Search Results (117)

The shear strength–suction (here suction induced from unsaturation) relationship is inherently challenging, yet this difficulty is compounded for cemented crushable sands, whose behavior fundamentally diverges from classical clay-centric theories. This paper presents an innovative teaching case study focusing on colloidal-silica-cemented calcareous sand, based on direct shear tests across a full saturation range (0–100%). Our experimental findings reveal two unconventional characteristics that challenge textbook models: (1) suction strength exhibits a positive dependency on normal stress—an inverse trend to conventional expectations; and (2) strength near desiccation drops below saturated values, contradicting the monotonic increasing function typically observed in clays. A review of 20 existing models confirms that none of them can simultaneously capture both features, highlighting a clear gap in both theory and instruction. To address this gap pedagogically, the core novelty of this work lies in the development of a classroom-friendly predictive model that introduces two physical innovations: first, it incorporates normal-stress-dependent suction strength by modifying capillary condensation probability—departing from constant-angle assumptions; second, it accounts for desiccation-induced strength deterioration through a gel crack size effect, which is absent in conventional unsaturated strength formulations. The model retains clear physical interpretability and demonstrates strong agreement with experimental data. By integrating unconventional behavior, model limitations, and novel physically inspired formulations into a coherent case study, this work equips students not only to recognize deviations from classical unsaturated strength theory but also to construct their own mechanistic models in geotechnical engineering education. Full article

This systematic research was conducted as the first comprehensive scientific analysis of ancient lime plaster samples from Anuradhapura, a World Heritage Site in Sri Lanka. Five ancient heritage sites from 1st to 10th Century AD, covering two stupa domes: Abhayagiri (AP01) and Jethavana (AP02), Monk residence building near Ruwanweliseya Stupa (AP03), Deeghapashan Rock Shelter Building of Abhayagiri Monastery Complex (AP04), and Vessagiriya Rock Shelter wall lime Plaster (AP05) were examined by employing Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray fluorescence (XRF), thermogravimetric analysis (TGA), optical microscopy (OM), scanning electron microscopy (SEM) and gas chromatography-mass spectrometry (GC-MS). The current work investigated the composition, mineralogical and microstructural properties, binding media, and organic additives. Our findings indicate that calcareous lime from seashells and river sand are the main raw materials, with ratios of 1:2.7, 1:2.0, 1:2.4, 1:4.4, and 1:3.7 for the AP01, AP02, AP03, AP04, and AP05 samples, respectively. Data also suggest that plant-based materials, mainly wood apple wax, along with nanoscale fibrous materials, were used as the main additives to enhance the properties of lime plasters. This study provides insights into the raw materials, their mixing ratios, and the techniques employed in the lime plastering of ancient Anuradhapura City, and serves as a scientific reference for the conservation and restoration of ancient buildings resilient to climate change. Full article

Geosynthetics-reinforced soil technology represents an innovative reinforcement method for calcareous sand foundations and revetment engineering in coral reef areas. The interaction response at the reinforced soil interface directly influences the safety and stability of reinforced soil structures. However, research on the interaction mechanisms between geosynthetics and calcareous sand interfaces remains insufficient. Therefore, this paper investigates the effects of different normal stresses and various interface types on the shear characteristics of the geosynthetics–calcareous sand interface through a series of large-scale monotonic direct shear tests. By integrating statistical damage theory and accounting for the influence of residual strength, we establish the constitutive relation for interface damage. The results indicate that the shear stress–displacement curves for both the geosynthetics–calcareous sand interface and the unreinforced calcareous sand exhibit softening behavior. Furthermore, the relationship between the interface shear modulus and horizontal displacement for the geogrid–calcareous sand and unreinforced calcareous sand adheres to a power function model, while the relationship for the geotextile–calcareous sand follows a logarithmic function model. In the structural design of geosynthetics-reinforced calcareous sand, it is crucial to consider the influence of residual shear strength on structural stability. This study proposes a statistical damage constitutive model that accounts for the strain-softening characteristics of the geosynthetics–calcareous sand interface, while also considering the impact of residual strength. The findings provide a theoretical basis for the stability analysis of geosynthetics-reinforced calcareous sand structures in coral reefs with significant engineering implications for island reef construction, coastal development, and bank slope protection projects. Full article

