Search Results (166)

The Ailinwudui gold deposit is located in central Jilin Province and represents a newly discovered typical vein-type gold deposit hosted in a Paleozoic metamorphic rock series in recent years. At present, the metallogenic epoch and regional metallogenic tectonic setting of the deposit remain poorly constrained, which seriously restricts the understanding of gold metallogenic regularities and subsequent mineral exploration deployment in central Jilin. Previous studies indicate that the Ailinwudui gold deposit is a structurally controlled vein-type gold deposit. In this study, zircon U-Pb and muscovite ⁴⁰Ar/³⁹Ar geo-chronology were employed to precisely constrain the metallogenic timing of the gold mineralization. Zircon U-Pb dating yields an emplacement age of 174.7 ± 0.85 Ma for the granodiorite and a formation age of 209.5 ± 1.40 Ma for the rhyolite porphyry. Muscovite ⁴⁰Ar/³⁹Ar dating yields a plateau age of 180.39 ± 1.83 Ma, which confines the gold mineralization to the Early–Middle Jurassic. Whole-rock geochemical results reveal that the granitoids in the study area are enriched in large-ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depleted in high-field-strength elements (HFSEs), showing typical arc-related magmatic affinities. The formation of this gold deposit is related to the subduction of the Paleo-Pacific Plate during the Early–Middle Jurassic. The research results can provide important geochronological and geochemical evidence for the study of gold metallogenic mechanisms and mineral exploration in central Jilin Province. Full article

Nephrite is a significant jade resource, and systematic investigation of its deposits contributes to regional metallogenic synthesis and exploration targeting. The recently discovered white nephrite deposit in the Dikou area, Fujian Province, remains inadequately characterized. This study presents a comprehensive mineralogical investigation employing polarizing microscopy, scanning electron microscopy, electron probe microanalysis, X-ray powder diffraction and laser Raman spectroscopy to elucidate the mineralogical and petrochemical characteristics of Dikou nephrite and constrain its genesis. The results demonstrate that tremolite constitutes the predominant mineral phase, accompanied by abundant diopside and quartz, with minor dolomite, prehnite, and apatite. Based on subtle compositional variations, tremolite can be categorized into two generations: early metasomatic Tr-I and late-stage Tr-II. All tremolite samples exhibit Fe-depleted, Mg-enriched composition with Mg# > 0.99. The mineral assemblage and textural relationships record multiple episodes of hydrothermal metasomatism. Integrated with the regional geological constraints, the deposit formation is genetically linked to the Neoproterozoic–Early Paleozoic ocean–continent transition of the South China Plate and is classified as D-type nephrite. The Dikou nephrite exhibits the mineral assemblage typical of dolomite-related deposits, displaying a distinctive felt-like fibrous texture that yields a homogeneous structure and superior aesthetic quality. Its Fe-depleted composition imparts a notably lighter coloration relative to D-type nephrite from other deposits. This study advances understanding of Dikou nephrite genesis, highlights the diversity of metallogenic environments in Fujian Province, and provides a theoretical framework for exploration of analogous deposits. Full article

The Circum-Rhodope Belt fringes the Rhodope and Serbo-Macedonian zones in the Alpine orogen of the northern Aegean region. This belt contains Late Paleozoic and Mesozoic metasedimentary successions that record depositional history along the continental margin of Eurasia. Critical successions of the eastern Circum-Rhodope Belt, such as those exposed in the Fanari and Petrota areas, are studied here, integrating their structure, whole-rock geochemistry and U-Pb LA-ICP-MS zircon geochronological context. The Fanari turbiditic succession contains quartz arenite, while the Petrota succession consists of Fe-rich shale and sandstone, and both successions are distinguished by REE-depleted and REE-enriched characteristics and acidic and intermediate arc-related sedimentary sources, respectively. Detrital U-Pb zircon geochronology reveals a Late Carboniferous–Early Permian maximum depositional age of 301.2 ± 8.4 Ma for Fanari quartz arenite and a Late Jurassic maximum depositional age of 147.0 ± 2.0 Ma for Petrota Fe-shale. The results are interpreted in terms of Late Paleozoic continental slope deposition of the Fanari succession along the Eurasian margin and trench-arc sedimentation of the Petrota succession linked to the development of a Jurassic island arc system pertinent to the eastern Circum-Rhodope Belt. These tectonic settings and depositional environments can be used to restore an overall picture of a Late Paleozoic to Mid-Mesozoic sedimentation at the Rhodope–Serbo-Macedonian continental margin of Eurasia. Structures that developed in greenschist facies conditions and N-directed kinematics of the studied successions unequivocally relate them to other units of the eastern Circum-Rhodope Belt and its Late Jurassic tectonic evolution. Full article

