Search Results (32)

A thin-film surface plasmon resonance (SPR) sensor is presented using a prism-coupled Kretschmann configuration and an optimized multilayer architecture incorporating black phosphorus (BP) as an ultrathin overlayer. The response is modeled at 633 nm under TM polarization using the transfer-matrix method. Low-concentration sensing conditions in the 1–5 ng/mL range are represented through small effective-refractive-index perturbations of the aqueous sensing medium, providing a preliminary optical framework for evaluating refractive-index response in biosensing-related scenarios. The coupling prism, Au film thickness, and Si₃N₄ spacer thickness are optimized to control resonance depth, linewidth, and angular shift. The optimized CaF₂/Au/Si₃N₄/BP configuration exhibits systematic condition-dependent displacement of the SPR minimum and an evanescent-field distribution that remains strongly localized at the sensing interface while extending into the sensing medium, enabling refractive-index interrogation. High angular sensitivity is obtained at low levels, reaching 517.62°/RIU at 2 ng/mL and 482.82°/RIU at 1 ng/mL, with quality factors above 120 RIU⁻¹ in the same regime. Composite indicators (figure of merit and contrast signal factor) peak at intermediate levels, whereas resonance broadening at higher levels reduces the quality factor and increases the inferred limit of detection, evidencing a sensitivity–resolution trade-off. Benchmarking against reported SPR platforms indicates that BP-assisted interface engineering provides a competitive low-level operating window within a preliminary refractive-index-sensing framework that is relevant to future biosensor design. These results motivate further experimental validation, including BP stabilization, surface biofunctionalization, and practical implementation under liquid-phase sensing conditions. Full article

High-precision detection of hazardous gases with low refractive indices ranging from 1.000 to 1.100, specifically including methane, carbon monoxide, and sulfur dioxide, is critical for industrial safety, yet conventional sensors often suffer from limited sensitivity and severe thermal cross-sensitivity. This work presents a Magneto-Optical Differential Photonic Crystals Sensor (MO-DPCS) utilizing indium antimonide (InSb) to address these constraints. Employing the Multi-Objective Dragonfly Algorithm (MODA), the system was inversely optimized to maximize magneto-optical polarization splitting while rigorously maintaining an ultra-high transmission efficiency. Crucially, an angular interrogation architecture operating under oblique incidence was established to maximize the magneto-optical non-reciprocity, where the detection was realized by fixing the terahertz source frequency and monitoring the precise angular displacements of the steep spectral edges. A differential detection technique was employed to utilize the non-reciprocal phase changes wherein Transverse Electric (TE) and Transverse Magnetic (TM) modes display contrasting kinematic characteristics in the presence of an external magnetic field. The findings indicate that with an adjusted magnetic field of 0.033 T, the MO-DPCS attains an exceptional differential sensitivity of 30.8°/RIU, much above the 0.8°/RIU seen in the unmagnetized condition. The differential approach efficiently eliminates common-mode thermal noise, minimizing temperature-induced drift to below 0.35° across a 1 K range. The suggested MO-DPCS offers a robust, self-referencing solution for stable and high-sensitivity gas sensing applications with a detection limit of 4.18 × 10⁻⁴ RIU. Full article

This study develops an optical surface plasmon resonance (SPR) biosensing platform for non-invasive glucose detection directly in urine and examines how two-dimensional (2D) nanomaterials modulate sensing performance. Angular interrogation at 633 nm is modeled using a transfer-matrix framework for Au/Si₃N₄ stacks capped with graphene, semiconducting single-walled carbon nanotubes (s-SWCNTs), graphene oxide (GO), or reduced graphene oxide (rGO). Urine–glucose (UGLU) refractive indices spanning clinically relevant concentrations are used to evaluate resonance angle shifts and line-shape evolution. Sensor metrics—sensitivity, detection accuracy, figure of merit, quality factor, and limit of detection—are computed to compare architectures and identify thickness windows. Across all designs, increasing glucose concentration produces monotonic angle shifts, while the 2D overlayer governs dip depth and full width at half maximum. Graphene- and s-SWCNT-capped stacks yield the lowest limits of detection and the most favorable figures of merit, particularly at higher concentrations where narrowing improves the quality factor. rGO exhibits a thin, low-loss regime that provides large shifts with acceptable broadening, whereas thicker films degrade detectability; GO offers stable line shapes suited to metrological robustness. These results indicate that nanoscale optical engineering of 2D overlayers can meet practical detectability targets in urine without biochemical amplification, supporting compact, label-free platforms for routine glucose monitoring. Full article