The city of Veracruz preserves buildings mainly constructed during the 16th and 17th centuries, where carved madreporic coral was used as ashlar and as a component in mortars. These historic structures, now part of Mexico’s built heritage, show various degrees of deterioration caused by erosion and prolonged exposure to environmental elements. Restoration using original materials is currently nearly impossible due to ecological restrictions protecting coral reefs. In this context, and under the principles of the tailor-made technique, the present research revisits physico-mechanical and chemical studies conducted on the corals used in the construction of one of the most representative buildings in the city. The results were compared with those obtained from the formulation of experimental mortars using readily available materials—such as air lime, siliceous aggregates, and calcium carbonate—with the aim of reproducing the physical, mechanical, and chemical properties observed in the original corals. Laboratory tests allowed evaluation of their compatibility and performance, seeking to develop alternative materials that enable conservation interventions without compromising the integrity of the base material or the historic structures. The design of mortars is intended to be used in the restoration processes of buildings that are part of the built historical heritage. This is the starting point for understanding the characteristics of the mortar and its compatibility with the substrate, which could be used for repairing stone blocks and for preparing new mortars for masonry and plastering, since research on restoration mortars has largely overlooked this type of building with coral masonry due to its rarity. Therefore, this research is of particular interest. The mixtures formulated with calcareous sand were the most compatible with the reference coral material, while those made with silica sand exhibited properties superior to the corals, and marine sands showed very poor behavior, potentially compromising the integrity of the buildings. In physical–mechanical tests, formulations that include calcareous sand and silica sand (2 mm) demonstrated behavior closest to that of coral, consistent with chemical analysis results, where mortars formulated with calcareous sand registered the highest contents of CaO and portlandite. Mercury intrusion porosimetry indicated that the mortar formulated with silica sand (2 mm) has a porosity only 4.07% lower than that of the coral, while mortars formulated with calcareous sand and lime paste are between 11.17% and 16.87% lower. Therefore, one of the mixtures that stands out as the best option due to its similarity in physical–mechanical and chemical results is the composite that is not found at the extremes of the results obtained in the various tests carried out. The use of calcareous sand, as previously mentioned, enhances its behavior and affinity with the coral masonry, as demonstrated in the tests. Full article

Island reef road construction faces a complex marine service environment characterized by high salinity and high humidity. Meanwhile, rapid construction and prompt subgrade repair are urgently required, creating a strong demand for novel calcareous-sand-based stabilization materials that combine excellent mechanical performance with resistance to seawater erosion. To this end, this study developed an early-strength cemented calcareous-sand reinforcement material for road base construction. Sulfoaluminate cement (SAC) and ferrite-aluminate cement (FAC), both featuring rapid setting/early strength development and superior corrosion resistance, were used to cement calcareous sand (CS) and to investigate its mechanical and microstructural characteristics under different water environments. Unconfined compressive strength tests (UCS) showed that SC-CS and FC-CS could meet subgrade requirements at 1 d and 7 d, with SC-CS and FC-CS reaching 3.12 MPa and 3.44 MPa at 1 d, and 3.26 MPa and 3.67 MPa at 7 d, respectively, under seawater SS conditions. Seawater mixing and immersion were found to promote the early strength and stiffness development of both SC-CS and FC-CS, with a more pronounced effect observed for FC-CS. Based on experimental results, a damage model for the stabilized specimens was established with a fitting accuracy of R² > 0.97. This constitutive model accurately describes the stress–strain relationship of the material and quantitatively characterizes its damage evolution. Microscopic XRD and SEM analyses indicated that the main hydration product in freshwater-cured specimens was ettringite, and the interparticle connection of CS was dominated by bridging through rod-like ettringite. In contrast, under seawater conditions, the ettringite content decreased, while hydrotalcite and calcium aluminate hydrate increased, forming massive and lamellar bridging products. Compared with SC-CS, the bridging structure in FC-CS was denser. Moreover, the compactness of the bridging structure not only affected its mechanical properties but also governed the movement mode of CS particles, thereby influencing the damage evolution and failure mode of the specimens. The findings provide theoretical support for the construction needs of island road. Full article

