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18 pages, 4489 KB  
Article
Elaboration and Solar Thermal Cycling of SiC/Al2O3/Fe–Cr–Al–Mo Multilayers
by Thiane Ndiaye, Reine Reoyo-Prats, Frédéric Mercier, Thierry Encinas, Stéphane Coindeau, Christophe Escape and Ludovic Charpentier
Corros. Mater. Degrad. 2026, 7(2), 28; https://doi.org/10.3390/cmd7020028 - 30 Apr 2026
Viewed by 405
Abstract
Concentrated Solar Power (CSP) tower systems require receiver materials capable of operating above 1000 °C to meet the efficiency targets of third-generation technologies (25–30%). Hybrid solutions, combining ceramic coatings with metallic substrates, offer promising thermomechanical stability under severe thermal cycling. This study investigates [...] Read more.
Concentrated Solar Power (CSP) tower systems require receiver materials capable of operating above 1000 °C to meet the efficiency targets of third-generation technologies (25–30%). Hybrid solutions, combining ceramic coatings with metallic substrates, offer promising thermomechanical stability under severe thermal cycling. This study investigates the high-temperature behavior of silicon carbide (SiC) coatings deposited on Fe-C-Al-Mo alloys under concentrated solar flux. Substrates were pre-oxidized to form a continuous 1–2 µm α-Al2O3 interlayer, serving as a chemical and mechanical buffer. SiC coatings (10–24 µm thick) were deposited via High-Temperature Chemical Vapor Deposition (HT-CVD). Characterization using XRD, SEM, EDS, and optical spectrophotometry identified cubic 3C-SiC with a globular microstructure and high compressive residual stresses (−2000 to −2400 MPa), inducing microcracking. Stress relaxation was achieved by increasing coating thickness or post-deposition annealing. Controlled oxidation formed a thin silica layer, enhancing solar absorptivity to over 90%. Accelerated thermal cycling (up to ~900 kW/m2, 1050–1200 °C) revealed that coating stability depends on SiC thickness, residual stress evolution, α-Al2O3 interlayer thickness, and cycling severity. Optimizing these parameters is essential for ensuring the long-term durability of hybrid CSP receivers. Full article
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25 pages, 13435 KB  
Article
Preliminary Design Optimization of CFRP Crash Box for High-Performance Automotive Applications
by Antonio Maria Caporale, Alessandro Amato and Gerardus Janszen
J. Compos. Sci. 2026, 10(2), 94; https://doi.org/10.3390/jcs10020094 - 11 Feb 2026
Viewed by 1180
Abstract
This study presents a hybrid experimental–numerical methodology for the preliminary design and optimization of a CFRP crash box intended for high-performance automotive applications. An initial experimental campaign was conducted on frustum-shaped crash boxes manufactured by Pagani Automobili S.p.A., comparing constant and variable thickness [...] Read more.
This study presents a hybrid experimental–numerical methodology for the preliminary design and optimization of a CFRP crash box intended for high-performance automotive applications. An initial experimental campaign was conducted on frustum-shaped crash boxes manufactured by Pagani Automobili S.p.A., comparing constant and variable thickness configurations through drop tower impact tests to evaluate energy absorption, crushing stability, and failure mechanisms. A lightweight finite element model was developed in Abaqus/Explicit using shell elements and Hashin-based damage criteria, achieving calibration errors below 10% for most parameters and under 15% for peak forces. Geometric enhancements, including continuous flanges, removal of the top surface, and an internal cruciform reinforcement, significantly improved energy absorption (up to 110%) but introduced trade-offs in stroke efficiency and mean force levels. To mitigate these effects, a genetic algorithm was employed to optimize laminate layup by varying ply orientations, resulting in improved stroke efficiency and reduced peak and average forces while maintaining crushing stability. The proposed approach demonstrates that integrating experimental validation with efficient numerical modeling and optimization accelerates the development of lightweight, high-performance crash absorbers, offering a robust framework for motorsport and automotive applications that balances safety, efficiency, and manufacturability. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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27 pages, 2038 KB  
Article
Demonstrating an Ontological Framework for Sustainable PVC Material Science: A Holistic Study Combining Granta EduPack, Bibliometric Analysis, Thematic Analysis, Content Analysis, and Protégé
by Alexander Chidara, Kai Cheng and David Gallear
Appl. Sci. 2026, 16(4), 1677; https://doi.org/10.3390/app16041677 - 7 Feb 2026
Viewed by 535
Abstract
Addressing the growing need for sustainable innovation in PVC materials, this study presents an illustrative framework that develops and demonstrates an ontological system that integrates lifecycle simulation using Granta EduPack, systematic literature analysis (including bibliometric, thematic, and content analytics) of peer-reviewed publications, and [...] Read more.
