Search Results (59)

Recently, we have described SrMo_1-xMg_xO_3-δ perovskites (x = 0.1, 0.2) as excellent anode materials for solid oxide fuel cells (SOFCs), with mixed ionic and electronic conduction (MIEC) properties. After depositing on the solid electrolyte, they were annealed for sintering at high temperatures (typically 1000 °C), giving rise to oxidized scheelite-type phases, with SrMo_1-xMg_xO_4-δ (x = 0.1, 0.2) stoichiometry. To obtain the active perovskite phases, they were reduced again in the working anode conditions, under H₂ atmosphere. Therefore, there must be an excellent reversibility between the oxidized Sr(Mo, Mg)O_4-δ scheelite and the reduced Sr(Mo, Mg)O_3-δ perovskite phases. This work describes the topotactical oxidation, by annealing at 400 °C in air, of the SrMo_0.9Mg_0.1O_3-δ perovskite oxide. The characterization by X-ray diffraction (XRD) and neutron powder diffraction (NPD) was carried out in order to determine the crystal structure features. The scheelite oxides are tetragonal, space group I4₁/a (No. 88), whereas the perovskites are cubic, s.g. Pm-3m (No. 221). The Rietveld refinement of the scheelite phase from NPD data after annealing the perovskite at 400 °C and cooling it down slowly to RT evidences the absence of intermediate phases between perovskite and scheelite oxides, as well as the presence of oxygen vacancies in both oxidized and reduced phases, essential for their performance as MIEC oxides. The topotactical relationship between both crystal structures is discussed. Full article

This study investigates the structure of a metal hydride (MH) cartridge as a hydrogen storage tank for small-scale fuel cells (FCs). This cartridge is designed to be stacked and used in layers, allowing flexible capacity adjustment according to demand. MH enables compact and safe hydrogen storage for small-scale fuel cell (FC) applications due to its high energy density and low-pressure operation. However, because hydrogen desorption from MH is an endothermic reaction, an external heat supply is required for stable performance. To enhance both the heat transfer efficiency and cartridge usability, we propose a heat supply method that utilizes waste heat from an air-cooled proton-exchange membrane fuel cell (PEMFC). The proposed cartridge incorporates four cylindrical MH tanks that require uniform heat transfer. Therefore, we proposed the tank arrangements within the cartridge to minimize the non-uniformity of heat transfer distribution on the surface. The flow of exhaust air from the PEMFC into the cartridge was analyzed using computational fluid dynamics (CFD) simulations. In addition, an empirical correlation for the Nusselt number was developed to estimate the heat transfer coefficient. As a result, it was concluded that the heat utilization rate of the exhaust heat flowing into the cartridge was 13.2%. Full article

In this study, the cooling performance of fuel cell electric vehicles (FCEVs) with regard to thermal derating is investigated. Particularly in hot climate conditions, low operating temperature of the fuel cell stack and hence low temperature difference to the environment can result in thermal derating of the fuel cell stack. Experimental investigations on a production vehicle with a fuel cell drive (Hyundai Nexo) are conducted to analyze the influence of climatic boundary conditions and a dynamic driving scenario on the thermal management system of the vehicle. Therefore, a new method based on energy balances is introduced to indirectly measure the average cooling air velocity at the cooling module. The results indicate that the two high-power radiator fans effectively maintain a high cooling airflow between a vehicle speed of approximately 30 and 100 $\mathrm{k}\mathrm{m}/\mathrm{h}$, leading to efficient heat rejection at the cooling module largely independent of vehicle speed. Furthermore, this study reveals that the efficiency of the fuel cell system is notably affected by ambient air temperature, attributed to the load on the electric air compressor (EAC) as well as on cooling system components like cooling pump and radiator fans. However, at the stack level, balance of plant (BoP) components demonstrate the ability to ensure ambient temperature-independent performance, likely due to reliable humidification control up to 45 °C. Additionally, a new method for determining thermal derating of FCEVs on roller dynamometer tests is presented. A real-world uphill drive under ambient temperatures exceeding 40 °C demonstrates derating occurring in 6.3% of the time, although a worst case with an aged stack and high payload is not investigated in this study. Finally, a time constant of 50 $\mathrm{s}$ is found to be suitable to correlate the average fuel cell stack power with a coolant temperature at the stack inlet, which gives information on the thermal inertia of the system observed and can be used for future simulation studies. Full article

