rate MEMS thermopile DSC chip is employed to systematically investigate the non-isothermal crystallization kinetics of polyamide 66 (PA66) under rapid temperature variations. The results show that PA66 forms a lamellar α phase under slow cooling (1 °C/s) and a cauliflower-like γ phase under rapid cooling (300 °C/s), and becomes completely amorphous under ultrafast cooling (quenching). Furthermore, the technique enables quantitative analysis of the cold crystallization kinetics of fully amorphous PA66 during rapid heating. The results indicate that PA66 exhibits a higher apparent activation energy for homogeneous nucleation cold crystallization at low heating rates (≤10 °C/s), reaching 172.3 kJ·mol−1, which is approximately 3.2 times that at high heating rates (≥25 °C/s). The results of this study demonstrate that the developed fast-scanning chip-based DSC provides a powerful tool for analyzing the processing heating and cooling rate conditions of rapidly crystallizing polymers. Full article
(This article belongs to the Special Issue Chip-Based MEMS Platforms—2nd Edition)
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22 pages, 10523 KB  
Article
Design and Performance Validation of a Multi-Layer Laminator for Photovoltaic Modules
by Pengju Duan, Yu Jin and Boda Song
Solar 2026, 6(3), 20; https://doi.org/10.3390/solar6030020 (registering DOI) - 25 Apr 2026
Abstract
To address the demands of large-scale production in the photovoltaic industry for laminators with a small footprint, low energy consumption, and high encapsulation quality, this paper presents research on the structural design, simulation optimization, and performance validation of a multi-layer laminator for photovoltaic [...] Read more.
To address the demands of large-scale production in the photovoltaic industry for laminators with a small footprint, low energy consumption, and high encapsulation quality, this paper presents research on the structural design, simulation optimization, and performance validation of a multi-layer laminator for photovoltaic modules. Different from existing single-layer or double-layer structures, this paper proposes for the first time an eight-layer, three-stage overall scheme, develops modular lamination units, completes the design of core systems, and achieves multi-chamber coordination. Simulation validation was conducted on the temperature uniformity of the heating plates and the thermo-mechanical coupling under vacuum conditions. A prototype, model HCDL2743DSiT, was developed and subjected to a 30-day production trial. The results show that the equipment reaches a vacuum degree of 92 Pa within 100 s and drops to 38 Pa within 120 s; the temperature uniformity error of the heating plates is ±1.3 °C; the maximum positioning deviation of the transmission is ±2.8 mm. All core indicators meet the design requirements, and the module encapsulation pass rate reaches 99.9%. At the same production rate, the footprint is reduced by approximately 72% compared with that of a traditional double-layer laminator, achieving dual optimization of space utilization and energy consumption and providing technical equipment support for the high-efficiency encapsulation of photovoltaic modules. Full article
(This article belongs to the Topic Advances in Solar Technologies, 2nd Edition)
12 pages, 6236 KB  
Article
A Novel Dual-Gradient Patterned Wettability Current Collector for Passive DMFCs
by Yingli Zhu, Leyao Ban, Yingying Jing and Yangyang Cheng
Nanomaterials 2026, 16(9), 518; https://doi.org/10.3390/nano16090518 (registering DOI) - 25 Apr 2026
Abstract
Direct methanol fuel cells (DMFCs) offer significant advantages including high energy density and rapid refueling, making them promising power sources for portable electronic products. However, their practical application, particularly in passive systems, is hindered by critical mass transport limitations: water flooding in the [...] Read more.