Addressing the growing need for sustainable innovation in PVC materials, this study presents an illustrative framework that develops and demonstrates an ontological system that integrates lifecycle simulation using Granta EduPack, systematic literature analysis (including bibliometric, thematic, and content analytics) of peer-reviewed publications, and Protégé-based semantic reasoning, and their combination, in a holistic manner. Material and use-phase data for PVC, HDPE, PP, PET, and FRP cooling-tower components were sourced from ANSYS Granta EduPack Level-3 Polymer Sustainability 2023 R2 Version; 23.2.1, and a systematic analysis of the literature was then encoded as ontology classes, properties, and individuals following the Seven-Step ontology development method. Eco-audit simulations, standardised to a functional unit of 1 kg cooling tower fill material, reveal that the use phase dominates environmental impact (67 MJ primary energy, ~80% of total lifecycle), while material production and end-of-life recycling contribute ~15% and credits of ~900 MJ and 28 kg CO2 via recycling offsets. Ontology reasoning with corrected SWRL rules and SPARQL queries classifies VirginPVCRef and PVC10ES as strong structural materials (tensile strength ≥ 40 MPa), identifies PVCRH40 as high-moisture-risk (water absorption > 0.10 g/g), and ranks hydro-thermal dechlorination (recyclability 0.90) over mechanical recycling (0.55). A systematic analysis of 40 Scopus-indexed publications (2015–2025) highlighted key themes in recycling technologies, LCA emissions, additive toxicity, ontology frameworks, machine learning integration, circular economy policy, and cooling-tower applications. Demonstrated via a simulation-based cooling-tower case study, hybrid PVC-FRP designs yield the highest justified Material Sustainability Performance Index (MSPI), outperforming PVC-only and FRP-only alternatives. This framework provides a conceptual decision-support tool for exploring PVC material optimisation, illustrating pathways to enhancing circularity and environmental responsibility in industrial applications. The proposed framework is, therefore, not intended as a validated decision-support tool, nor does it claim analytical optimisation or predictive performance but rather serves as a method of illustration that shows how domain knowledge can be formally structured using ontology principles linked to simulation representations, and that was examined for internal logical consistency. Full article
(This article belongs to the Section Materials Science and Engineering)
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20 pages, 5299 KB  
Article
Study on the Deterioration Characteristics of Sandstone Cultural Relics Under the Synergistic Action of Dry-Wet Cycles and Acids, Alkalis, Salts and Composite Solutions
by Jiawei Zhang, Pu Hu, Yushan Lian, Wei Huang, Yong Zheng, Qingyang Wu and Yuanchun Niu
Appl. Sci. 2026, 16(2), 770; https://doi.org/10.3390/app16020770 - 12 Jan 2026
Viewed by 698
Abstract
Stone cultural relics are primarily composed of sandstone, a water-sensitive rock that is highly susceptible to deterioration from environmental solutions and dry-wet cycles. Sandstone pagodas are often directly exposed to natural elements, posing significant risks to their preservation. Therefore, it is crucial to [...] Read more.
