Search Results (24,930)

In this study, an electrochemical system for methane conversion was developed, employing Ni- and Ce-doped LaCoO₃ perovskite as the anode catalyst in an Na₂CO₃ electrolyte. Structural characterization revealed that the La_1−yCe_yCo_1−xNi_xO₃ (x = 0–0.5, y = 0–0.12) synthesized by the sol–gel method maintains the perovskite structure, but is rich in oxygen vacancies. Electrochemical studies revealed that the performance of methane activation is related to the presence of Ni(III) in the catalyst, and reactive oxygen species (•OH and HOO⁻) are provided through water oxidation reactions (WOR) in the Na₂CO₃ electrolyte. The electrocatalytic performance of the synthesized La_0.92Ce_0.08Co_0.5Ni_0.5O₃ during methane conversion was verified in an electrolysis cell, and ethanol and acetic acid were identified as the methane conversion oxygenates. Under ambient conditions, the formation rate of ethanol reached 577.0 μmol g_cat⁻¹ h⁻¹ at 0.90 V (vs. Ag/AgCl) in 0.5 mol L⁻¹ Na₂CO₃. The catalyst was found to retain structural integrity and sustain catalytic activity over multiple reaction cycles. Full article

In protracted humanitarian crises, solid waste management (SWM) becomes a major challenge due to limited resources, inadequate infrastructure, and competing response priorities. Waste generated in humanitarian settings typically consist of heterogeneous streams, where plastics, biodegradable fractions, and packaging materials represent the dominant components. Proper management of this waste is essential to reduce health risks and environmental impacts on local communities. Within this framework, sustainable bio-based alternatives and compostable solutions represent promising alternatives. The EU-funded Bio4HUMAN project promotes the integration of innovative bio-based solutions aligned with humanitarian and sustainability goals. An exploratory assessment focused on analyzing waste production, material composition, and handling practices in two case study locations in Sub-Saharan Africa (Democratic Republic of Congo (DRC) and South Sudan (SS)). The results indicate that humanitarian waste cannot be clearly distinguished from household or commercial waste, as streams are typically mixed. Waste composition is dominated by organic matter (43–65%), followed by plastics (15–33%), while other fractions such as paper, glass, metals, and textiles are less significant. Further insights into challenges and opportunities were obtained through a combination of quantitative surveys (n = 29), qualitative interviews with key informants (KIIs) (44) and group discussions sessions (FDG) (9), direct observations, and literature review. Subsequently, a scoping approach was applied to map and classify suitable sustainable solutions into two main categories: bio-based products (BBPs) and organic waste valorization technologies. These were assessed through life cycle assessment (LCA) in accordance with ISO 14040 and 14044, applying SimaPro v.10.2.0.3 software and the Ecoinvent 3.10 database, and compared against fossil-based alternatives. This study compares two case scenarios: a HDPE oil bottle versus PLA alternative (functional unit 6 L), and PE water container versus PLA alternative (functional unit 10 L). For the oil bottle, PLA shows a lower carbon footprint (1.33 kg CO₂-eq) than HDPE (2.37 kg CO₂-eq). In contrast, for the water container, PLA performs worse (2.22 kg CO₂-eq) compared to PE (1.59 kg CO₂-eq), due to higher material demand. The results suggest that benefits are context-dependent and most evident for lightweight products with high leakage risks, particularly when composting infrastructure is accessible. This study advances previous work on humanitarian SWM by integrating field-based waste flow characterization with context-specific screening and life cycle assessment of bio-based alternatives, providing quantitative evidence on the conditions under which these solutions can effectively reduce environmental burdens in protracted crisis settings. Full article