The Donghe Sandstone in the Tarim Basin represents marine littoral deposits. Cyclical variations in hydrodynamic conditions during sedimentary evolution led to the widespread development of intercalations/interbeds within the reservoir, which directly impact hydrocarbon development. It is imperative to elucidate the genesis, types, and distribution of these intercalations, and to reveal their controlling effect on residual oil. Based on detailed core observations, the genesis and classification of interbeds in the study area were determined. A three-dimensional cross-plot method was employed to establish interbed identification criteria, and architectural element analysis was used to predict their spatial distribution. Results indicate that interbeds in the study area can be classified into muddy interbeds, calcareous interbeds, and calcareous-muddy interbeds. The heterogeneity of interlayer and intralayer interbeds and sand body connectivity were systematically characterized. This enabled the prediction of distribution patterns and styles of different interbeds within the coastal-plain reservoir, as well as the relationship between residual oil and interbeds. Production practice shows that residual oil is mainly distributed in high-position well areas. This solves the problem of declining reservoir production in the Hadson Oilfield caused by interbed distribution and provides a reference for predicting residual oil distribution in marine coastal sedimentary oilfields. Full article

Land subsidence in the Yellow River Floodplain, approaching 60 mm/year, is severely exacerbated by annual groundwater oscillations of 3 to 8 m. Conventional hydro-mechanical models, which primarily rely on effective stress principles, often struggle to fully capture the moisture-induced structural degradation of calcareous cemented soils under such hydraulic disturbances. To address this theoretical gap, we conducted a multifactor orthogonal triaxial experiment to quantitatively decouple the macroscopic factors governing the hydro-mechanical degradation. The results reveal that moisture content acts as the absolute dominant driver, accounting for 81.65% of the variance in macroscopic shear strength variance and completely overwhelming the mechanical advantages provided by initial compaction. A generalized dual-path water-sensitive damage model was explicitly derived, mathematically uncovering a fundamental asynchronous degradation mechanism. Cohesion exhibits an inward-concave, brittle fracture trajectory, which is macroscopically inferred to be associated with the water-induced softening of calcareous bonds (phase-transition parameter 0.81, maximum allocation 75.1%). Conversely, the internal friction angle demonstrates an outward-convex, hysteretic decline (parameter 1.59), maintaining structural interlocking until severe water-film lubrication occurs. By decoupling highly state-dependent initial strength parameters from invariant degradation operators, the modified Mohr–Coulomb model achieved exceptional forward blind-prediction accuracy. Validations across distinct initial skeletal structures constrained relative prediction errors strictly between −19.3% and +13.7% without any subjective parameter recalibration. The quantified extreme vulnerability theoretically proves that minor water infiltration can instantly eradicate over 75% of cohesive strength, necessitating a paradigm shift from shallow mechanical compaction to stringent waterproofing in regional engineering practices. Full article

This study investigates the mechanical behavior of polyurethane (PU)-stabilized calcareous sand with varying PU contents and relative sand densities using unconfined compression and direct shear tests. The results demonstrate that PU stabilization significantly enhances compressive and shear strength and induces a transition from brittle to ductile failure with increasing PU content. Strength and stiffness exhibit nonlinear growth as an interconnected polymer bonding network develops. Relative density controls the timing and efficiency of strength mobilization, with dense specimens strengthening earlier and loose specimens exhibiting accelerated strength development at higher PU contents. SEM and XRD analyses confirm that stabilization is dominated by a bonding–solidification mechanism, without altering the mineralogical composition. Overall, PU stabilization provides an effective approach for achieving rapid strength development and stable mechanical performance in calcareous sand. Full article

