Search Results (131)

In this work we investigate the integration possibility of a thermistor paste from ESL (ElectroScience Laboratory, now Vibrantz) to see if it is adapted for Vibrantz Low Temperature Cofired Ceramics (LTCC) L8 and A6M-E materials. An alumina-based sample is used as a reference circuit throughout this study. Square, two-squares-in-parallel and two-squares-in-series thermistors are tested, placed internally and externally. Resistive values are measured in a range from 25 °C to 300 °C. The variation in the resistive values among similar thermistors is significant, with a maximum standard deviation of 67%. However, in all cases, there is a positive linear relationship between resistance and temperature. The Temperature Coefficient of Resistance (TCR) value is calculated before and after annealing. In general, the L8 and Al₂O₃ samples exhibit higher TCR values than the A6M-E sample. Additionally, when placed internally, the TCR value decreases approximately 30% for both tested LTCC materials. An Energy-Dispersive X-ray Spectroscopy (EDX) material analysis has also been conducted on the samples, revealing that the main chemical components are oxide, silicon, calcium, and ruthenium but also some barium and titanium, which indicates SiO₂, TiO₂, BaTiO₃ and RuO₂ oxides in the thermistor paste. The possibility to implement thermistors internally and externally on Vibrantz LTCC without delamination problems is endorsed by this study. Full article

Patients undergo total knee arthroplasty (TKA) at younger ages with the expectation that the devices will perform well over two to three decades. During this time, the ultra-high molecular weight polyethylene (UHMWPE) bearing material properties of the implant may change due to aging induced by radiation and oxygen diffusion or other effects. Vitamin E or other antioxidants are promoted since several years to improve the oxidation resistance of UHMWPE. To compare the effectivity of these substances against established materials, a six weeks aging process was used and the chemical, mechanical and bio-tribological properties were analysed. Highly crosslinked and two weeks aged UHMWPE served as a reference for the currently established aging standards and virgin UHMWPE was aged for six weeks to separate the effects of crosslinking and vitamin E blending. Six weeks artificially aging changed the chemical, mechanical and bio-tribological properties of cross-linked UHMWPE significantly compared to only two weeks artificially aging, leading to cracks and delamination during the highly demanding activities wear test. The degradative effect of extended aging was also observed for virgin UHMWPE. These observations are in good accordance to retrieval findings. Minor changes on the chemical properties were observed for the cross-linked UHWMPE blended with vitamin E without impact on the mechanical and bio-tribological properties. Full article

The Shenduntou Site, a significant Zhou Dynasty settlement in Anhui Province, provides rare insights into early Chinese woodcraft. This study examines exceptionally preserved wooden structures from Well J1, dating to the Western Zhou period (9th–8th c. BCE). Anatomical analysis identified the timber as Firmiana simplex (L.), indicating ancient selection of this locally available species for its water resistance and mechanical suitability in well construction. Comprehensive degradation assessment revealed severe structural deterioration: maximum water content (1100% ± 85% vs. modern 120% ± 8%) demonstrated extreme porosity from hydrolysis; X-ray diffraction (XRD) showed a 69.5% reduction in cellulose crystallinity (16.1% vs. modern 52.8%); Fourier Transform Infrared Spectroscopy (FTIR) spectroscopy confirmed near-total hemicellulose degradation, partial cellulose loss, and lignin enrichment due to chemical recalcitrance; Scanning Electron Microscopy (SEM) imaging documented multiscale damage including vessel thinning, pit membrane loss, and cell wall delamination from hydrolytic, microbial, and mineral degradation. These findings reflect Western Zhou inhabitants’ pragmatic resource utilisation while highlighting advanced material deterioration that poses significant conservation challenges, providing critical insights into Zhou-era woodcraft and human–environment interactions in the lower Yangtze region. Full article

High-Bandwidth Memory (HBM) enables the bandwidth required by modern AI and high-performance computing, yet its three dimensional stack traps heat and amplifies thermo mechanical stress. We first review how conventional solutions such as heat spreaders, microchannels, high density Through-Silicon Vias (TSVs), and Mass Reflow Molded Underfill (MR MUF) underfills lower but do not eliminate the internal thermal resistance that rises sharply beyond 12layer stacks. We then synthesize recent hybrid bonding studies, showing that an optimized Cu pad density, interface characteristic, and mechanical treatments can cut junction-to-junction thermal resistance by between 22.8% and 47%, raise vertical thermal conductivity by up to three times, and shrink the stack height by more than 15%. A meta-analysis identifies design thresholds such as at least 20% Cu coverage that balances heat flow, interfacial stress, and reliability. The review next traces the chain from Coefficient of Thermal Expansion (CTE) mismatch to Cu protrusion, delamination, and warpage and classifies mitigation strategies into (i) material selection including SiCN dielectrics, nano twinned Cu, and polymer composites, (ii) process technologies such as sub-200 °C plasma-activated bonding and Chemical Mechanical Polishing (CMP) anneal co-optimization, and (iii) the structural design, including staggered stack and filleted corners. Integrating these levers suppresses stress hotspots and extends fatigue life in more than 16layer stacks. Finally, we outline a research roadmap combining a multiscale simulation with high layer prototyping to co-optimize thermal, mechanical, and electrical metrics for next-generation 20-layer HBM. Full article

