Search Results (129)

Traditional polymer-dispersed liquid crystal (PDLC) faces limitations in smart dimming applications due to high driving voltage and poor high-temperature stability. In this study, a high-birefringence liquid crystal (QYPDLC-901) was used to prepare PDLC films with liquid crystal contents ranging from 72 wt% to 80 wt%, achieved through synergistic regulation of a low-functional acrylic polymer system and a low-intensity curing process. The effects of liquid crystal content, cell gap, and temperature on electro-optical properties were systematically investigated. Optimal performance was obtained at a liquid crystal content of 77 wt%, with a low threshold voltage of 2.9 V, saturation voltage of 7 V, fast response (rise time 4.2 ms, decay time 47 ms), and a favorable balance between high on-state and low off-state transmittance. Microstructural analysis revealed that the superior performance results from uniform droplet dispersion and low interfacial energy. Furthermore, the PDLC exhibited excellent switching stability from 23 °C to 90 °C, maintaining a maximum transmittance of 93% at 90 °C, with increases of only 0.4 V in threshold voltage and 0.1 V in saturation voltage. This study provides an experimental basis for designing smart dimming devices suitable for low-voltage driving and extreme environments. Full article

High-quality spectral filters with versatile tuning mechanisms are essential for applications in photonic integrated circuits, including sensing, laser stabilization, and spectral signal processing. We report the implementation of thermo-optic (TO) and electro-optic (EO) spectral tuning in silicon nitride Mach–Zehnder interferometers (MZIs) and micro-ring resonators (MRRs) by functionalizing the devices with a PMMA:JRD1 polymer cladding and integrating titanium tracks as heaters and electrodes. The fabricated MZIs and MRRs exhibit narrow linewidths of 25–30 pm and achieved TO tuning efficiencies of 1.7 and 13 pm/mW and EO tuning efficiencies of 0.33 and 1.6 pm/V, respectively. Closed-loop regulation using TO and EO effects enables stable half-fringe locking under environmental perturbations. This simple, broadly compatible hybrid platform demonstrates a practical approach to dual-mode spectral tuning and modulation in integrated photonic filters, providing a flexible route toward compact, reconfigurable, and environmentally robust photonic circuits. Full article

Aniline (ANI) was electropolymerized on ITO substrates with different surface resistivities. The process was performed by cyclic voltammetry from an aqueous, homogeneous solution containing sulfuric acid and the aniline monomer using various numbers of cycles and scan rates. The resulting polymer films (PANI) were characterized by ATR-IR spectroscopy, spectroscopic ellipsometry and atomic force microscopy. The influence of ITO surface resistivity on the electropolymerization process, the quality of the obtained PANI layers, and their optical properties was evaluated. Homogeneous PANI films were produced on ITO substrates with surface resistivities of 15–25 Ω/sq, encompassing both emeraldine salt and emeraldine base forms. Although the film’s growth was rapid, it also led to adhesion issues. In contrast, for ITO substrates with surface resistivities of 70–100 Ω/sq and 80–100 Ω/sq, the resulting films showed improved adhesion but were less homogeneous. Nevertheless, the conductive emeraldine salt form of polyaniline was successfully obtained. The conductive form of polyaniline was obtained without any additional modifications to the electropolymerization procedure. Notably, the literature provides no systematic analysis of electropolymerization on ITO substrates with different surface resistivities, which opens up new research opportunities and provides a basis for the rational design and optimization of PANI-based electro-optical coatings for advanced sensing applications. Full article

Antibiotics are persistent organic pollutants that pose a serious problem for water resources, ultimately having a detrimental effect on human and animal health. The most important aspect of controlling and preventing the spread of antibiotics and their degradation products is continuous screening and monitoring of environmental samples. Optical sensing technologies represent a large group of sensors that allow short-term detection of antibiotics in non-laboratory settings. This article reviews the advances in optical sensing systems (colorimetric, fluorescent, surface-enhanced Raman spectra-based, surface plasmon resonance-based, localized surface plasmon resonance-based, photonic crystal-based, fiber optic, molecularly imprinted polymer-based and electro-optical platforms) for the detection of antibacterial drugs in water. Special attention is paid to the evaluation of the analytic characteristics of optical sensors for the analysis of antibiotics. Particular attention is paid to electro-optical sensing and to the unique possibility of its use in antibiotic determination. Potential strategies are considered for amplifying the recorded signals and improving the performance of sensor systems. The main trends in optical sensing for antibiotic analysis and the prospects for the commercial application of optical sensors are described. Full article