Due to the complex mesostructure of calcareous sand, accurately predicting the mechanical response of Asphalt-Bonded Calcareous Sand (ABCS) is extremely challenging. This study pioneers the development of a mesoscale model for ABCS that explicitly incorporates the Interfacial Transition Zone (ITZ) via a random particle algorithm. To overcome the efficiency bottlenecks of traditional time-domain integration, this study establishes a mesoscale framework coupling a random polygonal aggregate algorithm with direct Steady-State Dynamics (SSD) analysis. A major advantage of this framework is its capacity for large-scale parametric sensitivity analysis; herein, 920 independent mesoscale models were generated and rapidly solved across the broadband frequency domain. The framework was rigorously validated, demonstrating high predictive accuracy for both the baseline calibration and an independent 12% asphalt content mixture (baseline R² = 0.99, MAPE = 6.94%; independent validation R² = 0.96, MAPE = 9.73%). Notably, the SSD approach completes calculations (10⁻³ to 10³ Hz) for 10 massive 300 mm RVEs in just 6.5 min. Leveraging this high-throughput capability, the extensive parametric analysis reveals that variations in maximum aggregate size negligibly impact the dynamic modulus under a constant volume fraction. Conversely, an optimal Interfacial Transition Zone (ITZ) thickness of ~75 µm was identified, representing a physical equilibrium between interfacial reinforcement and bulk binder cohesion. Furthermore, an analytical RVE size criterion of 1.7–5.3 times the maximum aggregate size is proposed to satisfy a 5% engineering error tolerance, providing a highly efficient numerical tool for the virtual mix design of reef pavements. Full article

Neltuma juliflora (Sw.) Raf. (syn. = Prosopis juliflora (Sw.) DC.) is among the world’s most aggressive woody invaders, yet its ecological impacts remain poorly quantified in hyper-arid environments, where soils are calcareous and ecosystems recover slowly from disturbance. In this study, we tested two hypotheses: (1) the presence of N. juliflora changes native plant diversity, as well as soil and key physicochemical properties in hyper-arid Qatar, and (2) agricultural farms act as primary sources of N. juliflora invasion. Using a comparative observational design across 62 sites (45 invaded and 17 non-invaded), we applied a generalised additive model (GAM) and a generalised linear mixed model (GLMM) to quantify invasion drivers and the impact of invasion on perennial species diversity, respectively. Additionally, we used the Wilcoxon rank-sum test to compare the soil properties in the invaded and non-invaded sites. Our results indicate that N. juliflora is positively associated with farms, with the probability of occurrence declining by ca. 20% for each kilometre farther away from agricultural farms. This pattern suggests substantial propagule pressure from agricultural farms. Perennial species richness declined from 7.5 species at 0% N. juliflora cover to 4.8 species at full cover (36% reduction). Invaded sites were characterised by higher amounts of coarse sand (16%); reduced silt–clay fractions (5%); and elevated salinity indicators, including electrical conductivity (0.744 dS m⁻¹) and total dissolved solids (476 mg L⁻¹), while major N–P–K pools remained unchanged. These findings demonstrate measurable invasion-related changes in soil conditions and native perennial diversity in hyper-arid ecosystems and highlight the role of agricultural land use as a key driver of biological invasion. From a sustainability perspective, early detection, targeted control near agricultural and grazing zones, and integration of invasive species monitoring into land-use planning frameworks are essential to prevent further ecosystem degradation, protect biodiversity, and enhance the resilience of desert landscapes under increasing climate and land-use pressures. Full article