This study addresses the critical challenges of hydrogen permeation and embrittlement in metallic pipelines for hydrogen storage and transportation by developing an epoxy resin-based composite coating with enhanced hydrogen barrier properties. Using cold spray technology, the fabricated coatings with controlled 250–320 μm thicknesses incorporating graphene/ceramic composite particles uniformly dispersed in the epoxy matrix. Microstructural characterization revealed dense morphology and excellent interfacial bonding. Electrochemical hydrogen charging tests demonstrated remarkable hydrogen permeation reduction, showing a strong positive correlation between coating thickness and barrier performance. The optimal 320 μm-thick coating achieved a hydrogen content of only 0.28 ± 0.09 ppm, representing an 89% reduction compared to that in uncoated substrates. The superior performance originates from the Al₂O₃/SiO₂ networks providing physical barriers, graphene offering high-surface-area adsorption sites, and MgO chemically trapping hydrogen atoms. Post-charging analysis identified interfacial stress concentration and hydrogen-induced plasticization as primary causes of ceramic particle delamination. This work provides both fundamental insights and practical solutions for designing high-performance protective coatings in long-distance hydrogen pipelines. Full article

This paper presents a comprehensive analysis of recent advancements in the application of thermal spraying techniques to enhance the durability and wear resistance of agricultural machinery components, with a particular focus on disc harrow assemblies. Given the harsh conditions under which tillage tools operate—characterized by abrasive wear, impact stresses, and chemical exposure from various soil types—thermal sprayed coatings have emerged as a viable solution to extend the service life of these components. The study discusses various deposition methods, particularly Atmospheric Plasma Spraying (APS), and evaluates their effectiveness in creating high-performance surface layers that resist wear, corrosion, and mechanical degradation. The review also summarizes experimental and field test results for coatings based on materials such as NiCrBSi, WC-Co-Cr, TiO₂, Al₂O₃, Cr₂O_3, and ceramic–metal composites, highlighting their significant improvements in hardness, friction reduction, and resistance to delamination and oxidation. The paper highlights research using thermal spraying techniques, especially APS for agricultural applications, with emphasis mostly on components intended for soil processing and requiring good resistance to abrasive wear. Full article

Over the last two decades, the use of photovoltaic panels for the production of electricity has increased significantly, which leads to the need to solve the problems concerning the decommissioning and disposal of the panels and the development of appropriate technologies for their recycling. One of the key steps in this process is the separation of the tempered glass layer. Various technologies and devices are known for separating the glass of the solar panel by cutting it with a knife, as well as other instruments, with the different methods being based on mechanical, chemical, and thermal processes and accordingly having their own advantages and disadvantages. This article proposes an innovative approach for the mechanical delamination of solar panels using a metal wire heated by Joule heating, with the potential to become an energy-efficient, economical, and environmentally friendly method. This publication presents results from experiments using this type of tool to separate the layers of solar panels. Photos from a thermal camera are presented, showing the heat distribution in the panel and the reached operating temperature of the heated metal wire, necessary to soften the EVA bonding layer. Full article

The corrosion thinning behavior and mechanism of low-alloy water wall tubes of an ultra-supercritical power plant was investigated via SEM, EPMA, XRD, TEM, and laboratory simulation experiments. Fireside corrosion was first initiated by chemical potential- and concentration-governed transportation and diffusion, sequentially facilitated by sensitization, which was observed by TEM in terms of the carbide matrix precipitation on the grain boundary, and finally accelerated by the kinetic controlled growth, leading to the final thinning behavior. Laboratory experiments revealed that the reduced atmosphere corrosion kinetic simulation followed the linear law, as well as a different corrosion scale structure layer, compared to the furnace corrosion sample; the reduced atmosphere condition in the laboratory experiment inhibited the oxidation process and layer growth. The frequent shift between the oxidizing and reducing properties of the atmosphere around the water wall tubes during boiler operation may contribute to the delaminated oxidation layer. Full article

