Search Results (251)

Biomass gasification represents a pivotal technology for sustainable energy and chemical production, yet its efficiency and product quality are critically dependent on catalyst performance. This comprehensive review systematically synthesizes recent advancements in catalyst design, mechanistic insights, and process integration in biomass gasification. Firstly, it details the development and performance of catalysts in diverse categories, including metal-based catalysts, Ca-based catalysts, natural mineral catalysts, composite/supported catalysts, and emerging waste-derived catalysts. Secondly, this review delves into the fundamental catalytic reaction mechanisms governing key processes such as tar cracking/reforming, water–gas shift, and methane reforming. It further explores sophisticated strategies for catalyst structure optimization, focusing on pore structure/surface area control, strong metal–support interactions (SMSIs), alloying effects, nanodispersion, and crystal phase design. The critical challenges of catalyst deactivation mechanisms and the corresponding activation, regeneration strategies, and post-regeneration performance evaluation are thoroughly discussed. Thirdly, this review addresses the crucial integration of zero CO₂ emission concepts, covering in situ CO₂ adsorption/conversion, carbon capture and storage (CCS) integration, catalytic CO₂ reduction/valorization, multi-energy system synergy, and environmental impact/life cycle analysis (LCA). By synthesizing cutting-edge research, this review identifies key knowledge gaps and outlines future research directions towards designing robust, cost-effective, and environmentally benign catalysts for next-generation, carbon-neutral biomass gasification systems. Full article

Shale pore architecture governs gas storage capacity, permeability, and production potential in reservoirs. Therefore, this study systematically investigates the pore structure features and influencing factors of the Niutitang Formation shale from the QX1 well in northern Guizhou using field emission scanning electron microscopy (FE-SEM), high-pressure mercury intrusion (HPMI), low-temperature nitrogen adsorption (LTNA), and nuclear magnetic resonance (NMR) experiments. The results show that ① The pore size of the QX1 well’s Niutitang Formation shale is primarily in the nanometer range, with pore types including intragranular pores, intergranular pores, organic matter pores, and microfractures, with the former two types constituting the primary pore network. ② Pore shapes are plate-shaped intersecting conical microfractures or plate-shaped intersecting ink bottles, ellipsoidal, and beaded pores. ③ The pore size distribution showed a multi-peak distribution, predominantly mesopores, followed by micropores, with the fewest macropores. ④ The fractal dimension D₁ > D₂ indicates that the shale pore system is characterized by a rough surface and some connectivity of the pore network. ⑤ Carbonate mineral abundances are the main controlling factors affecting the pore structure of shales in the study area, and total organic carbon (TOC) content also has some influence, while clay mineral content shows negligible statistical correlation. Full article

Marine–continental transitional shale is a promising unconventional gas reservoir, playing an increasingly important role in China’s energy portfolio. However, compared to marine shale, research on marine–continental transitional shale’s fractal characteristics of pore structure and complete pore size distribution remains limited. In this work, high-pressure mercury intrusion, N₂ adsorption, and CO₂ adsorption techniques, combined with fractal geometry modeling, were employed to characterize the pore structure of the Shanxi Formation marine–continental transitional shale. The shale exhibits generally high TOC content and abundant clay minerals, indicating strong hydrocarbon-generation potential. The pore size distribution is multi-modal: micropores and mesopores dominate, contributing the majority of the specific surface area and pore volume, whereas macropores display a single-peak distribution. Fractal analysis reveals that micropores have high fractal dimensions and structural regularity, mesopores exhibit dual-fractal characteristics, and macropores show large variations in fractal dimension. Characteristics of pore structure is primarily controlled by TOC content and mineral composition. These findings provide a quantitative basis for evaluating shale reservoir quality, understanding gas storage mechanisms, and optimizing strategies for sustainable of oil and gas development in marine–continental transitional shales. Full article

