Search Results (63)

To address the problems of eutrophication exacerbation in water bodies caused by low carbon-to-nitrogen ratio (C/N) wastewater and the limited nitrogen removal efficiency of conventional constructed wetlands, this study proposes the use of biochar (Corncob biochar YBC, Walnut shell biochar HBC, and Manure biochar FBC) coupled with intermittent aeration technology to enhance nitrogen removal in constructed wetlands. Through the construction of vertical flow wetland systems, hydraulic retention time (HRT = 1–3 d) and influent C/N ratios (1, 3, 5) were regulated, before being combined with material characterization (FTIR/XPS) and microbial analysis (16S rRNA) to reveal the synergistic nitrogen removal mechanisms. HBC achieved efficient NH₄⁺-N adsorption (32.44 mg/L, Langmuir R² = 0.990) through its high porosity (containing Si-O bonds) and acidic functional groups. Under optimal operating conditions (HRT = 3 d, C/N = 5), the CW-HBC system achieved removal efficiencies of 97.8%, 98.8%, and 79.6% for NH₄⁺-N, TN, and COD, respectively. The addition of biochar shifted the dominant bacterial phylum toward Actinobacteriota (29.79%), with its slow-release carbon source (TOC = 18.5 mg/g) alleviating carbon limitation. Mechanistically, HBC synergistically optimized nitrogen removal pathways through “adsorption-biofilm (bacterial enrichment)-microzone oxygen regulation (pore oxygen gradient).” Based on technical validation, a dual-track institutionalization pathway of “standards-legislation” is proposed: incorporating biochar physicochemical parameters and aeration strategies into multi-level water environment technical standards; converting common mechanisms (such as Si-O adsorption) into legal requirements through legislative amendments; and innovating legislative techniques to balance precision and universality. This study provides an efficient technical solution for low C/N wastewater treatment while constructing an innovative framework for the synergy between technical specifications and legislation, supporting the improvement of watershed ecological restoration systems. Full article

The gas reservoir of the Sinian Dengying Formation (Member 4) in Sichuan Basin exhibits extensive development of inter-clast dissolution pores and vugs within its carbonate reservoirs, characterized by low porosity (average 3.21%) and low permeability (average 2.19 mD). With the progressive development of the Moxi (MX)structure, the existing stimulation techniques require further optimization based on the specific geological characteristics of these reservoirs. Through large-scale true tri-axial physical simulation experiments, this study systematically evaluated the performance of three principal acid systems in reservoir stimulation: (1) Self-generating acid systems, which enhance etching through the thermal decomposition of ester precursors to provide sustained reactive capabilities. (2) Gelled acid systems, characterized by high viscosity and effectiveness in reducing breakdown pressure (18~35% lower than conventional systems), are ideal for generating complex fracture networks. (3) Diverting acid systems, designed to improve fracture branching density by managing fluid flow heterogeneity. This study emphasizes hybrid acid combinations, particularly self-generating acid prepad coupled with gelled acid systems, to leverage their synergistic advantages. Field trials implementing these optimized systems revealed that conventional guar-based fracturing fluids demonstrated 40% higher breakdown pressures compared to acid systems, rendering hydraulic fracturing unsuitable for MX reservoirs. Comparative analysis confirmed gelled acid’s superiority over diverting acid in tensile strength reduction and fracture network complexity. Field implementations using reservoir-quality-adaptive strategies—gelled acid fracturing for main reservoir sections and integrated self-generating acid prepad + gelled acid systems for marginal zones—demonstrated the technical superiority of the hybrid system under MX reservoir conditions. This optimized protocol enhanced fracture length by 28% and stimulated reservoir volume by 36%, achieving a 36% single-well production increase. The technical framework provides an engineered solution for productivity enhancement in deep carbonate gas reservoirs within the G-M structural domain, with particular efficacy for reservoirs featuring dual low-porosity and low-permeability characteristics. Full article

The innovation of multi-material offers significant benefits to architectural systems. The fusion of multiple materials, transitioning from one to another in a graded manner, enables the creation of fused space without the need for mechanical connections. Given that plastic is a major contributor to ecological imbalance, this research on fused space aims to recycle plastic and use it as a multi-material for building applications, due to its capacity for being 3D printed and fused with other materials. Furthermore, to generate diverse properties for the fused space, several nature-inspired forming algorithms are employed, including Swarm Behavior, Voronoi, Game of Life, and Shortest Path, to shape the building enclosure. Subsequently, digital analyses, such as daylight analysis, structural analysis, porosity analysis, and openness analysis, are conducted on the enclosure, forming the color mapping digital diagram, which determines the distribution of varying thickness, density, transparency, and flexibility gradation parameters, resulting in spatial diversity. During the fabrication process, Dual Force V1 and Dual Force V2 were developed to successfully print multi-material gradations with fused plastic following an upgrade to the cooling system. Finally, three test sites in London were chosen to implement the fused space concept using multi-material. Full article