This article outlines the method of creating electrodes for electrochemical sensors using hybrid nanostructures composed of graphene and conducting polymers with insertion of gold nanoparticles. The technology employed for graphene dispersion and support stabilization was based on the chemical vapor deposition technique followed by electrochemical delamination. The method used to obtain hybrid nanostructures from graphene and conductive polymers was drop-casting, utilizing solutions of P3HT, PANI-EB, and F8T2. Additionally, the insertion of gold nanoparticles utilized an innovative dip-coating technique, with the graphene-conducting polymer frameworks submerged in a HAuCl₄/2-propanol solution and subsequently subjected to controlled heating. The integration of gold nanoparticles differs notably, with P3HT showing the least adhesion of gold nanoparticles, while PANI-EB exhibits the highest. An inkjet printer was employed to create electrodes with metallization accomplished through the use of commercial silver ink. Notable variations in roughness (grain size) result in unique behaviors of these structures, and therefore, any potential differences in the sensitivity of the generated sensing structures can be more thoroughly understood through this spatial arrangement. The electrochemical experiments utilized a diluted sulfuric acid solution at three different scan rates. The oxidation and reduction potentials of the structures seem fairly alike. Nevertheless, a notable difference is seen in the anodic and cathodic current densities, which appear to be largely influenced by the active surface of gold nanoparticles linked to the polymeric grains. The graphene–PANI-EB structure with Au nanoparticles showed the highest responsiveness and will be further evaluated for biomedical applications. Full article

A testing method is developed to evaluate the acceleration- and strain-based fatigue life of a thermal interface layer in the high-cycle fatigue regime. The methodology adopts vibration-based fatigue testing, where adhesively bonded beams are excited at their resonant frequency under variable amplitude loading using an electrodynamic shaker. Fatigue failure is monitored through shifts in modal frequency and modal damping. Key findings include the identification of a 4% frequency shift as the failure criterion, corresponding to macro-delamination. The thickness of the thermal interface material influences acceleration-based fatigue life, decreasing by a factor of 0.2 when reduced from 0.3 mm to 0.15 mm and increasing by 5.5 when increased to 0.5 mm. Surface quality has a significant impact on both acceleration-based and strain-based fatigue curves. Beams from chemically etched aluminum–magnesium alloy specimens exhibit a sevenfold increase in fatigue life compared to beams from untreated printed circuit boards. Strain-based fatigue life increases with temperature, with a 0.2 reduction at $-40$ °C and an eightfold increase at $100$ °C relative to $23$ °C. The first principal strain ${\epsilon }_{1,\mathrm{rms}}$ is validated as a reliable local damage parameter, effectively characterizing fatigue behavior across varying TIM thicknesses. Full article

Microfluidic technology is an emerging interdisciplinary field that uses micropipes to handle or manipulate tiny fluids in chemistry, fluid physics, and biomedical engineering. As one of the rapid prototyping methods, the three-dimensional (3D) printing technique, which is rapid and cost-effective and has integrated molding characteristics, has become an important manufacturing technology for microfluidic chips. Polymethyl-methacrylate (PMMA), as an exceptional thermoplastic material, has found widespread application in the field of microfluidics. This paper presents a comprehensive process study on the fabrication of fused deposition modeling (FDM) 3D-printed PMMA microfluidic chips (chips), encompassing finite element numerical analysis studies, orthogonal process parameter optimization experiments, and the application of 3D-printed integrated microfluidic reactors in the reaction between copper ions and ammonium hydroxide. In this work, a thermal stress finite element model shows that the printing platform temperature was a significant printing parameter to prevent warping and delamination in the 3D printing process. A single printing molding technique is employed to fabricate microfluidic chips with square cross-sectional dimensions reduced to 200 μm, and the microchannels exhibited no clogging or leakage. The orthogonal experimental method of 3D-printed PMMA microchannels was carried out, and the optimized printing parameter resulted in a reduction in the microchannel profile to Ra 1.077 μm. Finally, a set of chemical reaction experiments of copper ions and ammonium hydroxide are performed in a 3D-printed microreactor. Furthermore, a color data graph of copper hydroxide is obtained. This study provides a cheap and high-quality research method for future research in water quality detection and chemical engineering. Full article

Copper alloys are widely used in many branches of industry due to their excellent corrosion resistance and high level of both electrical conductivity and strength. Among others, there are copper alloys with magnesium, which are known and commonly used with Mg content of up to 0.7 wt.%. Here, we study Cu-Mg alloys with 2.8 wt.% and 3.2 wt.% of Mg, the properties of which are yet to be determined. One of these is the fatigue strength of materials, which is crucial for maintaining the long-term and safe operation of wires in engineering applications. Fatigue is a process during which materials are subjected to cyclic stress below the ultimate tensile strength of materials, leading to their damage or failure. In the current paper, CuMg2.8 and CuMg3.2 wires were obtained using a laboratory chain drawbench and an industrial drum-type drawing machine to verify the influence of manufacturing technology on the fatigue strength of materials. The obtained results were correlated with analogically obtained copper wires by taking into consideration the influence of the chemical composition, structure of fractures, stress and manufacturing technology. It was discovered that it is possible to obtain wires regardless of the drawing machine type and the concentration of Mg. However, CuMg3.2 wires obtained in the industrial conditions experienced delamination and brittle fractures during unwinding from the drum, and thus, their use was not possible. Full article

