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Keywords = centrifugal film

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17 pages, 5896 KiB  
Article
Simulation Study of the Effect of Oil Injection Speed on the Air Curtain of High-Speed Bearings
by Yanfang Dong, Botao Ye, Zibo Yan, Hai Zhang, Wei Yu, Jianyong Sun and Wenbo Zhou
Lubricants 2025, 13(8), 334; https://doi.org/10.3390/lubricants13080334 - 30 Jul 2025
Viewed by 225
Abstract
In order to improve the lubrication efficiency in the bearing cavity, this study establishes a simulation model of the fluid domain of the bearing cavity based on the computational fluid dynamics (CFD) method and systematically studies the flow characteristics of the lubricant and [...] Read more.
In order to improve the lubrication efficiency in the bearing cavity, this study establishes a simulation model of the fluid domain of the bearing cavity based on the computational fluid dynamics (CFD) method and systematically studies the flow characteristics of the lubricant and its lubrication mechanism in the high-speed rotary bearing. In the process of high-speed bearing operation, the lubricant is subject to the combined effect of centrifugal force and contact pressure, gradually spreads to both sides of the steel ball, and forms a stable oil film after injection from the nozzle. However, due to the influence of high pressure distribution in the contact area, the actual formation of the oil film coverage is relatively limited. In order to further optimize the lubrication effect, this study focuses on investigating the influence law of different injection speeds and rotational speeds on the bearing air curtain effect. The results of the study show that when the air curtain effect is enhanced, there will be significant shear interference on the trajectory of the lubricant, which is manifested in the phenomenon of “buckling” at the end of the lubricant, thus reducing the lubrication efficiency. To address this problem, this study innovatively proposes the air curtain obstruction coefficient K as a quantitative evaluation index, and through numerical simulation, it is found that the lubricant can effectively overcome the air curtain obstruction and achieve a better lubrication coverage when the value of K is reduced to below 0.4. Based on this finding, the study further confirmed that the lubrication efficiency of bearings can be significantly improved under different operating conditions by rationally regulating the injection rate. Full article
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20 pages, 4487 KiB  
Article
Investigation on Corrosion-Induced Wall-Thinning Mechanisms in High-Pressure Steam Pipelines Based on Gas–Liquid Two-Phase Flow Characteristics
by Guangyin Li, Wei He, Pengyu Zhang, Hu Wang and Zhengxin Wei
Processes 2025, 13(7), 2096; https://doi.org/10.3390/pr13072096 - 2 Jul 2025
Viewed by 316
Abstract
In high-pressure thermal power systems, corrosion-induced wall thinning in steam pipelines poses a significant threat to operational safety and efficiency. This study investigates the effects of gas–liquid two-phase flow on corrosion-induced wall thinning in pipe bends of high-pressure heaters in power plants, with [...] Read more.
