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Keywords = burial metamorphism

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23 pages, 15319 KB  
Article
Characteristics and Enrichment Regularity of Coalbed Methane in the No.8+9 Coal Seams of the Taiyuan Formation in the Mugua Area, Shenfu Gas Field
by Gang Zhao, Guangshan Guo, Jia Du, Zihan Zhang, Xiaohan Mei, Leiming Sun, Chuanjiang Tang, Haozhen Tang and Jiang He
Processes 2026, 14(10), 1637; https://doi.org/10.3390/pr14101637 - 19 May 2026
Viewed by 228
Abstract
Deep coalbed methane (CBM) is a core exploration and development domain for increasing the reserves and production of unconventional natural gas in China. A systematic understanding has been established on the enrichment and accumulation mechanism of high-rank deep CBM in the southern section [...] Read more.
Deep coalbed methane (CBM) is a core exploration and development domain for increasing the reserves and production of unconventional natural gas in China. A systematic understanding has been established on the enrichment and accumulation mechanism of high-rank deep CBM in the southern section of the eastern margin of the Ordos Basin. However, the medium-rank deep CBM in the Mugua Area of the Shenfu Gas Field in the northern section of the eastern margin has essential differences from that in the southern section in terms of coal rank and hydrocarbon generation–occurrence mechanism, and its accumulation and enrichment regularity remain unclear. The core innovations of this study are as follows: aiming at the unclear accumulation regularity of medium-rank deep CBM in the northern section of the eastern margin of the Ordos Basin, we first reveal the spatiotemporal synergistic coupling reservoir-controlling mechanism of five factors (sedimentation–thermal evolution–temperature–pressure–preservation), determine the 1750 m critical transition zone of the deep CBM occurrence state, and establish two types of accumulation models adapted to the geological characteristics of medium-rank coal. Taking the No.8+9 coal seams of the Taiyuan Formation in the Mugua Area as the research object, based on the theoretical foundation of the dual properties of coal seams as the “source rock–reservoir”, this paper comprehensively adopted technical means such as core observation, drilling and logging data, and high-pressure isothermal adsorption experiments to carry out systematic multi-dimensional studies on sedimentary microfacies, coal reservoir characteristics, thermal evolution degree, and gas-bearing property; identified the main controlling factors of CBM accumulation; and constructed the accumulation model. The results show the following: ① The main burial depth of the coal seams is more than 1700 m, with a thickness ranging from 7.0 to 21.3 m and an average of 15.1 m, and the coal structure is dominated by the primary structure; maximum vitrinite reflectance (Ro,max) is generally distributed from 0.90% to 1.39% with an average of 1.08%, belonging to typical medium-rank coal; and the organic matter type is mainly Type III, with an average gas content of 10.01 m3/t, where the average proportion of desorbed gas in the total gas content is 83.91%, featuring superior source and reservoir conditions and a good foundation for CBM enrichment. ② The CBM accumulation in this area is jointly controlled by the coupling of four factors: sedimentation, thermal evolution degree, temperature–pressure effect, and preservation conditions. The tidal flat–lagoon facies control the development of high-quality coal seams; regional metamorphism dominates the hydrocarbon generation capacity and gas quality of coal seams; the temperature–pressure coupling forms a critical adsorption zone at 1750 m, defining the differentiation boundary of the occurrence state of deep CBM; and high-quality mudstone cap rocks, a stable structural environment, and closed hydrodynamic conditions constitute the three key guarantees for gas enrichment. ③ Two types of accumulation models are divided: “source–reservoir integration + multi-factor synergistic enrichment type” and “source–reservoir limited + insufficient accumulation condition type”. Among them, the four reservoir-controlling factors of the synergistic enrichment type are highly coupled, with excellent gas-bearing property and strong recoverability. This study systematically clarifies the enrichment and accumulation regularity of medium-rank deep CBM in the Mugua Area and improves the accumulation theory of medium-rank deep CBM in the northern section of the eastern margin of the Ordos Basin. Full article
(This article belongs to the Section Petroleum and Low-Carbon Energy Process Engineering)
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34 pages, 21679 KB  
Article
Diagenetic Path of Deeply Buried Clastic Rocks and Pore Evolution of Reservoirs in the Oligocene Huagang Formation of the Xihu Sag
by Xichun Zhang, Fanghao Xu, Guosheng Xu, Wu Zhang, Qing Yu and Jinshui Liu
Energies 2026, 19(1), 238; https://doi.org/10.3390/en19010238 - 31 Dec 2025
Viewed by 723
Abstract
To elucidate the development control factors, diagenetic evolution, and pore evolution of oil and gas reservoirs of the Huagang Formation in the East China Sea Shelf Basin Central Anticlinal Belt, this study involved geological analyses, including thin-section petrography, scanning electron microscopy (SEM), mineral [...] Read more.