The polymer dispersed liquid crystals (PDLCs) with conical boundary conditions are considered. PDLC films with different values of the relative chirality parameter $N_0$ of chiral nematic droplets ranging from 0 to $1.32$ are studied experimentally and theoretically. In flattened spheroid-shaped chiral nematic droplets, a twisted axial-bipolar structure is formed whose twist angle increases with rising $N_0$ value. Two stable states of the structure are revealed: one with the bipolar axis oriented perpendicular to the short axis of the spheroid and another with the bipolar axis oriented parallel to it. Applying a small voltage causes the bipolar axes of the chiral nematic droplets to reorient parallel to the electric field. The structure is unwound in strong electric fields, and the droplet order parameter reaches a high value of nearly $0.95$. These features of the voltage-induced reorientation of the axial-bipolar structure explain the experimentally observed characteristic electro-optical properties of PDLC cells: high transmittance $T^{\max }\cong 0.90$ in the on-state and low control voltages of less than 35 V. The minimum transmittance of the PDLC cells decreases as the value of $N_0$ increases; for samples with $N_0\ge 0.60$, the contrast ratio exceeds 145. Full article

The present study focuses on the effect of doping KH560-modified cellulose nanocrystals (CNCs) on the electro-optical characteristics of polymer-dispersed liquid crystals (PDLCs). PDLC films were fabricated through the polymerization-initiated phase separation (PIPS) process and doped with CNC nanoparticles at various concentrations. At low concentrations, the CNCs at the interface, by virtue of their unique chiral characteristics, induce an orderly arrangement of liquid crystal molecules. Meanwhile, the interaction between the film’s fiber structure and the liquid crystal droplets brings about an augmentation in the arrangement efficiency. The excellent dispersion of CNCs diminishes the random alignment of liquid crystal molecules and mitigates light scattering. Additionally, it aids in the deflection of the liquid crystal director, facilitating the lubrication of the liquid crystals’ movement. It is remarkable that within the range of relatively lower CNCs doping concentrations, specifically from 0.005 wt% to 0.05 wt%, the PDLC films exhibit lower threshold and saturation voltages, faster response, enhanced viewing angle performance and higher contrast. Full article

We present the creation of an alignment layer for liquid crystal molecules based on DNA from fish waste and a selected cationic surfactant. The implemented biodegradable DNA-based surface offers excellent optical and physical properties, cost-effectiveness, and environmental benefits compared to conventional polymers. Our findings demonstrate that the biopolymer DNA-DODA effectively induces homeotropic alignment of nematic liquid crystals, which was confirmed by topography visualization using atomic force microscopy, macroscopy, and polarizing optical microscopy observations. Anchoring energy and response time studies in the well-known electro-optical effect show that DNA-DODA exhibits molecular interaction strengths comparable to those of commercial polyimide. The successful implementation of DNA-DODA as an alignment layer highlights its promise for next-generation technologies, including flexible, sustainable, and biocompatible optical devices. Full article

This study investigated the influence of different functional groups on the electro-optical properties of polymer-dispersed liquid crystal (PDLC) films. Twelve acrylate monomers with functional groups like amino, halogen, and double-bond were introduced into PDLC films, and twelve samples were prepared. The electro-optical properties and microstructure of the films were characterized. The results show that compared to films with amino and halogen groups, those with hydroxyl groups have the best balance of driving voltage and contrast, achieving higher contrast at lower driving voltage, making this preparation scheme ideal for low-voltage, high-contrast PDLC films. Also, in the presence of hydroxyl groups, introducing double bonds increases saturation voltage and decreases saturation. Hydrogen-bond engineering through strategically positioned hydroxyl groups in acrylate monomers optimizes PDLC performance by enabling compact polymer networks and controlled phase separation, achieving superior contrast ratios (163) and low saturation voltages (15.8 V), while amino groups induce steric limitations and dual-bond systems that disrupt hydrogen-bond efficacy, highlighting hydroxyl spatial design as critical for electro-optical optimization. Full article