The increasing presence of microplastics (MPs) and nanoplastics (NPs) in environmental matrices presents substantial analytical challenges due to their small size and chemical diversity. This study introduces a novel enzymatic biosensor based on the Surface Plasmon Resonance (SPR) platform for the sensitive detection of MPs and NPs, utilizing laccase as the recognition element. Standard plastic particles, including polystyrene (PS, 0.1 µm), polymethyl methacrylate (PMMA, 1.0 µm and 100 µm), and polyethylene (PE, 34–50 µm), were analyzed using SPR angular interrogation along with a fixed-angle scheme. The angular approach revealed a clear relationship between the resonance angle, particle size, and refractive index, while the fixed-angle method, combined with immobilized laccase, facilitated specific detection through enzyme/substrate interactions. The analytical parameters showed detection limits ranging from 7.5 × 10⁻⁴ µg/mL (PE, 34–50 µm) to 253.2 µg/mL (PMMA, 1 µm), with significant differences based on polymer type and enzymatic affinity. Application of the biosensor to real rainwater samples collected from two regions in Mexico (Tula and Molango) confirmed its functionality, although performance varied depending on matrix composition, exhibiting inhibition in samples with high manganese (Mn²⁺), chromium (Cr²⁺), and zinc (Zn²⁺) content. Despite these limitations, the sensor achieved a 113% recovery rate in Tula rainwater, demonstrating its potential for straightforward in situ environmental monitoring. This study highlights the capabilities of laccase-based SPR biosensors in enhancing microplastic detection and underscores the necessity of considering matrix effects for real-world applications. Full article

In this paper, we experimentally investigated the excitation of spoof surface plasmon polaritons (SSPPs) supported by a 1D subwavelength grating with a rectangular profile in the terahertz (THz) frequency range. Using the attenuated total reflection technique and the THz radiation of the Novosibirsk free electron laser, we carried out detailed studies of both angular and gap spectra at several wavelengths. A shallow grating supporting a fundamental mode was fabricated by means of multibeam X-ray lithography and used as a test sample. The results indicated that we achieved 1-THz tunability of resonance in the frequency range from 1.51 to 2.54 THz on a single grating, which cannot be obtained with active tunable metamaterials. The Q factors of the resonances in the angular spectra were within the range of 19.4–37.6, while the resonances of the gap spectra had a Q factor lying within the 1.17–2.03 range. The gap adjustment capability of the setup shown in the work has great potential in modulation of the absorption efficiency, whereas the angular tuning and recording data from each point of the grating will enable real-time monitoring of changes in the surrounding medium. All of this is highly important for enhanced terahertz real-time absorption spectroscopy and imaging. Full article

Accurate real-time temperature measurement under extreme thermal-pressure conditions remains challenging in aerospace. Sapphire fiber Bragg gratings (FBGs), exhibiting temperature measurement capabilities up to 1900 °C, demonstrate suitability for such extreme environments. However, the development of a high-performance demodulation system capable of processing sapphire FBG signals over wide spectral ranges at elevated speeds remains a technical challenge. This study presents a real-time FBG signal demodulation system that incorporates an all-dielectric subwavelength grating edge filter. The designed grating, comprising a TiO₂/Si₃N₄ subwavelength unit array, modulates Mie-type electric and magnetic multipole resonances to achieve precisely tailored transmission and reflection spectra. Simulation results indicate that the grating exhibits low ohmic loss, excellent linearity, complementary transmission/reflection characteristics, a wide linear range, and angular-dependent tunability. The designed edge-filter-based demodulation system incorporates dual single-point detectors to simultaneously monitor the transmitted and reflected signals. Leveraging the functional relationship between the center wavelength of the FBG and the detected signals, this system enables high-speed, wide-range interrogation of the center wavelength, thus facilitating real-time demodulation for wide-range temperature sensing. The proposed method and system are validated through theoretical modeling, offering an innovative approach for sapphire FBG signal demodulation under extreme thermal-pressure conditions. Full article

Plasmon waveguide resonances (PWRs) have been widely used to enhance the interaction between light and matter. PWRs have been used for chemical and biological sensing, molecular detection, and boosting other optical phenomena, such as Raman scattering and fluorescence. However, the performances of plasmon-waveguide-based structures have been investigated in the angular interrogation mode, and their potential in different spectral regions has hardly been explored. Moreover, the applications of PWRs have been limited to the weak light–matter coupling regime. In this study, we investigate leaky coupled waveguide plasmon resonances (LCWPRs) and explore their potential to enhance light–matter interaction in different spectral regions. In the weak coupling regime, we demonstrate the potential of LCWPRs for sensing in the near-IR region by detecting heavy water (D₂O) and ethanol in water. The experimental results show spectral sensitivity of 15.2 nm/% and 1.41 nm/% for ethanol and D₂O detection, respectively. Additionally, we show that LCWPRs can be used to achieve vibrational strong coupling (VSC) with organic molecules in the mid-IR region. We numerically show that the coupling between LCWPRs and the C=O stretching vibration of hexanal yields a Rabi splitting of 210 cm⁻¹, putting the system in the VSC regime. We anticipate that LCWPRs will be a promising platform for enhanced spectroscopy, sensing, and strong coupling. Full article