To elucidate the development control factors, diagenetic evolution, and pore evolution of oil and gas reservoirs of the Huagang Formation in the East China Sea Shelf Basin Central Anticlinal Belt, this study involved geological analyses, including thin-section petrography, scanning electron microscopy (SEM), mineral analysis via TESCAN Integrated Mineral Analyzer (TIMA), X-ray diffraction (XRD), and petrophysical measurements. We investigated the reservoir characteristics and primary diagenetic processes of the Huagang Formation reservoirs using logging and nuclear magnetic resonance (NMR) data, identified provenance differences between the north-central (FN) and south-central (FS) areas, divided diagenetic environments, established distinct diagenetic sequences, and uncovered high-quality reservoir pore evolution patterns. The results showed that the provenance in the FN area of the Central Anticlinal Belt is primarily acidic igneous rocks, which exhibits low resistance to compaction but is susceptible to dissolution modification, and the “high-dissolution zone” developed at burial depths of 3600–3900 m constitutes the primary high-quality reservoir; the provenance in the FS area is a mixture of medium- and high-grade metamorphic rocks and acidic igneous rocks, which exhibits stronger resistance to compaction, but dissolution zones are poorly developed. The Huagang Formation has experienced multiple diagenetic processes, such as compaction, cementation, and dissolution. During destructive diagenesis, the average reduction in pore volume due to compaction accounts for 76% (FN area) and 81% (FS area), while cementation accounts for 18% (FN area) and 12% (FS area). Vertically, 3900 m and 4000 m are the boundaries between the acidic zone and acid-alkaline transition zone of the Huagang Formation in the FN and FS areas, respectively, and the whole Huagang Formation is considered within the meso-diagenetic A2 stage. The pore evolution is closely related to diagenesis. The porosity of the sandstones in the Upper Member of the Huagang Formation in the FN area changes from 37.5% to 10.62%, and the porosity of the sand-stones in the Lower Member of the Huagang Formation in the FS area changes from 36.5% to 8.90%. The results of this study provide a reference for the study of differential diagenetic evolution of sandstones in the Xihu Sag and the exploration of deep high-quality reservoirs. Full article
(This article belongs to the Section H3: Fossil)
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23 pages, 5576 KB  
Article
Accumulation and Exploration Potential of Coalbed Methane Collected from Longtan Formation of Santang Syncline in Zhijin, Guizhou Province
by Shupeng Wen, Shuiqi Liu, Jian Li, Xinzhe Dai, Longbin Lan, Jianjun Hou, Zhu Liu, Junjian Zhang and Yunbing Hu
Processes 2025, 13(10), 3106; https://doi.org/10.3390/pr13103106 - 28 Sep 2025
Cited by 1 | Viewed by 700
Abstract
Understanding coalbed methane (CBM) enrichment patterns is essential for optimizing production capacity. This study evaluates the CBM reservoir-forming characteristics and exploration potential of the Longtan Formation in the Santang Syncline, Zhijin area, to systematically reveal CBM enrichment and high-production patterns. The investigation integrates [...] Read more.
Understanding coalbed methane (CBM) enrichment patterns is essential for optimizing production capacity. This study evaluates the CBM reservoir-forming characteristics and exploration potential of the Longtan Formation in the Santang Syncline, Zhijin area, to systematically reveal CBM enrichment and high-production patterns. The investigation integrates regional geology, logging, well testing, laboratory analyses, and drainage production data. Results indicate that coal seam vitrinite reflectance (Ro,max) ranges from 3.20% to 3.60%, with metamorphic grade increasing with burial depth. Coal lithotypes consist predominantly of semi-bright coal, with subordinate semi-bright to semi-dull coal and minor semi-dull coal. Coal seam roofs comprise gray-black mudstone and calcareous mudstone, locally developing limestone, while floors consist of bauxitic mudstone. Pore structure analysis reveals greater complexity in coal seams 6 and 14, whereas seams 7 and 16 display simpler structures. Coal seams 5-3 and 6 demonstrate the weakest adsorption capacity and lowest theoretical gas saturation, while other seams exceed 55% gas saturation. Langmuir volume (VL) increases with burial depth, reaching maximum values in coal seam 30. Langmuir pressure (PL) follows a low–high–low trend, with lower values at both ends and higher values in the middle section. Measured gas content is highest in the middle section, moderate in the lower section, and lowest in the upper section. Reservoir condition assessment indicates favorable conditions in coal seams 14, 16, and 21, relatively favorable conditions in seam 7, and unfavorable conditions in seams 6, 30, 32, and 35. Among the three coal groups penetrated, the middle coal group exhibits the most favorable reservoir conditions, followed by the upper and lower groups. Full article
(This article belongs to the Section Energy Systems)
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26 pages, 17521 KB  
Article
Multi-Scale Geophysics and Chemistry-Based Investigation of Alteration Evolution Mechanisms in Buried Hills of the Northern South China Sea
by Xinru Wang, Baozhi Pan, Yuhang Guo, Julin Zhang, Xun Yu and Pengji Zhang
J. Mar. Sci. Eng. 2025, 13(8), 1549; https://doi.org/10.3390/jmse13081549 - 12 Aug 2025
Viewed by 1109
Abstract
Alteration is a common metamorphic process in igneous formations and recorded geological information in different times and spaces. Owing to its unique location, the igneous rocks of the buried hills in the northern South China Sea exhibit complex lithology and alteration patterns resulting [...] Read more.
