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Keywords = Triassic metamorphism

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28 pages, 6974 KB  
Article
Metamorphic Fluids with Magmatic Overprint in the Huayagou Gold Deposit, West Qinling Orogen, Central China: Evidence from Apatite and Tourmaline In Situ Geochemistry
by Fei Teng, Jiangwei Zhang, Wendi Guo, Leon Bagas, Kang Yan, Yuxiang Teng, Ying Wei, Ningchao Zhou, Yongbao Gao and Liyong Wei
Geosciences 2026, 16(2), 80; https://doi.org/10.3390/geosciences16020080 - 13 Feb 2026
Viewed by 564
Abstract
Recent exploration has demonstrated significant prospecting potential at the Huayagou Au deposit in Longnan mineral Field, Gansu Province, West Qinling Orogen, Central China. However, the nature and evolution of the auriferous fluids responsible for gold enrichment remain poorly constrained, hindering effective exploration targeting [...] Read more.
Recent exploration has demonstrated significant prospecting potential at the Huayagou Au deposit in Longnan mineral Field, Gansu Province, West Qinling Orogen, Central China. However, the nature and evolution of the auriferous fluids responsible for gold enrichment remain poorly constrained, hindering effective exploration targeting of high-grade ores. In this study, apatite and tourmaline closely associated with gold mineralization are investigated as mineralogical recorders of fluid composition and evolution. Integrated petrographic observations, TIMA phase mapping, cathodoluminescence imaging, electron probe microanalysis, and in situ trace element analyses were used to distinguish magmatic, metamorphic, and syn-ore hydrothermal generations of apatite and tourmaline, together with in situ Nd isotopic analyses of apatite and B isotopic analyses of tourmaline. Syn-ore hydrothermal apatite is characterized by homogeneous blue cathodoluminescence, fluorapatite compositions, strong LREE depletion, and εNd(t) values overlapping those of Triassic magmatic apatite, whereas Early-Devonian magmatic and metamorphic apatites display more distinct signatures. Tourmaline records a systematic evolution from early dravite to late schorl, accompanied by trace element enrichment and a shift toward heavier δ11B values. These mineralogical and isotopic features, together with published sulfur isotope constraints, indicate that gold mineralization at Huayagou was dominantly controlled by structurally focused metamorphic fluids, with localized Triassic magmatic–hydrothermal overprinting enhancing gold enrichment in high-grade ores. The Huayagou Au deposit is, therefore, best interpreted as an atypical orogenic gold system, highlighting enhanced exploration potential in structurally favorable zones at depth, particularly in the western part of the district where Triassic magmatism is inferred. Full article
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20 pages, 3728 KB  
Article
Genesis and Mineralization Process of the Lanuoma Sediment-Hosted Pb–Zn Deposit, Sanjiang Metallogenic Belt, Southwestern China: Constraints from Zn, Pb, and S Isotopes
by Chunxia Xu, Jiantang Peng, Jianjun Gan, Chun Tang, Zhiming Yin and Cheng Huang
Minerals 2026, 16(2), 164; https://doi.org/10.3390/min16020164 - 30 Jan 2026
Viewed by 495
Abstract
The Lanuoma sediment-hosted lead–zinc (Pb–Zn) deposit, situated in the central part of the Sanjiang base metal metallogenic belt (SMB) within the Changdu Basin, is hosted by Triassic Bolila Formation limestone. The source of metals and sulfur (S), as well as the ore-forming processes [...] Read more.
