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21 pages, 1646 KiB  
Article
How Does New Quality Productive Forces Affect Green Total Factor Energy Efficiency in China? Consider the Threshold Effect of Artificial Intelligence
by Boyu Yuan, Runde Gu, Peng Wang and Yuwei Hu
Sustainability 2025, 17(15), 7012; https://doi.org/10.3390/su17157012 (registering DOI) - 1 Aug 2025
Abstract
China’s economy is shifting from an era of rapid expansion to one focused on high-quality development, making it imperative to tackle environmental degradation linked to energy use. Understanding how New Quality Productive Forces (NQPF) interact with energy efficiency, along with the mechanisms driving [...] Read more.
China’s economy is shifting from an era of rapid expansion to one focused on high-quality development, making it imperative to tackle environmental degradation linked to energy use. Understanding how New Quality Productive Forces (NQPF) interact with energy efficiency, along with the mechanisms driving this relationship, is essential for economic transformation and long-term sustainability. This study establishes an evaluation framework for NQPF, integrating technological, green, and digital dimensions. We apply fixed-effects models, the spatial Durbin model (SDM), a moderation model, and a threshold model to analyze the influence of NQPF on Green Total Factor Energy Efficiency (GTFEE) and its spatial implications. This underscores the necessity of distinguishing it from traditional productivity frameworks and adopting a new analytical perspective. Furthermore, by considering dimensions such as input, application, innovation capability, and market efficiency, we reveal the moderating role and heterogeneous effects of artificial intelligence (AI). The findings are as follows: The development of NQPF significantly enhances GTFEE, and the conclusion remains robust after tail reduction and endogeneity tests. NQPF has a positive spatial spillover effect on GTFEE; that is, while improving the local GTFEE, it also improves neighboring regions GTFEE. The advancement of AI significantly strengthens the positive impact of NQPF on GTFEE. AI exhibits a significant U-shaped threshold effect: as AI levels increase, its moderating effect transitions from suppression to facilitation, with marginal benefits gradually increasing over time. Full article
(This article belongs to the Section Energy Sustainability)
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42 pages, 3564 KiB  
Review
A Review on Sustainable Upcycling of Plastic Waste Through Depolymerization into High-Value Monomer
by Ramkumar Vanaraj, Subburayan Manickavasagam Suresh Kumar, Seong Cheol Kim and Madhappan Santhamoorthy
Processes 2025, 13(8), 2431; https://doi.org/10.3390/pr13082431 - 31 Jul 2025
Viewed by 3
Abstract
Plastic waste accumulation is one of the most pressing environmental challenges of the 21st century, owing to the widespread use of synthetic polymers and the limitations of conventional recycling methods. Among available strategies, chemical upcycling via depolymerization has emerged as a promising circular [...] Read more.
Plastic waste accumulation is one of the most pressing environmental challenges of the 21st century, owing to the widespread use of synthetic polymers and the limitations of conventional recycling methods. Among available strategies, chemical upcycling via depolymerization has emerged as a promising circular approach that converts plastic waste back into valuable monomers and chemical feedstocks. This article provides an in-depth narrative review of recent progress in the upcycling of major plastic types such as PET, PU, PS, and engineering plastics through thermal, chemical, catalytic, biological, and mechanochemical depolymerization methods. Each method is critically assessed in terms of efficiency, scalability, energy input, and environmental impact. Special attention is given to innovative catalyst systems, such as microsized MgO/SiO2 and Co/CaO composites, and emerging enzymatic systems like engineered PETases and whole-cell biocatalysts that enable low-temperature, selective depolymerization. Furthermore, the conversion pathways of depolymerized products into high-purity monomers such as BHET, TPA, vanillin, and bisphenols are discussed with supporting case studies. The review also examines life cycle assessment (LCA) data, techno-economic analyses, and policy frameworks supporting the adoption of depolymerization-based recycling systems. Collectively, this work outlines the technical viability and sustainability benefits of depolymerization as a core pillar of plastic circularity and monomer recovery, offering a path forward for high-value material recirculation and waste minimization. Full article
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16 pages, 832 KiB  
Article
Development and Evaluation of Neural Network Architectures for Model Predictive Control of Building Thermal Systems
by Jevgenijs Telicko, Andris Krumins and Agris Nikitenko
Buildings 2025, 15(15), 2702; https://doi.org/10.3390/buildings15152702 (registering DOI) - 31 Jul 2025
Viewed by 38
Abstract
The operational and indoor environmental quality of buildings has a significant impact on global energy consumption and human quality of life. One of the key directions for improving building performance is the optimization of building control systems. In modern buildings, the presence of [...] Read more.