Alteration is a common metamorphic process in igneous formations and recorded geological information in different times and spaces. Owing to its unique location, the igneous rocks of the buried hills in the northern South China Sea exhibit complex lithology and alteration patterns resulting from multi-phase tectonic, magmatic, and climatic influences. Here, we report buried hills igneous rock samples with both hydrothermal alteration and weathering leaching. Based on multi-scale geophysical–chemical data—including scanning electron microscopy, core slice identification, petrophysical–chemical experiments, zircon dating, wireline logs, element cutting logs, seismic profiles, and others—we analyzed the multi-scale alteration characteristics of buried hills igneous rocks and proposed a four-stage alteration model related to Earth activities. Results demonstrate that tectonic movements develop continuous cracks enabling hydrothermal alteration, while burial-hill uplift facilitates weathering leaching. We further find that multi-phase tectonic movements and associated magmatic activities not only influence global hydrothermal cycles but also govern elemental migration patterns, driving distinct alteration mechanisms in these igneous rocks—including plagioclase metasomatism, hornblende replacement, and carbonate dissolution. Additionally, we identify the Cretaceous arid–cold climate as the primary controller for generating chlorite-dominated hydrothermal alteration products. These multi-scale alteration characteristics confirm Late Jurassic Pacific Plate subduction and Cretaceous South China Plate orogeny and may indicate an earlier initial expansion of the South China Sea. Full article
(This article belongs to the Section Geological Oceanography)
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33 pages, 24486 KB  
Article
Controlling Factors of Diagenetic Evolution on Reservoir Quality in Oligocene Sandstones, Xihu Sag, East China Sea Basin
by Yizhuo Yang, Zhilong Huang, Tong Qu, Jing Zhao and Zhiyuan Li
Minerals 2025, 15(4), 394; https://doi.org/10.3390/min15040394 - 8 Apr 2025
Cited by 3 | Viewed by 1523
Abstract
The tight sandstone reservoirs within the Oligocene Huagang Formation represent one of the most promising exploration targets for future hydrocarbon development in the Xihu Depression of the East China Sea Basin. The reservoir has complex sedimentary and diagenetic processes. In this paper, a [...] Read more.
The tight sandstone reservoirs within the Oligocene Huagang Formation represent one of the most promising exploration targets for future hydrocarbon development in the Xihu Depression of the East China Sea Basin. The reservoir has complex sedimentary and diagenetic processes. In this paper, a variety of methods, such as microscopic image observation, particle size analysis, X-ray diffraction measurement (XRD), heavy minerals, carbon and oxygen isotopes of cement, the homogenization temperature of fluid inclusions, zircon (U-Th)/He isotopes, and high-pressure mercury intrusion (HPMI), are used to analyze the thermal evolution history, diagenetic evolution process, and the causes of differences in diagenetic processes and high-quality reservoirs. This study shows that the provenance of the southern region is derived from western metamorphic rock, while that of the northern region is dominated by northern metamorphic rock, including some eastern volcanic rock. The northern region exhibits a stronger compaction and lower porosity, primarily due to a greater proportion of volcanic rock provenance. Additionally, coarse-grained lithofacies exhibit a higher quartz content and lower proportions of clay minerals and lithic fragment compared to fine-grained lithofacies, consequently demonstrating greater resistance to compaction. The Huagang Formation reservoir has three stages of carbonate cementation, two stages of quartz overgrowth, and two stages of fluid charging. The two stages of fluid charging correspond to two stages of organic acid dissolution. In the northern region, the geothermal gradient is high, and the burial depth is large, so the diagenetic event occurred earlier and is now in the mesodiagenesis B stage, while in the southern region, the geothermal gradient is low, and the burial depth is small and is now in the mesodiagenesis A stage. The southern distributary channel sands and northern high-energy braided channel sands constitute high-quality reservoirs, characterized by a coarse grain size, large pore throats, and minimal cement content. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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17 pages, 3552 KB  
Article
Formation of Core-Rim Magnetite with a Carbonaceous Core in Mid-Archean Banded Iron Formation from the Barberton Greenstone Belt, South Africa
by Tatsuro Manabe and Hiromi Konishi
Minerals 2025, 15(3), 218; https://doi.org/10.3390/min15030218 - 24 Feb 2025
Viewed by 1798
Abstract
Through the analysis of core-rim magnetite, we demonstrate that the core contains carbonaceous materials (CMs) derived from a 3.2-billion-year-old banded iron formation within the Barberton Greenstone Belt in South Africa. Using scanning electron microscopy, energy-dispersive X-ray spectroscopy, and Raman spectroscopy, we establish a [...] Read more.