Hybrid aircraft offer a logical pathway to reducing aviation’s carbon footprint. The thermal management system (TMS) is often neglected in the assessment of hybrid aircraft performance despite it being of major importance. After presenting the TMS architecture, this study performs a sensitivity analysis on several parameters of a retrofitted hybrid fuel cell aircraft’s performance considering three hierarchical levels: the aircraft, fuel cell system, and TMS component levels. The objective is to minimize CO₂ emissions while maintaining performance standards. At the aircraft level, cruise speed, fuel cell power, and ISA temperature were varied to assess their impact. Lowering cruise speeds can decrease emissions by up to $49\%$, and increasing fuel cell power from 200 kW to 400 kW cuts emissions by $18\%$. Higher ambient air temperatures also significantly impact cooling demands. As for the fuel cell, lowering the stack temperature from 80 °C to 60 °C increases the required cooling air mass flow by $49\%$ and TMS drag by $40\%$. At the TMS component level, different coolants and HEX offset-fin geometries reveal low-to-moderate effects on emissions and payload. Overall, despite some design choice improvements, the conventional aircraft is still able to achieve lower CO₂ emissions per unit payload. Full article

Air-cooled proton exchange membrane fuel cells (PEMFCs) offer advantages such as light weight, compact size, and simple structure, and have been widely used in fields such as portable electronics, drones, and new energy electric vehicles. However, due to the influence of air convective cooling efficiency, air-cooled PEMFC can only operate at low power to avoid overheating. To improve the air-cooling efficiency and the maximum output power of PEMFCs, a new enhanced cooling structure has been proposed, which adds secondary micro-channels on the surface of the original bipolar plate flow channels. Thermal simulation analysis was conducted for flow channels with and without an array of micro-channels on the surface. Through orthogonal simulation experiments, the optimal geometric parameters for the secondary micro-channels were determined. The simulation results show that for flow channels with optimized secondary micro-channels, the maximum temperature at the center plane of the MEA is reduced by approximately 10 °C, the thermal resistance of heat transfer in the channel decreases by about 21.2%, and the experimental results on heat transfer in the channel indicate that the maximum heat flux density increases by approximately 22.5%. Finally, performance tests were conducted on air-cooled PEMFC stacks with and without enhanced cooling secondary micro-channels. The test results show that the fuel cell stack with enhanced cooling secondary micro-channels exhibits a temperature reduction of approximately 14 °C at a current density of 0.5 A/cm², a maximum output power increase of about 27%, and improved voltage uniformity across individual cells, demonstrating the effectiveness of the enhanced cooling secondary micro-channel structure. Full article

Hydrogen-based fuel-cell systems are a promising technology for reducing carbon footprint in the portfolio of future propulsion system concepts for small-range and regional aircraft In order to increase efficiency, the application of a turbo-charged air supply, using a compressor stage, a turbine stage, and an electric motor, has proven to be beneficial. This paper explores the thermal management aspects of a pioneering Electrified Turbo Charger designed for fuel-cell applications. A novel approach employing gas-cooling for the electric machine is investigated through simulation using an adiabatic Computational Fluid Dynamics (CFD) model. Bulk-flow-based Heat Transfer Coefficients (BHTCs) and temperatures are extracted from the CFD Analysis and serve as boundary conditions in a Solid Thermal model. Additionally, a 3D transient electromagnetic analysis is employed to assess losses in various components of the machine, which are then integrated into the 3D Solid Thermal Model. Initial evaluation of the temperature distribution is conducted, and subsequent analysis highlights uncertainties inherent in this methodology. Full article

The transition to renewable energy sources from fossil fuels requires that the harvested energy be stored because of the intermittent nature of renewable sources. Thus, lithium-ion batteries have become a widely utilized power source in both daily life and industrial applications due to their high power output and long lifetime. In order to ensure the safe operation of these batteries at their desired power and capacities, it is crucial to implement a thermal management system (TMS) that effectively controls battery temperature. In this study, the thermal performance of a 1S14P lithium-ion battery module composed of cylindrical 18650 cells was compared for distinct cases of natural convection (no cooling), forced air convection, and phase change material (PCM) cooling. During the tests, the greatest temperatures were reached at a 2C discharge rate; the maximum module temperature reached was 55.4 °C under the natural convection condition, whereas forced air convection and PCM cooling reduced the maximum module temperature to 46.1 °C and 52.3 °C, respectively. In addition, contacting the battery module with an aluminum mass without using an active cooling element reduced the temperature to 53.4 °C. The polyamide battery housing (holder) used in the module limited the cooling performance. Thus, simulations on alternative materials document how the cooling efficiency can be increased. Full article