The operational and indoor environmental quality of buildings has a significant impact on global energy consumption and human quality of life. One of the key directions for improving building performance is the optimization of building control systems. In modern buildings, the presence of numerous actuators and monitoring points makes manually designed control algorithms potentially suboptimal due to the complexity and human factors. To address this challenge, model predictive control based on artificial neural networks can be employed. The advantage of this approach lies in the model’s ability to learn and understand the dynamic behavior of the building from monitoring datasets. It should be noted that the effectiveness of such control models is directly dependent on the forecasting accuracy of the neural networks. In this study, we adapt neural network architectures such as GRU and TCN for use in the context of building model predictive control. Furthermore, we propose a novel hybrid architecture that combines the strengths of recurrent and convolutional neural networks. These architectures were compared using real monitoring data collected with a custom-developed device introduced in this work. The results indicate that, under the given experimental conditions, the proposed hybrid architecture outperforms both GRU and TCN models, particularly when processing large sequential input vectors. Full article
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20 pages, 2320 KiB  
Article
Electric Vehicle Energy Management Under Unknown Disturbances from Undefined Power Demand: Online Co-State Estimation via Reinforcement Learning
by C. Treesatayapun, A. D. Munoz-Vazquez, S. K. Korkua, B. Srikarun and C. Pochaiya
Energies 2025, 18(15), 4062; https://doi.org/10.3390/en18154062 (registering DOI) - 31 Jul 2025
Viewed by 46
Abstract
This paper presents a data-driven energy management scheme for fuel cell and battery electric vehicles, formulated as a constrained optimal control problem. The proposed method employs a co-state network trained using real-time measurements to estimate the control law without requiring prior knowledge of [...] Read more.
This paper presents a data-driven energy management scheme for fuel cell and battery electric vehicles, formulated as a constrained optimal control problem. The proposed method employs a co-state network trained using real-time measurements to estimate the control law without requiring prior knowledge of the system model or a complete dataset across the full operating domain. In contrast to conventional reinforcement learning approaches, this method avoids the issue of high dimensionality and does not depend on extensive offline training. Robustness is demonstrated by treating uncertain and time-varying elements, including power consumption from air conditioning systems, variations in road slope, and passenger-related demands, as unknown disturbances. The desired state of charge is defined as a reference trajectory, and the control input is computed while ensuring compliance with all operational constraints. Validation results based on a combined driving profile confirm the effectiveness of the proposed controller in maintaining the battery charge, reducing fluctuations in fuel cell power output, and ensuring reliable performance under practical conditions. Comparative evaluations are conducted against two benchmark controllers: one designed to maintain a constant state of charge and another based on a soft actor–critic learning algorithm. Full article
(This article belongs to the Special Issue Forecasting and Optimization in Transport Energy Management Systems)
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16 pages, 3669 KiB  
Article
Optimizing the Bioprocesses of Bacteriocin Production in Lacticaseibacillus paracasei HD1.7 by the “Acetate Switch”: Novel Insights into the Labor Division Between Energy Metabolism, Quorum Sensing, and Acetate
by Weige Yao, Rui Sun, Wen Zhang, Jie Kang, Zhenchao Wu, Liangyang Mao, Ying Yang, Shuo Li, Gang Song, Jingping Ge and Wenxiang Ping
Foods 2025, 14(15), 2691; https://doi.org/10.3390/foods14152691 (registering DOI) - 30 Jul 2025
Viewed by 114
Abstract
Acetate may act as a signaling molecule, regulating Paracin 1.7 production via quorum sensing (QS) in Lacticaseibacillus paracasei HD1.7. The “acetate switch” phenomenon requires mechanistic exploration to optimize Paracin 1.7 production. The “acetate switch” phenomenon delays with higher glucose levels (30 h, 36 [...] Read more.