This study systematically investigates the pore–fracture architecture of deep coal seams in the JiaTan (JT) block of the Ordos Basin using an integrated suite of advanced techniques, including nuclear magnetic resonance (NMR), high-pressure mercury intrusion, low-temperature nitrogen adsorption, low-pressure carbon dioxide adsorption, and micro-computed tomography (micro-CT). These complementary methods enable a quantitative assessment of pore structures spanning nano- to microscale dimensions. The results reveal a pore system overwhelmingly dominated by micropores—accounting for more than 98% of the total pore volume—which play a central role in coalbed methane (CBM) storage. Microfractures, although limited in volumetric proportion, markedly enhance permeability by forming critical flow pathways. Together, these features establish a dual-porosity system that governs methane transport and recovery in deep coal reservoirs. The multiscale characterization employed here proves essential for resolving reservoir heterogeneity and designing effective stimulation strategies. Notably, enhancing methane desorption in micropore-rich matrices and improving fracture connectivity are identified as key levers for optimizing deep CBM extraction. These insights offer a valuable foundation for the development of deep coalbed methane (DCBM) resources in the Ordos Basin and similar geological settings. Full article

The construction industry’s escalating environmental footprint, coupled with the underutilization of construction waste streams, necessitates innovative approaches to sustainable material design. This study investigates the dual functionality of recycled clay brick powder (RCBP) as both a supplementary cementitious material (SCM) and an alkali–silica reaction (ASR) inhibitor in hybrid mortar systems incorporating recycled glass (RG) and recycled clay brick (RCB) aggregates. Leveraging the pozzolanic activity of RCBP’s residual aluminosilicate phases, the research quantifies its influence on mortar durability and mechanical performance under varying substitution scenarios. Experimental findings reveal a nonlinear relationship between RCBP dosage and mortar properties. A 30% cement replacement with RCBP yields a 28-day activity index of 96.95%, confirming significant pozzolanic contributions. Critically, RCBP substitution ≥20% effectively mitigates ASRs induced by RG aggregates, with optimal suppression observed at 25% replacement. This threshold aligns with microstructural analyses showing RCBP’s Al³⁺ ions preferentially reacting with alkali hydroxides to form non-expansive gels, reducing pore solution pH and silica dissolution rates. Mechanical characterization reveals trade-offs between workability and strength development. Increasing RCBP substitution decreases mortar consistency and fluidity, which is more pronounced in RG-RCBS blends due to glass aggregates’ smooth texture. Compressively, both SS-RCBS and RG-RCBS mortars exhibit strength reduction with higher RCBP content, yet all specimens show accelerated compressive strength gain relative to flexural strength over curing time. Notably, 28-day water absorption increases with RCBP substitution, correlating with microstructural porosity modifications. These findings position recycled construction wastes and glass as valuable resources in circular economy frameworks, offering municipalities a pathway to meet recycled content mandates without sacrificing structural integrity. The study underscores the importance of waste synergy in advancing sustainable mortar technology, with implications for net-zero building practices and industrial waste valorization. Full article

Despite their high porosity and wide applicability, silica xerogels face mechanical strength limitations for high-performance applications. This study presents an ambient-pressure sol-gel strategy utilizing calcium-glycerol synergy to produce robust xerogels with enhanced properties. Physicochemical analyses reveal that controlled Ca²⁺ incorporation (optimal at 6 wt.%) accelerates gelation kinetics while establishing a hybrid network through ionic complexation and hydrogen bonding. The resulting xerogels achieve exceptional compressive strength (30.8 MPa) while maintaining uniform mesoporosity (50–90 nm pore size). Remarkably, the as-prepared silica xerogels demonstrate outstanding thermal insulation, maintaining a 220 °C temperature differential in 300 °C environments. These results prove that the ambient-pressure sol-gel strategy utilizing calcium-glycerol synergy can enhance the mechanical performance and thermal insulation performance of silica xerogels with the dual actions of Ca²⁺-induced network reinforcement via silanol coordination and glycerol-mediated stress relief during ambient drying. Overall, this work can offer a scalable, energy-efficient approach to produce high-performance silica xerogels with huge potential in building envelopes and aerospace systems. Full article