In high-pressure thermal power systems, corrosion-induced wall thinning in steam pipelines poses a significant threat to operational safety and efficiency. This study investigates the effects of gas–liquid two-phase flow on corrosion-induced wall thinning in pipe bends of high-pressure heaters in power plants, with particular emphasis on the mechanisms of void fraction and inner wall surface roughness. Research reveals that an increased void fraction significantly enhances flow turbulence and centrifugal effects, resulting in elevated pressure and Discrete Phase Model (DPM) concentration at the bend, thereby intensifying erosion phenomena. Simultaneously, the turbulence generated by bubble collapse at the bend promotes the accumulation and detachment of corrosion products, maintaining a cyclic process of erosion and corrosion that accelerates wall thinning. Furthermore, the increased surface roughness of the inner bend wall exacerbates the corrosion process. The rough surface alters local flow characteristics, leading to changes in pressure distribution and DPM concentration accumulation points, subsequently accelerating corrosion progression. Energy-Dispersive Spectroscopy (EDS) and Scanning Electron Microscopy (SEM) analyses reveal changes in the chemical composition and microstructural characteristics of corrosion products. The results indicate that the porous structure of oxide films fails to effectively protect against corrosive media, while bubble impact forces damage the oxide films, exposing fresh metal surfaces and further accelerating the corrosion process. Comprehensive analysis demonstrates that the interaction between void fraction and surface roughness significantly intensifies wall thinning, particularly under conditions of high void fraction and high roughness, where pressure and DPM concentration at the bend may reach extreme values, further increasing corrosion risk. Therefore, optimization of void fraction and surface roughness, along with the application of corrosion-resistant materials and surface treatment technologies, should be considered in pipeline design and operation to mitigate corrosion risks. Full article
(This article belongs to the Section Chemical Processes and Systems)
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17 pages, 13043 KiB  
Article
Lubrication Performance Promotion of GTL Base Oil by BN Nanosheets via Cascade Centrifugation-Assisted Liquid-Phase Exfoliation
by Jiashun Liu, Shuo Xiang, Xiaoyu Zhou, Shigang Lin, Kehong Dong, Yiwei Liu, Donghai He, Yunhong Fan, Yuehao Liu, Bingxue Xiong, Kai Ma, Kaiyang Xiao, Genmao Luo, Qinhui Zhang and Xin Yang
Lubricants 2025, 13(7), 281; https://doi.org/10.3390/lubricants13070281 - 23 Jun 2025
Viewed by 376
Abstract
Broad lateral size and thickness distributions impede the application of hexagonal boron nitride nanosheets (BNNSs) as friction modifiers in base oil, although they possess remarkable potential for lubrication performance promotion. In this work, a cascade centrifugation-assisted liquid-phase exfoliation approach was presented to prepare [...] Read more.
Broad lateral size and thickness distributions impede the application of hexagonal boron nitride nanosheets (BNNSs) as friction modifiers in base oil, although they possess remarkable potential for lubrication performance promotion. In this work, a cascade centrifugation-assisted liquid-phase exfoliation approach was presented to prepare BNNSs from hexagonal boron nitride (h-BN) efficiently and scalably. Subsequently, they were ultrasonically dispersed into gas-to-liquid (GTL) base oil, and their lubrication performance promotion was evaluated by a four-ball tribotester. Tribological tests demonstrated that BNNS possesses excellent friction-reducing and anti-wear properties in GTL. Furthermore, the findings indicate that at a BNNS content of 0.8 wt.%, the system displayed the lowest COF and WSD. Particularly, with an addition of 0.8 wt.% BNNS into GTL, the AFC and WSD are reduced significantly by 40.1% and 35.4% compared to pure base oil, respectively, and the surface roughness, wear depth, and wear volume were effectively reduced by 91.0%, 68.5%, and 76.8% compared to GTL base oil, respectively. Raman, SEM-EDS, and XPS results proved that the outstanding friction-reducing and anti-wear properties of BNNS can mainly be ascribed to the presence of physical adsorption film and tribo-chemical film, which were composed of FeOOH, FeO, Fe3O4, and B2O3. Full article
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15 pages, 2522 KiB  
Article
Effect of the Addition of Banana Stem Lignin (Musa acuminata ssp. balbisiana var. Dominico-Harton) on the Physicochemical Properties of Biodegradable Composites Based on Methylhydroxyethylcellulose
by Yonier Alejandro Ocampo-Gómez, Fabian Rico-Rodríguez, Rafael González-Cuello, Joaquín Hernández-Fernández and Rodrigo Ortega-Toro
J. Compos. Sci. 2025, 9(5), 244; https://doi.org/10.3390/jcs9050244 - 15 May 2025
Viewed by 584
Abstract
This study analyses the effect of lignin extracted from the Dominico-Harton banana on the physicochemical properties of biodegradable methylhydroxyethylcellulose (MHEC) composites. Lignin was obtained by grinding and sieving, followed by treatment with sulphuric acid and subsequent separation via centrifugation. Films were developed using [...] Read more.