The Lanuoma sediment-hosted lead–zinc (Pb–Zn) deposit, situated in the central part of the Sanjiang base metal metallogenic belt (SMB) within the Changdu Basin, is hosted by Triassic Bolila Formation limestone. The source of metals and sulfur (S), as well as the ore-forming processes for the deposits in this belt, are contentious. To constrain the metal and sulfur sources and to define the ore-forming mechanism, we analyzed Zn, Pb, and S isotopes of sphalerite and robinsonite, as well as Zn isotopes of the host limestone and the metamorphic basement. Sphalerite shows homogeneous δ66Zn values (−0.31‰ to −0.12‰; mean = −0.20‰). The calculated δ66Zn of the ore-forming fluid (~0.00‰) matches that of the Triassic limestone, indicating a sedimentary Zn source (δ66Zn = −0.11‰ to −0.09‰; average 0.00‰). Robinsonite displays a wider δ66Zn range (−0.22‰ to 0.44‰), reflecting a mixture of sedimentary and metamorphic sources (δ66Zn = 0.12‰ to 0.42‰; average 0.22‰). Lead isotopes of sphalerite are uniform (206Pb/204Pb = 19.041–19.079) and indicative of a sedimentary rock source, whereas robinsonite shows wide variation (206Pb/204Pb = 19.070–19.156) and linear trends between low- and high-radiogenic end-members, indicating mixed Pb sources from sedimentary rocks and metamorphic basement. Sulfur isotopic compositions of sulfides (δ34S = −1.4‰ to 2.6‰; mean = −0.1‰) cluster near 0‰, consistent with a deep magmatic origin. A strong linear correlation between 206Pb/204Pb and δ66Zn, coupled with a lack of correlation between both 206Pb/204Pb and δ34S and δ66Zn and δ34S in the sulfides, indicates that Pb and Zn were derived from a common metal source, whereas sulfur originated from a distinct reservoir. Combined with previously published fluid inclusion, rare earth element, and multi-isotopic constraints, these results suggest that Pb–Zn mineralization at Lanuoma was controlled by a mixing between metal-rich basinal brines and sulfur-rich deep-sourced fluids, leading to sulfide precipitation dominated by open-space filling. This study provides new insights into the genesis and mineralization process of sediment-hosted Pb–Zn deposits in the Sanjiang metallogenic belt. Full article
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18 pages, 5504 KB  
Article
Genesis of the Yawan Gold Deposit, West Qinling Orogen: Insights from Calcite U-Pb Geochronology and Geochemistry of Sulfides
by Chang-Qing Dong, Zhao-Hua Bai, Ke Yang, Meng-Zhen Hao, Jia-Yi Wang, Hao Zhou and Jia-Nan Fu
Minerals 2026, 16(1), 114; https://doi.org/10.3390/min16010114 - 22 Jan 2026
Viewed by 527
Abstract
The Yawan gold deposit, located in the Western Qinling Orogen, contains gold mineralisation that is predominantly controlled by approximately east-west-trending fault systems. This study integrates field geology, petrography, cathodoluminescence imaging, electron probe microanalysis of gold-bearing minerals (pyrite and arsenopyrite), and in situ laser [...] Read more.
The Yawan gold deposit, located in the Western Qinling Orogen, contains gold mineralisation that is predominantly controlled by approximately east-west-trending fault systems. This study integrates field geology, petrography, cathodoluminescence imaging, electron probe microanalysis of gold-bearing minerals (pyrite and arsenopyrite), and in situ laser ablation U-Pb dating of calcite to constrain the timing of mineralisation and to elucidate the mechanisms of gold enrichment. This study reveals that the deposit is significantly structurally controlled and comprises two discrete mineralisation stages: a quartz-pyrite (Py1)-arsenopyrite (Apy1)-chalcopyrite assemblage (Stage 1), and a quartz-calcite-pyrite (Py2)-arsenopyrite (Apy2)-stibnite-sphalerite-galena assemblage (Stage 2). Py1 displays distinct zonation, with rim As contents notably higher than core values, while Co and Ni contents gradually decrease from core to rim. Py2 is characterised by high As (0.00%–4.72%), low Fe/S ratios, and a porous texture, containing gold and arsenopyrite inclusions. Invisible gold occurs in lattice-bound form in both Py1 and Py2. The As-Fe-S ternary diagram of pyrite indicates that Au+ likely entered the crystal lattice as a solid solution. Arsenopyrite geothermometry yields a mineralisation temperature of 389 ± 44 °C, and sulfur fugacity (ƒS2) decreased markedly from Stage 1 to Stage 2. Combined with the S and Fe characteristics of pyrite, these features support a medium-temperature metamorphic hydrothermal environment. U-Pb dating of calcite from Stage 2 yields an age of 215.6 ± 7.1 Ma. In summary, the Yawan gold deposit belongs to the orogenic gold system, with its gold precipitation and enrichment controlled by sulfidation triggered by Late Triassic tectono-fluid activity. Full article