Acetate may act as a signaling molecule, regulating Paracin 1.7 production via quorum sensing (QS) in Lacticaseibacillus paracasei HD1.7. The “acetate switch” phenomenon requires mechanistic exploration to optimize Paracin 1.7 production. The “acetate switch” phenomenon delays with higher glucose levels (30 h, 36 h, and 96 h). Before the occurrence of the “acetate switch”, the ATP content increases and peaks at the “acetate switch” point and the NAD+/NADH ratio decreases, indicating energy changes. Moreover, the QS genes used for the pre-regulation of bacteriocin, such as prcKR, comCDE, were highly expressed. After the “acetate switch”, the ATP content decreased and the QS genes for the post-regulation of bacteriocin were highly expressed, such as rggs234 and sigma70-1/70-2. The “acetate switch” could act as an energy switch, regulating bacterial growth and QS genes. Before and after the “acetate switch”, some metabolic pathways were significantly altered according to the transcriptomic analysis by HD1.7 and HD1.7-Δpta. In this study, acetate was used as an input signal to regulate the two-component system, significantly influencing the bacteriocin expression system. And this study clarifies the roles of acetate, energy, and quorum sensing in promoting Paracin 1.7 production, providing a theoretical basis for optimizing the bacteriocin fermentation process of HD1.7. Full article
(This article belongs to the Section Food Microbiology)
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28 pages, 5779 KiB  
Article
Regional Wave Spectra Prediction Method Based on Deep Learning
by Yuning Liu, Rui Li, Wei Hu, Peng Ren and Chao Xu
J. Mar. Sci. Eng. 2025, 13(8), 1461; https://doi.org/10.3390/jmse13081461 - 30 Jul 2025
Viewed by 131
Abstract
The wave spectrum, as a key statistical feature describing wave energy distribution, is crucial for understanding wave propagation mechanisms and supporting ocean engineering applications. This study, based on ERA5 reanalysis spectrum data, proposes a model combining CNN and xLSTM for rapid gridded wave [...] Read more.
The wave spectrum, as a key statistical feature describing wave energy distribution, is crucial for understanding wave propagation mechanisms and supporting ocean engineering applications. This study, based on ERA5 reanalysis spectrum data, proposes a model combining CNN and xLSTM for rapid gridded wave spectrum prediction over the Bohai and Yellow Seas domain. It uses 2D gridded spectrum data rather than a spectrum at specific points as input and analyzes the impact of various input factors at different time lags on wave development. The results show that incorporating water depth and mean sea level pressure significantly reduces errors. The model performs well across seasons with the seasonal spatial average root mean square error (SARMSE) of spectral energy remaining below 0.040 m2·s and RMSEs for significant wave height (SWH) and mean wave period (MWP) of 0.138 m and 1.331 s, respectively. At individual points, the spectral density bias is near zero, correlation coefficients range from 0.95 to 0.98, and the peak frequency RMSE is between 0.03 and 0.04 Hz. During a typical cold wave event, the model accurately reproduces the energy evolution and peak frequency shift. Buoy observations confirm that the model effectively tracks significant wave height trends under varying conditions. Moreover, applying a frequency-weighted loss function enhances the model’s ability to capture high-frequency spectral components, further improving prediction accuracy. Overall, the proposed method shows strong performance in spectrum prediction and provides a valuable approach for regional wave spectrum modeling. Full article
(This article belongs to the Section Physical Oceanography)
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22 pages, 16421 KiB  
Article
Deep Neural Network with Anomaly Detection for Single-Cycle Battery Lifetime Prediction
by Junghwan Lee, Longda Wang, Hoseok Jung, Bukyu Lim, Dael Kim, Jiaxin Liu and Jong Lim
Batteries 2025, 11(8), 288; https://doi.org/10.3390/batteries11080288 - 30 Jul 2025
Viewed by 311
Abstract
Large-scale battery datasets often contain anomalous data due to sensor noise, communication errors, and operational inconsistencies, which degrade the accuracy of data-driven prognostics. However, many existing studies overlook the impact of such anomalies or apply filtering heuristically without rigorous benchmarking, which can potentially [...] Read more.