Prolonged cultivation of cereal-based cropping systems in the Indo-Gangetic Plain has contributed to soil degradation, groundwater depletion, and declining soil organic carbon levels, highlighting the urgent need for climate-resilient, sustainable crop diversification strategies that enhance soil carbon sequestration and improve overall soil health. A 6-year field experiment assessed 10 cropping systems (CSs) using a randomized complete block design with four replications, focusing on their effects on soil carbon stocks and sequestration at two soil depths (0–15 cm and 15–30 cm). It was inferred from the results that there is a significant variation in soil carbon stocks, with maize–peas–spring groundnut (CS6) having the highest surface carbon stock (13.0 Mg ha⁻¹) and baby corn–potato–okra (CS10) having the highest sub-surface carbon stock (11.9 Mg ha⁻¹). Carbon sequestration peaked in CS6 at 5.06 Mg ha⁻¹ at 0–15 cm, and its sequestration rate was the highest (0.84 Mg ha⁻¹ yr⁻¹). Total organic carbon (TOC) ranged from 0.63% in Rice–Wheat (CS1) to 0.73% in CS6, with similarly high values in other diversified systems. Very labile carbon (VLC) was highest in basmati rice, late-sown wheat, and cowpea (CS3) and CS6, demonstrating the benefits of legume-based systems. At depths of 15–30 cm, trends were consistent but lower. Water-soluble carbon (WSC) and hot water-soluble carbon (HWSC) showed significant differences across systems, with CS3 recording the highest values. The findings indicate that cropping systems incorporating legume diversification and green manuring enhance carbon stocks, sequestration rates, and soil carbon stability, demonstrating that crop diversification is an effective means of increasing soil carbon storage, promoting soil health, and supporting sustainable agricultural production in Northwestern India. Full article

Non-isocyanate polyurethanes (NIPUs) produced by the aminolysis of cyclic carbonates are often presented as safer and more sustainable alternatives to conventional polyurethanes. Their monomer sourcing and synthetic pathways are by now fairly well explored, but the physical principles controlling their properties remain much less understood. This perspective challenges the notion that these materials follow the paradigm of conventional polyurethanes. Emphasis is placed on the hydroxyl group formed next to the urethane moiety, which distinguishes these materials from conventional polyurethanes and makes them more precisely poly(hydroxy urethanes). The available evidence indicates that this pendent hydroxyl is not a minor structural detail but a central actor affecting hydrogen bonding, microphase separation, and through them, many macroscopic physical properties of NIPUs, such as glass transition, mechanical response, water uptake and reprocessability. In addition, it enables thermally activated bond-exchange reactions, which dynamically change chain connectivity and, in networks, topology. As a result, concepts borrowed from conventional segmented polyurethanes cannot be transferred directly to non-isocyanate ones. Instead, a new, physics-oriented predictive framework is the necessary next step for the rational design of non-isocyanate polyurethanes. Such a framework should take bond-exchange reactions into account and connect molecular structure and thermal history with the macroscopic physical properties. Full article

The global water situation is deteriorating not only due to the progressing climate change but also to irrational consumer behaviors, which are driven by attitudes. Given the above, it seemed essential to identify attitudes toward the issue of access to freshwater in households, considering sustainable development guidelines. The aim of this study was, therefore, to develop a research tool for the identification of respondents’ attitudes toward this problem and then to determine its validity and reliability. The object of the study was an original questionnaire serving as a research tool for identifying the specified attitudes. The data required for this study were acquired through a critical review of the literature and a questionnaire survey method. The study was conducted in one of the Polish urban agglomerations using the Paper-and-Pencil Interviewing (PAPI) technique. An in-depth analysis of the validity and reliability of the tool, carried out using a statistical procedure, confirmed it to be a viable means to identify these attitudes in Poland. Therefore, there are reasonable grounds to assume that, following the application of the procedure presented in this manuscript, the developed tool may also be used to identify the specified attitudes when implemented in a different population. Full article

The article examines how India and Pakistan have interpreted the Indus Water Treaty (IWT) in the broader context of their preference, needs, and constraints. Rather than treating the IWT as a static legal instrument or as a case of institutional resilience, the analysis conceptualizes the Treaty as a performance-based regime, where treaty stability emerges from how states perform their obligations over time rather than from institutional design alone. Adopting a qualitative process-tracing approach grounded in treaty interpretation as operationalized through state practice, this article advances three interrelated arguments: first, the durability of the IWT cannot be explained solely by institutional design, but must be understood as a “performance-based equilibrium” sustained through state practice. Second, this stability historically relied on a pattern of “compliance asymmetry,” in which India, as the upper riparian, exercised restraint well beyond minimal entitlement while Pakistan consolidated downstream dependence through infrastructural development. Third, the growing juridification of dispute resolution since the 2000s, driven by escalating infrastructural friction, has altered the political meaning of compliance, narrowed interpretive flexibility, and reshaped reciprocal expectations. The article contributes to the scholarship of international legal theory and hydro-politics, particularly by reconceptualizing treaty resilience as a function of material and political performance, rather than the formal text alone. Full article

