Search Results (287)

Heavy metal pollution from human activities is an increasing environmental concern. This study investigates the concentrations of Cu, Pb, Zn, Cd, Hg, and As in the coastal seawater offshore of Beihai, Guangxi, in April 2021, and explores their relationships with dissolved inorganic nitrogen, phosphate, and salinity. Our results reveal higher heavy metal concentrations in the northern nearshore waters and lower levels in southern offshore areas, with surface waters generally exhibiting greater enrichment than bottom waters. Surface concentrations show a decreasing trend from the northeast to the southwest, likely influenced by prevailing northeast monsoon winds. While bottom water concentrations decline from the northwest to the southeast, which indicates the influence of riverine runoff, particularly from the Qinzhou Bay estuary. Heavy metal levels in southern Beihai waters are comparable to those in the Beibu Gulf, except for Hg and Zn, which are significantly higher in the water of the Beibu Gulf. Notably, heavy metal concentrations in both Beihai and Beibu Gulf remain considerably lower than those observed in the coastal waters of Guangdong. Overall, Beihai’s coastal seawater meets China’s Class I quality standards. Nonetheless, continued monitoring is essential, especially of the potential ecological impacts of Hg and Zn on marine life. Full article

Cadmium (Cd) is a highly toxic heavy metal that can greatly affect crops and pose a threat to food security. Plant growth-promoting rhizobacteria (PGPR) are capable of alleviating the harm of Cd to crops. In this research, a Cd-tolerant PGPR strain was isolated and screened from the root nodules of semi-wild soybeans. The strain was identified as Pseudomonas sp. strain KM25 by 16S rRNA. Strain KM25 has strong Cd tolerance and can produce indole-3-acetic acid (IAA) and siderophores, dissolve organic and inorganic phosphorus, and has 1-aminocyclopropane-1-carboxylate (ACC) deaminase activity. Under Cd stress, all growth indicators of soybean seedlings were significantly inhibited. After inoculation with strain KM25, the heavy metal stress of soybeans was effectively alleviated. Compared with the non-inoculated group, its shoot height, shoot and root dry weight, fresh weight, and chlorophyll content were significantly increased. Strain KM25 increased the superoxide dismutase (SOD), peroxidase (POD), and catalase (CAT) activities of soybean seedlings, reduced the malondialdehyde (MDA) content, increased the Cd content in the roots of soybeans, and decreased the Cd content in the shoot parts. In addition, inoculation treatment can affect the community structure of endophytic bacteria in the roots of soybeans under Cd stress, increasing the relative abundance of Proteobacteria, Bacteroidetes, Sphingomonas, Rhizobium, and Pseudomonas. This study demonstrates that strain KM25 is capable of significantly reducing the adverse effects of Cd on soybean plants while enhancing their growth. Full article

The formation of acidic goaf water in abandoned coal mines poses significant environmental threats, especially in karst regions where the risk of groundwater contamination is heightened. This study investigates the geochemical processes responsible for the generation of acidic water through batch and column leaching experiments using coal mine surrounding rocks (CMSR) from Yangquan, China. The coal-bearing strata, primarily composed of sandstone, mudstone, shale, and limestone, contain high concentrations of pyrite (up to 12.26 wt%), which oxidizes to produce sulfuric acid, leading to a drastic reduction in pH (approximately 2.5) and the mobilization of toxic elements. The CMSR samples exhibit elevated levels of arsenic (11.0 mg/kg to 18.1 mg/kg), lead (69.5 mg/kg to 113.5 mg/kg), and cadmium (0.6 mg/kg to 2.6 mg/kg), all of which exceed natural crustal averages and present significant contamination risks. The fluorine content varies widely (106.1 mg/kg to 1885 mg/kg), with the highest concentrations found in sandstone. Sequential extraction analyses indicate that over 80% of fluorine is bound in residual phases, which limits its immediate release but poses long-term leaching hazards. The leaching experiments reveal a three-stage release mechanism: first, the initial oxidation of sulfides rapidly lowers the pH (to between 2.35 and 2.80), dissolving heavy metals and fluorides; second, slower weathering of aluminosilicates and adsorption by iron and aluminum hydroxides reduce the concentrations of dissolved elements; and third, concentrations stabilize as adsorption and slow silicate weathering regulate the long-term release of contaminants. The resulting acidic goaf water contains extremely high levels of metals (with aluminum at 191.4 mg/L and iron at 412.0 mg/L), which severely threaten groundwater, particularly in karst areas where rapid cross-layer contamination can occur. These findings provide crucial insights into the processes that drive the acidity of goaf water and the release of contaminants, which can aid in the development of effective mitigation strategies for abandoned mines. Targeted management is essential to safeguard water resources and ecological health in regions affected by mining activities. Full article