TiVCr-based alloys are well-explored body-centered cubic (BCC) materials for hydrogen storage applications that can potentially store higher amounts of hydrogen at moderate temperatures. The challenge remains in optimizing the alloy-hydrogen stability, and several transition elements have been found to support the reduction in the hydride stability. In this study, Ni and Nb transition elements were incorporated into the TiVCr alloy system to thoroughly understand their influence on the (de)hydrogenation kinetics and thermodynamic properties. Three different compositions, (TiVCr)₉₅Ni₅, (TiVCr)₉₀ Ni₁₀, and (TiVCr)₉₅Ni₅Nb₅, were prepared via arc melting. The as-prepared samples showed the formation of a dual-phase BCC solid solution and secondary phase precipitates. The samples were characterized using hydrogen sorption studies. Among the studied compositions, (TiVCr)₉₀Ni₁₀ exhibited the highest hydrogen absorption capacity of 3 wt%, whereas both (TiVCr)₉₅Ni₅ and (TiVCr)₉₀Ni₅Nb₅ absorbed up to 2.5 wt% hydrogen. The kinetics of (de)hydrogenation were modeled using the JMAK and 3D Jander diffusion models. The kinetics results showed that the presence of Ni improved hydrogen adsorption at the interface level, whereas Nb substitution enhanced diffusion and hydrogen release at room temperature. Thus, the addition of Ni and Nb to Ti-V-Cr-based high-entropy alloys significantly improved the hydrogen absorption and desorption properties at room temperature for gas-phase hydrogen storage. Full article

The investigation of the pore structure and fractal characteristics of coal-bearing shale is critical for unraveling reservoir heterogeneity, storage-seepage capacity, and gas occurrence mechanisms. In this study, 12 representative Upper Paleozoic coal-bearing shale samples from the Yangquan Block of the Qinshui Basin were systematically analyzed through field emission scanning electron microscopy (FE-SEM), high-pressure mercury intrusion, and gas adsorption experiments to characterize pore structures and calculate multi-scale fractal dimensions (D₁–D₅). Key findings reveal that reservoir pores are predominantly composed of macropores generated by brittle fracturing and interlayer pores within clay minerals, with residual organic pores exhibiting low proportions. Macropores dominate the total pore volume, while mesopores primarily contribute to the specific surface area. Fractal dimension D₁ shows a significant positive correlation with clay mineral content, highlighting the role of diagenetic modification in enhancing the complexity of interlayer pores. D₂ is strongly correlated with the quartz content, indicating that brittle fracturing serves as a key driver of macropore network complexity. Fractal dimensions D₃–D₅ further unveil the synergistic control of tectonic activity and dissolution on the spatial distribution of pore-fracture systems. Notably, during the overmature stage, the collapse of organic pores suppresses mesopore complexity, whereas inorganic diagenetic processes (e.g., quartz cementation and tectonic fracturing) significantly amplify the heterogeneity of macropores and fractures. These findings provide multi-scale fractal theoretical insights for evaluating coal-bearing shale gas reservoirs and offer actionable recommendations for optimizing the exploration and development of Upper Paleozoic coal-bearing shale gas resources in the Yangquan Block of the Qinshui Basin. Full article

We studied the adsorption thermodynamics and mechanism behind the binding of nitric oxide (NO) in the interior surfaces and structural fragments of the high metal center density microporous Metal-Organic Framework (MOF) CPO-27-Cu, by gas sorption, at a series of temperatures. For the purpose of comparison, we also measured the corresponding CO₂ adsorption isotherms, and as a result, the isosteric heats of adsorption for the two studied adsorptives were derived, being in the range of 12–15 kJ/mol for NO at loadings up to 0.5 NO molecules per formula unit (f.u.) of the bare compound (C₄O₃HCu), and 23–25 kJ/mol CO₂ in the range 0–1 CO₂ per f.u. Microscopically, the mode of NO binding near the square pyramid Cu(II) centers was directly accessed with the use of in situ NO gas adsorption X-ray Absorption Spectroscopy (XAS). Additionally, during the vacuum/temperature activation of the material and consequent NO adsorption, the electronic state of the Cu-species was monitored by observing the corresponding X-ray Near Edge Spectra (XANES). Contrary to the previously anticipated chemisorption mechanism for NO binding at Cu(II) species, we found that at slightly elevated temperatures, under ambient, but also cryogenic conditions, only relatively weak physisorption takes place, with no evidence for a particular adsorption preference to the coordinatively unsaturated Cu-centers of the material. Full article

