Search Results (1,117)

Food waste has emerged as a critical worldwide concern, resulting in environmental deterioration and economic detriment. Bio-based natural polymer coatings and films have emerged as a sustainable solution to food preservation challenges, particularly in reducing postharvest losses and extending shelf life. Compared to their synthetic counterparts, these polymers, such as chitosan, starch, cellulose, proteins, and alginate, are derived from renewable sources that are biodegradable, safe, and functional. Within this context, this review examines the various bio-based natural polymer coatings and films as biodegradable, edible alternatives to conventional packaging solutions. It examines the different fabrication methods, like solution casting, electrospinning, and spray coating, and incorporates antimicrobial agents to enhance performance. Emphasis is placed on their mechanical, barrier, and antimicrobial properties, their application in preserving fresh produce, how they promote food safety and environmental sustainability, and accompanying limitations. This review highlights the importance of bio-based natural polymer coatings and films as a promising, eco-friendly solution to enhancing food quality, safety, and shelf life while addressing global sustainability challenges. Full article

Aquatic biomass—ranging from fish scales and crustacean shells to various algae species—offers an abundant, renewable source for carbon dot (CD) synthesis, aligning with circular economy principles. This review highlights recent studies for valorizing aquatic biomass into high-performance carbon-based nanomaterials—specifically aquatic biomass-based carbon dots (AB-CDs)—briefly summarizing green synthesis approaches (e.g., hydrothermal carbonization, pyrolysis, and microwave-assisted treatments) that minimize environmental impact. Subsequent sections highlight the varied applications of AB-CDs, particularly in biosensing (including the detection of marine biotoxins), environmental monitoring of water pollutants, and drug delivery systems. Physically AB-CDs show unique optical and physicochemical properties—tunable fluorescence, high quantum yields, enhanced sensitivity, selectivity, and surface bio-functionalization—that make them ideal for a wide array of applications. Overall, the discussion underlines the significance of this approach; indeed, transforming aquatic biomass into carbon dots can contribute to sustainable nanotechnology, offering eco-friendly solutions in sensing, environmental monitoring, and therapeutics. Finally, current challenges and future research directions are discussed to give a perspective of the potential of AB-CDs; the final aim is their integration into multifunctional, real-time monitoring and therapeutic systems—for sustainable nanotechnology innovations. Full article

One of the most important challenges the tire industry faces is becoming carbon-neutral and using 100% sustainable materials by 2050. Utilizing materials from renewable sources and recycled substances is a key aspect of achieving this goal. Petroleum-based oils, such as Treated Distillate Aromatic Extract (TDAE), are frequently used in rubber compounds, and a promising strategy to enhance sustainability is to use bio-based plasticizer alternatives. However, research has shown that the replacement of TDAE oil with bio-based oils or resins can significantly alter the glass transition temperature (T_g) of the final compound, influencing the tire properties. In this study, the theory was proposed that using a plasticizer blend, comprising oil and resin, in a rubber compound would result in similar T_g values as the reference compound containing TDAE. To test this, the cycloaliphatic di-ester oil Hexamoll DINCH, which can be made out of bio-based feedstock by the BioMass Balance approach, was selected and blended with the cycloaliphatic hydrocarbon resin Escorez 5300. Various oil-to-resin ratios were investigated, and a linear increase in the T_g of the vulcanizate was obtained when increasing the resin content and decreasing the oil content. Additionally, a 50/50 blend, consisting of 18.75 phr Hexamoll DINCH and 18.75 phr Escorez 5300, resulted in the same T_g of −19 °C as a compound containing 37.5 phr TDAE. Furthermore, this blend resulted in similar curing characteristics and cured Payne effect as the reference with TDAE. Moreover, a similar rolling resistance indicator (tan δ at 60 °C = 0.115), a slight deterioration in wear resistance (ARI = 83%), but an improvement in the stress–strain behavior (M300 = 9.18 ± 0.20 MPa and Ts = 16.3 ± 0.6 MPa) and wet grip indicator (tan δ at 0 °C = 0.427) were observed. The results in this work show the potential of finding a balance between optimal performance and sustainability by using plasticizer blends. Full article

Tidal seashell waste represents an abundant, underutilized marine resource that poses environmental disposal challenges but offers potential as a sustainable bio-filler in epoxy composites. This study investigates its incorporation into bio-based epoxy systems to reduce reliance on non-renewable materials and promote circular economy objectives. Processed seashell powder was blended into epoxy formulations, and response surface methodology was applied to optimize filler loading and resin composition. Comprehensive characterization included tensile strength, impact resistance, hardness, density, and thermal conductivity testing, along with microscopy analysis to evaluate filler dispersion and interfacial bonding. The optimized composites demonstrated improved hardness, density, and thermal stability while maintaining acceptable tensile and impact strength. Microscopy confirmed uniform filler distribution at optimal loadings but revealed agglomeration and void formation at higher contents, which can reduce interfacial bonding efficiency. These findings highlight the feasibility of valorizing marine waste as a reinforcing filler in sustainable composite production, supporting environmental goals and offering a scalable approach for the development of durable, lightweight materials suitable for structural, coating, and industrial applications. Full article