Through the analysis of core-rim magnetite, we demonstrate that the core contains carbonaceous materials (CMs) derived from a 3.2-billion-year-old banded iron formation within the Barberton Greenstone Belt in South Africa. Using scanning electron microscopy, energy-dispersive X-ray spectroscopy, and Raman spectroscopy, we establish a direct association between these CMs and the magnetite. Although the possibility that CMs formed from the hydrothermal decomposition of siderite cannot be ruled out, several lines of evidence indicate a likely microbial origin for the CMs. Firstly, Raman spectroscopy reveals that the CMs exhibit characteristics of low-maturity biogenic organic matter (OM) featuring aliphatic carbon chains, which supports the notion that organic carbon compounds mature during burial metamorphism at temperatures below approximately 200 °C. Secondly, phosphorus and sulfur detected in the CMs suggest a microbial origin. Lastly, the formation of the unique texture of core-rim magnetite can be conceptualized as follows: Fe2+ is oxidized through anoxygenic photosynthesis, leading to the precipitation of ferrihydrite. This ferrihydrite is then transformed into magnetite by iron-reducing microorganisms. Subsequently, the magnetite grows larger through oriented attachment, which also confines OM. Ultimately, smooth magnetite rims may have preserved the OM for up to 3.2 billion years. Full article
(This article belongs to the Special Issue Microbial Biomineralization and Organimineralization)
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21 pages, 3623 KB  
Article
Characteristics of the Microfracture and Pore Structure of Middle- and High-Rank Coal and Their Implications for CBM Exploration and Development in Northern Guizhou
by Haiying Ren, Zhijun Guo, Honggao Xie, Sijie Han, Xiaozhi Zhou, Lingyun Zhao, Yuanlong Wei and Wenci Qiu
Energies 2025, 18(1), 5; https://doi.org/10.3390/en18010005 - 24 Dec 2024
Cited by 2 | Viewed by 1266
Abstract
The microfracture and pore structure characteristics of coal reservoirs are crucial for coalbed methane (CBM) development. This study examines the evolution of pore and fracture structures at the microscopic level and their fractal characteristics, elucidating their impact on CBM development in the northern [...] Read more.
The microfracture and pore structure characteristics of coal reservoirs are crucial for coalbed methane (CBM) development. This study examines the evolution of pore and fracture structures at the microscopic level and their fractal characteristics, elucidating their impact on CBM development in the northern Guizhou coal reservoirs. The results indicate that the pores and fractures in the coal reservoirs are relatively well-developed, which facilitates the adsorption of CBM. The density of primary fractures ranges from 5.8 to 14.4 pcs/cm, while the density of secondary fractures ranges from 3.6 to 11.8 pcs/cm. As the metamorphic degree of coal increases, the density of primary fractures initially increases and then decreases, whereas the density of secondary fractures decreases with increasing metamorphic degree. With increasing vitrinite reflectance, the specific surface area and pore volume of the coal samples first decrease and then increase. The fractal dimension ranges from 2.3761 to 2.8361; as the vitrinite reflectance of the coal samples increases, the fractal dimension D1 decreases initially and then increases, while D2 decreases. In the northern Guizhou region, CBM is characterized by an enrichment model of “anticline dominance + fault-hydrogeological dual sealing” along with geological controlling factors of” burial depth controlling gas content and permeability + local fault controlling accumulation”. The research findings provide a theoretical basis for the occurrence and extraction of CBM in northern Guizhou. Full article
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32 pages, 9777 KB  
Article
Geochemical Characterization of and Exploration Guide for the World-Class Mafic–Siliciclastic-Hosted Touro VMS Cu Deposit, Northwestern Iberian Peninsula
by Pablo Nuñez, Alvaro Rubio, Daniel Arias, Jorge Fuertes-Blanco, Fernando Cortés, Fernando Díaz-Riopa and Agustin Martin-Izard
Minerals 2024, 14(11), 1159; https://doi.org/10.3390/min14111159 - 16 Nov 2024
Viewed by 2092
Abstract
A geochemical study was conducted on the Touro deposit, which is situated within the Iberian Variscan Massif on the allochthonous terrain of the Galicia–Tras-os-Montes Zone. This study encompassed both mineralogical and geochemical analyses of the host rocks, with a particular focus on the [...] Read more.