Shale and coal in the transitional marine–continental facies of the Ordos Basin serve as unconventional natural gas reservoirs, with their pore structures controlling gas adsorption characteristics and occurrence states. To quantitatively characterize the pore structure features and differences between these two reservoirs, this study takes the Shanxi Formation shale and coal in the Daning–Jixian area on the eastern margin of the Ordos Basin as examples. Field-emission scanning electron microscopy (FE-SEM), high-pressure mercury intrusion, low-temperature N₂ adsorption, and low-pressure CO₂ adsorption experiments were employed to analyze and compare the full-scale pore structures of the shale and coal reservoirs. Combined with methane isothermal adsorption experiments, the gas adsorption capacity and its differences in these reservoirs were investigated. The results indicate that the average total organic carbon (TOC) content of shale is 2.66%, with well-developed organic pores, inorganic pores, and microfractures. Organic pores are the most common, typically occurring densely and in clusters. The average TOC content of coal is 74.22%, with organic gas pores being the dominant pore type, significantly larger in diameter than those in transitional marine–continental facies shale and marine shale. In coal, micropores contribute the most to pore volume, while mesopores and macropores contribute less. In shale, mesopores dominate, followed by micropores, with macropores being underdeveloped. Both coal and shale exhibit a high SSA primarily contributed by micropores, with organic matter serving as the material basis for micropore development. The methane adsorption capacity of coal is 8–29 times higher than that of shale. Coal contains abundant organic micropores, providing a large SSA and numerous adsorption sites for methane, facilitating gas adsorption and storage. This study comprehensively reveals the similarities and differences in pore structures between transitional marine–continental facies shale and coal reservoirs in the Ordos Basin at the microscale, providing a scientific basis for the precise evaluation and development of unconventional oil and gas resources. Full article

Progressive research on reducing engine emissions is highly valued due to the emissions’ significant environmental and health impacts. This comprehensive comparative study examines the catalytic efficiency of manganese (Mn) and cerium silica (Ce-Si) synthesis catalyst-based molds in a diesel engine using a selective catalytic reduction (SCR) technique with diesel and diesel–plastic oil blend (DPB) (B50). In addition to Fourier transform infrared spectroscopy (FTIR) studies, X-ray diffraction (XRD), scanning electron microscopy (SEM), and the Brunauer–Emmett–Teller (BET) method are utilized to characterize the produced molds before and after exhaust gas passes. The Ce-Si-based mold demonstrates superior redox capacity, better adsorption capacity, and better thermal stability, attributed to enhanced oxygen storage and structural integrity compared to the Mn-based mold. Under minimum load conditions, nitrogen oxide (NO) reduction efficiency peaks at 80.70% for the Ce-Si-based mold in the SCR treatment with DPB fuel. Additionally, significant reductions of 86.84%, 65.75%, and 88.88% in hydrocarbon (HC), carbon monoxide (CO), and smoke emissions, respectively, are achieved in the SCR treatment under optimized conditions. Despite a wide temperature range, Ce-Si-based mold promotes high surface area and superior gas diffusion properties. Overall, the Ce-Si-based mold provides efficient emission control in diesel engines, which paves a path for developing better environmental sustainability. The outcomes contribute to advancing environmental sustainability by supporting the achievement of SDGs 7, 11, and 13. Full article

Heavy industry is a significant contributor to CO₂ global emissions, accounting for approximately 25% of the total. In Europe, the continent’s largest emitting industries, including steel, cement, and power generation, face significant decarbonization challenges due to multiple interrelated factors. Heavy industry must achieve carbon neutrality by 2050, as outlined in the 13th United Nations Sustainable Goals. One strategy to achieve this goal involves Carbon Capture Utilization and Storage (CCUS) with post-combustion carbon capture (PCC) technologies playing a critical role. Key methods include absorption, which uses chemical solvents like amines; adsorption, employing solid sorbents; cyclic CO₂ capture, such as calcium looping methods; cryogenic separation, which involves chilling flue gas to liquefy CO₂; and membrane separation, leveraging polymeric materials. Each technology offers unique advantages and challenges, necessitating hybrid approaches and policy support for widespread adoption. In this sense, this review provides a comprehensive overview of the existing European pilot and demonstration units and projects, funded by the EU across several industries. It specifically focuses on PCC. This study examines 111 industrial facilities across Europe, documenting the PCC technologies deployed at plants of varying capacities, geographic locations, and operational stakeholders. The review further evaluates the techno-economic performance of these systems, assessing their potential to advance carbon neutrality in heavy industries. Full article