Stone cultural relics are primarily composed of sandstone, a water-sensitive rock that is highly susceptible to deterioration from environmental solutions and dry-wet cycles. Sandstone pagodas are often directly exposed to natural elements, posing significant risks to their preservation. Therefore, it is crucial to investigate the performance of sandstone towers in complex solution environments and understand the degradation mechanisms influenced by multiple environmental factors. This paper focuses on the twin towers of the Huachi Stone Statue in Qingyang City, Gansu Province, China, analyzing the changes in chemical composition, surface/microstructure, physical properties, and mechanical characteristics of sandstone under the combined effects of various solutions and dry-wet cycles. The results indicate that distilled water has the least effect on the mineral composition of sandstone, while a 5% Na2SO4 solution can induce the formation of gypsum (CaSO4·2H2O). An acidic solution, such as sulfuric acid, significantly dissolves calcite and diopside, leading to an increase in gypsum diffraction peaks. Additionally, an alkaline solution (sodium hydroxide) slightly hydrolyzes quartz and albite, promoting calcite precipitation. The composite solution demonstrates a synergistic ion effect when mixed with various single solutions. Microstructural examinations reveal that sandstone experiences only minor pulverization in distilled water. In contrast, the acidic solution causes micro-cracks and particle shedding, while the alkaline solution results in layered spalling of the sandstone surface. A salt solution leads to salt frost formation and pore crystallization, with the composite solution of sodium hydroxide and 5% Na2SO4 demonstrating the most severe deterioration. The sandstone is covered with salt frost and spalling, exhibiting honeycomb pores and interlaced crystal structures. From a physical and mechanical perspective, as dry-wet cycles increase, the water absorption and porosity of the sandstone initially decrease slightly before increasing, while the longitudinal wave velocity and uniaxial compressive strength continually decline. In summary, the composite solution of NaOH and 5% Na2SO4 results in the most significant deterioration of sandstone, whereas distilled water has the least impact. The combined effects of acidic/alkaline and salt solutions generally exacerbate sandstone damage more than individual solutions. This study offers insights into the regional deterioration characteristics of the Huachi Stone Statue Twin Towers and lays the groundwork for disease control and preventive preservation of sandstone cultural relics in similar climatic and geological contexts. Full article
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21 pages, 5944 KB  
Article
Effect of Vibratory Mixing on the Quasi-Static and Dynamic Compressive Properties of a Sustainable Concrete for Transmission Tower Foundations
by Guangtong Sun, Xingliang Chen, Fei Yang, Xinri Wang, Wanhui Feng and Hongzhong Li
Buildings 2026, 16(2), 310; https://doi.org/10.3390/buildings16020310 - 11 Jan 2026
Viewed by 353
Abstract
This study addresses the need for flexible and high-toughness materials for transmission tower pile foundations subjected to typhoons and earthquakes by investigating the static and dynamic mechanical behavior of rubberized concrete prepared using vibratory mixing. The objectives are to assess how vibratory mixing [...] Read more.
This study addresses the need for flexible and high-toughness materials for transmission tower pile foundations subjected to typhoons and earthquakes by investigating the static and dynamic mechanical behavior of rubberized concrete prepared using vibratory mixing. The objectives are to assess how vibratory mixing influences strength evolution, failure modes, strain rate sensitivity, and energy absorption of rubberized concrete compared with conventional mixing at 0%, 20%, and 30% rubber contents. Quasi-static compression tests and Split Hopkinson Pressure Bar (SHPB) dynamic compression tests were conducted to quantify these effects. The results show that vibratory mixing significantly improves the paste–aggregate–rubber interfacial structure. It increases the compressive strength by 8.4–30% compared with conventional mixing and reduces the strength loss at the 30% rubber content from 51.12% to 38.98%. Under high-speed impact loading, vibratory mixed rubber concrete exhibits higher peak strength, stronger energy absorption capacity, and a more stable strain rate response. The mixture with 20% rubber content shows the best comprehensive performance and is suitable for impact-resistant design of transmission tower foundations. Future research should extend this work by considering different rubber particle sizes and vibratory mixing frequencies to identify optimal combinations, and by incorporating quantitative fragment size distribution analysis under impact loading to further clarify the fracture mechanisms and enhance the application of rubberized concrete. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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18 pages, 4717 KB  
Article
Investigation on Damage and Energy Absorption Performance of Aluminum Foam Sandwich Plates Under Low-Velocity Impact
by Kailing Guo, Yunfang Zhu, Shuo Zhou and Ling Zhu
Materials 2026, 19(1), 46; https://doi.org/10.3390/ma19010046 - 22 Dec 2025
Cited by 1 | Viewed by 727
Abstract
Marine structures may suffer collision during navigation, leading to plastic deformation or even fracture failure of the structure, which poses a serious threat to ship structural safety. In this study, INSTRON 9350 Drop Tower was employed to carry out the impact test on [...] Read more.