A geochemical study was conducted on the Touro deposit, which is situated within the Iberian Variscan Massif on the allochthonous terrain of the Galicia–Tras-os-Montes Zone. This study encompassed both mineralogical and geochemical analyses of the host rocks, with a particular focus on the high-grade Fornás metamorphic unit of the Órdenes Complex. The deposit is composed of massive and semi-massive sulfides, the host rocks are amphibolites and paragneisses, and the ore is hosted in garnet amphibolites and mineralized paragneisses. A microscopic study of thin sections and over 300 electron probe microanalyses on various minerals were conducted with the objective of geochemical characterization. Furthermore, a study of approximately 6000 samples processed by mining companies for multielement analyses of over 1350 drill cores was conducted to geochemically characterize the host and mineralized rocks for use as exploration guides. Additionally, five samples underwent Sm-Nd isotope analysis. The data from the Touro Cu (Zn-Co) deposit are consistent with its classification as a mafic–siliciclastic (Besshi-type) VMS deposit constructed in a back-arc environment during the Ordovician period. Following burial and high-grade metamorphism during the Middle Devonian period, these rocks were subsequently exposed during the later Variscan deformation phases, resulting in the formation of the Arinteiro antiform. Full article
(This article belongs to the Special Issue Mineralization and Geochemistry of VMS Deposits)
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19 pages, 5654 KB  
Article
A Rock Physics Modeling Method for Metamorphic Rock Reservoirs in Buried Hill
by Hongjian Hao, Guangzhi Zhang and You Zhou
Minerals 2024, 14(9), 892; https://doi.org/10.3390/min14090892 - 30 Aug 2024
Cited by 2 | Viewed by 2167
Abstract
The buried hills of the Archean metamorphic rocks in the Bozhong Depression of the Bohai Bay Basin are the main gas-bearing strata, with burial depths ranging from 4000 m to 5500 m. However, metamorphic rocks have internal structural characteristics, such as diverse mineral [...] Read more.
The buried hills of the Archean metamorphic rocks in the Bozhong Depression of the Bohai Bay Basin are the main gas-bearing strata, with burial depths ranging from 4000 m to 5500 m. However, metamorphic rocks have internal structural characteristics, such as diverse mineral components, oriented arrangement of mineral particles, complex pore connectivity, variable crystal structures, orthogonal development of multiple sets of fractures, and uneven fluid filling. Compared with conventional reservoirs, they have obvious heterogeneity and anisotropy characteristics. Traditional rock physics modeling methods are no longer suitable for predicting the elastic and anisotropic parameters of metamorphic reservoirs. Therefore, we introduced a vector mixed random medium model to calculate the effect of the oriented arrangement of metamorphic rock minerals on the modulus of the rock matrix and introduced a metamorphic factor to describe the impact of metamorphic recrystallization and alteration metasomatism on the elastic modulus of the rock matrix. Practical applications have shown that the new, improved rock physics modeling method can better estimate the S-wave velocity and anisotropy parameters in wells compared to traditional rock physics modeling methods, providing a reliable basis for predicting fractured reservoirs in metamorphic rock at buried hills. Full article
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17 pages, 11594 KB  
Article
Geochemical Characteristics and Hydrocarbon Generation Potential of Coal-Measure Source Rocks in Julu Sag
by Yang Wang, Hanyu Zhang, Liu Yang, Yanming Zhu and Zhixiang Chang
Processes 2024, 12(7), 1399; https://doi.org/10.3390/pr12071399 - 4 Jul 2024
Cited by 3 | Viewed by 1803
Abstract
To uncover the reservoir characteristics and enrichment law of coal-measure gas in Julu sag, Hebei Province, and achieve co-exploration and co-mining, it is necessary to conduct a comprehensive analysis. In this study, we investigated the characteristics of coal-measure gas accumulation in the Taiyuan [...] Read more.
To uncover the reservoir characteristics and enrichment law of coal-measure gas in Julu sag, Hebei Province, and achieve co-exploration and co-mining, it is necessary to conduct a comprehensive analysis. In this study, we investigated the characteristics of coal-measure gas accumulation in the Taiyuan Formation and Shanxi Formation in the Julu area. This was achieved by collecting data on coal-measure source rocks and organic geochemistry, which were then combined with regional geological conditions. This study indicates that the coal seams and shales of Shanxi Formation and Taiyuan Formation in the study area serve as the primary source rocks. The predominant macerals found in coal rock are vitrinite. Furthermore, the organic matter type present in shale is primarily categorized as type II2, with the organic matter maturity falling within the immature–mature stage. Based on the simulation results of tectonic-burial history, thermal evolution history, and hydrocarbon generation history in the study area, it is evident that the coal-measure source rocks experienced their first peak of hydrocarbon generation during the Mesozoic era as a result of deep metamorphism. Subsequently, the area experienced uplift and erosion, leading to the release of coal-bearing natural gas. Since the Paleogene period, the coal-bearing source rocks have undergone sedimentary burial and entered the secondary hydrocarbon generation stage, resulting in significant production of oil and gas. Based on the analysis of gas content, buried depth, source rock thickness, and sealing conditions in the study area, it is evident that the potential of coal-measure gas resources in the study area is primarily comprised of shale gas with supplementary coalbed methane. It can be inferred that the deeper areas within the study area hold greater exploration prospects. Full article
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16 pages, 6070 KB  
Article
Thermochronology of the Laojunshan–Song Chai Granite Gneiss Massif (North Vietnam, South China)
by Alexey Travin, Nikolai Murzintsev and Nikolai Kruk
Minerals 2024, 14(3), 251; https://doi.org/10.3390/min14030251 - 28 Feb 2024
Cited by 3 | Viewed by 2228
Abstract
A reconstruction of the tectonothermal evolution of the Laojunshan–Song Chai granite gneiss massif (North Vietnam, South China) was carried out, based on summaries of the latest isotopic and fission-track dating results. The recorded wide range (420–465 Ma) of the age of granite gneiss [...] Read more.