This study presents a comprehensive experimental evaluation of pure methane (CH₄) and carbon dioxide (CO₂) adsorption on organic-rich shale samples from the Cesar-Ranchería Basin, Colombia. Adsorption isotherms were measured at two temperatures (50 °C and 80 °C) and up to 3 MPa using a manometric method. The data were fitted using the Langmuir model. The samples exhibit high total organic carbon (TOC) contents, ranging from 33.44% to 69.63%, but surprisingly low BET surface areas (1–7 m²/g), an uncommon combination in shale systems. Despite these low surface areas, the samples showed notable adsorption capacities, particularly for CO₂, which consistently outperformed CH₄ across all conditions. Maximum CO₂ adsorption capacities reached up to 1.6 mol/kg, while CH₄ values peaked at 0.49 mol/kg. The Langmuir parameters reflect a stronger affinity and greater capacity for CO₂, supporting its potential role in enhanced gas recovery and CO₂ sequestration. These findings contribute to understanding gas–shale interactions in thermally immature and highly organic-rich formations and highlight the importance of mineralogy and organic matter characteristics beyond surface area alone. This work provides novel insights into the adsorption behavior of Colombian shales and serves as a valuable reference for future gas in-place estimations and shale reservoir evaluations in similar geological contexts. Full article

The coal reservoir in the Ordos Mizhi block is buried at a depth of over 2000 m. This study aims to obtain the characteristics of the coal reservoir in the Mizhi block through various experimental methods and combine the gas-bearing characteristics obtained from on-site desorption experiments to analyze the gas content and logging response characteristics of the study area. On this basis, a reservoir parameter interpretation model for the study area is established. This provides a reference for the exploration and development of coal-rock gas in the Mizhi block. The research results show that: (1) The study area is characterized by the development of the No. 8 coal reservoirs of the Benxi Formation, with a thickness ranging from 2 to 11.6 m, averaging 7.2 m. The thicker coal reservoirs provide favorable conditions for the formation and storage of coal-rock gas. The lithotypes are mainly semi-bright and semi-dark. The coal maceral is dominated by the content of the vitrinite, followed by the inertinite, and the exinite is the least. The degree of metamorphism is high, making it a high-grade coal. In the proximate analysis, the moisture ranges from 0.36 to 1.09%, averaging 0.65%. The ash ranges from 2.34 to 42.17%, averaging 16.57%. The volatile ranges from 9.18 to 15.7%, averaging 11.50%. The fixed carbon ranges from 45.24 to 87.51%, averaging 71.28%. (2) According to the results of scanning electron microscopy (SEM), the coal samples in the Mizhi block have developed fractures and pores. Based on the results of the carbon dioxide adsorption experiment, the micropore adsorption capacity is 7.8728–20.3395 cm³/g, with an average of 15.2621 cm³/g. The pore volume is 0.02492–0.063 cm³/g, with an average of 0.04799 cm³/g. The specific surface area of micropores is 79.514–202.3744 m²/g, with an average of 153.5118 m²/g. The micropore parameters are of great significance for the occurrence of coal-rock gas. Based on the results of the desorption experiment, the gas content of the coal rock samples in the study area is 12.97–33.96 m³/t, with an average of 21.8229 m³/t, which is relatively high. (3) Through the correlation analysis of the logging parameters of the coal reservoir, the main logging response parameters of the reservoir are obtained. Based on the results of the logging sensitivity analysis of the coal reservoir, the interpretation model of the reservoir parameters is constructed and verified. Logging interpretation models for parameters such as industrial components, microscopic components, micropore pore parameters, and gas content are obtained. The interpretation models have interpretation effects on the reservoir parameters in the study area. Full article

Anthropogenic CO₂ emissions are a major driver of climate change, highlighting the urgent need for effective mitigation strategies. Carbon Capture, Utilization, and Storage (CCUS) offers a promising approach, particularly through CO₂-enhanced gas recovery (EGR) in shale reservoirs, which enables simultaneous hydrocarbon production and CO₂ sequestration. This study employs a numerical simulation model to compare two injection strategies: CO₂ flooding and huff-and-puff (H&P). The results indicate that, without accounting for key mechanisms such as adsorption and molecular diffusion, CO₂ H&P provides minimal improvement in methane recovery. When adsorption is included, methane recovery increases by 9%, with 14% of the injected CO₂ stored over 40 years. Incorporating diffusion enhances recovery by 19%, although with limited storage potential. In contrast, CO₂ flooding improves methane production by 26% and retains up to 94% of the injected CO₂. Higher storage efficiency is observed in reservoirs with high porosity and low permeability, particularly in nano-scale pore systems. Overall, CO₂ H&P may be a viable EGR option when adsorption and diffusion are considered, while CO₂ flooding demonstrates greater effectiveness for both enhanced gas recovery and long-term CO₂ storage in shale formations. Full article