Globally, phosphogypsum (PG) is the primary by-product of the phosphorus industry. Aspergillus niger (A. niger), one of the most powerful types of phosphate-solubilizing fungi (PSF), can secrete organic acids to dissolve the phosphates in PG. This study investigated heavy metal (HM) remediation by PG and A. niger under the co-existence of Pb and Cd. It demonstrated that 1 mmol/L Pb²⁺ stimulated the bioactivity of A. niger during incubation, based on the CO₂ emission rate. PG successfully functioned as P source for the fungus, and promoted the growth of the fungal cells. Meanwhile, it also provided sulfates to immobilize Pb in the solution. The subsequently generated anglesite was confirmed using SEM imaging. The immobilization rate of Pb reached over 95%. Under co-existence, Pb²⁺ and 0.01 mmol/L Cd²⁺ maximized the stimulating effect of A. niger. However, the biotoxicity of Pb²⁺ and elevated Cd²⁺ (0.1 mmol/L) counterbalanced the stimulating effect. Finally, 1 mmol/L Cd²⁺ dramatically reduced the fungal activity. In addition, organic matters from the debris of A. niger could still bind Pb²⁺ and Cd²⁺ according to the significantly lowered water-soluble Pb and Cd concentrations. In all treatments with the addition of Cd²⁺, the relatively high biotoxicity of Cd²⁺ induced A. niger to absorb more Pb²⁺ to minimize the sorption of Cd²⁺ based on the XRD results. The functional group analysis of ATR-IR also confirmed the phenomenon. This pathway maintained the stability of Pb²⁺ immobilization using the fungus and PG. This study, hence, shed light on the application of A. niger and solid waste PG to remediate the pollution of Pb and Cd. Full article

High water quality in reservoirs used for drinking water supply and located within protected areas is of crucial importance for sustainable water-resource management. This study aims to evaluate the multi-depth water quality dynamics of the Ribnica Reservoir in western Serbia, combining two standardized assessment tools: the Serbian Water Quality Index (SWQI) and the Canadian Water Quality Index (CWQI). Data collected at various depths during 2021 and 2022 were analyzed to assess physico-chemical parameters and their impact on water quality, while the absence of microbiological data was noted as a limitation affecting the comprehensiveness of the assessment. The SWQI results indicated a general improvement in water quality over time, with values ranging from medium (82) to excellent (95) in 2021 and increasing from good (89) to excellent (98) in 2022. In contrast, the CWQI revealed specific risks, notably elevated concentrations of aluminum, mercury, and chromium, and reduced dissolved oxygen levels, with overall CWQI values ranging from poor (40) to good (88) depending on depth and parameter variability. The study highlights the necessity for continuous, comprehensive monitoring, including microbiological analyses and seasonal assessments, both within the reservoir and in the Crni Rzav River and its tributaries, to better understand pollutant sources and catchment influences. Strengthening microbiological and heavy metal monitoring, along with implementing proactive management strategies, is essential for preserving the Ribnica Reservoir’s ecological integrity and securing its long-term role in drinking water provision. Full article

This study investigated the distribution and source of heavy metals and dispersed elements in the high-salinity brine of Qarhan Salt Lake. The brine with an average total dissolved solid content of 332.22 g/L, dominated by Cl⁻ (216.41 g/L) and Mg²⁺ (44.76 g/L), indicated strong evaporation and dolomite dissolution. As (6.57 ± 3.59 μg/L) and Hg (0.48 ± 0.14 μg/L) showed uniform distribution while Li (69.66 mg/L), B₂O₃ (317.80 mg/L), and Zn (5.69 mg/L) were highly enriched, highlighting the resource potential and geochemical complexity. Correlation analysis revealed that water–rock interaction played a key role in element differentiation, with Sr and Ca²⁺/Cl⁻ showing strong positive correlations (r = 0.693/0.768), reflecting isomorphic substitution and dissolution. Meanwhile, Na⁺ and Mg²⁺/Ca²⁺ showed negative correlations (r = −0.732/−0.889), suggesting cation exchange and gypsum precipitation. The self-organizing map yielded four clusters of elements and positive matrix factorization model identified four sources; the elements in the Salt Lake brine mainly came from the river water supply, weathering and leaching of minerals, and dissolution of salt-bearing layers and were locally influenced by human activities. The research provided valuable insights for future sustainable development and the environmental protection of the region. Full article