Northeast China, situated in the eastern Central Asian Orogenic Belt (CAOB), marks the terminal closure zone of the Paleo-Asian Ocean (PAO) (eastern segment). At present, due to extensive Quaternary cover, the structural deformation characteristics and deep structure of the Solonker Suture Zone in the east of the Nenjiang–Balihan fault remain poorly constrained, which limits our understanding of the tectonic evolution of the PAO. This study integrates deep seismic reflection (DSR) and magnetotelluric (MT) sounding profiles to investigate the crustal structural, sedimentary framework, and tectonic evolution of the oceanic and continental crusts along the western slope of the Songliao Basin. Two regional detachment surfaces (D1 and D2) were identified. The D2 interface demarcates the upper crust’s basal boundary, overlain by multiple high-amplitude monoclinic reflections. The area below the D2 interface exhibits a network structure of arcuate and variably oriented reflections, indicating a dual-layered orogenic structure. The upper crust exhibits distinct structural domains defined by strongly contrasting monoclinal reflections: north-dipping, low-resistivity zones in the southern sector and south-dipping, high-resistivity zones in the northern sector. These oppositely oriented reflections have been interpreted as marking an Early Paleozoic accretionary wedge and oceanic island arc, respectively. Interposed between these opposing structural domains, the Paleozoic to Early Mesozoic forearc basin sequences are preserved, with a pre-Middle Permian oceanic basin identified north of the study area. By integrating characteristics of seismic reflection sequences with regional geological data, this paper clarifies the processes of closure and collision at the northern margin of the PAO (Eastern Segment). Full article

To constrain the Late Paleozoic tectonic evolution of Taiyuan Formation, we conducted detrital zircon U-Pb dating and Hf isotopes analysis. The U-Pb age spectra from ten sandstone samples (taken from both the top and bottom of the formation) display four major age groups of 2.6–2.4 Ga, 2.2–1.8 Ga, 496–421 Ma and 350–270 Ma with highest peaks at ca. 323 Ma and 443 Ma. Moreover, on the basis of the weighted mean age of the five youngest detrital zircons (293.0 ± 4.1 Ma), combined with published results, we propose that the Taiyuan Formation formed during the Early Permian. Comparison of detrital zircon U-Pb age spectra and Hf isotopic compositions with potential source regions indicates that the early Paleozoic zircons were largely derived from the North Qinling orogenic belt, whereas the late Paleozoic zircons originated from the Inner Mongolia uplift. This shift reveals a significant provenance change recorded in the Taiyuan Formation. The uplift of the northern North China Craton (Inner Mongolia uplift) is interpreted as a response to the resubduction of the Paleo-Asian Ocean during the Late Paleozoic. The resulting paleogeographic pattern—higher in the north and lower in the south—redirected sediment supply for the uppermost sandstone and overlying strata of the Taiyuan Formation in the Qinshui Basin from the earlier North Qinling orogenic belt to the Inner Mongolia uplift. Full article