Organic matter pores constitute a significant storage space in shale gas reservoirs, contributing to approximately 50% of the total porosity. This study employed a comprehensive approach, utilizing scanning electron microscopy, low-pressure N₂ adsorption, thermal analysis, image statistics, and fractal theory, to quantitatively characterize the structure and complexity of organic matter pores in the Wufeng–lower Longmaxi Formations (WLLFs). The WLLFs exhibit a high organic matter content, averaging 3.20%. Organic matter pores are typically well-developed, predominantly observed within organic matter clusters, organic matter–clay mineral complexes, and the internal organic matter of pyrite framboid. The morphology of these pores is generally elliptical and spindle-shaped, with the primary pore diameter displaying a bimodal distribution at 10~40 nm and 100~160 nm, potentially influenced by the observational limit of scanning electron microscopy. Shales from greater burial depths within the same gas well contain more organic matter pores; however, the development of organic matter pores in deep gas wells is roughly equivalent to that in medium and shallow gas wells. Fractal dimension values can be utilized to characterize the complexity of organic matter pores, with organic matter macropores (D_>50) being more complex than organic matter mesopores (D_2–50), which in turn are more complex than organic matter micropores (D_<2). The development of macropores and mesopores is a key factor in the heterogeneity of organic matter pores. The complexity of organic matter pores in the same well increases gradually with the burial depth of the shale, and the complexity of organic matter pores in deep gas wells is roughly equivalent to that in medium and shallow gas wells. The structure and fractal characteristics of organic matter pores in shale are primarily controlled by components, diagenesis, tectonism, etc. The lower Longmaxi shale exhibit a high biogenic quartz content and robust hydrocarbon generation from organic matter. This composition effectively shields organic matter pores from multi-directional extrusion, leading to the formation of macropores and mesopores without specific orientation. High-quality shale sections (one and two sublayers) have relatively high fractal dimension D_2–50 and D_>50 values of organic matter pores and gas content. Consequently, the quality parameters of shale and fractal dimension characteristics can be comprehensively evaluated to identify high-quality shale sections. Full article

Recognizing the growing importance of natural gas as a transition fuel in Poland’s energy mix and the necessity of reducing CO₂ emissions, this article aims to assess the use of carbon capture and storage (CCS) technology to effectively reduce CO₂ emissions from combined cycle gas turbine (CCGT). The research employs the pressure–temperature swing adsorption (PTSA) to capture CO₂ from flue gases. Computer simulations, using IPSEpro (SimTech), are used to calculate the heat and mass balances for CCGT and PTSA units and assess their performance. In the first part of the research, the effect of sorbent type (Na-A and 5A) and flue gas share directed to the PTSA unit on the performance of the CCGT was investigated. Secondly, the parametric analysis regarding the adsorption and desorption pressures in the PTSA was carried out. The results showed that CO₂ emissions from CCGT can be reduced by 1.1 Mt (megatons) per year, but the use of PTSA was associated with a reduction in net electrical power and efficiency of the CCGT by up to 14.7% for Na-A and 11.1% for 5A sorbent. It was also found that the heat and electricity demand of the PTSA depends on the adsorption and desorption pressures. Full article

A technology that directly injects CO₂-rich industrial waste gas (CO₂-rich IWG) into underground spaces for unconventional natural gas extraction and waste gas storage has received increasing attention. The pore characteristics of coal and shale in a coal-bearing rock series before and after CO₂-rich IWG treatment are closely related to gas recovery and storage. In this study, three coals ranging from low to high rank and one shale sample were collected. The samples were treated with CO₂-rich IWG using a high-precision geochemical reactor. The changes in the pore volume (PV), specific surface area (SSA), and pore size distribution of micropores, mesopores, and macropores were analyzed. The correlations between the Langmuir volume and the PV and SSA of the micropores and mesopores were analyzed. It was confirmed that for micropores, SSA was the dominant factor influencing adsorption capacity. The effectively interconnected pore volume was calculated using macropores to characterize changes in the sample’s connectivity. It was found that the PV and SSA of the micropores in the coal samples increased with increasing coal rank. The CO₂-rich IWG treatment increased the PV and SSA of the micropores in all of the samples. In addition, for mesopores and macropores, the treatment reduced the SSA in the coal samples but enhanced it in the shale. The results of this study improve the understanding of the mechanisms of the CO₂-rich IWG treatment method and emphasize its potential in waste gas storage and natural gas extraction. Full article