(This article belongs to the Special Issue Gold–Polymetallic Deposits in Convergent Margins)
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22 pages, 13298 KB  
Article
Contribution from Subducted Continental Materials to Ultrapotassic Lamprophyre Dykes Associated with Gold Mineralization in the Baiyun Area, Liaodong Peninsula, NE China
by Chenggui Lin, Jingwen Mao, Zhicheng Lv, Xin Chen, Tingjie Yan, Zhizhong Cheng, Zhenshan Pang and Jianling Xue
Minerals 2026, 16(1), 96; https://doi.org/10.3390/min16010096 - 19 Jan 2026
Viewed by 534
Abstract
Ultrapotassic lamprophyre dykes are spatially closely related to gold deposits in collision tectonic belts. However, the potential implication of these lamprophyre dykes to gold deposits remains poorly constrained. Abundant ultrapotassic lamprophyre dykes in the Baiyun gold deposit of Liaodong Peninsula, NE China, are [...] Read more.
Ultrapotassic lamprophyre dykes are spatially closely related to gold deposits in collision tectonic belts. However, the potential implication of these lamprophyre dykes to gold deposits remains poorly constrained. Abundant ultrapotassic lamprophyre dykes in the Baiyun gold deposit of Liaodong Peninsula, NE China, are closely associated with Au orebodies. This presents an excellent opportunity to investigate the genesis and tectonic significance of these dykes, as well as their potential connection to gold mineralization. Here, based on LA-ICPMS zircon U-Pb age, petrogeochemistry, and Sr-Nd-Hf isotopic composition characteristics, we studied the ultrapotassic lamprophyre dykes in the Baiyun gold deposit. Zircon U-Pb dating of lamprophyre dykes is 225.7 ± 1.3 Ma, which is consistent with the previous auriferous pyrite Re-Os data results within error, indicating that the lamprophyre dykes and gold deposits formed simultaneously in the Late Triassic, which coincided with the exhumation of the deeply subducted South Chin Block (SCB). The lamprophyre dykes belong to the shoshonitic series (K2O + Na2O = 6.39–7.57 wt.%, K2O/Na2O = 3.99–8.74) and are enriched with magnesium (MgO = 5.33–6.40 wt.%, Mg# = 58–65), barium (Ba = 2225–3046 ppm), and strontium (Sr = 792–927 ppm), and their (87Sr/86Sr)i isotopic composition ranges from 0.712514 to 0.714831, εNd(t) ranges from −15.4 to −14.1, and zircon εHf(t) values range from −14.3 to −12.5. These correspond to Paleoproterozoic model ages between 2.1 and 2.3 Ga, which are comparable to the ultra-high-pressure metamorphic rocks with the SCB nature found in the Dabie–Sulu orogenic belt. The results demonstrate that the overlying lithospheric mantle was possibly metasomatized by subducted SCB-derived melts before magma generation under the North China Block (NCB) in the Late Triassic. The lamprophyre dykes with high Nb/U and Th/Yb values, enriched Ba, Sr, REE, Na2O + K2O, K2O/Na2O, and the LOI demonstrate that the metasomatic agents were hydrous, high-pressure melts. These melts likely resulted from the partial melting of subducted continental crust, which is attributed to phengite breakdown in the subduction continental channel. The silica-rich melts migrate from the plate into the sub-continental lithospheric mantle (SCLM) and form potassic- and volatile-enriched metasomatized SCLM. Subsequently, the partial melting of metasomatized SCLM due to the decompression and thinning may be the main mechanism to generate the syn-exhumation ultrapotassic magma in a post-collision setting. This study suggests that the SCLM, metasomatized by melts derived from continental crust, plays a key role in generating volatile-rich hydrous SCLM during the continental subduction and collision stage. In contrast, during the post-collision stage, as tectonic forces transition from compressional to extensional, the abundant volatiles and ultrapotassic magma produced from the partially melted and metasomatized lithospheric mantle may significantly contribute to the transportation, enrichment, and precipitation of gold through magmatic-hydrothermal processes, facilitating the formation of gold deposits. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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23 pages, 4551 KB  
Article
Provenance Tracing of Uranium-Bearing Sandstone of Saihan Formation in Naomugeng Sag, Erlian Basin, China
by Caili Zhang, Zhao Li, Hu Peng, Yue Wu, Ning Luo, Kang Pang, Zhiwei Qiu, Xiaolin Yu, Haiqi Quan, Miao Wang, Qi Li, Yongjiu Liu, Yinan Zhuang and Chengyuan Jin
Minerals 2026, 16(1), 76; https://doi.org/10.3390/min16010076 - 13 Jan 2026
Cited by 1 | Viewed by 544
Abstract
The northern part of the Naomugeng Sag in the Erlian Basin shows favorable sandstone-type uranium mineralization in the lower member of the Saihan Formation. The sandstone thickness ranges from 39.67 to 140.36 m, with an average sand content ratio of 76.33%, indicating broad [...] Read more.