Marine structures may suffer collision during navigation, leading to plastic deformation or even fracture failure of the structure, which poses a serious threat to ship structural safety. In this study, INSTRON 9350 Drop Tower was employed to carry out the impact test on the aluminum foam sandwich plates (AFSPs). The penetration performance of AFSPs were analyzed, including deformation mode, failure mode, impact force, displacement, energy absorption, and loading–unloading process. Additionally, the effects of impactor diameter and low-temperature environment on the penetration behavior of AFSPs were explored. The results indicate that the upper face sheet primarily exhibits shear failure, while the lower face sheet mainly undergoes global bending and tensile fracture. As the impact energy increases, the deformation zone of the lower face sheet extends to the boundary of the effective area of the sandwich plates. The loading stage of AFSPs under different impact energies generally coincide, but the unloading stage shows significant differences. Moreover, the peak impact force of the case D40 is nearly twice that of the case D25, while the 25 mm impactor is more likely to penetrate the lower face sheet, so that the energy absorption of the smaller impactor is reduced. Under penetration conditions, higher impact energies resulted in faster energy absorption rates, but the final absorbed energy values were almost identical. Ambient temperature affects the penetration performance of AFSPs; as the temperature decreases, the permanent deflection of the upper face sheet and the rebound velocity of the impactor decrease, whereas energy absorption increases. Compared with the normal temperature (20 °C), the energy absorption increases by about 8% at low temperature (−60 °C). Full article
(This article belongs to the Section Metals and Alloys)
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22 pages, 4183 KB  
Article
Estimation of PM2.5 Vertical Profiles from MAX-DOAS Observations Based on Machine Learning Algorithms
by Qihua Li, Jinyi Luo, Hanwen Qin, Shun Xia, Zhiguo Zhang, Chengzhi Xing, Wei Tan, Haoran Liu and Qihou Hu
Remote Sens. 2025, 17(17), 3063; https://doi.org/10.3390/rs17173063 - 3 Sep 2025
Cited by 2 | Viewed by 2292
Abstract
The vertical profile of PM2.5 is important for understanding its secondary formation, transport, and deposition at high altitudes; it also provides important data support for studying the causes and sources of PM2.5 near the ground. Based on machine learning methods, this [...] Read more.
The vertical profile of PM2.5 is important for understanding its secondary formation, transport, and deposition at high altitudes; it also provides important data support for studying the causes and sources of PM2.5 near the ground. Based on machine learning methods, this study fully utilized simultaneous Multi-Axis Differential Optical Absorption Spectroscopy measurements of multiple air pollutants in the atmosphere and employed the measured vertical profiles of aerosol extinction—as well as the vertical profiles of precursors such as NO2 and SO2—to evaluate the vertical distribution of PM2.5 concentration. Three machine learning models (eXtreme Gradient Boosting, Random Forest, and back-propagation neural network) were evaluated using Multi-Axis Differential Optical Absorption Spectroscopy instruments in four typical cities in China: Beijing, Lanzhou, Guangzhou, and Hefei. According to the comparison between estimated PM2.5 and in situ measurements on the ground surface in the four cities, the eXtreme Gradient Boosting model has the best estimation performance, with the Pearson correlation coefficient reaching 0.91. In addition, the in situ instrument mounted on the meteorological observation tower in Beijing was used to validate the estimated PM2.5 profile, and the Pearson correlation coefficient at each height was greater than 0.7. The average PM2.5 vertical profiles in the four typical cities all show an exponential pattern. In Beijing and Guangzhou, PM2.5 can diffuse to high altitudes between 500 and 1000 m; in Lanzhou, it can diffuse to around 1500 m, while it is primarily distributed between the near surface and 500 m in Hefei. Based on the vertical distribution of PM2.5 mass concentration in Beijing, a high-altitude PM2.5 pollutant transport event was identified from January 19th to 21st, 2021, which was not detected by ground-based in situ instruments. During this process, PM2.5 was transported from the 200 to 1500 m altitude level and then sank to the near surface, causing the concentration on the ground surface to continuously increase. The sinking process contributes to approximately 7% of the ground surface PM2.5 every hour. Full article
(This article belongs to the Section AI Remote Sensing)
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24 pages, 18515 KB  
Article
Simplified Fly Tower Modeling for Preliminary Acoustic Predictions in Opera Houses
by Fabrizio Cumo, Umberto Derme and Sofia Agostinelli
Appl. Sci. 2025, 15(15), 8393; https://doi.org/10.3390/app15158393 - 29 Jul 2025
Viewed by 1687
Abstract
The acoustic field of an opera house is much more difficult to predict than those of concert halls because, in the fly tower, the absorption characteristics vary from time to time, according to the opera piece layout. For this reason, the paper aims [...] Read more.