This study analyses the effect of lignin extracted from the Dominico-Harton banana on the physicochemical properties of biodegradable methylhydroxyethylcellulose (MHEC) composites. Lignin was obtained by grinding and sieving, followed by treatment with sulphuric acid and subsequent separation via centrifugation. Films were developed using the casting method, incorporating lignin and glycerol in a matrix of MHEC dissolved in distilled water. They were characterised according to their physical, barrier, mechanical, optical, and antioxidant properties, using 2,2-diphenyl-1-picrylhydrazyl (DPPH) and 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid (ABTS). The results showed that lignin provides antioxidant capacity and improves mechanical and barrier properties, while MHEC contributes flexibility and biodegradability. These films have a dense and resistant structure, with potential applications in food packaging, agriculture, and medicine. The research highlights the use of agricultural waste to develop sustainable materials as an alternative to conventional plastics. Full article
(This article belongs to the Special Issue Sustainable Biocomposites, 3rd Edition)
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17 pages, 15459 KiB  
Article
Integrated CFD and Experimental Analysis on Slinger Ring Condensate Discharge Mechanism for Energy-Efficient Window Air Conditioners
by Chin Hyuk Chang, Adarsh Rajasekharan Nair, Man Yeong Ha, Hyun Sik Yoon and Seok Beom Hong
Energies 2025, 18(7), 1622; https://doi.org/10.3390/en18071622 - 24 Mar 2025
Cited by 1 | Viewed by 459
Abstract
As global demand for energy-efficient cooling technologies grows, optimizing window air conditioners (WACs) is crucial. This study integrates computational fluid dynamics (CFD) and experimental fluid dynamics (EFD) to analyze condensate transport induced by the slinger ring in a WAC system. To investigate condensate [...] Read more.
As global demand for energy-efficient cooling technologies grows, optimizing window air conditioners (WACs) is crucial. This study integrates computational fluid dynamics (CFD) and experimental fluid dynamics (EFD) to analyze condensate transport induced by the slinger ring in a WAC system. To investigate condensate behavior, the WAC domain is divided into six regions based on the slinger ring’s rotational direction and impact. In the initial impact zone, large liquid structures adhere to the slinger ring before breaking into ligaments. In the upward transport region, condensate films rise along the wall due to centrifugal forces, forming short ligaments. In the rebound region, condensate impacts the top surface and transitions into droplets. In the accumulation zone, droplet coalescence occurs in a confined space, leading to localized mass buildup. In the dispersion region, condensate spreads widely due to increased rotational speed. In the splash zone, splashing and wave-like structures form near the reservoir surface. A newly identified mechanism of condensate mass discharge shows that mass ejection is concentrated in four key regions near the condenser coils. These findings offer insights into optimizing a slinger ring design for improved condensate dispersion. Future research should explore airflow variations and alternative slinger ring configurations to enhance WAC performance. Full article
(This article belongs to the Section G: Energy and Buildings)
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25 pages, 5486 KiB  
Article
Study on the Dynamic Modeling of Two-Phase Flow and Lubrication Characteristics of Toothless Stirring Oil Pans
by Yiming Huang, Man Ge and Gaoan Zheng
Processes 2025, 13(3), 829; https://doi.org/10.3390/pr13030829 - 12 Mar 2025
Viewed by 612
Abstract
The toothless oil stirring disk is vital in modern transmission technology, particularly in fields like aviation, aerospace, and nuclear power, significantly impacting equipment performance. Oil-stirring lubrication is widely used in internal systems due to its simplicity and high reliability, but oil-stirring losses during [...] Read more.