The Tawenchahanxi mining area, situated in the southeastern Qimantagh region of the East Kunlun Orogenic Belt, hosts a skarn-type Fe–polymetallic deposit associated with acidic granitic intrusions. Laser ablation–inductively coupled plasma–mass spectrometry zircon U–Pb dating yields ages of 233.3 ± 1.2 to 234.3 ± 1.1 Ma for a granodiorite and 397.7 ± 1.4 Ma for a quartz porphyry, indicating two magmatic intrusive events during the Early Devonian and Late Triassic. The Early Devonian quartz porphyry is characterized by high ${\mathrm{S}\mathrm{i}\mathrm{O}}_2$ (72.39%–74.04%), high total alkalis (7.81%–7.83%), high TFeO (>1.0%) and high crystallization temperatures (~865 °C), together with low CaO (1.64%–1.70%) and MgO (0.61–0.65%), which are all consistent with A-type granite affinity. The granodiorite exhibits aluminum saturation index (A/CNK) values of 0.67–1.07 (metaluminous to weakly peraluminous) and belongs to the high-K calc-alkaline series. It exhibits moderate negative Eu anomalies (δEu = 0.71–0.83), and zircon saturation temperatures of ~748 °C, collectively indicative of I-type granite affinity. Both rock suites display depletion in Nb, Ta, and Sr and enrichment in Rb and LREEs. Zircon Hf isotopic data show εHf(t) values of −0.64 to 0.57 for the quartz porphyry and −4.37 to −1.06 for the granodiorite, indicating derivation primarily from partial melting of ancient crust with variable mantle contributions. These intrusions formed during post-collisional extensional (Early Paleozoic) and collisional to post-collisional (Late Paleozoic–Early Mesozoic) stages, respectively, associated with mantle magma underplating and crust–mantle mixing. Such processes formed the material basis for the polymetallic mineralization in the Tawenchahanxi district by providing Fe–Cu–Pb–Zn and other ore-forming elements from deeper crust. Full article

The southern Central Asian Orogenic Belt (CAOB) underwent a major Early Paleozoic tectonic transition, yet its timing and mechanisms remain unclear. We present zircon U-Pb-Hf, whole-rock geochemical, and Sr–Nd isotopic data for newly identified Early Silurian (ca. 439–431 Ma) granitoids from the Liuyuan area of the southern Beishan Orogenic Belt. These high-silica, high-K calc-alkaline intrusions not only show arc-like trace-element patterns but also display elevated Ga/Al ratios and enriched Sr–Nd isotopic compositions ((⁸⁷Sr/⁸⁶Sr)_i = 0.7158–0.7189; ε_Nd(t) = −4.6 to −3.9), consistent with aluminous A₂-type granites derived mainly from ancient crust. Their heterogeneous zircon ε_Hf(t) values (−6.3 to +3.7) suggest a minor, localized input from mantle-derived mafic magmas superimposed on the dominant crustal signature. Integrating regional metamorphic constraints, we interpret this magmatism to have formed during the transition from oceanic subduction to incipient collision/continent involvement and subsequent post-subduction extension, plausibly triggered by slab break-off at the slab root (ocean–continent transition). Slab-window-related asthenospheric inflow and localized thermal perturbation could have promoted high-temperature crustal melting and facilitated Early Silurian crustal reworking in the southern CAOB. Full article

The Felbertal tungsten mineralisation in the Tauern Window (Eastern Alps) is hosted by the Early Paleozoic Habach Complex belonging to the Lower Schieferhülle. In predominantly mafic meta-volcanic rocks, mostly amphibolites, green amphibole crystallised in assemblages with plagioclase, epidote, chlorite, sphene and quartz. Microstructural features and preferential orientation of the amphiboles define planar-linear structures of finite strain and indicate that their crystallisation is coeval to the main deformation event. Amphibole crystals display core-to-rim zonations with increasing ^IVAl, ^VIAl, Na and Ti and decreasing Si, covering actinolite over magnesio-hornblende to tschermakite compositions. Amphibole zonations and assemblages are similar to metabasites in the classical Barrovian mineral zones in the Dalradian of Scotland and typical of a prograde metamorphism from the greenschist over epidote-amphibolite to the lower amphibolite facies. Amphibole endmember geothermobarometry defines an early P-T path segment from 400 °C/2 kbar to 540 °C/6 kbar, and a consecutive later P-T path segment from ~500–540 °C/6 kbar to maximal P-T conditions of ~620–640 °C/7–8 kbar. As Carboniferous granitoid intrusions within the Habach Complex underwent penetrative ductile deformation, an Alpine Tertiary age of the lower amphibolite facies metamorphism, as observed in other parts of the Lower Schieferhülle, appears suitable. Full article