The acoustic field of an opera house is much more difficult to predict than those of concert halls because, in the fly tower, the absorption characteristics vary from time to time, according to the opera piece layout. For this reason, the paper aims to find a simplified fly tower model to be used as a fixed reference in a preliminary acoustic prediction for opera houses. Firstly, referring to a case study, the effects of the fly tower Depth and absorptive characteristics are investigated to identify the simplified model. As a traditional opera is set on an empty stage, and modern pieces are supported by a virtual projected environment, the influence of the variable stage elements on Reverberation Time RT, Clarity C80, and Strength G is considered, comparing the traditional Semiramide opera to a modern digital one, according to the Just Noticeable Difference JND. Results confirm the utility of the suggested fly tower model, which does not require any set definition. Full article
(This article belongs to the Special Issue Acoustics Analysis and Noise Control for Buildings)
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45 pages, 9372 KB  
Article
Low-Carbon Optimization Operation of Rural Energy System Considering High-Level Water Tower and Diverse Load Characteristics
by Gang Zhang, Jiazhe Liu, Tuo Xie and Kaoshe Zhang
Processes 2025, 13(5), 1366; https://doi.org/10.3390/pr13051366 - 29 Apr 2025
Cited by 2 | Viewed by 1200
Abstract
Against the backdrop of the steady advancement of the national rural revitalization strategy and the dual-carbon goals, the low-carbon transformation of rural energy systems is of critical importance. This study first proposes a comprehensive architecture for rural energy supply systems, incorporating four key [...] Read more.
Against the backdrop of the steady advancement of the national rural revitalization strategy and the dual-carbon goals, the low-carbon transformation of rural energy systems is of critical importance. This study first proposes a comprehensive architecture for rural energy supply systems, incorporating four key dimensions: investment, system configuration, user demand, and policy support. Leveraging the abundant wind, solar, and biomass resources available in rural areas, a low-carbon optimization model for rural energy system operation is developed. The model accounts for diverse load characteristics and the integration of elevated water towers, which serve both energy storage and agricultural functions. The optimization framework targets the multi-energy demands of rural production and daily life—including electricity, heating, cooling, and gas—and incorporates the stochastic nature of wind and solar generation. To address renewable energy uncertainty, the Fisher optimal segmentation method is employed to extract representative scenarios. A representative rural region in China is used as the case study, and the system’s performance is evaluated across multiple scenarios using the Gurobi solver. The objective functions include maximizing clean energy benefits and minimizing carbon emissions. Within the system, flexible resources participate in demand response based on their specific response characteristics, thereby enhancing the overall decarbonization level. The energy storage aggregator improves renewable energy utilization and gains economic returns by charging and discharging surplus wind and solar power. The elevated water tower contributes to renewable energy absorption by storing and releasing water, while also supporting irrigation via a drip system. The simulation results demonstrate that the proposed clean energy system and its associated operational strategy significantly enhance the low-carbon performance of rural energy consumption while improving the economic efficiency of the energy system. Full article
(This article belongs to the Section Energy Systems)
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19 pages, 8791 KB  
Article
Analysis of Damage Mechanism of Ellipsoidal Assembled Tower Joint
by Miao Li, Jiaxin Ma and Yang Wen
Buildings 2025, 15(4), 572; https://doi.org/10.3390/buildings15040572 - 13 Feb 2025
Viewed by 855
Abstract
An assembled elliptical joint was designed for a lattice wind turbine tower, and four samples were analyzed under static loads. Additionally, finite element analysis software was employed to create 40 models, with the wall thickness of the ball seat and the web being [...] Read more.