The toothless oil stirring disk is vital in modern transmission technology, particularly in fields like aviation, aerospace, and nuclear power, significantly impacting equipment performance. Oil-stirring lubrication is widely used in internal systems due to its simplicity and high reliability, but oil-stirring losses during lubrication contribute to increased system temperatures, affecting lifespan and performance. Accurate simulation of the two-phase flow during the lubrication process of high-speed toothless oil stirring disks is crucial for extending the lubrication system service life. This paper proposes a dynamic modeling approach for the lubrication of high-speed toothless oil stirring disks, integrating the volume of fluid (VOF) model and the RNG k-ε turbulence model, alongside spring smoothing and dynamic mesh reconstruction techniques. The model explores fluid flow and oil distribution in high-speed, toothless oil stirring pans, investigating the effects of different stirring pan speeds and oil heights on lubrication performance. Results indicate that stirring pan speed and oil height are key to improving lubrication efficiency. At high speeds, centrifugal force and gravity cause the lubricating oil to detach from the stirring pan surface, continuing to splash due to inertia. At 3200 r/min and an oil level of 20 mm, a stable oil film forms in the gearbox. Higher stirring pan speeds generate greater turbulence, enhancing lubrication effectiveness. The findings offer theoretical insights for dynamic lubrication system modeling and support gearbox design and optimization in aerospace and similar fields. Full article
(This article belongs to the Section AI-Enabled Process Engineering)
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21 pages, 6841 KiB  
Article
Effect of Centrifugal Load on Residual Stresses in Nickel-Based Single-Crystal Substrate and Thermal Barrier Coating System
by Liming Yu, Yifei Zhang, Rujuan Zhao, Yi Wang and Qingmin Yu
Processes 2025, 13(1), 269; https://doi.org/10.3390/pr13010269 - 18 Jan 2025
Viewed by 924
Abstract
Thermal barrier coatings (TBCs) and air film-cooling technology have been extensively utilized in nickel-based, single-crystal turbine blades to enhance their heat resistance. However, structural complexity and material property mismatches between layers can affect residual stresses and potentially lead to coating failure. In this [...] Read more.
Thermal barrier coatings (TBCs) and air film-cooling technology have been extensively utilized in nickel-based, single-crystal turbine blades to enhance their heat resistance. However, structural complexity and material property mismatches between layers can affect residual stresses and potentially lead to coating failure. In this study, a three-dimensional finite element model with atmospheric plasma-spraying thermal barrier coatings (APS-TBCs) deposited on air-cooled, nickel-based, single-crystal blades was established to investigate residual stress character under centrifugal load, considering the effect of temperature, crystal orientation deviation angle, oxide layer thickness, and the number of cycles. The results show that when the centrifugal load is increased from 300 MPa to 700 MPa, the absolute value of the residual stress at the crest of the interface between Top Coat (TC) and Thermally Grown Oxide (TGO) increases by only 8.5%, whereas in the region of compressive to tensile stress conversion, residual stress decreases by 100.9%. As the crystal orientation deviation angle increases, the absolute value of the residual compressive stress increases and the absolute value of the residual tensile stress decreases, but the performance is more special in the valley region, where the absolute value of the residual stress increases with the increase in the deviation angle. Special attention is required, as the increase in temperature leads to a rise in the absolute value of residual stress. For example, at the trough of the TC–TGO interface, when the temperature increases from 910 °C to 1100 °C, the residual stress increases by 9.8%. The effect of the number of cycles on residual stress is relatively weak. For instance, at the wave crest of the TC–TGO interface, the residual stress differs by only 0.6 MPa between one cycle and three cycles. The effect of oxide layer thickness on residual stress in the TBCs after a single cycle is nonlinear. When the oxide layer thickness is 0, 4, and 7 μm, the residual stress undergoes a transition between tensile and compressive directions at different locations. The exploration of these results has yielded some valuable laws that can provide a reference for the study of the damage mechanism of TBCs, as well as a guide for the optimization of nickel-based turbine blades in the manufacturing and use processes. Full article
(This article belongs to the Section Materials Processes)
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12 pages, 804 KiB  
Article
Development of Vitamin C-Enriched Oral Disintegration Films Using Chia Mucilage
by Simone Canabarro Palezi, Juliana Machado Latorres, Sibele Santos Fernandes and Vilásia Guimarães Martins
Processes 2025, 13(1), 250; https://doi.org/10.3390/pr13010250 - 16 Jan 2025
Viewed by 1281
Abstract
Oral disintegration films (ODFs) offer a convenient alternative for administering active compounds with quick absorption, no need for water, customizable formulation, and promising pharmaceutical applications. This study aimed to develop chia mucilage films as a new polymer to carry vitamin C. Chia mucilage [...] Read more.