Large-scale battery datasets often contain anomalous data due to sensor noise, communication errors, and operational inconsistencies, which degrade the accuracy of data-driven prognostics. However, many existing studies overlook the impact of such anomalies or apply filtering heuristically without rigorous benchmarking, which can potentially introduce biases into training and evaluation pipelines. This study presents a deep learning framework that integrates autoencoder-based anomaly detection with a residual neural network (ResNet) to achieve state-of-the-art prediction of remaining useful life at the cycle level using only a single-cycle input. The framework systematically filters out anomalous samples using multiple variants of convolutional and sequence-to-sequence autoencoders, thereby enhancing data integrity before optimizing and training the ResNet-based models. Benchmarking against existing deep learning approaches demonstrates a significant performance improvement, with the best model achieving a mean absolute percentage error of 2.85% and a root mean square error of 40.87 cycles, surpassing prior studies. These results indicate that autoencoder-based anomaly filtering significantly enhances prediction accuracy, reinforcing the importance of systematic anomaly detection in battery prognostics. The proposed method provides a scalable and interpretable solution for intelligent battery management in electric vehicles and energy storage systems. Full article
(This article belongs to the Special Issue Machine Learning for Advanced Battery Systems)
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34 pages, 13488 KiB  
Review
Numeric Modeling of Sea Surface Wave Using WAVEWATCH-III and SWAN During Tropical Cyclones: An Overview
by Ru Yao, Weizeng Shao, Yuyi Hu, Hao Xu and Qingping Zou
J. Mar. Sci. Eng. 2025, 13(8), 1450; https://doi.org/10.3390/jmse13081450 - 29 Jul 2025
Viewed by 117
Abstract
Extreme surface winds and wave heights of tropical cyclones (TCs)—pose serious threats to coastal community, infrastructure and environments. In recent decades, progress in numerical wave modeling has significantly enhanced the ability to reconstruct and predict wave behavior. This review offers an in-depth overview [...] Read more.
Extreme surface winds and wave heights of tropical cyclones (TCs)—pose serious threats to coastal community, infrastructure and environments. In recent decades, progress in numerical wave modeling has significantly enhanced the ability to reconstruct and predict wave behavior. This review offers an in-depth overview of TC-related wave modeling utilizing different computational schemes, with a special attention to WAVEWATCH III (WW3) and Simulating Waves Nearshore (SWAN). Due to the complex air–sea interactions during TCs, it is challenging to obtain accurate wind input data and optimize the parameterizations. Substantial spatial and temporal variations in water levels and current patterns occurs when coastal circulation is modulated by varying underwater topography. To explore their influence on waves, this study employs a coupled SWAN and Finite-Volume Community Ocean Model (FVCOM) modeling approach. Additionally, the interplay between wave and sea surface temperature (SST) is investigated by incorporating four key wave-induced forcing through breaking and non-breaking waves, radiation stress, and Stokes drift from WW3 into the Stony Brook Parallel Ocean Model (sbPOM). 20 TC events were analyzed to evaluate the performance of the selected parameterizations of external forcings in WW3 and SWAN. Among different nonlinear wave interaction schemes, Generalized Multiple Discrete Interaction Approximation (GMD) Discrete Interaction Approximation (DIA) and the computationally expensive Wave-Ray Tracing (WRT) A refined drag coefficient (Cd) equation, applied within an upgraded ST6 configuration, reduce significant wave height (SWH) prediction errors and the root mean square error (RMSE) for both SWAN and WW3 wave models. Surface currents and sea level variations notably altered the wave energy and wave height distributions, especially in the area with strong TC-induced oceanic current. Finally, coupling four wave-induced forcings into sbPOM enhanced SST simulation by refining heat flux estimates and promoting vertical mixing. Validation against Argo data showed that the updated sbPOM model achieved an RMSE as low as 1.39 m, with correlation coefficients nearing 0.9881. Full article
(This article belongs to the Section Ocean and Global Climate)
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34 pages, 4141 KiB  
Article
Factors Impacting Projected Annual Energy Production from Offshore Wind Farms on the US East and West Coasts
by Rebecca J. Barthelmie, Kelsey B. Thompson and Sara C. Pryor
Energies 2025, 18(15), 4037; https://doi.org/10.3390/en18154037 - 29 Jul 2025
Viewed by 127
Abstract
Simulations are conducted using a microscale model framework to quantify differences in projected Annual Energy Production (AEP), Capacity Factor (CF) and wake losses for large offshore wind farms that arise due to different input datasets, installed capacity density (ICD) and/or wake parameterizations. Differences [...] Read more.