An assembled elliptical joint was designed for a lattice wind turbine tower, and four samples were analyzed under static loads. Additionally, finite element analysis software was employed to create 40 models, with the wall thickness of the ball seat and the web being the variable parameters. This enabled the identification of the variation pattern in the ultimate bearing capacity. It was found that the failure parts of the four test pieces were located in the connection area between the tensioned web member and the ball table. Increasing the wall thickness of the ball table and the web member significantly increased the joint’s load-bearing capacity. However, increasing the table wall thickness somewhat reduced the joint’s deformation capacity. Increasing the web member thickness significantly improved the deformation capacity and the energy absorption capacity of the joint. Increasing the table wall and the member web thickness reduced the peak equivalent stress in the ball table area and the press plate, as well as the overall stress level. Finite element simulations showed that the joint’s load-bearing ability was adversely impacted when the table wall thickness exceeded 10 mm. When the web member wall thickness exceeded 5 mm, the joint bearing capacity was less sensitive to the increase in the wall thickness. Full article
(This article belongs to the Section Building Structures)
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23 pages, 6419 KB  
Article
Experimental and Numerical Simulation of the Resistance Characteristics and Desulfurization Efficiency of Rod-Shaped Turbulators in WFGD for Green Power Systems
by Likun Yang, Fuyong Su, Xiangpeng Li, Xunliang Liu, Zhi Wen, Guofeng Lou and Wenlei Zhou
Energies 2025, 18(4), 761; https://doi.org/10.3390/en18040761 - 7 Feb 2025
Cited by 1 | Viewed by 1418
Abstract
The Wet Flue Gas Desulfurization (WFGD) process has always been an important part in the low-carbon/green power realization process of traditional power plants. Adding a turbulator to the spray scrubber can improve the desulfurization efficiency, whereas it also increases the flow resistance. In [...] Read more.
The Wet Flue Gas Desulfurization (WFGD) process has always been an important part in the low-carbon/green power realization process of traditional power plants. Adding a turbulator to the spray scrubber can improve the desulfurization efficiency, whereas it also increases the flow resistance. In this study, a small experiment device based on a spray scrubber with a turbulator in a power plant was built on a 1:10 scale to address the problem. The influence of the flue gas flow rate and the liquid–gas ratio on the flow resistance was investigated. A mathematical model was established for the two-phase flow and the SO2 liquid phase absorption reaction, and numerical simulations were achieved by the Fluent code. The resistance characteristics and the liquid droplet residence time were studied in detail. By fitting the experimental data, the relationship between the resistance coefficient, the Reynolds number, and the liquid–gas ratio in the tower was determined as the following: f = 0.0288 Re0.359(L/G)0.754. The desulfurization efficiency was calculated by adopting a user-defined function (UDF) code in a computational fluid dynamics (CFD) model, and the effects of the flue gas flow rate, temperature, and the liquid–gas ratio were analyzed. The results show that the effect of the rod-shaped turbulator on the flow resistance is much less than the effect of the liquid spray. The residence time of droplets around the turbulator is doubled. The pressure loss in the scrubber increases with the liquid–gas ratio (associated with the number of spray layer) and the flue gas flow rate. The turbulator can improve the uniformity of the flue gas velocity to some extent and increase the utilization rate of the spraying liquid, thereby increasing the desulfurization efficiency by 2.49%. Considering the operation cost, the reasonable value range of the liquid–gas ratio is 20~30. This work presents a good demonstration of combining the experiment and numerical simulations on a laboratory scale for large systems and associated components research, which is helpful for the engineering design and optimization of modern green power systems. Full article
(This article belongs to the Section B: Energy and Environment)
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19 pages, 4069 KB  
Article
Performance of Ground-Based Solar-Induced Chlorophyll Fluorescence Retrieval Algorithms at the Water Vapor Absorption Band
by Yongqi Zhang, Xinjie Liu, Shanshan Du, Mengjia Qi, Xia Jing and Liangyun Liu
Sensors 2025, 25(3), 689; https://doi.org/10.3390/s25030689 - 24 Jan 2025
Cited by 2 | Viewed by 1614
Abstract
Solar-induced chlorophyll fluorescence (SIF) is essential for monitoring vegetation photosynthesis. The water vapor absorption band, the broadest absorption window, has a deeper absorption line than the O2-B band, providing significant potential for SIF retrieval; however, substantial variation in atmospheric water vapor [...] Read more.