The enhanced infrared shielding function of antimony tin oxide (ATO)-doped polymer-dispersed liquid crystal (PDLC) film enables its use for smart windows, because it can switch between transparent and scattered states, which can protect people’s privacy. When PDLC film is used for a building’s doors and windows or external walls, we hope that it can have a higher infrared shielding capability, in order to reduce the indoor temperature affected by solar irradiation, so as to reduce the energy consumption caused by refrigeration equipment. However, the infrared shielding capability of the existing PDLC is far from sufficient. In this work, modified ATO nanoparticles of different sizes were introduced into the PDLC system to improve its infrared shielding capability. It was found that when the ATO particle size is 20 nm and the doping content is 0.6 wt%, the modified PDLC sample provides optimal infrared shielding function while maintaining excellent electro-optical properties. Full article

Polymer-stabilized liquid crystal (PSLC) dimming film has attracted widespread attention due to its normally transparent state, energy-saving capability, and excellent electro-optical performance, which has promising applications in smart cars and building windows. However, achieving good electro-optical performance and high peel strength simultaneously still remains challenging. In this study, a PSLC film based on monoepoxy and diepoxy monomers was prepared through rapid cationic polymerization, showing low driving voltages and high peel strength simultaneously. The influence of the content and composition of two epoxy monomers on the microstructures, mechanical properties, and electro-optical performance of the PSLC films were systematically studied. The polymer morphology of PSLC could be effectively modulated by doping monoepoxy monomers. The PSLC film with total monomer content of ≤15 wt% showed enhanced electro-optical properties and peel strength when doping monoepoxy monomers due to the lateral polymer in the networks and denser polymer on the substrate. When the ratio of E6M to E6PM was 12:3, compared with pure E6M, the threshold voltage decreased from 18.2 V to 12.6 V, and the peel strength increased from 62.53 kPa to 136.37 kPa. These PSLC films can adapt to the requirements of different application scenarios by changing the content and proportion of two epoxy monomers, and the strategy has good prospects in the actual production and application of PSLC films. Full article

Polymer-dispersed liquid crystals (PDLCs) are composite materials, in which LCs are dispersed in the form of microdroplets in a polymer matrix. As a composite material, its electro-optical properties are affected by many factors such as molecular structure, composition, and the microstructure of the LCs and polymers. In this work, PDLC films were prepared based on the thiol-ene click reaction, and effects of refractive indexes of polymers and LCs on their electro-optical properties were studied. The refractive indexes of the polymer matrix are adjusted by controlling the content of sulfur element, and those of the LCs are adjusted by adding multi-fluorinated LCs with high refractive index. By regulating the refractive indexes of the polymer matrix and LCs, the maximum transmittance of the film is raised and the viewing angle of the film is also extended. This work could afford some ideas for the directional regulation of the viewing angles and the electro-optical properties of the PDLC film. Full article

Nanostructured polymer-dispersed liquid crystals (nano-PDLCs) are transparent and optically isotropic materials in which submicron-sized liquid crystal (LC) domains are dispersed within a polymer matrix. Nano-PDLCs can induce birefringence by applying an electric field (E-field) based on the reorientation of the LC molecules. If nano-PDLCs are utilized as light-scattering-less birefringence memory materials, it is necessary to suppress the relaxation of the LC molecule orientation after the removal of the E-field. We focused on the ferroelectric smectic A (SmA) phase to suppress the relaxation of LC molecules, owing to its layered structure and high viscosity. Although nano-PDLCs require a strong E-field to reorient their LC molecules because of the anchoring effect at the LC/polymer interface, the required field strength can be reduced using a ferroelectric smectic A (SmA_F) LC with a large dielectric constant. In this study, we fabricated a nano-PDLC by shining an ultraviolet light on a mixture comprised an SmA_F LC, photocurable monomers, and a photo-initiator. The electro-birefringence effect was evaluated using polarizing optical microscopy. After the removal of the E-field, an enhanced memory effect was observed in the sample using SmA_F LC compared with nematic LC-based nano-PDLCs. Full article