The stress sensitivity of shale caprock permeability is a critical factor influencing the long-term security of CO₂ geological sequestration systems. Substantial amounts of clay minerals and nanoscale pore structures reduce shale permeability by trapping water films and throat contraction. Conventional permeability models, which are based on homogeneous pore compressibility, tend to overestimate the contribution of non-effective pores to water mobility, resulting in significant inaccuracies in predicting stress-dependent permeability. Therefore, this study conducted NMR–seepage experiments under varying confining pressures on four shale samples with distinct lithologies to investigate pore compression deformation and permeability stress sensitivity. The T₂ cutoff was subsequently determined through displacement tests to distinguish seepage and adsorption pores. Two distinct constitutive models were calculated with respective compressibility coefficients. Finally, the effects of seepage and adsorption pores on shale permeability stress sensitivity were investigated. The results indicate the following. (1) Increasing confining pressure from 15 to 19 MPa reduces porosity by 14.2–39.6%, with permeability exhibiting a significant decline of 35.6–67.8%. (2) Adsorption pores, stabilized by bound water films of clay minerals, exhibit limited closure under stress. In contrast, seepage pores, influenced by brittle minerals, experience significant deformation, which predominantly contributes to permeability decline. (3) A dual-spring model, differentiating the compressibility of seepage and adsorption pores, reduces prediction errors by 92–96% compared to traditional models. These results highlight that neglecting pore-type-specific compressibility leads to overestimated permeability in heterogeneous shale, with critical implications for optimizing CO₂ storage integrity and hydrocarbon recovery strategies. Full article

The subject of the current paper is cooling heat sinks using the TPMS structure. An experiment was conducted using water and a mixture of 10% vol. ethylene glycol in water, which was used to cool heat sinks in the presence of the TPMS structure. The gyroid was developed using 3D printing with three different porosities: 0.7, 0.8, and 0.9, respectively. The shell network is a single domain, and fluid is circulated at various flow rates. A comparison with the numerical model, as simulated using COMSOL software (version 6.2), showed good agreement. A uniform temperature distribution is a clear indication of uniform cooling. Then, the TPMS structure is changed from one domain to two unconnected domains, and a different flow rate is applied to each domain entry. This approach is unique in that it investigates the cooling of the heat sink with a two-domain structure, which has not been previously studied. The novelty of this paper lies in utilizing two TPMS structure domains to cool the heat sink. Thus, dual-domain TPMS heat sinks are implemented and optimized with separate inlets. Statistical testing of the model for the Nusselt number and the performance evaluation criterion is performed using Fisher’s statistical test to analyze variance (ANOVA). It was found that the cooling heat sink is more accurate with two-domain systems. The average Nusselt number polynomial is found to vary linearly with the two-inlet velocity, the porosity and the fluid Prandtl number. Similar linearity is found for the performance evaluation criterion. The optimum Nusselt number equals 77, the PEC equals 49 for a porosity of 0.85, and the Prandtl number is 36.9. Full article

This study developed a vinyl acetate-ethylene rapid repair mortar (VAE-RRM) by using a binary blended cementitious system (ordinary Portland cement and sulfoaluminate cement) and vinyl acetate-ethylene (VAE) redispersible polymer powder. The effects of the polymer-to-cement ratio (P/C: 0~2.0%) on setting time, mechanical properties, interfacial bonding, and microstructure were systematically investigated. The results reveal that VAE delayed cement hydration via physical encapsulation and chemical chelation, extending the initial setting time to 182 min at P/C = 2.0%. At the optimal P/C = 0.9%, a synergistic organic–inorganic network enhanced flexural strength (14.62 MPa at 28 d, 34.0% increase) and interfacial bonding (2.74 MPa after interface treatment), though compressive strength decreased to 65.7 MPa due to hydration inhibition. Excessive VAE (P/C ≥ 1.5%) suppressed AFt/C-S-H growth, increasing harmful pores (>1 μm) and degrading performance. Microstructural analysis via scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) demonstrates that VAE films bridged hydration products, filled interfacial transition zones (ITZ), and refined pore structures, reducing the most probable pore size from 62.8 nm (reference) to 23.5 nm. VAE-RRM 3 (P/C = 0.9%) exhibited rapid hardening (initial setting time: 75 min), high substrate recovery (83.3%), and low porosity (<10%), offering an efficient solution for urban infrastructure repair. This work elucidates the dual mechanisms of pore refinement and interface reinforcement driven by VAE, providing theoretical guidance for designing high-performance repair materials. Full article