Rainfall variability strongly influences both flood and drought hazards, especially in climatic transition zones where precipitation is highly seasonal and spatially heterogeneous. This study assessed long-term changes in rainfall patterns and compound flood–drought hazard in the Huaihe River Basin, China, using ERA5-Land-derived daily precipitation series at 174 spatial sampling locations during 1950–2025. Rainfall pattern indicators, flood-related rainfall extremes, and SPI-3-based drought indicators were calculated to characterize rainfall amount, frequency, intensity, dry–wet persistence, heavy rainfall events, and meteorological drought conditions. The Mann–Kendall test and Sen’s slope estimator were used to detect long-term trends, and a compound flood–drought hazard classification framework was developed based on a flood-related rainfall hazard index (FHI) and a drought-related hazard index (DHI). The results showed that annual total precipitation, wet days, and consecutive wet days decreased significantly, indicating reduced rainfall occurrence and wet spell persistence. Flood-related rainfall indicators generally showed decreasing tendencies, with more evident declines in persistent multi-day extremes than in single-day rainfall. In contrast, mean SPI-3 showed a significant drying tendency, although drought frequency, severe drought frequency, and drought intensity did not exhibit significant monotonic trends. Spatially, rainfall pattern, flood-related, and drought-related indicators showed clear heterogeneity across the basin. The compound hazard classification identified flood-dominated and drought-dominated areas as the two major hazard types, each accounting for 31.03% of the spatial sampling locations, while low compound hazard and compound flood–drought hazard areas each accounted for 18.97%. These findings indicate that flood- and drought-related hazards coexist but vary spatially across the Huaihe River Basin. The proposed framework provides preliminary rainfall-based information for differentiated flood–drought hazard assessment, climate-adaptive water resources planning, and the sustainable management of water resources in regions facing spatially heterogeneous hydroclimatic hazards. Full article

Tailings are solid waste generated during mining and mineral processing. Their tremendous accumulation not only encroaches on arable land but also pollutes the environment. Currently, tailings are considered a viable alternative to natural fine aggregates in concrete because of their suitable physicochemical properties. However, existing studies remain highly fragmented and often report inconsistent conclusions owing to the considerable variability in tailings mineralogy, particle morphology, and physicochemical characteristics. To date, a comprehensive synthesis linking these intrinsic properties to the fresh, mechanical, durable, microstructural, environmental, and economic performance of tailings concrete remains lacking. Therefore, this review provides a systematic and critical assessment of tailings as aggregate in concrete and proposes an integrated framework connecting tailings characteristics, microstructural evolution, engineering performance, and sustainability outcomes. It systematically examines the physico-mechanical properties, durability, microstructure, hydration characteristics, environmental impact, and economic benefits of the resulting tailings concrete. The results showed that although tailings varied considerably in particle size, chemical composition, and mineralogy, they typically exhibited a rough surface texture and high water absorption. Furthermore, partial substitution of fine aggregates with tailings was found to improve the physical–mechanical properties and durability. However, to prevent performance decline, the substitution ratio should not exceed 50%. These benefits originated primarily from the filling effect and optimized particle packing, which increased matrix density. Microstructural analyses indicated that moderate tailings contents refined the pore structure, strengthened the interfacial transition zone (ITZ), and promoted hydration. In contrast, excessive substitution ratios weakened bonding and increased porosity. From an environmental perspective, the use of tailings generally reduced carbon emissions (by up to ~28%) and production costs (by up to ~50%) by lowering natural resource consumption and enabling large-scale waste valorization. Overall, tailings represent a sustainable aggregate alternative, provided that substitution levels are carefully controlled to balance workability, performance, and durability. Full article