Benzoxazine resins are gaining attention for their impressive thermal stability, low water uptake, and strong mechanical properties. In this work, two new bio-based benzoxazine monomers were developed using renewable arbutin: one combined with 3-(2-aminoethylamino) propyltrimethoxysilane (AB), and the other with furfurylamine (AF). Both were synthesized using a simple Mannich-type reaction and verified through FT-IR and ¹H-NMR spectroscopy. By blending these monomers in different ratios, copolymers with adjustable thermal, dielectric, and surface characteristics were produced. Thermal analysis showed that the materials had broad processing windows and cured effectively, while thermogravimetric testing confirmed excellent heat resistance—especially in AF-rich blends, which left behind more char. The structural changes obtained during curing process were monitored using FT-IR, and XPS verified the presence of key elements like carbon, oxygen, nitrogen, and silicon. SEM imaging revealed that AB-based materials had smoother surfaces, while AF-based ones were rougher; the copolymers fell in between. Dielectric testing showed that increasing AF content raised both permittivity and loss, and contact angle measurements confirmed that surfaces ranged from water-repellent (AB) to water-attracting (AF). Overall, these biopolymers (AB/AF copolymers) synthesized from arbutin combine environmental sustainability with customizability, making them strong candidates for use in electronics, protective coatings, and flame-resistant composite materials. Full article

Modern microgrids face critical challenges in maintaining stability and efficiency due to renewable energy intermittency and dynamic load demands. This paper proposes a novel real-time energy management framework that synergizes a bio-inspired T-Cell optimization algorithm with decentralized voltage-based droop control to address these challenges. A JADE-based multi-agent system (MAS) orchestrates coordination between the T-Cell optimizer and edge-level controllers, enabling scalable and fault-tolerant decision-making. The T-Cell algorithm, inspired by adaptive immune system dynamics, optimizes global power distribution through the MAS platform, while droop control ensures local voltage stability via autonomous adjustments by distributed energy resources (DERs). The framework is rigorously validated through Hardware-in-the-Loop (HIL) testing using OPAL-RT, which interfaces MATLAB/Simulink models with Raspberry Pi for real-time communication (MQTT/Modbus protocols). Experimental results demonstrate a 91% reduction in grid dependency, 70% mitigation of voltage fluctuations, and a 93% self-consumption rate, significantly enhancing power quality and resilience. By integrating centralized optimization with decentralized control through MAS coordination, the hybrid approach achieves scalable, self-organizing microgrid operation under variable generation and load conditions. This work advances the practical deployment of adaptive energy management systems, offering a robust solution for sustainable and resilient microgrids. Full article

Xylanase is an essential industrial enzyme for degrading plant biomass, pulp and paper, textiles, bio-scouring, food, animal feed, biorefinery, chemicals, and pharmaceutical industries. Despite its significant industrial importance, the extensive application of xylanase is hampered by high production costs and concerns regarding the safety of xylanase-producing microorganisms. The utilisation of renewable polymers for enzyme production is becoming a cost-effective alternative. Among the prospective candidates, non-pathogenic lactic acid bacteria (LAB) are promising for safe and eco-friendly applications. Our investigation revealed that Pediococcus pentosaceus G4, isolated from plant sources, is a notable producer of extracellular xylanase. Improving the production of extracellular xylanase is crucial for viable industrial applications. Therefore, the current study investigated the impact of various medium components and optimised the selected medium composition for extracellular xylanase production of P. pentosaceus G4 using Plackett–Burman Design (PBD) and Central Composite Design (CCD) statistical approaches. According to BPD analysis, 8 out of the 19 investigated factors (glucose, almond shell, peanut shell, walnut shell, malt extract, xylan, urea, and magnesium sulphate) demonstrated significant positive effects on extracellular xylanase production of P. pentosaceus G4. Among them, glucose, almond shells, peanut shells, urea, and magnesium sulphate were identified as the main medium components that significantly (p < 0.05) influenced the production of extracellular xylanase of P. pentosaceus G4. The optimal concentrations of glucose, almond shells, peanut shells, urea, and magnesium sulphate, as determined via CCD, were 26.87 g/L, 16 g/L, 30 g/L, 2.85 g/L, and 0.10 g/L, respectively. The optimised concentrations resulted in extracellular xylanase activity of 2.765 U/mg, which was similar to the predicted extracellular xylanase activity of 2.737 U/mg. The CCD-optimised medium yielded a 3.13-fold enhancement in specific extracellular xylanase activity and a 7.99-fold decrease in production costs compared to the commercial de Man, Rogosa and Sharpe medium, implying that the CCD-optimised medium is a cost-effective medium for extracellular xylanase production of P. pentosaceus G4. Moreover, this study demonstrated a positive correlation between extracellular xylanase production, growth, lactic acid production and the amount of sugar utilised, implying the multifaceted interactions of the physiological variables affecting extracellular xylanase production in P. pentosaceus G4. In conclusion, statistical methods are effective in rapidly assessing and optimising the medium composition to enhance extracellular xylanase production of P. pentosaceus G4. Furthermore, the findings of this study highlighted the potential of using LAB as a cost-effective producer of extracellular xylanase enzymes using optimised renewable polymers, offering insights into the future use of LAB in producing hemicellulolytic enzymes. Full article