Insect pollination, a critical ecological process, pre-dates the emergence of angiosperms by nearly 200 million years, with fossil evidence indicating pollination interactions between insects and non-angiosperm seed plants during the Late Paleozoic. This review examines the symbiotic relationships between insects and gymnosperms in pre-angiosperm ecosystems, highlighting the complexity of these interactions. Fossil records suggest that the mutualistic relationships between insects and gymnosperms, which facilitated plant reproduction, were as intricate and diverse as the modern interactions between angiosperms and their pollinators, particularly bees. These early pollination systems likely involved specialized behaviors and plant adaptations, reflecting a sophisticated evolutionary dynamic long before the advent of flowering plants. The Anthropocene presents a dichotomy: while climate change and anthropogenic pressures threaten insect biodiversity and risk disrupting angiosperm reproduction, such upheaval may simultaneously generate opportunities for novel plant–insect interactions as ecological niches are vacated. Understanding the deep evolutionary history of pollination offers critical insight into the mechanisms underlying the resilience and adaptability of these mutualisms. The evolutionary trajectory of bees—originating from predatory wasps, diversifying alongside angiosperms, and reorganizing after mass extinctions—exemplifies this dynamic, demonstrating how pollination networks persist and reorganize under environmental stress and underscoring the enduring health, resilience, and adaptability of these essential ecological systems. Full article

As a tectonically stable and extensively superimposed basin situated in the North China Craton, the Ordos Basin hosts abundant reserves of oil, natural gas, and coal within its Paleozoic strata, rendering it a focal area in energy-related geological research. The basin’s evolutionary history provides a comprehensive record of key geological transitions—from an Early Paleozoic carbonate platform to Late Paleozoic marine–continental transitional deposits and ultimately to continental clastic sedimentation—largely governed by the regional tectonic dynamics associated with the North China Plate. This study presents a systematic review of the sedimentary and tectonic evolution of the Paleozoic sequence in the basin. Findings indicate that during the Early Paleozoic, the basin developed under a passive continental margin setting, characterized by widespread epicontinental marine carbonate deposition. By the Late Ordovician, subduction of the Qinqi Ocean triggered the Caledonian orogeny, resulting in regional uplift across the basin, widespread erosion, and a significant hiatus in Middle to Late Ordovician sedimentation, which facilitated the formation of paleo-weathered crust karst reservoirs. In the Late Paleozoic, the basin evolved into an intracratonic depression. From the Late Carboniferous to the Early Permian, the Hercynian tectonic event influenced the transformation from isolated rift basins to a broad epicontinental sea, leading to the deposition of critical coal-bearing strata within marine–continental transitional facies. Starting in the Middle Permian, the closure of surrounding oceanic domains induced widespread tectonic uplift, shifting the depositional environment to a terrestrial fluvial-lacustrine system and marking the termination of marine sedimentation in the region. Based on the comprehensive research findings, this study underscores that the superposition, inheritance, and interaction of multiple tectonic events are the primary controls on the paleogeographic architecture and sedimentary. Full article

Currently, the formation and evolution processes of overpressure in the Upper Paleozoic tight sandstones of the Ordos Basin are not clearly understood. Taking the Shan 1 Member of the Shanxi Formation in the Yanchang area, southeastern Ordos Basin, as an example, we adopted a numerical simulation method considering pressurization effects (e.g., hydrocarbon generation and disequilibrium compaction) to quantitatively reconstruct the paleo-overpressure evolution history of target sandstone and shale layers before the end of the Early Cretaceous. We calculated two types of formation pressure changes since the Late Cretaceous tectonic uplift: the pressure reduction induced by pore rebound, temperature decrease and pressure release from potential brittle fracturing of overpressured shales, and the pressure increase in tight sandstones caused by overpressure transmission, thus clarifying the abnormal pressure evolution process of the Upper Paleozoic Shanxi Formation tight sandstones in the study area. The results show that at the end of the Early Cretaceous, the formation pressures of the target shale and sandstone layers in the study area reached their peaks, with the formation pressure coefficients of shale and sandstone being 1.41–1.59 and 1.10, respectively. During tectonic uplift since the early Late Cretaceous, temperature decrease and brittle fracture-induced pressure release caused significant declines in shale formation pressure, by 12.95–17.75 MPa and 20.00–25.24 MPa, respectively, resulting in the current shale formation pressure coefficients of 1.00–1.06. In this stage, temperature decrease and pore rebound caused sandstone formation pressure to decrease by 12.07–13.85 MPa and 16.93–17.41 MPa, respectively. Meanwhile, the overpressure transfer from two phases of hydrocarbon charging during the Late Triassic–Early Cretaceous and pressure release from shale brittle fracture during the Late Cretaceous tectonic uplift induced an increase in adjacent sandstone formation pressure, with a total pressure increase of 7.32–8.58 MPa. The combined effects of these three factors have led to the evolution of the target sandstone layer from abnormally high pressure in the late Early Cretaceous to the current abnormally low pressure. This study contributes to a deeper understanding of the formation process of underpressured gas reservoir in the Upper Paleozoic of the Ordos Basin. Full article