During the construction of large-diameter shield tunnels, tunnel lining segments frequently experience uplift after exiting the shield tail, inducing structural defects such as dislocation, cracking, and water leakage. This issue threatens both construction safety and the long-term sustainable operation of large-diameter shield tunnels. Shield tail grouting slurry buoyancy is the primary cause of segment uplift. However, existing studies mainly rely on atmospheric pressure tests and simplified models, failing to capture the dynamic evolution of grout buoyancy under real confining pressures. This study optimized grout mix proportions through laboratory tests and developed a novel buoyancy testing apparatus. Systematic time-dependent buoyancy tests were conducted. Results show that cement-based grouts exhibit a distinct three-stage buoyancy dissipation pattern, which is strongly influenced by confining pressure, stratum conditions, and mix design, whereas inert grouts follow a single-stage exponential decay. The optimized mix YH1 reduced the complete buoyancy dissipation time by 20–35% compared with conventional cement-based grout S9. Based on field monitoring at the Yangcheng West Lake Third Channel project, approximately 90% of segment uplift deformation occurred during the grout buoyancy persistence stage. These findings provide reliable theoretical support for optimizing anti-floating grout design and contribute to the resilience and sustainability of urban underground infrastructure. Full article

Karst terrains hold vital global groundwater reserves, underpinning regional water security and ecological stability. To elucidate groundwater hydrochemical patterns and formation mechanisms in Wuhan’s karst zone, this study adopted the Gibbs model, correlation analysis, principal component analysis and positive matrix factorization to explore water–rock interactions, hydrochemical origins, element migration, hydrogeochemical facies and genetic processes. The results show that water in both confined porous loose rock aquifers (CPLRAs) and karst fissure carbonate rock aquifers (KFCRAs) is mainly of HCO₃–Ca and HCO₃·SO₄–Ca types. Carbonate dissolution dominates hydrochemical evolution, with Ca²⁺, Mg²⁺, and HCO₃⁻ as major ions. Natural water–rock interactions control the ionic characteristics of both groundwater types. Silicate weathering exerts a greater influence on water in the KFCRA, while water in the CPLRA has more complex ion sources. Anthropogenic activities contribute 17.52% and 17.61% to their hydrochemical variations, suggesting moderate human influence. Water in the CPLRA is mainly affected by domestic sewage and soil organic nitrogen, locally superimposed with industrial and mining disturbances. Water in the KFCRA is primarily influenced by agricultural pollution, with minor domestic sewage input. These findings provide a scientific basis for sustainable development, protection, and targeted pollution control of groundwater resources in the Wuhan karst area, and offer a reference for hydrochemical studies in comparable karst regions. Full article

The contamination of aquatic ecosystems by synthetic dyes such as Safranin O poses significant environmental and health risks. This study reports the synthesis of TiO₂-ZnO heterostructures via a Ruta graveolens-mediated sol–gel method, where the plant extract acts as a structure-directing agent and precursor for residual carbon species. The resulting bio-hybrid catalyst achieved a degradation efficiency of 94% ± 2% under simulated solar irradiation, outperforming UV light (78% ± 3%) and visible light alone (81.18%). The optimal catalyst loading was determined to be 1.0 g L⁻¹, with maximum performance observed at near-neutral pH (6–7). Optical characterization revealed a direct bandgap of 2.69 eV, representing a significant red-shift from pristine TiO₂ and ZnO. The catalyst maintained 90% of its initial degradation efficiency after five consecutive regeneration cycles, demonstrating excellent reusability. Kinetic analysis confirmed pseudo-first-order behavior, while radical scavenging experiments identified superoxide radicals (•O₂⁻) as the dominant reactive species. This work establishes that plant-derived carbon precursors can effectively modify the electronic properties of TiO₂-ZnO heterojunctions, offering a sustainable approach for photocatalytic water remediation. Full article

Trihalomethanes (THMs) are priority disinfection by-products in drinking water, and their effective removal remains a persistent challenge for sustainable treatment. Here, olive mill solid waste (OMSW) was valorized into biochar (BC) and evaluated as a low-cost adsorbent for chloroform, bromodichloromethane (BDCM), chlorodibromomethane (CDBM), and bromoform under environmentally relevant conditions. Among the prepared materials, thermally activated BC (BC-T) performed best, achieving equilibrium removals of 74.7 ± 6.6% for chloroform, 91.1 ± 0.8% for BDCM, 87.2 ± 1.9% for CDBM, and 93.8 ± 0.3% for bromoform at 3000 mg/L. Adsorption increased with bromine substitution, following the order of bromoform > CDBM ≈ BDCM > chloroform, consistent with rising hydrophobicity. In contrast, KOH and Zn/Fe activation increased the BET surface area but did not improve THM removal, suggesting that adsorption was controlled by surface chemistry and site accessibility rather than surface area alone. Persulfate (PSF) addition reduced THM removal, indicating that oxidant activation did not compensate for the loss of adsorption capacity. Adsorption data were well described by the Freundlich isotherm and pseudo-second-order kinetics. BC-T also maintained high removal efficiency in drinking water, demonstrating its promise as a practical polishing adsorbent for THM control and as a route for high-value valorization of an abundant agricultural residue. Full article