The northern part of the Naomugeng Sag in the Erlian Basin shows favorable sandstone-type uranium mineralization in the lower member of the Saihan Formation. The sandstone thickness ranges from 39.67 to 140.36 m, with an average sand content ratio of 76.33%, indicating broad prospecting potential. This study focuses on samples from uranium ore holes and uranium-mineralized holes in the area, conducting grain-size analysis of uranium-bearing sandstones, heavy mineral assemblage analysis, and detrital zircon U-Pb dating to systematically investigate provenance characteristics. The results indicate that the uranium-bearing sandstones in the lower member of the Saihan Formation were primarily transported by rolling and suspension, characteristic of braided river channel deposits. The heavy mineral assemblage is dominated by zircon + limonite + garnet + ilmenite, suggesting that the sedimentary provenance is mainly composed of intermediate-acid magmatic rocks with minor metamorphic components. Detrital zircon U-Pb ages are mainly concentrated in the ranges of 294–217 Ma (Early Permian to Late Triassic), 146–112 Ma (Middle Jurassic to Early Cretaceous), 434–304 Ma (Late Carboniferous to Early Permian), and 495–445 Ma (Middle–Late Ordovician to Early Silurian). Combined with comparisons of the ages of surrounding rock masses, the provenance of the uranium-bearing sandstones is mainly derived from intermediate-acid granites of the Early Permian–Late Triassic and Middle Jurassic–Early Cretaceous periods in the southern part of the Sonid Uplift, with minor contributions from metamorphic and volcanic rock fragments. The average zircon uranium content is 520.53 ppm, with a Th/U ratio of 0.73, indicating that the provenance not only supplied detrital materials but also provided uranium-rich rock bodies that contributed essential metallogenic materials for uranium mineralization. This study offers critical insights for regional prospecting and exploration deployment. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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36 pages, 12719 KB  
Article
Petrogenesis and Provenance of the Triassic Metasedimentary Succession in the Sakar Unit, Bulgaria: Constraints from Petrology, Geochemistry, and U-Pb Detrital Geochronology
by Tzvetomila Filipova Vladinova and Milena Georgieva Georgieva
Geosciences 2025, 15(9), 343; https://doi.org/10.3390/geosciences15090343 - 2 Sep 2025
Viewed by 2078
Abstract
This study investigates the metasedimentary sequences of terrigenous–carbonate Sakar-type Triassic (TCSTT) and Sakar-type Triassic (STT) in the Sakar Unit, southeastern Bulgaria. Both share lithological similarities (alternation of carbonate–silicate schists, mica schists, marbles, and impure marbles) and are affected by post-Triassic metamorphism, but with [...] Read more.