Dynamic characterization of calcareous (carbonate) sands is essential for performance-based design of offshore foundations, coastal reclamation, and marine infrastructure in tropical and subtropical regions. In contrast to silica sands, carbonate sediments are biogenic and typically comprise angular, irregular grains with intra-particle voids and fragile skeletal microstructure. These traits promote grain crushing and fabric evolution at relatively low-to-moderate confinement, leading to pronounced stress dependency, strong nonlinearity with strain amplitude, and substantial scatter in laboratory stiffness and damping measurements. Consequently, empirical correlations calibrated primarily on quartz sands may yield biased estimates when transferred to carbonate environments. This study presents an ML-driven, leakage-aware benchmarking framework for predicting two key dynamic parameters of biogenic calcareous sands, damping ratio $D$ and shear modulus $G$, using standard tabular descriptors commonly available in geotechnical practice. Two consolidated experimental databases were curated from resonant column and cyclic triaxial measurements ($D$: $n=890$; $G$: $n=966$), spanning mean effective confining stress $25 \le {\sigma }_m^{\prime }\le 1600 \mathrm{k}$Pa and a wide range of density and gradation conditions. To emphasize transferability, explicit deposit/site labels were excluded, and missingness arising from heterogeneous reporting was handled through a consistent preprocessing pipeline (training-only imputation, categorical encoding, and scaling). Eleven regression algorithms were evaluated, covering linear baselines, regularized regression, neighborhood learning, single trees, bagging and boosting ensembles, kernel regression, and a feedforward neural network. Performance was assessed using $R^2$, RMSE, and MAE on training/validation/test splits, and engineering credibility was supported through explainability-based diagnostics to verify mechanically plausible sensitivities. Results show that ensemble-tree models (Extra Trees and Random Forest) provide the most reliable accuracy–robustness balance across both targets, consistently outperforming linear models and the tested SVR configuration and exhibiting stable validation-to-test behavior. The explainability audit confirms physically meaningful separation of governing controls: stiffness is primarily stress-controlled (${\sigma }_m^{\prime }$ dominant for $G$), whereas damping is primarily strain-controlled ($\gamma$ dominant for $D$). The proposed framework supports practical deployment as a fast surrogate for generating $G\hspace{0.17em}-\hspace{0.17em}\gamma$ and $D\hspace{0.17em}-\hspace{0.17em}\gamma$ curves within the training domain and for guiding targeted laboratory test planning in carbonate settings. Full article

Spatial variability within soil profiles can substantially influence plant growth and productivity by modifying soil water and nutrient availability. In this study, we evaluated the relationship between soil physicochemical properties and productivity in a young almond orchard established on a Calcaric Solimovic Regosol under Mediterranean conditions. The soil profile comprised three horizons showing marked variability in depth and texture. Based on these differences, the experimental plot was divided into two zones: Zone A, characterized by a thicker upper horizon and a lower proportion of sand in the subsoil, and Zone B, with a thinner topsoil and higher sand content in the buried horizon. Within each zone, the almond cultivars ‘Marta’ and ‘Marinada’ were planted in a balanced design using two rootstocks: INRA GF-677 and GARNEM^®. Almond productivity was the parameter most strongly affected by soil heterogeneity, showing pronounced differences among soil zones and rootstock–cultivar combinations. Almond productivity followed the sequence Marta > Marinada/GF-677 > Marinada/GARNEM^®, and was reduced in Zone B by 37%, 68%, and 72%, respectively, compared with Zone A. In contrast, soil zones had no significant effect on leaf and kernel mineral nutrient concentrations, which varied mainly according to cultivar. Full article

To overcome the high cost, marine ecological risks of traditional coral sand reinforcement, and the insufficient mechanical performance of standalone Enzyme-Induced Carbonate Precipitation (EICP), this study proposes a novel soil improvement method integrating EICP with aluminum chloride hexahydrate (AlCl₃·6H₂O). The objectives are to identify optimal EICP curing parameters, evaluate AlCl₃·6H₂O’s enhancement effect, and reveal the synergistic micro-mechanism. Through aqueous solution, unconfined compressive strength, permeability, X-ray diffraction (XRD), nuclear magnetic resonance (NMR), and Scanning Electron Microscope (SEM) tests, this study systematically investigated the reaction conditions, mechanical properties, anti-seepage performance, mineral composition, and pore structure. The results demonstrate that EICP achieves the best curing effect under specific conditions: temperature of 30 °C, pH of 8, and cementing solution concentration of 1 mol/L. Under these optimal conditions, the unconfined compressive strength of EICP-solidified coral sand columns reaches 761.6 kPa, and the permeability coefficient is reduced by one order of magnitude compared to unsolidified samples. Notably, AlCl₃·6H₂O incorporation yields a significant synergistic effect, boosting the UCS to 2389.1 kPa (3.14 times standalone EICP) and further reducing permeability by 26%. Micro-mechanism analysis reveals that AlCl₃·6H₂O acts both by generating cementitious aggregates that provide nucleation sites for uniform calcite deposition and by accelerating the transformation of metastable aragonite and vaterite to stable calcite, thereby enhancing cementation stability. This study delivers a cost-effective, eco-friendly solution for coral sand reinforcement, providing practical technical support for marine engineering in environments like the South China Sea. By addressing the core limitations of conventional bio-cementation, it opens new avenues for advancing soil improvement science and applications. Full article