Direct methanol fuel cells (DMFCs) offer significant advantages including high energy density and rapid refueling, making them promising power sources for portable electronic products. However, their practical application, particularly in passive systems, is hindered by critical mass transport limitations: water flooding in the cathode and CO2 bubble blockage in the anode. Herein, a novel dual-gradient patterned wettability current collector (CC) was designed to alleviate this mass transport impedance. The design uniquely integrates wedge-shaped gradients with surface energy gradients to create a unified, self-driven mechanism for efficient water and CO2 bubble transport at both electrodes. A mathematical model was developed to quantitatively evaluate the effects of the dual-gradient structure. The results confirm that water removal is enhanced when the cathode current collector features a hydrophobic periphery with a dual-gradient patterned wettability interior on the gas-diffusion-layer side and a fully hydrophilic air-side surface, whereas an inverted pattern facilitates anode CO2 removal. Optimal fabrication parameters on 316 L stainless steel were established by investigating laser scanning conditions and low-surface-energy agent concentrations. The experimental results show that the passive DMFCs incorporating the optimized current collectors delivered marked performance improvements. At 1 mol·L−1 methanol, the novel anode and cathode current collectors increased peak power density by 15.6% and 14.5%, respectively. Electrochemical impedance spectroscopy revealed a 31.4% and 31.9% reduction in mass transfer resistance of the cell with novel anode and cathode current collectors, respectively, confirming improved gas–liquid self-driven efficiency. Furthermore, the new cells exhibited substantially enhanced long-term stability over 18 h of continuous discharge, attributed to the robust wettability achieved via laser–silane modification. Overall, these findings suggest that the proposed dual-gradient wettability design is a promising method for improving internal mass transport, potentially supporting the development of more robust passive DMFCs. Full article
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17 pages, 3952 KB  
Article
Modulation of Microstructure, Magnetic, and Magnetocaloric Properties in La0.80Ag0.20MnO3 via Eu/Pb Co-Doping
by Fucheng Zhu, Yang Xu, Yanghui Chu, Zekai Wang, Xingyu Hong, Huiyan Zhang, Hailing Li, Weihua Gu, Zhiyuan Liu, Juan Liu and Ailin Xia
Materials 2026, 19(9), 1755; https://doi.org/10.3390/ma19091755 (registering DOI) - 25 Apr 2026
Abstract
Four perovskite manganite samples, La0.80Ag0.20MnO3 (LA), La0.78Eu0.02Ag0.20MnO3 (LEA), La0.80Pb0.05Ag0.15MnO3 (LPA), and La0.77Eu0.03Pb0.05Ag0.15MnO3 (LEPA), were prepared [...] Read more.
Four perovskite manganite samples, La0.80Ag0.20MnO3 (LA), La0.78Eu0.02Ag0.20MnO3 (LEA), La0.80Pb0.05Ag0.15MnO3 (LPA), and La0.77Eu0.03Pb0.05Ag0.15MnO3 (LEPA), were prepared by the Pechini sol–gel method. The samples were characterized by X-ray diffraction, scanning electron microscopy, energy-dispersive spectroscopy, X-ray photoelectron spectroscopy, and a magnetic property measurement system. A systematic investigation was conducted into the individual effects of Eu and Pb doping, as well as their co-doping, on the microstructural, magnetic and magnetocaloric properties of the materials. The results show that all samples are mainly composed of a rhombohedral perovskite phase with the R3¯c space group, accompanied by a trace amount of Ag. Addition of Eu3+ and Pb2+ induces lattice contraction and expansion, respectively. Under the same processing conditions, the average crystallite and particle sizes of the LEA sample (45.3 nm and 0.18 μm) are smaller than those of the other three samples (69.6~80.6 nm and 0.38~0.44 μm), indicating that the introduction of Eu alone suppresses crystallization ability, which can be avoided through Eu/Pb co-doping. All samples undergo a second-order ferromagnetic–paramagnetic transition, and the Curie temperature TC shifts to either lower or higher temperatures upon the introduction of Eu or Pb alone (from 310.8 K to 298.0 K or 318.0 K, respectively), which is attributed to the variation of the Mn3+/Mn4+ double-exchange (DE) interaction resulting from the ionic size mismatch and lattice distortion. In the LPA sample, an additional contribution arises from the altered Mn3+/Mn4+ ratio and enhanced DE interaction caused by the substitution of Pb2+ for Ag+. By modifying the Eu/Pb ratio, the TC of the LEPA sample was tuned to 299.3 K, and its maximum magnetic entropy change was enhanced to 3.90 J·kg−1·K−1 (H = 2 T). These results indicate that multicomponent synergistic regulation can improve the magnetocaloric performance of La-based perovskite manganites, providing a useful strategy for the development of room-temperature magnetic refrigeration materials. Full article
(This article belongs to the Section Advanced and Functional Ceramics and Glasses)
21 pages, 1802 KB  
Article
Feasibility of Reuse of EPS Insulation from Buildings and Infrastructure
by Malin Sletnes, Arian Loli, Birgit Risholt and Carine Lausselet
Buildings 2026, 16(9), 1693; https://doi.org/10.3390/buildings16091693 (registering DOI) - 25 Apr 2026
Abstract
As demand for energy-efficient buildings grows, the use of expanded polystyrene (EPS) insulation is expected to increase, intensifying the need for material-efficient strategies such as recycling and reuse. This study investigates the technical feasibility, chemical safety, and climate implications of reusing EPS insulation [...] Read more.