Red mud (RM) is a strongly alkaline waste residue produced during alumina production, and its high alkali and fine particle characteristics are prone to cause soil, water, and air pollution. Phosphogypsum (PG), as a by-product of the wet process phosphoric acid industry, poses a significant risk of fluorine leaching and threatens the ecological environment and human health due to its high fluorine content and strong acidic properties. In this study, RM-based cemented paste backfill (RCPB) based on the synergistic curing of PG and ordinary Portland cement (OPC) was proposed, aiming to achieve a synergistic enhancement of the material’s mechanical properties and fluorine fixation efficacy by optimizing the slurry concentration (63–69%). Experimental results demonstrated that increasing slurry concentration significantly improved unconfined compressive strength (UCS). The 67% concentration group achieved a UCS of 3.60 MPa after 28 days, while the 63%, 65%, and 69% groups reached 2.50 MPa, 3.20 MPa, and 3.40 MPa, respectively. Fluoride leaching concentrations for all groups were below the Class I groundwater standard (≤1.0 mg/L), with the 67% concentration exhibiting the lowest leaching value (0.6076 mg/L). The dual immobilization mechanism of fluoride ions was revealed by XRD, TGA, and SEM-EDS characterization: (1) Ca²⁺ and F⁻ to generate CaF₂ precipitation; (2) hydration products (C-S-H gel and calixarenes) immobilized F⁻ by physical adsorption and chemical bonding, where the alkaline component of the RM (Na₂O) further promotes the formation of sodium hexafluoroaluminate (Na₃AlF₆) precipitation. The system pH stabilized at 9.0 ± 0.3 after 28 days, mitigating alkalinity risks. High slurry concentrations (67–69%) reduced material porosity by 40–60%, enhancing mechanical performance. It was confirmed that the synergistic effect of RM and PG in the RCPB system could effectively neutralize the alkaline environment and optimize the hydration environment, and, at the same time, form CaF₂ as well as complexes encapsulating and adsorbing fluoride ions, thus significantly reducing the risk of fluorine migration. The aim is to improve the mechanical properties of materials and the fluorine-fixing efficiency by optimizing the slurry concentration (63–69%). The results provide a theoretical basis for the efficient resource utilization of PG and RM and open up a new way for the development of environmentally friendly building materials. Full article

Objectives: This study engineered a colon-targeted drug delivery system (CTDS) using the dual pharmaceutical and edible properties of Pueraria lobata to encapsulate Lactobacillus paracasei for Type 2 diabetes mellitus (T2DM) therapy. Methods: The CTDS was designed as a core–shell composite through microwave–hydrothermal engineering, comprising the following: (1) a retrograded starch shell with acid/enzyme-resistant crystallinity to protect probiotics from gastric degradation; (2) a porous cellulose core derived from Pueraria lobata’s natural microstructure, serving as a colonization scaffold for probiotics. Results: Structural characterization confirmed the shell’s resistance to acidic/pancreatic conditions and the core’s hierarchical porosity for bacterial encapsulation. pH/enzyme-responsive release kinetics were validated via fluorescence imaging, demonstrating targeted probiotic delivery to the colon with minimal gastric leakage. In diabetic models, the CTDS significantly reduced fasting blood glucose and improved dyslipidemia, while histopathological analysis revealed restored hepatic and pancreatic tissue architecture. Pharmacologically, the system acted as both a probiotic delivery vehicle and a microbiota modulator, selectively enriching Allobaculum and other short-chain fatty acid (SCFA)-producing bacteria to enhance SCFA biosynthesis and metabolic homeostasis. The CTDS further exhibited direct compression compatibility, enabling its translation into scalable oral dosage forms (e.g., tablets). Conclusions: By integrating natural material engineering, microbiota-targeted delivery, and tissue repair, this platform bridges the gap between pharmaceutical-grade probiotic protection and metabolic intervention in T2DM. Full article

Due to the spatial constraints of underground environments, the spacing between dual-line tunnels in urban metro systems is often limited, leading to potential mutual interference during the operation of trains in closely spaced parallel tunnels. In this study, a twin-tunnel model was developed using PFC2D to simulate the variations in displacement, velocity, porosity, and strain of the T2 structure and its surroundings under eight conditions (F_i = 62.4–131.5 kN, i = 1, 2, 3…, 8), elucidating the static and dynamic responses of the adjacent tunnel structure and its surroundings. The results indicate that the vertical response of T2 sleepers is significantly larger than the horizontal response under the same load. Increasing train loads induce non-uniform deformation in T2 liners, and excessive overloading may result in microcracks or structural failure. The velocity and displacement at the ground surface are substantially more significant than those in the surrounding areas closer to the vibration source, primarily due to the surface amplification effect. The surroundings of the adjacent tunnel experience uneven compressive forces, potentially causing liner separation. Under the A₇ condition, the static and dynamic responses of the tunnel structure and its surroundings sharply decreased due to the combined effects of pressure and train load dynamics. This phenomenon is attributed to the interplay between the pressure effect and the dynamic amplification effect of the train load. It is recommended that the operational train load in practical engineering should not exceed the A₄ condition (92.0 kN). This study can provide a reference for analyzing the static and dynamic responses of twin-tunnel structures under metro overloading conditions. Full article