Coastal lakes are highly vulnerable transitional systems in which sedimentological processes and benthic ecological conditions jointly control contaminant accumulation and preservation, particularly in densely urbanized settings. A robust understanding of the physical and ecological characteristics of bottom sediments is therefore essential for the correct interpretation of contaminant distributions, including those of potentially toxic metals. In this study, an integrated sedimentological–ecological approach was applied to Lake Ganzirri, a Mediterranean shallow coastal lake located in northeastern Sicily (Italy), where recent investigations have identified localized heavy metal anomalies in surface sediments. Sediment texture, petrographic and mineralogical composition, malacofaunal assemblages, and lake-floor morpho-bathymetry were systematically analysed using grain-size statistics, faunistic determinations, GIS-based spatial mapping, and bivariate and multivariate statistical methods. The modern lake bottom is dominated by bioclastic quartzo-lithic sands with low fine-grained fractions and variable but locally high contents of calcareous skeletal remains, mainly derived from molluscs. Sediments are texturally heterogeneous, consisting predominantly of coarse-grained sands with lenses of very coarse sand, along with gravel and subordinate medium-grained sands. Both sedimentological features and malacofaunal death assemblages indicate deposition under open-lagoon conditions characterized by brackish waters and relatively high hydrodynamic energy. Spatial comparison between sedimentological–ecological parameters and previously published heavy metal distributions reveals no significant correlations with metal hotspots. The generally low metal concentrations, mostly below regulatory threshold values, are interpreted as being favoured by the high permeability and mobility of coarse sediments and by energetic hydrodynamic conditions limiting fine-particle accumulation. Overall, the integration of sedimentological and ecological data provides a robust framework for interpreting contaminant patterns and offers valuable insights for the environmental assessment and management of vulnerable coastal lake systems, as well as for the understanding of modern lagoonal sedimentary processes. Full article

Calcareous sandstones, acting as sealing layers, play a crucial role in hydrocarbon accumulation of formations with high sand content (sand content > 80%). However, the genetic mechanisms, sealing mechanisms, and effectiveness of calcareous sandstones remain unclear. This study takes the Zhuhai–Enping formations in the Panyu A Sag as an example. By comprehensively analyzing data from well logs, cores, cast thin sections, elemental geochemical analysis and carbon–oxygen isotopes, the genetic mechanisms, development patterns, and controlling effects on hydrocarbon accumulation of calcareous cement layers are investigated. The main findings are as follows: (1) The calcareous sandstone cements are mainly composed of dolomite, ankerite, and anhydrite. With increasing burial depth, dolomite transitions from micritic dolomite to silt-sized and fine-crystalline dolomite, and finally to coarse-crystalline dolomite. (2) The local transgression provided ions such as Ca²⁺ and Mg²⁺, forming the material basis for early dolomite formation. As burial depth increased, the diagenetic environment shifted from acidic to alkaline, leading to the dolomitization of early-formed calcite and the formation of ankerite. (3) The high source-reservoir displacement pressure difference effectively seals hydrocarbon accumulation. Vertically interbedded tight calcareous sandstones and thin marine transgressive mud-stones collectively control efficient hydrocarbon preservation and enrichment. This research addresses the current limits in the study of “self-sealing sandstone layers,” and provides new geological insights and predictive models for hydrocarbon exploration in sand-rich settings. Full article