This study investigates the metasedimentary sequences of terrigenous–carbonate Sakar-type Triassic (TCSTT) and Sakar-type Triassic (STT) in the Sakar Unit, southeastern Bulgaria. Both share lithological similarities (alternation of carbonate–silicate schists, mica schists, marbles, and impure marbles) and are affected by post-Triassic metamorphism, but with differences in metamorphic grade and partly in the variation of potential sources of the sedimentary material. STT shows a higher metamorphic grade (lower amphibolite facies) when compared to TCSTT (lower greenschist facies). Petrographic observations and geochemical analyses indicate protoliths composed of arkosic sandstones, shales, and limestones derived from a quartz-dominated source with minor contributions from intermediate magmatic sources. The U-Pb geochronology of the detrital zircons reveals a dominant Carboniferous age complemented by an Early Ordovician age, which is consistent with the presence of Carboniferous–Permian igneous rocks in the basement. The presence of Early Paleozoic and Cambrian–Neoproterozoic zircons in the detrital zircon populations suggests that older rocks of the basement of the Sakar Unit and the Srednogorie Zone are also sources of the sedimentary material. Based on the immobile trace element content and discrimination diagrams, the siliciclastic component originates from rocks formed in a continental-arc setting. REE patterns indicate a negative Eu anomaly inherited from granitic-source rocks. Full article
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19 pages, 3459 KB  
Article
Triassic Retrograde Metamorphism and Anatexis in the Sulu Orogenic Zone, Central China: Constraints from U–Pb Ages, Trace Elements, and Hf Isotopic Compositions of Zircon
by Yongkang Ye, Hengcong Lei, Fei Xia, Hui Zhang and Congjun Yu
Appl. Sci. 2025, 15(11), 6145; https://doi.org/10.3390/app15116145 - 29 May 2025
Viewed by 1074
Abstract
We report information on the protolith, the Triassic retrograde metamorphism, and anatexis recorded in zircons extracted from granitic gneiss and biotite schist in the Sulu orogenic zone, central China. The schist is enclosed within the granitic gneiss in the form of a lens. [...] Read more.
We report information on the protolith, the Triassic retrograde metamorphism, and anatexis recorded in zircons extracted from granitic gneiss and biotite schist in the Sulu orogenic zone, central China. The schist is enclosed within the granitic gneiss in the form of a lens. Zircon grains from the schist sample indicate anatexis occurred at 214.6 ± 3.6 Ma (MSWD = 5.1), with εHf (t) values ranging from −22.6 to −18.3, corresponding to TDMC(Hf) ages between 2675 Ma and 2407 Ma. The granitic gneiss originated from magmatic rock formed at 774 ± 32 Ma (MSWD = 5.7) and subsequently underwent metamorphism at ~211 Ma. Three zircon cores from the granitic gneiss exhibit εHf (t) values ranging from −13.6 to −6.3, with TDM C(Hf) ages spanning 2487–2075 Ma. Six zircon rims from the gneiss yield εHf (t) values of −14.7 to −13.3, and TDM C(Hf) ages ranging from 2176 to 2092 Ma. We believe that the protolith of granitic gneiss is the Neoproterozoic magmatic rock, whose tectonic affinity is the northern margin of the Yangtze craton. The granitic gneiss experienced Triassic collisional orogeny-related metamorphism and subsequent retrograde metamorphism, with the timing of retrograde overprinting consistent with zircon-recorded anatexis in the schist. In addition, the protoliths of both the gneiss and schist exhibit close affinity to Archean-Paleoproterozoic crustal sources. Full article
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22 pages, 18204 KB  
Article
Late Paleozoic–Mesozoic Tectonic Evolution of the Mudanjiang Ocean: Constraints from the Zircon U-Pb and Ar-Ar Chronology of the Heilongjiang Complex, NE China
by Jianxin Xu, Peiyuan Hu, Wendong Wang, Hongyu Guo and Xin Zhang
Minerals 2025, 15(5), 517; https://doi.org/10.3390/min15050517 - 14 May 2025
Viewed by 1156
Abstract
The Heilongjiang Complex provides a crucial geological record of the evolutionary history of the Mudanjiang Ocean, making it significant for understanding the accretion process between the Jiamusi Block and the Songliao Block. In this study, we analyzed samples from the Heilongjiang Complex in [...] Read more.