This study examined the impact of watering with air and oxygen nanobubble-saturated water (NBSW) on soil moisture retention, electrical conductivity (EC), nutrient leaching, and CO₂ emissions in sandy loam (SL) and silty clay loam (SCL) soils amended with composted sludge (CS). The results revealed that air nanobubbles (air NBs) had greater stability, while oxygen nanobubbles (ONBs) showed lower stability but higher oxygen diffusion potential. Soil moisture under NBSW treatment was more sensitive to changes in ambient conditions and tended to decrease due to higher evaporation compared to conventional water. NBSW was more effective in enhancing moisture in SL soil than in SCL soil. Overall, the results revealed that the application of NBSW tended to increase soil compaction due to stimulation of microbial activity; however, air NBs may temporarily reduce compaction and enhance soil–water interactions. Additionally, NBSW increased soil EC due to increased dissolved ion concentration, with effects more apparent in SL soil than in SCL. This may indicate increased nutrient availability for plant uptake. Notably, NBSW, particularly ONB, showed quick but short-lived changes in soil physical and microbial properties, and soil texture played a significant role in treatment results. Furthermore, the leaching of nutrients and heavy metals remained negligible across all treatments. The study confirms that using NB in controlled environments is more practical for boosting short-term plant growth than improving long-term soil water retention to support more sustainable agriculture systems. Full article

Acid rain alters soil chemistry significantly and is a key driver of heavy metal pollution. This study investigates the environmental impact of acid rain-induced heavy metal migration in the Siding Lead–Zinc mining area in south China. Tailings, surrounding soils, and riverbed sediments were examined through simulated acid rain soil column leaching experiments. Leachate parameters—including pH, redox potential (Eh), total dissolved solids (TDSs) and heavy metal concentrations—were used to develop machine learning models (Random Forest and Support Vector Machine) to quantify the influence of environmental factors on metal migration. The results showed that leachates were generally alkaline and reductive after leaching, with Cd, Pb, and Zn as the dominant migrating metals. Leachates from tailings and nearby soils exceeded safe drinking water standards, with significantly higher cumulative metal release than other samples. The RF model outperformed the SVM model in predicting heavy metal concentrations. Feature importance analysis revealed that, beyond sample characteristics, pH and Eh were critical factors driving metal migration. Zn and Cd showed strong sensitivity to these parameters, with pH and Eh contributing over 80% to their migration. The findings highlight that acid rain can enhance the solubility and migration of heavy metals, posing a serious threat to the quality of surrounding water and underscoring the requirement for effective mitigation strategies to protect the ecological environment in mining areas. Full article

Estuarine ecosystems, characterized by dynamic salinity gradients and complex physicochemical interactions, serve as critical transition zones between freshwater and marine environments. This study investigates the spatial evolution of sediment microbial communities across a freshwater–seawater continuum and their correlations with water quality parameters. Five sampling zones (upstream, midstream, downstream, transition zone, and ocean) were established in a typical estuary (Kuiyu Park, China). High-throughput 16S rRNA sequencing revealed significant shifts in microbial composition, with dominant phyla including Firmicutes, Bacteroidetes, Proteobacteria, and Actinobacteria. Alpha diversity decreased from freshwater to the transition zone but rebounded in seawater, suggesting habitat filtering and niche differentiation. Redundancy analysis identified salinity, dissolved oxygen, nutrients, and heavy metals as key drivers of microbial community structure. Functional predictions highlighted metabolic adaptations such as methanogenesis, sulfur oxidation, and aerobic chemoheterotrophy across zones. This study explores how sediment microorganisms adapt to water quality variations during the freshwater–seawater transition, offering insights into estuarine resilience under global change. These findings elucidate microbial assembly rules in estuarine ecosystems and provide insights for ecological management under global environmental change. Full article