The SE Baltic area, the former Eastern Prussia, is renowned for complex natural history. Over the past millions of years, the area experienced major geological events and geomorphic landscape transformations, resulting in the present relief configuration. Past climates and environments gave rise to the specific life-forms that proliferated in the Paleozoic and Mesozoic–Early Cenozoic shallow sea/lacustrine basins, and the Late Cenozoic riverine and continental settings. During the Paleogene, forested sub-tropical lands and deltaic settings of coastal sea lagoons gave rise to the famed amber formations (Blue Ground) hosting inclusions of resin-sealed insect and other small invertebrates that offer an unprecedented look into the 35–34 million-year habitats. Ferruginous sandstones, formed in shallow waters incorporating remains of thermophilous fauna—bivalves and gastropods, bryozoans, and sea urchins, among others—lie above the amber-bearing deposits. Oligocene–Miocene continental (riverine, lacustrine, and palustrine) conditions relate to the “Brown Coal Formation”, embedding a variety of fossil plants. Finally, the Quaternary Period brought dramatic geo-environmental shifts, with cyclic interstadial sea transgressions and massive glacial erosion events delivering fossiliferous erratics with an array of primitive Paleozoic and later Mesozoic life-forms. Overall, the extraordinary paleontology of the SE Baltic area adds, within its geological context, to the European geoheritage and the world natural heritage. Full article

The observed shortage of water resources in the western and southern regions of the Russian Federation may soon affect the territory of the Republic of Bashkortostan. An increase in the share of groundwaters can help to solve this problem. To provide the population of the republic with water resources, the groundwater of magnesium–bicarbonate-type from the Kraka ophiolite massifs can be used. The massifs occur on the western slope of the Southers Urals. In this work we studied ultramafic rocks and their influence on the formation of the chemical composition of water. The research area is located in the northern part of the Zilair synclinorium, which occurs within the Central Ural megazone. In terms of hydrogeology, of particular importance to the territory of the synclinorium is the Zilair basin of fracture waters of the second order, which is part of the Uralian hydrogeologic folded zone. The ultramafic rocks from the studied area have consistently high CaO/Al₂O₃ ratios (0.4–1.6), which indicates the widespread development of parageneses with participation of clinopyroxene and a low degree of depletion of the primitive mantle source. Because of the complex geological structure of the area, water samples collected from both water points in the Kraka massifs, and the surrounding Early–Middle Paleozoic rocks were analyzed for major ions using a laboratory method to identify possible hydro-geochemical zoning. A statistical analysis was then conducted based on the obtained anion–cation composition data. From the viewpoint of the hydrolytic concept, the formation of the chemical composition of groundwater takes place due to the removal of Mg²⁺ from the rock-forming minerals of ultramafic rocks (olivine and pyroxene) and the supply of Na⁺, K⁺, Ca²⁺, and SO₄²⁻ Cl⁻ from atmospheric precipitations. The bicarbonate anion has a complex nature, where both biochemical processes in the soil and atmospheric precipitation play a significant role. Magnesium–bicarbonate-type of waters, due to low mineralization (to 1 g/L) and the majority of other geochemical parameters (pH of the medium, and content of Na, K, Ca, SO₄, and Cl), whose values that are within the limits set by the World Health Organization (WHO), can be used as drinking water. The increased values of total hardness (0.20–3.39 mmol/L) in accordance with the regulatory document SanPiN 1.2.3685–21, adopted by the Russian Federation, do not exceed the maximum permissible concentrations (up to 7.00 (10.00) mEq/L or 3.50 (5.00) mmol/L). The high magnesium content, in accordance with GOST (state standard) R 54316–2020, allows the magnesium–bicarbonate waters of the Kraka massifs to be classified as table mineral waters for the treatment of various diseases (including hypomagnesemia). Full article