This study evaluates the risk assessment and hazard identification of hydrothermal liquefaction (HTL)-derived bio-oil from the MARINES project, which converts military organic waste into fuel. The high oxygen content (35–50 wt%), acidic pH (2–4), and viscosity (10–1000 cP) of bio-oils pose unique challenges, including oxidative polymerization, corrosion, and micro-explosions during combustion. Key hazards include storage instability, particulate emissions (20–30% higher than diesel), and aquatic toxicity (LC50 < 10 mg/L for phenolics). Mitigation strategies such as inert gas blanketing, preheating, and spill containment are proposed. While offering renewable fuel potential, HTL bio-oil demands rigorous safety protocols for military/industrial deployment, warranting further experimental validation. Full article

The composite materials industry is increasingly seeking sustainable alternatives to mitigate the environmental impact of end-of-life materials. As a result, many sectors are transitioning toward bio-based or partially bio-based matrices (e.g., epoxy resins) to preserve material properties while improving sustainability. The transportation sector, in particular, demands materials that meet stringent mechanical and fire resistance standards. In this study, various epoxy systems with bio-based and/or recyclable content were investigated, along with renewable additives designed to enhance fire resistance through their functional groups and chemical structure. The research focused on developing formulations compatible with Sheet Moulding Compound (SMC) technology, which is widely used in transportation applications. Through extensive testing, materials with high bio-based content were successfully developed, exhibiting competitive mechanical properties and compliance with key fire safety requirements of the railway sector, as per the EN 45545-2 standard. Full article

The One Health paradigm—recognizing the interconnected health of humans, animals, and the environment—promotes the development of sustainable technologies that enhance human health while minimizing ecological impact. In this context, bio-based hydrogels have emerged as a promising class of biomaterials for advanced medical applications. Produced through biotechnological methods such as genetic engineering and microbial fermentation, these hydrogels are composed of renewable and biocompatible materials, including recombinant collagen, elastin, silk fibroin, bacterial cellulose, xanthan gum, and hyaluronic acid. Their high water content, structural tunability, and biodegradability make them ideal candidates for various biomedical applications such as wound healing, tissue regeneration, and the design of extracellular matrix (ECM)-mimicking scaffolds. By offering controlled mechanical properties, biocompatibility, and the potential for minimally invasive administration, sustainable hydrogels represent a strategic innovation for regenerative medicine and therapeutic interventions. This review discusses the characteristics and medical applications of these hydrogels, highlighting their role in advancing sustainable healthcare solutions within the One Health framework. Full article

Lignin, the most abundant renewable aromatic biopolymer on Earth, is rapidly emerging as a powerful enabler of next-generation sustainable technologies. This review shifts the focus to the latest industrial breakthroughs that exploit lignin’s multifunctional properties across energy, agriculture, healthcare, and environmental sectors. Lignin-derived carbon materials are offering scalable, low-cost alternatives to critical raw materials in batteries and supercapacitors. In agriculture, lignin-based biostimulants and controlled-release fertilizers support resilient, low-impact food systems. Cosmetic and pharmaceutical industries are leveraging lignin’s antioxidant, UV-protective, and antimicrobial properties to create bio-based, clean-label products. In water purification, lignin-based adsorbents are enabling efficient and biodegradable solutions for persistent pollutants. These technological leaps are not merely incremental, they represent a paradigm shift toward a materials economy powered by renewable carbon. Backed by global sustainability roadmaps like the European Green Deal and China’s 14th Five-Year Plan, lignin is moving from industrial residue to strategic asset, driven by unprecedented investment and cross-sector collaboration. Breakthroughs in lignin upgrading, smart formulation, and application-driven design are dismantling long-standing barriers to scale, performance, and standardization. As showcased in this review, lignin is no longer just a promising biopolymer, it is a catalytic force accelerating the global transition toward circularity, climate resilience, and green industrial transformation. The future of sustainable innovation is lignin-enabled. Full article