Simulations are conducted using a microscale model framework to quantify differences in projected Annual Energy Production (AEP), Capacity Factor (CF) and wake losses for large offshore wind farms that arise due to different input datasets, installed capacity density (ICD) and/or wake parameterizations. Differences in CF (and AEP) and wake losses that arise due to the selection of the wake parameterization have the same magnitude as varying the ICD within the likely range of 2–9 MW km−2. CF simulated with most wake parameterizations have a near-linear relationship with ICD in this range, and the slope of the dependency on ICD is similar to that in mesoscale simulations with the Weather Research and Forecasting (WRF) model. Microscale simulations show that remotely generated wakes can double AEP losses in individual lease areas (LA) within a large LA cluster. Finally, simulations with the Coupled Ocean-Atmosphere-Wave-Sediment Transport (COAWST) model are shown to differ in terms of wake-induced AEP reduction from those with the WRF model by up to 5%, but this difference is smaller than differences in CF caused by the wind farm parameterization used in the mesoscale modeling. Enhanced evaluation of mesoscale and microscale wake parameterizations against observations of climatological representative AEP and time-varying power production from wind farm Supervisory Control and Data Acquisition (SCADA) data remains critical to improving the accuracy of predictive AEP modeling for large offshore wind farms. Full article
(This article belongs to the Section A3: Wind, Wave and Tidal Energy)
27 pages, 881 KiB  
Article
Review of Methods and Models for Forecasting Electricity Consumption
by Kamil Misiurek, Tadeusz Olkuski and Janusz Zyśk
Energies 2025, 18(15), 4032; https://doi.org/10.3390/en18154032 - 29 Jul 2025
Viewed by 142
Abstract
This article presents a comprehensive review of methods used for forecasting electricity consumption. The studies analyzed by the authors encompass both classical statistical models and modern approaches based on artificial intelligence, including machine-learning and deep-learning techniques. Electricity load forecasting is categorized into four [...] Read more.
This article presents a comprehensive review of methods used for forecasting electricity consumption. The studies analyzed by the authors encompass both classical statistical models and modern approaches based on artificial intelligence, including machine-learning and deep-learning techniques. Electricity load forecasting is categorized into four time horizons: very short term, short term, medium term, and long term. The authors conducted a comparative analysis of various models, such as autoregressive models, neural networks, fuzzy logic systems, hybrid models, and evolutionary algorithms. Particular attention was paid to the effectiveness of these methods in the context of variable input data, such as weather conditions, seasonal fluctuations, and changes in energy consumption patterns. The article emphasizes the growing importance of accurate forecasts in the context of the energy transition, integration of renewable energy sources, and the management of the evolving electricity system, shaped by decentralization, renewable integration, and data-intensive forecasting demands. In conclusion, the authors highlight the lack of a universal forecasting approach and the need for further research on hybrid models that combine interpretability with high predictive accuracy. This review can serve as a valuable resource for decision-makers, grid operators, and researchers involved in energy system planning. Full article
(This article belongs to the Special Issue Electricity Market Modeling Trends in Power Systems: 2nd Edition)
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27 pages, 3262 KiB  
Article
Energy-Efficient Gold Flotation via Coarse Particle Generation Using VSI and HPGR Comminution
by Sindhura Thatipamula and Sheila Devasahayam
Materials 2025, 18(15), 3553; https://doi.org/10.3390/ma18153553 - 29 Jul 2025
Viewed by 127
Abstract
This study investigates the impact of two comminution technologies—Vertical Shaft Impactors (VSI) and High-Pressure Grinding Rolls (HPGR)—on gold flotation performance, using ore samples from the Ballarat Gold Mine, Australia. The motivation stems from the growing need to improve energy efficiency and flotation recovery [...] Read more.