A reconstruction of the tectonothermal evolution of the Laojunshan–Song Chai granite gneiss massif (North Vietnam, South China) was carried out, based on summaries of the latest isotopic and fission-track dating results. The recorded wide range (420–465 Ma) of the age of granite gneiss rocks testifies to the long-term existence of a partially molten layer at a depth of 20–30 km for several tens of Ma. By the Devonian–early Carboniferous, a section of the excessively thickened crust was denudated, the massif was exhumated to the level of the upper crust, and isotope systems were “frozen”. The rate of uplift of the rocks of the massif is estimated to be about 0.2–0.5 mm/year. In the further history of the granite gneiss massif, episodes of repeated burial to a depth of about 13 km are recorded, associated with the Indosinian collision. The rocks have experienced metamorphism of the amphibolite-green schist facies, accompanied by tectonic transport in the form of a thrust sheet. Over the next 200 Ma, the uplift of the massif and the erosion of the overlying strata occurred in discrete pulses, during a sequence of active tectonic events. Thus, the thermochronological and P-T history of the Laojunshan–Song Chai massif is a kind of chronicle of regional tectonic–thermal events. In the history of the massif, traces of two orogenic cycles associated with the collision of the Cathaysia and Yangtze blocks in the Lower Paleozoic and the Indosinian collision in the Triassic are recorded. Full article
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19 pages, 5330 KB  
Article
Quantitative Prediction of Deep Coalbed Methane Content in Daning-Jixian Block, Ordos Basin, China
by Zheyuan Ouyang, Haichao Wang, Bin Sun, Yunxuan Liu, Xuehai Fu, Wei Dou, Liang Du, Beixi Zhang, Bing Luo, Mengmeng Yang and Zhiwei Zeng
Processes 2023, 11(11), 3093; https://doi.org/10.3390/pr11113093 - 27 Oct 2023
Cited by 25 | Viewed by 3058
Abstract
The potential of deep coalbed methane resources is substantial. Gas content is an important parameter for resource assessment. At present, the gas content test method commonly used for shallow coal reservoirs is not suitable for determining deep coalbed methane gas content. Therefore, it [...] Read more.
The potential of deep coalbed methane resources is substantial. Gas content is an important parameter for resource assessment. At present, the gas content test method commonly used for shallow coal reservoirs is not suitable for determining deep coalbed methane gas content. Therefore, it is urgent to establish a prediction method for deep coalbed methane gas content. This study aims to quantitatively predict the gas content of coalbed methane in deep coal reservoirs and uncover its influencing factors. For this purpose, we selected the Daning-Jixian area, a region in China with relatively advanced development of deep coalbed methane, as a case study. It established a prediction model for adsorbed gas and free gas content in deep coal reservoirs through a series of experimental tests, encompassing gas content, coal quality, isothermal adsorption, and nuclear magnetic resonance. The model sheds light on the impact of coal-rock characteristics, coal quality attributes, and pore characteristics on adsorbed gas and free gas content. The results show that adsorbed gas dominates in deep coal reservoirs with a high metamorphic degree and that the average proportion of adsorbed gas under reservoir burial depth is 80.15%. At a depth of approximately 1800~2000 m, a turning point is observed where adsorbed gas content begins to decline. Beyond this depth range, the detrimental effect of temperature on coalbed methane content surpasses the beneficial impact of pressure. Coal quality characteristics play a major role in controlling adsorbed gas content, and an increase in water content and ash yield significantly reduces the adsorption performance of coal reservoirs. The content of free gas increases with the increase in burial depth, with its controlling factors primarily being confining pressure and porosity. The increase in the proportion of micropores in the pores of deep coal reservoirs has an adverse effect on the content of free gas. The proportion of adsorbed gas in deep coal reservoirs gradually decreases with the increase in burial depth, while the proportion of free gas gradually rises with the increase in burial depth. The development potential of free gas cannot be overlooked in the exploration and development of deep coalbed methane. Full article
(This article belongs to the Special Issue Exploration, Exploitation and Utilization of Coal and Gas Resources)
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35 pages, 20304 KB  
Review
Metamorphic Remnants of the Variscan Orogeny across the Alps and Their Tectonic Significance
by Manuel Roda, Maria Iole Spalla, Marco Filippi, Jean-Marc Lardeaux, Gisella Rebay, Alessandro Regorda, Davide Zanoni, Michele Zucali and Guido Gosso
Geosciences 2023, 13(10), 300; https://doi.org/10.3390/geosciences13100300 - 6 Oct 2023
Cited by 10 | Viewed by 5849
Abstract
Lithospheric slices preserving pre-Alpine metamorphic imprints are widely described in the Alps. The Variscan parageneses recorded in continental, oceanic, and mantle rocks suggest a heterogeneous metamorphic evolution across the Alpine domains. In this contribution, we collect quantitative metamorphic imprints and ages of samples [...] Read more.