Epoxy resin is regarded as a reliable option for coating advanced materials owing to its outstanding strength, adhesion, and stability. However, its relatively weak toughness compared to common materials has limited its application. In this study, the toughness of epoxy resin was enhanced by incorporating bamboo fibers, and a novel polymer coating material for bamboo-fiber-reinforced epoxy resin was developed. Different fiber pretreatment methods were employed to address the issue of poor interfacial performance between bamboo fibers and epoxy resin, aiming to optimize its performance as an advanced material coating. The effects of curing agents, fiber mesh sizes, fiber contents, and fiber pretreatment methods on the mechanical properties of the fiber-modified resin composites were investigated. The findings indicate that the JH45 and T31 curing agents were more effective in promoting the homogeneous dispersion of fibers within the epoxy resin. Additionally, bamboo fibers modified with KH550 exhibited enhanced interfacial properties: the tensile strength of the composite demonstrated a respective increase of 31.1% and 27.0% compared to untreated fibers. Increasing the mesh size proved advantageous for improving tensile properties, albeit potentially impacting the compressive properties. Particularly noteworthy was the significantly enhanced interfacial compatibility between bamboo fibers treated with the silane coupling agent KH550 and the epoxy resin. Analysis using Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray diffraction (XRD) revealed that treating bamboo fibers with sodium hydroxide effectively enhanced bonding at the fiber–resin interface. This enhancement was attributed to the combined effects of bamboo fiber hydrolysis and delamination reactions. The silane coupling agent promoted the chemical reaction between bamboo fibers and epoxy resin through grafting, thereby strengthening the cross-linking property of the composites. These findings offer valuable insights into the design and fabrication of natural-fiber-reinforced polymer composites suitable for coating advanced materials. Full article

Epoxy composites play a crucial role in modern materials technologies, with their exceptional properties such as high strength and thermal and chemical resistance, making them ideal for a wide range of industrial applications, including aerospace, automotive, construction, and energy. This review article provides a comprehensive overview of the current trends and advancements in epoxy composites, focusing on mechanical properties and their optimization. Attention is given to technological innovations, including the use of nanotechnologies, hybrid reinforcement, and eco-friendly materials, which are key to enhancing the performance and sustainability of these materials. The analysis shows that the introduction of nanomaterials, such as graphene, titanium dioxide, and silicon dioxide, can significantly improve the strength, fatigue resistance, and electrical properties of epoxy composites, opening new possibilities in advanced technologies. Another significant contribution is the development of hybrid composites, which combine different types of fibers, such as carbon, aramid, and glass fibers, enabling the optimization of key properties, including interlayer strength and delamination resistance. The article also highlights the importance of environmental innovations, such as bio-based resins and self-healing mechanisms, which enable more sustainable and long-term effective use of composites. The combination of theoretical knowledge with practical applications provides valuable guidance for designing materials with precisely defined properties for future industrial use. This text thus offers a comprehensive view of the possibilities of epoxy composites in the context of increasing demands for performance, reliability, and environmental sustainability. Full article

Colored polymer microspheres have attracted significant attention in both academia and industry due to their unique optical properties and extensive application potential. However, achieving a uniform distribution of dyes within these microspheres remains a challenge, particularly when heavy concentrations of dye are used, as this can lead to aggregation or delamination, adversely affecting their application. Additionally, many dyes are prone to degradation or fading when exposed to light, heat, or chemicals, which compromises the long-term color stability of the microspheres. Consequently, the preparation of colored polymer microspheres with high stability continues to be a significant challenge. This review offers a comprehensive overview of the preparation techniques for colored polymer microspheres and their dyeing mechanisms, introducing the fundamental concepts of these microspheres and their applications in various fields, such as biomedicine, optical devices, and electronic display technologies. It further presents a detailed discussion of the different preparation methods, including physical adsorption, chemical bonding, and copolymerization. The advantages, limitations, and potential improvements of each method are explored, along with an analysis of the interactions between dyes and the polymer matrix, and how these interactions influence the properties of the microspheres, including their color uniformity, stability, and durability. Finally, the review discusses future perspectives on the development of colored polymer microspheres, highlighting the advancement of novel materials, innovations in preparation technology, and the exploration of potential new application areas. Full article