Solar-induced chlorophyll fluorescence (SIF) is essential for monitoring vegetation photosynthesis. The water vapor absorption band, the broadest absorption window, has a deeper absorption line than the O2-B band, providing significant potential for SIF retrieval; however, substantial variation in atmospheric water vapor column concentrations limits research on SIF retrieval using this band. This study evaluates seven common SIF retrieval algorithms, including sFLD, 3FLD, iFLD, pFLD, SFM, SVD, and DOAS, using simulated datasets under varying atmospheric water vapor concentrations, spectral resolution (SR), and signal-to-noise ratios (SNRs). Additionally, the SIF retrieval results from the H2O, O2-B, and O2-A absorption bands are compared and analyzed to explore the fluorescence retrieval potential of the water vapor band. Furthermore, the potential of commonly used spectrometers, including Ocean Optics QE Pro and ASD FieldSpec 3, for SIF retrieval using the water vapor absorption band was evaluated. The results were further validated using ground-based tower observations. The results show that sFLD consistently overestimates SIF in the water vapor band, limiting its reliability, while SFM performs best across varying conditions. In comparison, 3FLD and pFLD, along with SVD, are accurate at high resolutions but less effective at lower ones. iFLD performs relatively poorly overall, whereas DOAS excels in low SR retrievals. At the same time, our study also shows that the water vapor band offers higher accuracy in ground-based SIF retrieval compared to the O2-B band, demonstrating strong application potential and providing valuable references for selecting SIF retrieval algorithms. Full article
(This article belongs to the Section Sensing and Imaging)
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19 pages, 6227 KB  
Article
Resonance Frequency as an Indicator of the Damage in Carbon Composite Plates: Analysis on Composites Prepared with Conventional and Sustainable Resins Subjected to Impact Tests
by Raffaele Ciardiello, Carlo Boursier Niutta and Andrea Tridello
Polymers 2025, 17(2), 141; https://doi.org/10.3390/polym17020141 - 8 Jan 2025
Cited by 1 | Viewed by 1811
Abstract
This paper experimentally investigates the impact response of composite laminates made with conventional and bio-based epoxy resin. Drop tower impact tests were conducted at varying energy levels, including repeated low-energy impacts, to evaluate perforation resistance. The laminates’ residual strength and damage tolerance were [...] Read more.
This paper experimentally investigates the impact response of composite laminates made with conventional and bio-based epoxy resin. Drop tower impact tests were conducted at varying energy levels, including repeated low-energy impacts, to evaluate perforation resistance. The laminates’ residual strength and damage tolerance were assessed using the Damage Index (DI) and by analysing the resonance frequency variations through the Impulse Excitation Technique (IET). The study demonstrates a strong correlation between the DI and the resonance frequencies of the specimens, suggesting that IET can effectively track damage progression in composite laminates. Bio-based resin laminates exhibited higher energy absorption at perforation and lower damage progression during repeated impacts due to the higher ductility of the resin. This method of using resonance frequencies to assess impact damage progression directly in composite laminates throughout the IET technique has not been previously reported in the literature. Full article
(This article belongs to the Section Polymer Analysis and Characterization)
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16 pages, 2261 KB  
Article
Extractive Ethanol Fermentation with Ethanol Recovery by Absorption in Open and Closed Systems
by Kaio César da Silva Rodrigues, Ivan Ilich Kerbauy Veloso, Diego Andrade Lemos, Antonio José Gonçalves Cruz and Alberto Colli Badino
Fermentation 2025, 11(1), 12; https://doi.org/10.3390/fermentation11010012 - 2 Jan 2025
Viewed by 4539
Abstract
Conventional ethanol production has limitations, including substrate and product inhibitions, which increase both energy requirements for ethanol recovery and vinasse generation. Extractive fermentation, which removes ethanol as it is produced within the fermentation vat, offers an effective alternative to reducing the inhibitory effects [...] Read more.