Lithospheric slices preserving pre-Alpine metamorphic imprints are widely described in the Alps. The Variscan parageneses recorded in continental, oceanic, and mantle rocks suggest a heterogeneous metamorphic evolution across the Alpine domains. In this contribution, we collect quantitative metamorphic imprints and ages of samples that document Variscan tectonometamorphic evolution from 420 to 290 Ma. Based on age distribution and metamorphic imprint, three main stages can be identified for the Variscan evolution of the Alpine region: Devonian (early Variscan), late Devonian–late Carboniferous (middle Variscan), and late Carboniferous–early Permian (late Variscan). The dominant metamorphic imprint during Devonian times was recorded under eclogite and HP granulite facies conditions in the Helvetic–Dauphinois–Provençal, Penninic, and eastern Austroalpine domains and under Ep-amphibolite facies conditions in the Southalpine domain. These metamorphic conditions correspond to a mean Franciscan-type metamorphic field gradient. During the late Devonian–late Carboniferous period, in the Helvetic–Dauphinois–Provençal and central Austroalpine domains, the dominant metamorphic imprint developed under eclogite and HP granulite facies conditions with a Franciscan field gradient. Amphibolite facies conditions dominated in the Penninic and Southalpine domains and corresponded to a Barrovian-type metamorphic field gradient. At the Carboniferous–Permian transition, the metamorphic imprints mainly developed under amphibolite-LP granulite facies conditions in all domains of the Alps, corresponding to a mean metamorphic field gradient at the transition between Barrovian and Abukuma (Buchan) types. This distribution of the metamorphic imprints suggests a pre-Alpine burial of oceanic and continental crust underneath a continental upper plate, in a scenario of single or multiple oceanic subductions preceding the continental collision. Both scenarios are discussed and revised considering the consistency of collected data and a comparison with numerical models. Finally, the distribution of Devonian to Triassic geothermal gradients agrees with a sequence of events that starts with subduction, continues with continental collision, and ends with the continental thinning announcing the Jurassic oceanization. Full article
(This article belongs to the Section Structural Geology and Tectonics)
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21 pages, 3786 KB  
Article
Genesis of Significance of Carbonated Thermal Water Springs in Xining Basin, China
by Yude Lei, Zhen Zhao, Baojian Zhang, Xianchun Tang, Yinfei Luo, Guiling Wang, Jun Gao and Dailei Zhang
Water 2022, 14(24), 4058; https://doi.org/10.3390/w14244058 - 12 Dec 2022
Cited by 10 | Viewed by 3599
Abstract
There are 30 carbonate hot springs in Yaoshuitan geothermal field, Xining Basin, China, with a temperature of 18~41.5 °C; and there are 10 carbonate hot springs in Qijiachuan geothermal field, with a temperature of 10~19.5 °C. Both geothermal fields are carbonate hot springs [...] Read more.