This study investigates the impact of two comminution technologies—Vertical Shaft Impactors (VSI) and High-Pressure Grinding Rolls (HPGR)—on gold flotation performance, using ore samples from the Ballarat Gold Mine, Australia. The motivation stems from the growing need to improve energy efficiency and flotation recovery in mineral processing, particularly under increasing economic and environmental constraints. Despite the widespread use of HPGR and VSI in the industry, limited comparative studies have explored their effects on downstream flotation behavior. Laboratory-scale experiments were conducted across particle size fractions (300–600 µm) using two collector types—Potassium Amyl Xanthate (PAX) and DSP002 (a proprietary dithiophosphate collector) to assess differences in flotation recovery, concentrate grade, and specific energy consumption. The results reveal that HPGR produces more fines and micro-cracks, enhancing liberation but also increasing gangue entrainment and energy demand. Conversely, VSI produces coarser, cubical particles with fewer slimes, achieving higher flotation grades and recoveries at lower energy input. VSI at 600 µm demonstrated the highest flotation efficiency (4241) with only 9.79 kWh/t energy input. These findings support the development of hybrid or tailored comminution strategies for improved flotation selectivity and sustainable processing. Full article
(This article belongs to the Section Construction and Building Materials)
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16 pages, 2171 KiB  
Review
Polystyrene Upcycling via Photocatalytic and Non-Photocatalytic Degradation
by Terry Yang and Yalan Xing
Molecules 2025, 30(15), 3165; https://doi.org/10.3390/molecules30153165 - 29 Jul 2025
Viewed by 168
Abstract
The rapid increase in polystyrene (PS) production has led to substantial growth in plastic waste, posing serious environmental and waste management challenges. Current disposal techniques are unsustainable, relying heavily on harsh conditions, high energy input, and generating environmentally harmful byproducts. This review critically [...] Read more.
The rapid increase in polystyrene (PS) production has led to substantial growth in plastic waste, posing serious environmental and waste management challenges. Current disposal techniques are unsustainable, relying heavily on harsh conditions, high energy input, and generating environmentally harmful byproducts. This review critically discusses alternative green approaches for PS treatment through photocatalytic and non-photocatalytic upcycling methods. Photocatalytic methods utilize light energy (UV, visible, or broad-spectrum irradiation) to initiate radical reactions that cleave the inert carbon backbone of PS. In contrast, non-photocatalytic strategies achieve backbone degradation without direct light activation, often employing catalysts and thermal energy. Both approaches effectively transform PS waste into higher-value compounds, such as benzoic acid and acetophenone, though yields remain moderate for most reported methods. Current limitations, including catalyst performance, low yields, and impurities in real-world PS waste, are highlighted. Future directions toward enhancing the efficiency, selectivity, and scalability of PS upcycling processes are proposed to address the growing plastic waste crisis sustainably. Full article
(This article belongs to the Special Issue Green Catalysis Technology for Sustainable Energy Conversion)
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27 pages, 5196 KiB  
Article
Impact of Hydrogen Release on Accidental Consequences in Deep-Sea Floating Photovoltaic Hydrogen Production Platforms
by Kan Wang, Jiahui Mi, Hao Wang, Xiaolei Liu and Tingting Shi
Hydrogen 2025, 6(3), 52; https://doi.org/10.3390/hydrogen6030052 - 29 Jul 2025
Viewed by 169
Abstract
Hydrogen is a potential key component of a carbon-neutral energy carrier and an input to marine industrial processes. This study examines the consequences of coupled hydrogen release and marine environmental factors during floating photovoltaic hydrogen production (FPHP) system failures. A validated three-dimensional numerical [...] Read more.
Hydrogen is a potential key component of a carbon-neutral energy carrier and an input to marine industrial processes. This study examines the consequences of coupled hydrogen release and marine environmental factors during floating photovoltaic hydrogen production (FPHP) system failures. A validated three-dimensional numerical model of FPHP comprehensively characterizes hydrogen leakage dynamics under varied rupture diameters (25, 50, 100 mm), transient release duration, dispersion patterns, and wind intensity effects (0–20 m/s sea-level velocities) on hydrogen–air vapor clouds. FLACS-generated data establish the concentration–dispersion distance relationship, with numerical validation confirming predictive accuracy for hydrogen storage tank failures. The results indicate that the wind velocity and rupture size significantly influence the explosion risk; 100 mm ruptures elevate the explosion risk, producing vapor clouds that are 40–65% larger than 25 mm and 50 mm cases. Meanwhile, increased wind velocities (>10 m/s) accelerate hydrogen dilution, reducing the high-concentration cloud volume by 70–84%. Hydrogen jet orientation governs the spatial overpressure distribution in unconfined spaces, leading to considerable shockwave consequence variability. Photovoltaic modules and inverters of FPHP demonstrate maximum vulnerability to overpressure effects; these key findings can be used in the design of offshore platform safety. This study reveals fundamental accident characteristics for FPHP reliability assessment and provides critical insights for safety reinforcement strategies in maritime hydrogen applications. Full article
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17 pages, 661 KiB  
Article
Adaptive Learning Control for Vehicle Systems with an Asymmetric Control Gain Matrix and Non-Uniform Trial Lengths
by Yangbo Tang, Zetao Chen and Hongjun Wu
Symmetry 2025, 17(8), 1203; https://doi.org/10.3390/sym17081203 - 29 Jul 2025
Viewed by 75
Abstract
Intelligent driving is a key technology in the field of automotive manufacturing due to its advantages in environmental protection, energy efficiency, and economy. However, since the intelligent driving model is an uncertain multi-input multi-output dynamic system, especially in an interactive environment, it faces [...] Read more.