System failure in large-scale electrolyzer and fuel cell installations may cause the formation of explosive H₂–air–steam mixtures. Detonation properties (e.g., detonation cell size) and flame dynamics features (e.g., flame acceleration, runup distance, and deflagration-to-detonation transition “DDT”) of these mixtures were investigated experimentally and numerically to gain a more in-depth understanding of the hazards of H₂–air–steam under conditions pertinent to PEM-based electrolyzers and fuel cells (temperatures between 50 °C and 80 °C and pressures between 20 and 40 bar). While our results confirm the findings of previous studies in terms of the cooling effects of steam on detonation, we found that operating pressures between 20 and 40 bar counteract the effect of steam, making the H₂–air–steam mixture more detonable. This is particularly evident from the experimental data on detonation cell size and runup distance at pressures greater than 20 bar. Full article

The current limitations of air-cooled proton exchange membrane fuel cells (AC-PEMFCs) in water and heat management remain a major obstacle to their commercialization. A 90 cm² full-size AC-PEMFC multi-physical field-coupled numerical model was constructed; isothermal and non-isothermal calculations were performed to explore the effects of univariate and multivariate variables on cell performance, respectively. The isothermal results indicate that lower temperature is beneficial to increase the humidity of MEA, and distribution uniformity at lower stoichiometric ratios and lower temperatures is better. The correlation between current density distribution and temperature, water content, and concentration distribution shows that the performance of AC-PEMFCs is influenced by multiple factors. Notably, under high current operation, the large heat generation may lead to high local temperature and performance decline, especially in the under-channel region with drier MEA. The higher stoichiometric ratio can enhance heat dissipation, improve the uniformity of current density, and increase power density. Optimal fuel cell performance is achieved with a stoichiometric ratio of 300, balancing the mixed influence of multiple factors. Full article

This paper aims to develop a dynamic simulation model for the reduction of energy consumption through the use of organic waste from a residential district, supplied by a hybrid renewable energy plant. The proposed layout is based on a novel paradigm of a renewable energy community focused on the biocircular economy and a sustainable approach. The novelty with respect to the majority of papers developed in the literature on renewable energy communities lies in the use of both solar photovoltaic production and the organic fraction of municipal solid waste collected by the community. Energy production by biomass conversion and by photovoltaic fields shared among the buildings is used to satisfy in a sustainable manner the community loads for heating, cooling, and power. The district heating network is based on water loop heat pumps and air-to-air heat pumps and it includes the power-to-heat energy storage strategy. The biogas produced by the anaerobic digestion process is cleaned in order to supply a solid oxide fuel cell for the production of additional power, mainly during the hours of poor or null solar energy production. Then, the layout integrates several innovative topics, such as the power-to-heat strategy, the biocircular economy, the low-temperature district heating, the use of a solid oxide fuel cell, and a renewable energy community. The dynamic model of the proposed hybrid renewable layout is developed in the TRNSYS environment, but some innovative energy components, such as anaerobic digestion, the biogas upgrading unit, and the solid oxide fuel cell, are dynamically modeled in MATLAB and then integrated into the whole plant model. The proposed plant has been confirmed to be extremely profitable and able to obtain important energy savings, considering the achieved payback period of 4.48 years and the primary energy saving of 23%. This layout resulted in an interesting solution for pushing the development of smart and sustainable cities. Full article