River morphological changes significantly influence water purification functions; however, systematic research on the evolution of natural river morphology and its underlying mechanisms remains insufficient. This study investigates the Shiwuli River, a typical tributary of Chaohu Lake, by quantitatively analyzing its morphological evolution characteristics based on high-resolution satellite imagery from 2014 to 2024. Combined with field monitoring data from all four seasons of 2024, the study explores the influence mechanisms of river sinuosity, cascade flow, and wetlands on water purification. The results indicate significant morphological changes in the Shiwuli River: the total length decreased by 3.95 km, sinuosity decreased by 0.22, and the average width increased by 27.85 m. The comprehensive attenuation coefficient of pollutants in the monitored sections was consistently greater than zero, demonstrating the self-purification capacity of the natural meandering river, with the highest purification capacity observed in summer and the weakest in winter. Dissolved oxygen (DO) content was generally higher in concave banks than in convex banks, and the rate of increase in DO per unit length rose with increasing sinuosity. The cascade flow formed by rolling dams significantly enhanced DO concentration (by 19.23–26.25%), with average pollutant reduction rates ranging from 12.64% to 33.76%. The wetland sections exhibited average reduction rates of 79.07% for total phosphorus (TP), 39.33% for total nitrogen (TN), 47.43% for ammonia nitrogen (NH₃-N), and 45.67% for chemical oxygen demand (COD), demonstrating significantly better purification effects compared to the main river channel. This study reveals that the synergistic interaction among river sinuosity, cascade flow, and wetland systems enhances the water body’s self-purification capacity, providing a scientific basis for river ecological restoration and sustainable utilization of water resources. Full article

Rapid increase in mining activities, outdated management approaches, and climate change pose risks to the safe operation of mines. We explore public databases on mine tailings storage facilities (TSF) in Kazakhstan, a major mineral producer. We proceed to an in-depth analysis of a representative TSF, located in an area that has been affected by spring flooding. Our geospatial analysis and review of company reports reveal serious challenges related to the TSF design, tailings deposition patterns, and changing weather conditions. Despite modifying the TSF design in response to its failure, the company has struggled with persistent TSF overtopping and seepage in the subsequent years. Our findings from both the country-level review of TSF and the case study highlight the urgency of adopting best practices of TSF management. Specifically, our study demonstrates that risks stemming from spring flooding in Kazakhstan call for proactive TSF management, transparency, and stakeholder engagement. Such changes in TSF governance are essential for achieving a number of Sustainable Development Goals, in particular, SDG 12 Responsible Consumption and Production and SDG6 Clean Water and Sanitation. Full article

Sustainable rice production requires management strategies that reduce drainage-related nitrogen export while maintaining grain yield under increasingly constrained water and labor conditions. This study evaluated a controlled-irrigation-based integrated management regime in direct-seeded and mechanically transplanted rice under production-field conditions in the lower Yangtze River region, China. The optimized regime combined threshold-based controlled irrigation, functional basal fertilizer, and key-stage foliar regulation, whereas the traditional treatments followed local conventional flooding and fertilization practices. Drainage-related total nitrogen (TN) export was mainly associated with rainfall or irrigation-overflow events after fertilization. Compared with the corresponding traditional treatments, optimized management reduced irrigation input by 28.5% and 26.4%, cumulative drainage volume by 54.8% and 46.5%, and monitored-event TN export load by 63.6% and 60.0% in mechanically transplanted and direct-seeded rice, respectively. Grain yields reached 10,088 and 9870 kg ha⁻¹ in Opt-MT and Opt-DS, increasing by 6.5% and 7.2%, respectively. The optimized treatments also reduced chalky grain rate and chalkiness degree, although head rice rate did not improve synchronously. These findings provide field-based evidence that integrated management may help coordinate monitored drainage-related nitrogen-export mitigation, water-saving irrigation, and yield maintenance under similar production-field conditions. Full article