In this study, we tested a flexible polyurethane (PU) foam, synthesized from bio-based components, for the removal of petroleum-derived fuels from water samples. The PU was synthesized via the prepolymer method through the reaction of PEG 400 with L-lysine ethyl ester diisocyanate (L-LDI), followed by chain extension with 2,5-bis(hydroxymethyl)furan (BHMF), a renewable platform molecule derived from carbohydrates. Freshwater and seawater samples were artificially contaminated with commercial diesel, gasoline, and kerosene. Batch adsorption experiments revealed that the total sorption capacity (S, g/g) of the PU was slightly higher for diesel in both water types, with values of 67 g/g in freshwater and 70 g/g in seawater. Sorption kinetic analysis indicated that the process follows a pseudo-second-order kinetic model, suggesting strong chemical interactions. Equilibrium data were fitted using Langmuir and Freundlich isotherm models, with the best fit achieved by the Langmuir model, supporting a monolayer adsorption mechanism on homogeneous surfaces. The PU foam can be regenerated up to 50 times by centrifugation, maintaining excellent performance. This study demonstrates a promising application of this sustainable and bio-based polyurethane foam for environmental remediation. Full article

Microbial fuel cells (MFCs) are bio-electrochemical systems that harness microorganisms to convert organic pollutants in wastewater directly into electricity, offering a dual solution for sustainable wastewater treatment and renewable energy generation. This paper presents a holistic techno-economic and environmental feasibility assessment of large-scale MFC deployment in Dhaka’s industrial zone, Bangladesh, as a relevant case study. Here, treating 100,000 cubic meters of wastewater daily would require a capital investment of approximately USD 500 million, with a total project cost ranging between USD 307.38 million and 1.711 billion, depending on system configurations. This setup has an estimated theoretical energy recovery of 478.4 MWh/day and a realistic output of 382 MWh/day, translating to a per-unit energy cost of USD 0.2–1/kWh. MFCs show great potential for treating wastewater and addressing energy challenges. However, this paper explores remaining challenges, including high capital costs, electrode and membrane inefficiencies, and scalability issues. Full article

Wood is a green and renewable bio-based building material, but its hygroscopicity affects its dimensional stability, limiting its use in construction. Chemical modification can improve its properties, yet its effectiveness depends on wood permeability and traditional modifiers. This study first used a deep eutectic solvent (DES) to boost the permeability of North American alder wood. Then, methyl trimethoxysilane was impregnated under supercritical carbon dioxide (SCI), pressure (PI), vacuum (VI), and atmospheric pressure (AI) conditions. DES treatment damaged the cell structure, increasing wood permeability. Silane was deposited and polymerized in the cell lumen, chemically bonding with cell-wall components, filling walls and pits, and thickening walls. The VI group had the highest absolute density (0.59 g/cm³, +36.6%) and the lowest moisture absorption (4.4%, −33.3%). The AI group had the highest ASE (25%). The PI group showed the highest surface hardness (RL, 2592 N) and a water contact angle of 131.9°, much higher than natural wood. Overall, the VI group had the best performance. Silane reacts with cellulose, hemicellulose, and lignin in wood via hydrolysis and hydroxyl bonding, forming stable bonds that enhance the treated wood’s hydrophobicity, dimensional stability, and surface hardness. Full article

This review examines the chemical functionalization of Camelina, hemp, and rapeseed oils for the development of sustainable bio-based resins. Key strategies, including epoxidation, acrylation, and click chemistry, are discussed in the context of tailoring molecular structure to enhance reactivity, compatibility, and material performance. Particular emphasis is placed on overcoming the inherent limitations of vegetable oil structures to enable their integration into high-performance polymer systems. The agricultural sustainability and environmental advantages of these feedstocks are also highlighted alongside the technical challenges associated with their chemical modification. Functionalized oils derived from Camelina, hemp, and rapeseed have been successfully applied in various resin systems, including protective coatings, pressure-sensitive adhesives, UV-curable oligomers, and polyurethane foams. These advances demonstrate their growing potential as renewable alternatives to petroleum-based polymers and underline the critical role of structure–property relationships in designing next-generation sustainable materials. Ultimately, the objective of this review is to distill the most effective functionalization pathways and design principles, thereby illustrating how Camelina, hemp, and rapeseed oils could serve as viable substitutes for petrochemical resins in future industrial applications. Full article