The Khanbogd-Erdene region in southern Mongolia is a globally important copper–polymetallic metallogenic province, hosting large to super-large deposits, such as Oyu Tolgoi and Tsagaan Suvarga. The area experiences frequent tectonic–magmatic activity, particularly Late Paleozoic subduction-related magmatism, which controls the occurrence of large-scale copper–polymetallic mineralization. This study focuses on the Late Paleozoic granitic intrusive rocks in the Khanbogd-Erdene region of southern Mongolia. Using LA-ICP-MS and SHRIMP dating techniques, precise zircon U–Pb ages were obtained for 10 samples. A total of 209 zircon grains from these 10 intrusive rocks were analyzed, with most cathodoluminescence (CL) images of zircon grains showing distinct oscillatory zoning. Th/U ratios ranging from 0.11 to 2.92 indicate they are magmatic. The younger group of granitic rocks yielded ages between 260.2 ± 1.2 Ma and 286.6 ± 0.9 Ma, indicating an Early Permian geological age. The other seven samples yielded older ages between 315.9 ± 1.8 Ma and 340.9 ± 0.9 Ma, indicating a Carboniferous geological age. These large-scale Carboniferous to Early Permian intrusive rocks in the Khanbogd-Erdene region are products of tectonic–magmatic activity during specific stages of crustal evolution. The findings provide reliable chronological data for regional tectonic–magmatic activity and offer new evidence for constraining the timing of the Variscan orogeny in southern Mongolia. Full article

The western Ordos Basin (OB) is situated at the junction of multiple tectonic units with distinct properties. The prolonged and complex tectonic interactions from adjacent tectonic units have resulted in diverse structural phenomena and intricate evolutionary history in this region. The late Paleozoic represents a critical period for the transition of the tectonic regime in this area. However, due to the effects of intense later-stage modification, the late Paleozoic provenance system and paleogeomorphology of this region remain poorly constrained. Against this background, systematic fieldwork and detrital zircon geochronological analyses of the Youjingshan and Quwushan Permian sections were conducted to determine sediment provenance, and spatial variations in detrital zircon geochronological characteristics across different parts of the OB are further discussed. The results indicate that the detrital zircon age spectra of the Permian Dahuangou and Yaogou formations in the Youjingshan and Quwushan sections are dominated by late Paleozoic (250–360 Ma), early Paleozoic (360–500 Ma), and Paleoproterozoic (1600–2500 Ma) age populations. However, significant differences in age composition are also observed among different samples. This study proposes that the detritus of the Dahuangou Formation in the Youjingshan area was mainly derived from the Alxa Block (AB), while that from the Yaogou Formation was sourced from the Yinshan-Daqingshan-Wulashan Orogenic Belt (YDWOB). In contrast, the West Qinling Orogenic Belt (WQOB) and North Qilian Orogenic Belt (NQOB) were identified as the source areas for the Dahuangou and Yaogou Formations in the Quwushan area. Based on a comprehensive comparison of detrital zircon geochronological data of the Permian strata in the OB, three major provenance systems can be identified: the southwestern source area (WQOB and NQOB); the northwestern source area (YDWOB and AB); and the interior source area (YDWOB). During the Permian, the tectonic-sedimentary evolution of the OB was primarily controlled by the combined effects of the Paleo-Asian Ocean (PAO) to the north and the Paleo-Tethys Ocean (PTO) to the south. Differences in the timing and intensity of subduction/collision between the PAO and the PTO resulted in a general paleogeographic pattern of “higher in the north and lower in the south” in the OB. Full article