There are 30 carbonate hot springs in Yaoshuitan geothermal field, Xining Basin, China, with a temperature of 18~41.5 °C; and there are 10 carbonate hot springs in Qijiachuan geothermal field, with a temperature of 10~19.5 °C. Both geothermal fields are carbonate hot springs containing large amounts of CO2 gas. In order to reveal the origin of the carbonated hot springs in Yaoshuitan and Qijiachuan of Xining Basin, this paper offers a comprehensive study of the regional deep geology, tectonic setting, total analysis of carbonated hot springs, δ2H, δ18O, δ13C isotopes, main gas composition, and geochemical characteristics of travertine dating, travertine δ13C, and rare earth elements. The geological process of carbonated hot spring formation and the evolution of H+ content from deep to shallow is revealed, and the genetic mechanism of the carbonated hot spring in Xining Basin is systematically summarized. The results show that: (1) The characteristics of δ2H and δ18O isotopes indicate that the recharge source of carbonated thermal water springs in Xining Basin is mainly atmospheric precipitation. The age of carbonated thermal water springs at 14C is more than 20 ka, indicating that some of them may come from deep fluid (gas) sources. The R/Ra in carbonated thermal water springs is mostly less than 1, indicating that the helium in geothermal water is mainly crustal source helium, and there is no deep mantle source material. (2) The Piper three-plot indicates that the direction of groundwater evolution from the recharge area at the edge of Xining Basin to Yaoshuitan and Qijiachuan carbonated thermal water spring area near the edge of the basin is opposite to the normal path of groundwater evolution in the basin, which is due to the large amount of CO2 gas mixed in the deep fault along the northern margin of Laji Mountain. The ratio of (Ca2+ + Mg2+) and (HCO3 + SO42−) in the Potan and Qijiachuan carbonated thermal water springs is close to 1, and the ratio of (Na+ + K+)/HCO3 is less than 1. It indicates that the chemical composition of the Yaoshuitan carbonated thermal water spring and the Qijiachuan carbonated thermal water spring in Xining Basin is dominated by the dissolution of calcite, dolomite, and gypsum in deep carbonate reservoirs, supplemented by the dissolution of silicate minerals. The relationship between the volume fraction of CO2 and the δ13C value of carbon isotope of CO2 indicates that the source of CO2 is inorganic, which is mainly formed by metamorphism and decomposition of deep carbonate and marble. The δEu < 1 and δCe > 1 of the rare earth elements in the calcium center of the carbonated thermal water springs indicate that the groundwater supplying the travertine material has been in the acidic environment receiving CO2 from the deep crust for a long time. (3) A series of tectonic activities, such as late collision and post-collision between the Indian and Eurasian plates, has led to the uplift, asthenosphere upwelling, and thermal invasion of the northern Tibetan Plateau and other deep dynamic processes. The deep faults in the northern margin of the Laji Mountain and other deep faults with obvious neotectonic activity have provided channels for the up-invasion of deep thermal materials, and local geothermal anomalies were formed near the deep faults. The hidden carbonate rocks and silicate rocks with large thickness undergo thermal metamorphism under high temperature and high pressure in the deep geothermal anomaly area and form a large amount of CO2, which is dissolved in water and enhances the acidity of water. At the same time, the dissolution reaction of acidic water to carbonate rocks consumes H+, which keeps the carbonated thermal water spring weakly acidic. (4) The composition of travertine in carbonated thermal water springs is dominated by calcite, indicating that travertine may be formed in a deep geological environment with a temperature of 150~200 °C, indicating that there are abnormal heat sources in shallow carbonate strata with a burial depth of 3000~4000 m. The abnormal heat source may be caused by the deep fault in the northern margin of Laji Mountain, as well as other deep and large faults channeled in the deep crust and mantle heat source, indicating that the deep fault in the northern margin of Laji Mountain has an obvious heat-controlling effect, and there is a good prospect of geothermal resources exploration near the fault. Full article
(This article belongs to the Special Issue Hydrochemical Characteristics of Geothermal Water)
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Article
Constraining the Timing of Evolution of Shear Zones in Two Collisional Orogens: Fusing Structural Geology and Geochronology
by Rodolfo Carosi, Chiara Montomoli, Salvatore Iaccarino, Beatriz Benetti, Alessandro Petroccia and Matteo Simonetti
Geosciences 2022, 12(6), 231; https://doi.org/10.3390/geosciences12060231 - 31 May 2022
Cited by 23 | Viewed by 5757
Abstract
In recent decades, constraining the timing of shear activity has been one of the main topics of research about the tectono-metamorphic evolution of orogenic belts. We present a review of a combined structural and geochronological approach to two major ductile regional shear zones, [...] Read more.
In recent decades, constraining the timing of shear activity has been one of the main topics of research about the tectono-metamorphic evolution of orogenic belts. We present a review of a combined structural and geochronological approach to two major ductile regional shear zones, in two collisional orogens: the first one affecting the Variscan basement in northern Sardinia (Italy) and the External Crystalline Massifs of the Alps (East Variscan Shear Zone; EVSZ), and the second one deforming the medium- to high-grade rocks of the metamorphic core of the Himalaya (High Himalayan Discontinuity). High-resolution, texturally and chemically controlled monazite geochronology applied in separated shear zones of the Variscan belt allowed recognizing a similar timing of activity ranging between c. 340–330 and 300 Ma. This approach led to a better understanding of the evolution of the EVSZ, supporting a model where several branches were active according to a growth by linkage model. Following a similar approach, in situ U-Th-Pb analysis of monazite constrained the timing of top-to-the-S/SW shearing of a regional-scale High Himalayan Discontinuity in the Himalayan belt to between c. 28 Ma and 17 Ma. Earlier exhumation of the hanging wall was triggered by shear zone activity, whereas at the same time, the footwall was still experiencing burial with increasing P-T conditions. The timing of shearing of this shear zone fits with an in-sequence shearing tectonic model for the exhumation of the Himalayan mid-crust. Full article
(This article belongs to the Special Issue Evolution of Modern and Ancient Orogenic Belts)
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