Oral disintegration films (ODFs) offer a convenient alternative for administering active compounds with quick absorption, no need for water, customizable formulation, and promising pharmaceutical applications. This study aimed to develop chia mucilage films as a new polymer to carry vitamin C. Chia mucilage was extracted using the method of immersing the seeds in water, separated by vacuum filtration and using a sieve to remove the mucilaginous gel, then centrifuged and finally freeze-dried, with the mucilage obtained being used to produce films using the casting technique. The formulations included a control and a 1% vitamin C variant, with glycerol as a plasticizer. The produced films showed high solubility, pH close to the oral and a disintegration time of 53.17 s for the formulation with 1% vitamin C. The presence of vitamin C in the polymer matrix, as well as the interactions between them, were confirmed by DSC and FTIR spectra. On the first day of storage, after 1 min of reaction at 30 °C, the vitamin C concentration obtained was 477.50 mg/g, while at 40 °C was 411.28 mg/g. After 35 days of storage, the films showed a reduction in vitamin C concentration. Chia mucilage proved to be a promising polymer in the production of ODFs carrying vitamin C. Full article
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21 pages, 3403 KiB  
Article
Extraction of Purple Prickly Pear (Opuntia ficus-indica) Mucilage by Microfiltration, Composition, and Physicochemical Characteristics
by María Carmen Fernández-Martínez, Cristian Jiménez-Martínez, Mónica Rosalía Jaime-Fonseca and Liliana Alamilla-Beltrán
Polymers 2024, 16(23), 3383; https://doi.org/10.3390/polym16233383 - 30 Nov 2024
Cited by 5 | Viewed by 2946
Abstract
Mucilages are valuable to the food industry, but the solvents used to extract and concentrate them are detrimental to the environment. Therefore, environmentally friendly technologies that preserve the properties of biopolymers and reduce the use of solvents are being sought. In this work, [...] Read more.
Mucilages are valuable to the food industry, but the solvents used to extract and concentrate them are detrimental to the environment. Therefore, environmentally friendly technologies that preserve the properties of biopolymers and reduce the use of solvents are being sought. In this work, the mucilage of Opuntia ficus-indica (mesocarp–endocarp) was extracted by two methods: In the first one, the pulp from the mesocarp–endocarp was extracted by ethanol precipitation and centrifugation cycles, then dried at room temperature. For the second, the pulp was processed in a three-step tangential microfiltration process: microfiltration (separation), diafiltration (purification), and concentration. The mucilages obtained differed significantly (p < 0.05) in color, betalains, total sugars, and proteins. The proportions of insoluble and soluble dietary fiber were similar. GC/MS analysis identified seven neutral sugars and a high content of uronic acids (31.3% in the microfiltered mucilage and 47.5% in the ethanol-precipitated mucilage). These show a low degree of esterification, which gives them a polar and hydrophilic character and the possibility of interacting with divalent ions through the carboxylic acid groups, which could form gels stabilized by an egg-box mechanism, with application as a thickening, stabilizing, gelling, or film-forming agent for foods with low sugar content. Full article
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22 pages, 956 KiB  
Article
Theory of Gas Purification by Liquid Absorber in Small Rotating Channels with Application to the Patented Rotational Absorber Device
by J. J. H. Brouwers
Separations 2024, 11(12), 338; https://doi.org/10.3390/separations11120338 - 26 Nov 2024
Viewed by 851
Abstract
A new design for absorbing vapour-phase impurities from gases is presented. It consists of small channels packed in a rotating vertical cylinder. Gas flows through the channels adjacent to a thin film of absorber liquid. The liquid film is pressed to the radially [...] Read more.