Polymers containing π-conjugated segments are a diverse group of large molecules with semiconducting and emissive properties, with strong potential for use as active layers in Organic Light-Emitting Diodes (OLEDs). Stable blue-emitting materials, which are utilized as emissive layers in solution-processed OLED devices, are essential for their commercialization. Achieving balanced charge injection is challenging due to the wide bandgap between the HOMO and LUMO energy levels. This study examines the optical and photophysical characteristics of blue-emitting polymers to contribute to the understanding of the fundamental mechanisms of color purity and its stability during the operation of OLED devices. The investigated materials are a novel synthesized lab scale polymer, namely poly[(2,7-di(p-acetoxystyryl)-9-(2-ethylhexyl)-9H-carbazole-4,4′-diphenylsulfone)-co-poly(2,6-diphenylpyrydine-4,4′-diphenylsulfone] (CzCop), as well as three commercially supplied materials, namely Poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PFO), poly[9,9-bis(2′-ethylhexyl) fluorene-2,7-diyl] (PBEHF), and poly (9,9-n-dihexyl-2,7-fluorene-alt-9-phenyl-3,6-carbazole) (F6PC). The materials were compared to evaluate their properties using Spectroscopic Ellipsometry, Photoluminescence, and Atomic Force Microscopy (AFM). Additionally, the electrical characteristics of the OLED devices were investigated, as well as the stability of the electroluminescence emission spectrum during the device’s operation. Finally, the determined optical properties, combined with their photo- and electro-emission characteristics, provided significant insights into the color stability and selectivity of each material. Full article

A systematic investigation of optical, electrochemical, photophysical, and electrooptical properties of printable green color-emitting polymer (poly(9,9-dioctylfluorene-alt-bithiophene)) (F8T2) and spiro-copolymer (SPG-01T) was conducted to explore their potentiality as an emissive layer for wearable polymer light-emitting diode (PLED) applications. We compared the two photoactive polymers in terms of their spectral characteristics and color purity, as these are the most critical factors for wearable lighting sources and optical sensors. Low-cost, solution-based methods and facile architecture were applied to produce rigid and flexible light-emitting devices with high luminance efficiencies. Emission bandwidths, color coordinates, operational characteristics, and luminance were also derived to evaluate the device’s stability. The tuning of emission’s spectral features by layer thickness variation was realized and was correlated with the interplay between H-aggregates and J-aggregates formations for both conjugated polymers. Finally, we applied the functional green light-emitting PLED devices based on the two studied materials for the detection of Rhodamine 6G. It was determined that the optical detection of the R6G photoluminescence is heavily influenced by the emission spectrum characteristics of the PLED and changes in the thickness of the active layer. Full article

The reverse-mode smart windows, which usually fabricated by polymer stabilized liquid crystal (PSLC), are more practical for scenarios where high transparency is a priority for most of the time. However, the polymer stabilized cholesteric liquid crystal (PSCLC) film exhibits poor spacing stability due to the mobility of CLC molecules during the bending deformation. In this work, a reverse-mode PSCLC flexible film with excellent bending resistance was fabricated by the construction of polymer spacer columns. The effect of the concentration of the polymerizable monomer C6M and chiral dopant R811 on the electro-optical properties and polymer microstructure of the film were studied. The sample B2 containing 3 wt% of C6M and 3 wt% R811 presented the best electro-optical performance. The electrical switch between transparent and opaque state of the flexible PSCLC film after bending not only indicated the excellent electro-optical switching performance, but also demonstrated the outstanding bending resistance of the sample with polymer spacer columns, which makes the PSCLC film containing polymer spacer columns have a great potential to be applied in the field of flexible devices. Full article