Conventional ethanol production has limitations, including substrate and product inhibitions, which increase both energy requirements for ethanol recovery and vinasse generation. Extractive fermentation, which removes ethanol as it is produced within the fermentation vat, offers an effective alternative to reducing the inhibitory effects in conventional processes. However, an efficient method for recovering the extracted ethanol is also crucial. Thus, this study investigated an alternative ethanol production process using extractive ethanol fermentation integrated with ethanol recovery by absorption in both open and closed systems, specifically, comparing scenarios with and without CO2 recirculation produced during fermentation. The recovery system used two absorbers connected in series using monoethylene glycol (MEG) as an absorbent. Under extractive fermentation conditions without CO2 recirculation, the conversion of 300.0 g L−1 of substrate resulted in a total ethanol concentration of 135.2 g L−1, which is 68% higher than that achieved in conventional fermentation (80.4 g L−1). The absorption recovery efficiency reached 91.6%. In the closed system, with CO2 recirculation produced by fermentation, 280.0 g L−1 of substrate was consumed, achieving ethanol production of 126.0 g L−1, with an absorption recovery percentage of 98.3%, similar to that of industrial facilities that use a gas scrubber tower. Additionally, the overall process efficiency was close to that of conventional fermentation (0.448 gethanol gsubstrate−1). These results highlight the potential of this alternative process to reduce vinasse volume and energy consumption for ethanol recovery, lowering total costs and making it a viable option for integrated distilleries that combines ethanol production with other related processing operations. Full article
(This article belongs to the Special Issue Bioprocesses for Biomass Valorization in Biorefineries)
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16 pages, 6089 KB  
Article
Performance of Combined Woven Roving and Mat Glass-Fiber Reinforced Polymer Composites Under Absorption Tower Lifting Loads
by Víctor Tuninetti and Matías Mariqueo
Polymers 2024, 16(20), 2937; https://doi.org/10.3390/polym16202937 - 19 Oct 2024
Cited by 4 | Viewed by 2132
Abstract
This study investigates the structural integrity of a glass-fiber reinforced polymer absorption tower during lifting operations, evaluating factors of safety and stress distribution for both horizontal and vertical scenarios. A key focus is the comparative analysis of surface and volumetric meshing techniques in [...] Read more.
This study investigates the structural integrity of a glass-fiber reinforced polymer absorption tower during lifting operations, evaluating factors of safety and stress distribution for both horizontal and vertical scenarios. A key focus is the comparative analysis of surface and volumetric meshing techniques in finite element modeling. Results demonstrate that surface models achieve comparable stress predictions to computationally intensive volumetric models, significantly reducing computational demands without compromising accuracy. For instance, stress at the flange edge with holes was accurately captured using a surface model with 5675 elements (12.79 MPa), yielding similar results to a volumetric model requiring over 94,000 elements (13.37 MPa). Similar computational efficiency and agreement between modeling approaches were observed at the packing support ring-shell joint. Finite element analysis employing Hashin’s failure criterion, informed by industry-standard experimental data, revealed safety factors ranging from 1.9 to 2.5 for horizontal lifting and four for vertical lifting. These safety factors indicate sufficient margins for safe operation. While these findings support the feasibility of both lifting methods, further investigation is recommended to address the lower safety factors observed in specific horizontal lifting scenarios. A comprehensive assessment incorporating industry standards, dynamic load effects, and potential mitigation strategies is crucial to ensure the long-term structural integrity of the GFRP absorption tower. Full article
(This article belongs to the Section Polymer Composites and Nanocomposites)
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