The bioavailability of heavy metals is profoundly influenced by their interactions with active soil components (microorganisms, organic matter, and iron minerals). However, the effects of urease-producing bacteria combined with organo-Fe hydroxide coprecipitates (OFCs) on Cd accumulation in wheat, as well as the mechanisms underlying these effects, remain unclear. In this study, pot experiments integrated with high-throughput sequencing were employed to investigate the impacts of the urease-producing bacterial strain TJ6, ferrihydrite (Fh), and OFCs on Cd enrichment in wheat grains, alongside the underlying soil–microbial mechanisms. The results demonstrate that the strain TJ6-Fh/OFC consortium significantly (p < 0.05) reduced (50.1–66.7%) the bioavailable Cd content in rhizosphere soil while increasing residual Cd fractions, thereby decreasing (77.4%) Cd accumulation in grains. The combined amendments elevated rhizosphere pH (7.35), iron oxide content, and electrical conductivity while reducing (14.5–21.1%) dissolved organic carbon levels. These changes enhanced soil-colloid-mediated Cd immobilization and reduced Cd mobility. Notably, the NH₄⁺ content and NH₄⁺/NO₃⁻ ratio were significantly (p < 0.05) increased, attributed to the ureolytic activity of TJ6, which concurrently alkalinized the soil and inhibited Cd uptake via competitive ion channel interactions. Furthermore, the relative abundance of functional bacterial taxa (Proteobacteria, Gemmatimonadota, Enterobacter, Rhodanobacter, Massilia, Nocardioides, and Arthrobacter) was markedly increased in the rhizosphere soil. These microbes exhibited enhanced abilities to produce extracellular polymeric substances, induce phosphate precipitation, facilitate biosorption, and promote nutrient (C/N) cycling, synergizing with the amendments to immobilize Cd. This study for the first time analyzed the effect and soil science mechanism of urease-producing bacteria combined with OFCs in blocking wheat’s absorption of Cd. Moreover, this study provides foundational insights and a practical framework for the remediation of Cd-contaminated wheat fields through microbial–organic–mineral collaborative strategies. Full article

The influence of petroleum hydrocarbons (PHCs) on the transport and transformation of heavy metals may limit bioremediation efficiency. The mechanisms by which PHC degradation intermediates control heavy metal distribution in calcareous soils from karst areas require further exploration. This study systematically investigated how compositional changes in diesel fuel during aging regulated the fate of Cd and Pb in calcareous soils. The results demonstrated that the low-molecular-weight fractions of diesel fuel (C₁₀−C₁₆) were preferentially degraded. This degradation process altered zeta potential, cation exchange capacity (CEC), and pH, thereby promoting Cd stabilization through electrostatic attraction and speciation transformation. Particularly, reducible Cd content showed a strong positive correlation with C₁₆ content (r = 0.88, p < 0.05). Furthermore, the degradation of C₁₀−C₁₆ fractions caused Pb transformation from residual to bioavailable fractions by stimulating microbial activity. Residual Pb content was positively correlated with C₁₀−C₁₆ fractions (r = 0.55, p < 0.05). Notably, dissolved organic matter (DOM) and CaCO₃ content in calcareous soils enhanced Cd and Pb adsorption, thereby weakening the interactions between these metals and C₁₀−C₁₆ fractions. Consequently, multiple linear regression (MLR) models relying exclusively on C₁₀−C₁₆ degradation parameters showed poor fitting coefficients for Cd/Pb mobility. The present work provides scientific guidance for heavy metal bioremediation in calcareous soils. Full article

Climate change and extreme events such as droughts, heavy rainfall and flooding can influence the water column stratification in reservoir dams, decrease storage capacity, increase sediment and pollutant loads and, as a result, affect water quality. The seasonal variation in the water column stratification of reservoirs is an important parameter for the study of dam life cycle as well as water management and use. In the present study a detailed bathymetric survey was carried out, and a digital elevation model (DEM) of the reservoir was constructed. Seasonal physicochemical monitoring data such as temperature, dissolved oxygen, pH and conductivity are presented. The seasonal thermal stratification was recorded, resulting in an isolated hypolimnion where anoxic layers formed below 17 m in summer and autumn. Manganese and iron concentrations exhibited values higher than 150 mg/L in the anoxic hypolimnion during summer and autumn, indicating solubilization from the sediment. The observed seasonal and depth-dependent variations in physicochemical parameters underline the reservoir’s susceptibility to eutrophication and metal mobilization, particularly during stratified periods. These findings are critical for designing management strategies to mitigate potential water quality issues. Full article