The three-component accelerometer array has garnered significant attention in seismic wave detection. In this paper, we designed a three-dimensional optical fiber accelerometer based on a circular cross-section cantilever beam and distributed optical fiber strain interrogator. An externally modulated optical frequency domian reflectometry (OFDR) system with centimeter-level spatial resolution is developed to demodulate the dynamic strain on fiber. An algorithm to reconstruct the three-component acceleration from the strain of the optical fiber was derived, and the factors affecting the errors in reconstruction were also investigated. The developed accelerometer exhibits comparable performance to an electrical accelerometer in the experiment. The correlation coefficient between the reconstructed signal waveforms from the two accelerometers exceeded 0.9, and the angular error was less than 8°. The proposed accelerometer is highly compatible with distributed optical fiber sensing technology, presenting significant potential for long-distance array deployment of three-component seismic wave monitoring. Full article

We show that analyzing archived and future multibeam backscatter and bathymetry data, in tandem with regional environmental parameters, can help to identify polymetallic nodule fields in the world’s oceans. Extensive archived multibeam transit data through remote areas of the world’s oceans are available for data mining. New multibeam data will be made available through the Seabed 2030 Project. Uniformity of along- and across-track backscatter, backscatter intensity, angular response, water depth, nearby ground-truth data, local slope, sedimentation rate, and seafloor age provide thresholds for discriminating areas that are permissive to nodule presence. A case study of this methodology is presented, using archived multibeam data from a remote section of the South Pacific along the Foundation Seamounts between the Selkirk paleomicroplate and East Pacific Rise, that were collected during the 1997 Foundation–Hotline expedition on R/V Atalante. The 12 kHz Simrad EM12D multibeam data and the other forementioned data strongly suggest that a previously unknown nodule occurrence exists along the expedition transit. We also compare the utility of three different backscatter products to demonstrate that scans of printed backscatter maps can be a useful substitute for digital backscatter mosaics calculated using primary multibeam data files. We show that this expeditious analysis of legacy multibeam data could characterize benthic habitat types efficiently in remote deep-ocean areas, prior to more time-consuming and expensive video and sample acquisition surveys. Additionally, utilizing software other than specialty sonar processing programs during this research allows an exploration of how multibeam data products could be interrogated by a broader range of scientists and data users. Future mapping, video, and sampling cruises in this area would test our prediction and investigate how far it might extend to the north and south. Full article

Surface plasmon resonance (SPR) biosensors have experienced rapid development in recent years and have been widely applied in various fields. Angular-interrogation SPR biosensors play an important role in the field of biological detection due to their advantages of reliable results and high stability. However, angular-interrogation SPR biosensors also suffer from low detection sensitivity, poor real-time performance, and limited dynamic detection range, which seriously restricts their application and promotion. Therefore, we designed an angular-interrogation SPR biosensor based on black phosphorus (BP)/graphene two-dimensional (2D) van der Waals heterojunction (vdWhs). On the basis of using the angle-fixed method, this biosensor not only has good real-time performance but also detection sensitivity enhancement. The optical anisotropy characteristic of BP is used to widen the dynamic detection range of biosensors. The simulation results show that the maximum detection sensitivity of the proposed biosensor is 258.6 deg/RIU. Compared with the bare-Ag film structure biosensor, the detection sensitivity was enhanced by 209.2% by 2D vdWhs. The use of anisotropic 2D material BP can not only enhance the detection sensitivity but also widen the detection range. When the fixed incident angle is θ = 5 deg, a maximum dynamic detection range enhanced factor of 123.1% can be achieved, and a detection sensitivity of 185.2 deg/RIU in the corresponding interval can be obtained. The proposed biosensor in this study has potential broad application prospects in several fields, such as biological detection. Full article

This paper presents a new biosensor design based on the Kretschmann configuration, for the detection of analytes at different refractive indices. Our studied design consists of a TiO₂/SiO₂ bi-layer sandwiched between a BK7 prism and a bimetallic layer of Ag/Au plasmonic materials, covered by a layer of black phosphorus placed below the analyte-containing detection medium. The different layers of our structure and analyte detection were optimized using the angular interrogation method. High performance was achieved, with a sensitivity of 240 deg/RIU and a quality factor of 34.7 RIU⁻¹. This biosensor can detect analytes with a wide refractive index range between 1.330 and 1.347, such as glucose detection in urine samples using a refractive index variation of ${10}^{-3}$. This capability offers a wide range of applications for biomedical and biochemical detection and selectivity. Full article