The hydrogen oxygen fuel cell is a power source with significant potential for development. The air compressor provides ample oxygen for the fuel cell, and as a key component of the air compressor, the performance of the motor greatly impacts the efficiency of the fuel cell. In order to enhance the system performance of high-speed permanent magnet motors, optimization was conducted on the motor’s geometric dimensions to minimize rotor loss and maximize power density, taking into account the comprehensive constraints of electromagnetic and mechanical properties. The finite-element method was employed to analyze the motor’s performance, conducting a multi-physical field analysis that included electromagnetic field, rotor loss, and mechanical strength analysis, as well as temperature field analysis. Aiming at the problem of high temperature rise in high-speed motor winding, the influence of the cooling water flow rate on the winding temperature rise was analyzed and simulated. Based on the analysis results, the minimum cooling water flow rate was obtained. According to the optimized design results, a prototype of an 18 kW, 100,000 rpm motor was manufactured, and the efficiency and temperature rise were tested. The experimental results verify the correctness and effectiveness of the optimal design. Full article

This numerical study presents six three-dimensional (3D) cathode flow field designs for a passive air-cooled polymer electrolyte membrane (PEM) fuel cell to enhance heat removal and H₂O retention. The data collected are evaluated in terms of water content, average temperature, and current flux density. The proposed cathode flow field designs are a straight baseline channel (Design 1), converging channel (Design 2), diverging channel (Design 3), straight channel with cylindrical pin fins (Design 4), trapezium cross-section channel (Design 5), and semi-circle cross-section channel (Design 6). The lowest cell temperature value of 56.67 °C was obtained for Design 2, while a noticeable water retention improvement of 6.5% was achieved in a semi-circle cathode flow field (Design 5) compared to the baseline channel. However, the current flux density shows a reduction of 0.1% to 1.2%. Nevertheless, those values are relatively small compared to the improvement in the durability of the fuel cell due to heat reduction. Although the modifications to the cathode flow field resulted in only minor improvements, ongoing advancements in fuel cell technology have the potential to make our energy landscape more sustainable. These advancements can help reduce emissions, increase efficiency, integrate renewable energy sources, enhance energy security, and support the transition to a hydrogen-based economy. Full article

Air-breathing proton exchange membrane fuel cells (PEMFCs) show enormous potential in small and portable applications because of their brief construction time without the need for gas supply, humidification and cooling devices. In the current work, a 3D multiphase model of single air-breathing PEMFCs is developed by considering the contact resistance between the gas diffusion layer and bipolar plate and the anisotropic thermal conduction and electric conductive in the through-plane and in-plane directions. The 3D model presents good grid independence and agreement with the experimental polarization curve. The single PEMFC with the best open area ratio of 55% achieves the maximum peak power density of 179.3 mW cm⁻². For the fuel cell stack with 10 single fuel cells, the application of the anode window flow field is beneficial to improve the stack peak power density compared to the anode serpentine flow field. The developed model is capable of providing assistance in designing high-performance air-breathing PEMFC stacks. Full article

Due to the lack of oil injection cooling, it is usually necessary for dry twin-screw compressors to design cooling jackets to carry away the heat generated during operation. In order to investigate to what extent a cooling jacket can improve the performance of screw compressors, this study set up an experimental platform for a dry twin-screw compressor applied in fuel cell vehicles and used water as the working liquid in the cooling jacket. Then, the performance parameters of the screw compressor under different rotating speeds, discharge pressures, and cooling water flow rates were measured. It can be considered that the existence of a water cooling jacket is of great significance for improving the performance of dry screw compressors and improving extreme operating conditions. The research results may provide a reference for the development and improvement of dry twin-screw compressors in the future. Full article

Hydrogen is a promising energy carrier in all fields of transportation, including unmanned aerial vehicles (UAVs) and manned vehicles for urban air mobility (UAM). In these applications, one of the biggest challenges is to overcome the limitations of lithium battery technologies, while keeping the advantage of clean energy, at least in terms of direct emissions. For these reasons, there is an ever-increasing interest in the development, simulation, and testing of propulsion systems adopting air-cooled proton exchange membrane fuel cells (PEMFCs). Fuel cells for aerospace must be designed for power-to-weight maximization. For this reason, auxiliary systems are simplified, and the adoption of air-cooling and passive cooling techniques is favored. However, the performance and dynamic behavior of PEMFCs are affected by the operating conditions, which, in applications like UAVs and UAM, are continuously changing due to the variation of speed and altitude during the flight. This investigation analyzes semi-empirical and control-oriented models of fuel cell systems proposed in the scientific literature. The review addresses the whole fuel cell system, inclusive of the balance of the plant, and introduces the transition from dynamic models to digital twins. Full article