Intelligent driving is a key technology in the field of automotive manufacturing due to its advantages in environmental protection, energy efficiency, and economy. However, since the intelligent driving model is an uncertain multi-input multi-output dynamic system, especially in an interactive environment, it faces uncertainties such as non-uniform trial lengths, unknown nonlinear parameters, and unknown control direction. In this paper, an adaptive iterative learning control method is proposed for vehicle systems with non-uniform trial lengths and asymmetric control gain matrices. Unlike the existing research on adaptive iterative learning for non-uniform test lengths, this paper assumes that the elements of the system’s control gain matrix are asymmetric. Therefore, the assumption made in traditional adaptive iterative learning methods that the control gain matrix of the system is known or real, symmetric, and positive definite (or negative definite) is relaxed. Finally, to prove the convergence of the system, a composite energy function is designed, and the effectiveness of the adaptive iterative learning method is verified using vehicle systems. This paper aims to address the challenges in intelligent driving control and decision-making caused by environmental and system uncertainties and provides a theoretical basis and technical support for intelligent driving, promoting the high-quality development of intelligent transportation. Full article
(This article belongs to the Special Issue Symmetry and Asymmetry in Intelligent Control and Computing)
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15 pages, 12959 KiB  
Article
Sodium Oxide-Fluxed Aluminothermic Reduction of Manganese Ore with Synergistic Effects of C and Si Reductants: SEM Study and Phase Stability Calculations
by Theresa Coetsee and Frederik De Bruin
Reactions 2025, 6(3), 40; https://doi.org/10.3390/reactions6030040 - 28 Jul 2025
Viewed by 165
Abstract
Aluminothermic reduction is an alternative processing route for the circular economy because Al is produced electrochemically in the Hall–Héroult process with minimal CO2 emissions if the electricity input is sourced from non-fossil fuel energy sources. This circular processing option attracts increased research [...] Read more.
Aluminothermic reduction is an alternative processing route for the circular economy because Al is produced electrochemically in the Hall–Héroult process with minimal CO2 emissions if the electricity input is sourced from non-fossil fuel energy sources. This circular processing option attracts increased research attention in the aluminothermic production of manganese and silicon alloys. The Al2O3 product must be recycled through hydrometallurgical processing, with leaching as the first step. Recent work has shown that the NaAlO2 compound is easily leached in water. In this work, a suitable slag formulation is applied in the aluminothermic reduction of manganese ore to form a Na2O-based slag of high Al2O3 solubility to effect good alloy–slag separation. The synergistic effect of carbon and silicon reductants with aluminium is illustrated and compared to the test result with only carbon reductant. The addition of small amounts of carbon reductant to MnO2-containing ore ensures rapid pre-reduction to MnO, facilitating aluminothermic reduction. At 1350 °C, a loosely sintered mass formed when carbon was added alone. The alloy and slag chemical analyses are compared to the thermochemistry predicted phase chemistry. The alloy consists of 66% Mn, 22–28% Fe, 2–9% Si, 0.4–1.4% Al, and 2.2–3.5% C. The higher %Si alloy is formed by adding Si metal. Although the product slag has a higher Al2O3 content (52–55% Al2O3) compared to the target slag (39% Al2O3), the fluidity of the slags appears sufficient for good alloy separation. Full article
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