A new design for absorbing vapour-phase impurities from gases is presented. It consists of small channels packed in a rotating vertical cylinder. Gas flows through the channels adjacent to a thin film of absorber liquid. The liquid film is pressed to the radially outward side of each channel by the centrifugal force and flows downwards by gravity. Formulae are presented which describe the concentration distributions of gaseous impurities subject to absorption in gas and liquid. Results include expressions for laminar and turbulent diffusion coefficients to be used in mass balance equations. The role of rotation is quantified including the effect on wavy motion and enhanced diffusion in the liquid layer. Application in design is indicated for the case of separation of the greenhouse gas CO2 from flue gases of fossil fuel combustion processes. At other equal dimensions, the height of the Rotational Absorber Device is calculated to be 25 times shorter than the enormous heights of conventional tray and packed columns. Full article
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29 pages, 4541 KiB  
Article
Impact of Soot on Internal Combustion Engine Lubrication—Oil Condition Monitoring, Tribological Properties, and Surface Chemistry
by Adam Agocs, Marcella Frauscher, Andjelka Ristic and Nicole Dörr
Lubricants 2024, 12(11), 401; https://doi.org/10.3390/lubricants12110401 - 20 Nov 2024
Cited by 2 | Viewed by 1324
Abstract
In the study at hand, a systemic investigation regarding the tribochemical effects of crankcase soot is presented. Sooted oils were generated via an engine dynamometer test. Both conventional as well as advanced oil condition monitoring methods indicated a mild degradation of additives. The [...] Read more.
In the study at hand, a systemic investigation regarding the tribochemical effects of crankcase soot is presented. Sooted oils were generated via an engine dynamometer test. Both conventional as well as advanced oil condition monitoring methods indicated a mild degradation of additives. The wear volume was greatly increased with the sooted oils in model tribometer tests, despite the high residual zinc dialkyl dithiophosphate (ZDDP) antiwear (AW) levels. Once the soot was removed via ultracentrifugation, the wear volume returned to levels comparable to the fresh oil. Surface investigations revealed that ZDDP tribofilms could not form in the sooted oils, as only a thin sulfide layer was present on the metal surfaces. Meanwhile, typical tribofilms were observable with centrifuged oils. The results indicated that a tribocorrosive mechanism is most likely responsible for the elevated wear in the sooted oils, where only the iron sulfide base layer of ZDDP films is formed, which is then rapidly removed by the soot particles in an abrasive manner. Full article
(This article belongs to the Special Issue Recent Advances in Automotive Powertrain Lubrication)
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19 pages, 19678 KiB  
Article
Optimizing Thermoplastic Starch Film with Heteroscedastic Gaussian Processes in Bayesian Experimental Design Framework
by Gracie M. White, Amanda P. Siegel and Andres Tovar
Materials 2024, 17(21), 5345; https://doi.org/10.3390/ma17215345 - 31 Oct 2024
Cited by 1 | Viewed by 2129
Abstract
The development of thermoplastic starch (TPS) films is crucial for fabricating sustainable and compostable plastics with desirable mechanical properties. However, traditional design of experiments (DOE) methods used in TPS development are often inefficient. They require extensive time and resources while frequently failing to [...] Read more.