(1) Background: The imaging energy range of a typical Compton camera is limited due to the fact that scattered gamma photons are seldom fully absorbed when the incident energies are above 3 MeV. Further improving the upper energy limit of gamma-ray imaging has important application significance in the active interrogation of special nuclear materials and chemical warfare agents, as well as range verification of proton therapy. (2) Methods: To realize gamma-ray imaging in a wide energy range of 0.3~7 MeV, a principle prototype, named a portable three-layer Compton camera, is developed using the scintillation detector that consists of an silicon photomultiplier array coupled with a Gd₃Al₂Ga₃O₁₂:Ce pixelated scintillator array. Implemented in a list-mode maximum likelihood expectation maximization algorithm, a far-field energy-domain imaging method based on the two interaction events is applied to estimate the initial energy and spatial distribution of gamma-ray sources. The simulation model of the detectors is established based on the Monte Carlo simulation toolkit Geant4. The reconstructed images of a ¹³³Ba, a ¹³⁷Cs and a ⁶⁰Co point-like sources have been successfully obtained with our prototype in laboratory tests and compared with simulation studies. (3) Results: The proportion of effective imaging events accounts for about 2%, which allows our prototype to realize the reconstruction of the distribution of a 0.05 μSv/h ¹³⁷Cs source in 10 s. The angular resolution for resolving two ¹³⁷Cs point-like sources is 15°. Additional simulated imaging of the 6.13 MeV gamma-rays from 14.1 MeV neutron scattering with water preliminarily demonstrates the imaging capability for high incident energy. (4) Conclusions: We conclude that the prototype has a good imaging performance in a wide energy range (0.3~7 MeV), which shows potential in several MeV gamma-ray imaging applications. Full article

The two most common oxidation states of copper in biochemistry are Cu(II) and Cu(I), and while Cu(II) lends itself to spectroscopic interrogation, Cu(I) is silent in most techniques. Ag(I) and Cu(I) are both closed-shell d¹⁰ monovalent ions, and to some extent share ligand and coordination geometry preferences. Therefore, Ag(I) may be applied to explore Cu(I) binding sites in biomolecules. Here, we review applications of ¹¹¹Ag perturbed angular correlation (PAC) of γ-ray spectroscopy aimed to elucidate the chemistry of Cu(I) in biological systems. Examples span from small blue copper proteins such as plastocyanin and azurin (electron transport) over hemocyanin (oxygen transport) to CueR and BxmR (metal-ion-sensing proteins). Finally, possible future applications are discussed. ¹¹¹Ag is a radionuclide which undergoes β-decay to ¹¹¹Cd, and it is a γ-γ cascade of the ¹¹¹Cd daughter nucleus, which is used in PAC measurements. ¹¹¹Ag PAC spectroscopy may provide information on the coordination environment of Ag(I) and on the structural relaxation occurring upon the essentially instantaneous change from Ag(I) to Cd(II). Full article

This numerical research presents a simple hybrid structure comprised of TiO₂-Cu-BaTiO₃ for a modified Kretschmann configuration that exhibits high sensitivity and high resolution for biosensing applications through an angular interrogation method. Recently, copper (Cu) emerged as an exceptional choice as a plasmonic metal for developing surface plasmon sensors (SPR) with high resolution as it yields finer, thinner SPR curves than Ag and Au. As copper is prone to oxidation, especially in ambient conditions, the proposed structure involves the utilization of barium titanate (BaTiO₃) film as a protection layer that not only preserves Cu film from oxidizing but enhances the performance of the sensor to a great extent. Numerical results also show that the utilization of a thin adhesive layer of titanium dioxide (TiO₂) between the prism base and Cu film not only induces strong interaction between them but also enhances the performance of the sensor. Such a configuration, upon suitable optimization of the thickness of each layer, is found to enhance sensitivity as high as 552°/RIU with a figure of merit (FOM) of 136.97 RIU⁻¹. This suggested biosensor design with enhanced sensitivity is expected to enable long-term detection with greater accuracy and sensitivity even when using Cu as a plasmonic metal. Full article

The paper presents the application of the acousto-optic tunable filter (AOTF) in surface plasmon resonance (SPR) spectroscopy to measure the optical thickness of thin dielectric coatings. The technique presented uses combined angular and spectral interrogation modes to obtain the reflection coefficient under the condition of SPR. Surface electromagnetic waves were excited in the Kretschmann geometry, with the AOTF serving as a monochromator and polarizer of light from a white broadband radiation source. The experiments highlighted the high sensitivity of the method and the lower amount of noise in the resonance curves compared with the laser light source. This optical technique can be implemented for nondestructive testing in the production of thin films in not only the visible, but also the infrared and terahertz ranges. Full article