As demand for energy-efficient buildings grows, the use of expanded polystyrene (EPS) insulation is expected to increase, intensifying the need for material-efficient strategies such as recycling and reuse. This study investigates the technical feasibility, chemical safety, and climate implications of reusing EPS insulation recovered from building and infrastructure applications. EPS boards with service lives exceeding 20 years were collected from demolition sites and characterised for density, compressive strength, thermal conductivity, and hazardous substance content. Measured material properties were compared with historical test reports from 1976 to 2009 to assess long-term performance. The thermal conductivity and compressive strength of the used EPS samples fell within or close to the 95% prediction intervals for the corresponding products at the time of production, indicating limited long-term degradation. No brominated flame retardants or other substances of concern were detected above the detection limits. Life cycle assessment (LCA) results showed that reuse provides greater greenhouse gas (GHG) emission reduction potential than improved recycling alone, primarily through avoided virgin EPS production and reduced processing needs. An important insight from this study is that key material properties of used EPS can be reliably estimated from simple measurements of density, dimensions, and weight, and that direct reuse is feasible for less demanding applications. Additionally, further work is needed to test additional samples from diverse demolition sites across various applications and climates to establish a consistent basis for reuse. Full article
(This article belongs to the Special Issue A Circular Economy Paradigm for Construction Waste Management)
19 pages, 58392 KB  
Article
Amaranth as a Biogas Crop: Agronomic Performance and Methane Potential from a Field Evaluation in Southwest Germany
by Moritz von Cossel, Kathrin Klasen, Joana Iwaniw, Iris Lewandowski and Andrea Bauerle
Energies 2026, 19(9), 2087; https://doi.org/10.3390/en19092087 (registering DOI) - 25 Apr 2026
Abstract
While silage maize (Zea mays L.) remains the dominant biogas feedstock crop in Germany, concerns about landscape homogenization and ecological risks have stimulated the search for more diverse energy crops. This study evaluated twelve amaranth genotypes (GT01–12; Amaranthus spp.) in southwest Germany [...] Read more.
While silage maize (Zea mays L.) remains the dominant biogas feedstock crop in Germany, concerns about landscape homogenization and ecological risks have stimulated the search for more diverse energy crops. This study evaluated twelve amaranth genotypes (GT01–12; Amaranthus spp.) in southwest Germany using field experiments combined with biomass composition analysis and laboratory batch biogas assays. In contrast to earlier studies focusing primarily on the cultivar ‘Baernkraft’ (GT04), a broader set of genetic material was examined. Significant differences among GTs were observed for plant density, dry matter yield (DMY), dry matter content (DMC), and biomass composition. The most productive genotypes (GT09 and GT11) exceeded 10 Mg ha−1 DMY, clearly outperforming Baernkraft. However, even these GTs did not reach the ≈28% DMC threshold considered necessary for reliable ensiling. Lignin concentrations ranged from 4.7% to 7.2% of dry matter. Methane concentrations remained relatively stable (54–55%), resulting in an average methane yield of 1788 ± 441 m3 CH4 ha−1 (maximum: 2677.8 m3 CH4 ha−1) across all genotypes and harvest dates. These findings indicate that amaranth may contribute to diversification of biogas cropping systems, although its agronomic and substrate-related performance remains inferior to that of maize under the conditions studied. Full article
(This article belongs to the Special Issue Optimized Production of Bioenergy, Biofuels, and Biogas)
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