The development of thermoplastic starch (TPS) films is crucial for fabricating sustainable and compostable plastics with desirable mechanical properties. However, traditional design of experiments (DOE) methods used in TPS development are often inefficient. They require extensive time and resources while frequently failing to identify optimal material formulations. As an alternative, adaptive experimental design methods based on Bayesian optimization (BO) principles have been recently proposed to streamline material development by iteratively refining experiments based on prior results. However, most implementations are not suited to manage the heteroscedastic noise inherently present in physical experiments. This work introduces a heteroscedastic Gaussian process (HGP) model within the BO framework to account for varying levels of uncertainty in the data, improve the accuracy of the predictions, and increase the overall experimental efficiency. The aim is to find the optimal TPS film composition that maximizes its elongation at break and tensile strength. To demonstrate the effectiveness of this approach, TPS films were prepared by mixing potato starch, distilled water, glycerol as a plasticizer, and acetic acid as a catalyst. After gelation, the mixture was degassed via centrifugation and molded into films, which were dried at room temperature. Tensile tests were conducted according to ASTM D638 standards. After five iterations and 30 experiments, the films containing 4.5 wt% plasticizer and 2.0 wt% starch exhibited the highest elongation at break (M = 96.7%, SD = 5.6%), while the films with 0.5 wt% plasticizer and 7.0 wt% starch demonstrated the highest tensile strength (M = 2.77 MPa, SD = 1.54 MPa). These results demonstrate the potential of the HGP model within a BO framework to improve material development efficiency and performance in TPS film and other potential material formulations. Full article
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33 pages, 7096 KiB  
Review
Processing and Properties of Polyhydroxyalkanoate/ZnO Nanocomposites: A Review of Their Potential as Sustainable Packaging Materials
by Mieke Buntinx, Chris Vanheusden and Dries Hermans
Polymers 2024, 16(21), 3061; https://doi.org/10.3390/polym16213061 - 30 Oct 2024
Cited by 3 | Viewed by 2639
Abstract
The escalating environmental concerns associated with conventional plastic packaging have accelerated the development of sustainable alternatives, making food packaging a focus area for innovation. Bioplastics, particularly polyhydroxyalkanoates (PHAs), have emerged as potential candidates due to their biobased origin, biodegradability, and biocompatibility. PHAs stand [...] Read more.
The escalating environmental concerns associated with conventional plastic packaging have accelerated the development of sustainable alternatives, making food packaging a focus area for innovation. Bioplastics, particularly polyhydroxyalkanoates (PHAs), have emerged as potential candidates due to their biobased origin, biodegradability, and biocompatibility. PHAs stand out for their good mechanical and medium gas permeability properties, making them promising materials for food packaging applications. In parallel, zinc oxide (ZnO) nanoparticles (NPs) have gained attention for their antimicrobial properties and ability to enhance the mechanical and barrier properties of (bio)polymers. This review aims to provide a comprehensive introduction to the research on PHA/ZnO nanocomposites. It starts with the importance and current challenges of food packaging, followed by a discussion on the opportunities of bioplastics and PHAs. Next, the synthesis, properties, and application areas of ZnO NPs are discussed to introduce their potential use in (bio)plastic food packaging. Early research on PHA/ZnO nanocomposites has focused on solvent-assisted production methods, whereas novel technologies can offer additional possibilities with regard to industrial upscaling, safer or cheaper processing, or more specific incorporation of ZnO NPs in the matrix or on the surface of PHA films or fibers. Here, the use of solvent casting, melt processing, electrospinning, centrifugal fiber spinning, miniemulsion encapsulation, and ultrasonic spray coating to produce PHA/ZnO nanocomposites is explained. Finally, an overview is given of the reported effects of ZnO NP incorporation on thermal, mechanical, gas barrier, UV barrier, and antimicrobial properties in ZnO nanocomposites based on poly(3-hydroxybutyrate), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), and poly(3-hydroxybutyrate-co-3-hydroxyhexanoate). We conclude that the functionality of PHA materials can be improved by optimizing the ZnO incorporation process and the complex interplay between intrinsic ZnO NP properties, dispersion quality, matrix–filler interactions, and crystallinity. Further research regarding the antimicrobial efficiency and potential migration of ZnO NPs in food (simulants) and the End-of-Life will determine the market potential of PHA/ZnO nanocomposites as active packaging material. Full article
(This article belongs to the Special Issue Processing, Characterization and Modeling of Polymer Nanocomposites)
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14 pages, 1664 KiB  
Article
Flexible Highly Thermally Conductive PCM Film Prepared by Centrifugal Electrospinning for Wearable Thermal Management
by Jiaxin Qiao, Chonglin He, Zijiao Guo, Fankai Lin, Mingyong Liu, Xianjie Liu, Yifei Liu, Zhaohui Huang, Ruiyu Mi and Xin Min
Materials 2024, 17(20), 4963; https://doi.org/10.3390/ma17204963 - 11 Oct 2024
Cited by 2 | Viewed by 1391
Abstract
Personal thermal management materials integrated with phase-change materials have significant potential to satisfy human thermal comfort needs and save energy through the efficient storage and utilization of thermal energy. However, conventional organic phase-change materials in a solid state suffer from rigidity, low thermal [...] Read more.