This study investigated the role of indigenous inoculum (primarily sulfur-oxidizing Acidithiobacillus thiooxidans and other acidophilic bacteria) in heavy metal removal from sewage sludge (SS) and anaerobic digested sludge (ADS). Four treatments were evaluated: inoculum + elemental sulfur (S/ADS + E), inoculum alone (S/ADS + B), elemental sulfur alone (S/ADS + S), and a control with no additives. After 7 days of bioleaching, SS and ADS exhibited comparable heavy metal removal rates on Ni (92–98%) and Pb (88–92%), which were significantly more mobilized than Cu (30–44%) and Cr (63–73%). After bioleaching treatment, residual metals in both sludge types were predominantly sequestered in the oxidizable (F3) and residual (F4) fractions, markedly reducing their environmental mobility and pollution risk during land application. The dewaterability performance, assessed via capillary suction time (CST), reached the optimal values in S + E and ADS + E within 24–48 h, after which CST increased alongside rising extracellular polymeric substances and dissolved organic carbon. While the S/ADS + B configuration exhibited marginally reduced Cu, Ni, and Pb removal efficiencies relative to S/ADS + E, it demonstrated superior dewaterability characteristics under equivalent reaction durations. These results suggest that limiting the sulfur (S₀) supply to moderate the growth and activity of autotrophic A. thiooxidans can maintain the bioleaching pH within 2.0–3.0, striking a balance between effective heavy metal removal and favorable dewatering performance. Full article

Harmful heavy metals (HHMs) in marine sediments pose significant ecological and human health risks. This research developed a novel one-dimensional mathematical model to investigate the desorption rates and background concentrations ($C_{bg}$) of HHMs in cohesive sediments of coastal environments, using Cartagena Bay (CB), Colombia, as a reference for estuarine systems. The model integrates mass balance and molecular diffusion equations incorporating porosity and tortuosity. Both the particulate and dissolved phases of HHMs were considered. Numerical experiments were conducted over 28 years with a daily time step, simulating four primary hydrodynamic processes: molecular diffusion, desorption, sedimentation, and turbulent water exchange. The spatiotemporal evolution of $C_{bg}$ provides valuable insights for sediment modeling, policy development, and advancing the understanding of HHM pollution in sediments. Results of the model align closely with empirical data from CB, demonstrating its applicability not only to local conditions but also to similar contaminated areas through a generalized approach. This model can be used as a reliable computational tool for managing coastal environments. Full article

The structural complexity and variability of dissolved organic matter (DOM) significantly affect its binding capacity with heavy metals (HMs). This study evaluated the remediation efficacy of biochar (BC) and humic acid (HA) on Mn- and Cu-contaminated soils using four maize pot treatments: 3% BC (YB3), 6% BC (YB6), 3% BC + 1% HA (YB3H), and 6% BC + 1% HA (YB6H). The results showed that compared to the control (Y), Results showed Mn and Cu concentrations in rhizosphere soil decreased by 11.08–17.76%, while DOM content increased by 44.2–103.83%. BC enhanced DOM aromaticity and humification, further intensified by HA, leading to a more complex and stable DOM structure. PARAFAC identified four DOM components in BC (BC-DOM): C1 (fulvic-like), C2/C3 (humic-like), and C4 (protein-like), and in BC + HA (BC + H-DOM), an enhanced structural complexity with additional aromatic C–H groups was observed. 2D-COS analysis revealed that in BC-DOM, polysaccharides primarily interacted with Mn and Cu, followed by carboxylic acids and phenolic hydroxyl groups, but in BC + H-DOM, aromatic C–H groups preferentially bound Cu before polysaccharides, showing weaker affinity for Mn. These results elucidate the DOM-mediated immobilization mechanisms of BC and HA for HMs, offering insights for soil remediation and carbon sequestration strategies. Full article