Coal permeability, a key parameter influencing coalbed methane production and geological storage, is strongly governed by the dual-porosity nature of coal and the stress-dependent evolution of its fracture network. This study investigates the development characteristics of filled and unfilled fractures, and the resulting permeability anisotropy, in typical bright and dull coals from the deep 8# coal seam of the Ordos Basin. Utilizing CT scanning and permeability anisotropy testing, we analyze how fracture development impacts coal permeability and its evolution under stress. Bright coal exhibits a grid-like distribution of mineral-filled fractures with good vertical connectivity, and a complex network of unfilled fractures. In contrast, dull coal displays a scattered distribution of mineral-filled fractures with poor vertical connectivity and a limited number of unfilled fractures. Results indicate an exponential decay trend in permeability with increasing confining pressure, strongly correlated with fracture system development. Permeability also demonstrates significant heterogeneity (face cleat > butt cleat > vertical). Bright coal exhibits a greater permeability decay rate than dull coal, indicating heightened stress sensitivity, while its permeability anisotropy is weaker, aligning with the observed fracture development patterns. Full article

The Carboniferous reservoirs in the northwestern margin of the Junggar Basin exhibit complex lithological assemblages, primarily composed of siltstone, sandy conglomerate, tuff, and igneous rocks. These reservoirs are rich in oil and gas resources but have entered the middle to late stages of development. The reservoir spaces in the Carboniferous system are mainly composed of pores and fractures, resulting in a complex storage system. To provide effective strategies for stabilizing and enhancing production during the middle to late development stages, it is essential to establish a dual-porosity and dual-permeability model based on a clear understanding of lithological distribution patterns. This will facilitate the identification of favorable zones and the proposal of effective development strategies through numerical simulation. The present study systematically identified the lithology of the study area through microscopic lithological identification combined with logging data, conducted reservoir matrix property research under facies constraints, and established a three-dimensional geological model of lithology and physical properties. To more reasonably study the reservoir development process and establish an optimal development plan, a machine learning model for fracture density was trained using imaging logging interpretation results and conventional logging curve data. The model was then utilized to calculate single-well fracture density. Finally, a fracture model of the study area was established based on the collaborative constraints of fracture density and three-dimensional seismic attributes. Using the results of the established dual-porosity and dual-permeability model and production data, reservoir production evaluation and residual oil distribution research were conducted. The results indicate that the southwestern part of the study area features thick sandy conglomerate reservoirs with good physical properties, continuous lateral distribution, and high residual oil content, making it a dominant area favorable for horizontal well development and production. Additionally, reservoir numerical simulation was employed to study enhanced production development strategies. It is recommended to adopt gas–water alternating injection to improve production, with the optimal gas–water injection ratio of 4:1 yielding the maximum reservoir recovery factor. This study provides theoretical and technical support for the development of complex lithologic buried-hill reservoirs in the Carboniferous system of the western margin of the Junggar Basin. Full article

The coupling mechanism between the multi-scale flow mechanisms and the pressure dynamic response of complex fracture networks in fractured tight sandstone gas reservoirs remains unclear. In this study, a mathematical model was developed by incorporating the non-Darcy flow (non-DF) behavior in both matrix and fracture systems within the framework of the embedded discrete fracture model (EDFM). The governing equations were solved numerically through finite volume discretization. By employing numerical well-testing techniques, the dynamic impacts of low-velocity non-DF (matrix domain) and high-velocity non-DF (fracture domain) on the pressure transient response were systematically evaluated. Furthermore, the characteristic patterns of transient pressure responses under different natural fracture development modes were revealed. This study demonstrates that the pressure and pressure derivative (PD) log–log curves of fractured tight sandstone gas wells exhibit a wide opening shape, indicative of complex fracture morphologies. The presence of a threshold pressure gradient in the matrix system results in an upward convex shape in the PD profile, whereas the high-velocity non-DF in the fracture network causes a downward concave characteristic in the derivative curve. The spatial distribution of the natural fracture network significantly influences the response characteristics during the mid-term radial flow stage. As the fracture density decreases, the system gradually transitions toward a dual-porosity medium. This research contributes to the theoretical foundation required for the accurate interpretation of dynamic well tests and the optimization of effective development schemes in gas reservoirs with extremely low permeability. Full article