Personal thermal management materials integrated with phase-change materials have significant potential to satisfy human thermal comfort needs and save energy through the efficient storage and utilization of thermal energy. However, conventional organic phase-change materials in a solid state suffer from rigidity, low thermal conductivity, and leakage, making their application challenging. In this work, polyethylene glycol (PEG) was chosen as the phase-change material to provide the energy storage density, polyethylene oxide (PEO) was chosen to provide the backbone structure of the three-dimensional polymer network and cross-linked with the PEG to provide flexibility, and carbon nanotubes (CNTs) were used to improve the mechanical and thermal conductivity of the material. The thermal conductivity of the composite fiber membranes was boosted by 77.1% when CNTs were added at 4 wt%. Water-resistant modification of the composite fiber membranes was successfully performed using glutaraldehyde-saturated steam. The resulting composite fiber membranes had a reasonable range of phase transition temperatures, and the CC4PCF-55 membranes had melting and freezing latent heats of 66.71 J/g and 64.74 J/g, respectively. The results of this study prove that the green CC4PCF-55 composite fiber membranes have excellent flexibility, with good thermal energy storage capacity and thermal conductivity and, therefore, high potential in the field of flexible wearable thermal management textiles. Full article
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24 pages, 3185 KiB  
Article
Dynamic Coefficient Investigation for Supercritical Carbon Dioxide Dry Gas Seal Based on Complete Variable Perturbation Model
by Ruqi Yan, Baodui Chai, Lu Ma, Hanqing Chen and Xuexing Ding
Lubricants 2024, 12(9), 298; https://doi.org/10.3390/lubricants12090298 - 23 Aug 2024
Cited by 1 | Viewed by 1055
Abstract
In this work, a new model to analyse the dynamic characteristic coefficient of the S-CO2 dry gas seal was reported. Taking into account that the flow within the S-CO2 dry gas seal is close to adiabatic flow, the impact of the [...] Read more.
In this work, a new model to analyse the dynamic characteristic coefficient of the S-CO2 dry gas seal was reported. Taking into account that the flow within the S-CO2 dry gas seal is close to adiabatic flow, the impact of the temperature change on the dynamic characteristic coefficient of the gas film cannot be ignored. To address this issue, a complete variable perturbation model (CVPM) under the adiabatic flow process was established using the frequency perturbation method while considering multiple complex effects. Then, the finite difference method was used to solve the CVPM. The gas film’s dynamic stiffness and damping coefficients were calculated and analysed for different conditions, operating parameters, and frequency ratios. From our analysis, it was demonstrated that the dynamic coefficient of the gas film exhibited frequency dependence. The turbulence coefficient perturbation had the most remarkable influence on the gas film’s dynamic coefficient, compared to the temperature, viscosity, and centrifugal inertia force perturbations. The isothermal flow, adiabatic flow, inlet pressure, and inlet temperature also affected the magnitude of the dynamic characteristic coefficient of the gas film. However, no significant impact on their tendency to vary with the frequency ratio was found. Our work provides new theoretical support for the dynamic analysis of S-CO2 dry gas seals, which is of great importance for future applications. Full article
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