The Heilongjiang Complex provides a crucial geological record of the evolutionary history of the Mudanjiang Ocean, making it significant for understanding the accretion process between the Jiamusi Block and the Songliao Block. In this study, we analyzed samples from the Heilongjiang Complex in the Huanan region using zircon U-Pb and 40Ar/39Ar isotopic dating. The LA-ICP-MS U-Pb dating results show that the deposition time of the mica quartz schist is Late Triassic (237–207 Ma), while the protolith age of the amphibolite is Middle Triassic (245.5 ± 1.2 Ma). Detrital zircon ages from the mica quartz schist reveal four groups: 155–229 Ma, 237–296 Ma, 485–556 Ma, and 585–2238 Ma. The provenances are related to the magmatic and metamorphic activities at the junction of the Jiamusi Block and Songliao Block. 40Ar/39Ar isotopic dating yielded a plateau age of 183.40 ± 1.83 Ma for phengite in the mica quartz schist, with the metamorphic ages obtained from zircon U-Pb dating. We identify three major metamorphic events in the Heilongjiang Complex: (1) ~229 Ma, marking the earliest tectonic thermal disturbance in the complex; (2) 207–202 Ma, corresponding to the metamorphic event related to the collision between the Jiamusi Block and Songliao Block; and (3) ~183 Ma, indicating the closure of the Mudanjiang Ocean. Integrating these new findings with the results of previous research on magmatism and metamorphism, we reconstruct the tectonic evolution of the Mudanjiang Ocean from the Late Paleozoic to the Mesozoic. During the Early Permian, the Mudanjiang Ocean had already opened. Between the Middle Permian and Middle Triassic, bidirectional subduction occurred. In the Late Triassic, the Mudanjiang Ocean entered a subduction dormancy period. By the Early to Middle Jurassic, the Mudanjiang Ocean closed due to continental collision, leading to the final positioning of the Heilongjiang Complex. Full article
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21 pages, 8306 KB  
Article
Magmatic–Hydrothermal Processes of the Pulang Giant Porphyry Cu (–Mo–Au) Deposit, Western Yunnan: A Perspective from Different Generations of Titanite
by Mengmeng Li, Xue Gao, Guohui Gu and Sheng Guan
Minerals 2025, 15(3), 263; https://doi.org/10.3390/min15030263 - 3 Mar 2025
Cited by 2 | Viewed by 1902
Abstract
The Yidun island arc was formed in response to the Late Triassic westward subduction of the Ganzi–Litang oceanic plate, a branch of the Paleo-Tethys Ocean. The Zhongdian arc, located in the south of the Yidun island arc, has relatively large number of porphyry [...] Read more.
The Yidun island arc was formed in response to the Late Triassic westward subduction of the Ganzi–Litang oceanic plate, a branch of the Paleo-Tethys Ocean. The Zhongdian arc, located in the south of the Yidun island arc, has relatively large number of porphyry (skarn) type Cu–Mo ± Au polymetallic deposits, the largest of which is the Pulang Cu (–Mo–Au) deposit with proven Cu reserves of 5.11 Mt, Au reserves of 113 t, and 0.17 Mt of molybdenum. However, the relationship between mineralization and the potassic alteration zone, phyllic zone, and propylitic zone of the Pulang porphyry deposit is still controversial and needs further study. Titanite (CaTiSiO5) is a common accessory mineral in acidic, intermediate, and alkaline igneous rocks. It is widely developed in various types of metamorphic rocks, hydrothermally altered rocks, and a few sedimentary rocks. It is a dominant Mo-bearing phase in igneous rocks and contains abundant rare earth elements and high-field-strength elements. As an effective geochronometer, thermobarometer, oxybarometer, and metallogenic potential indicator mineral, titanite is ideal to reveal the magmatic–hydrothermal evolution and the mechanism of metal enrichment and precipitation. In this paper, major and trace element contents of the titanite grains from different alteration zones were obtained using electron probe microanalysis (EPMA) and laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to define the changes in physicochemical conditions and the behavior of these elements during the process of hydrothermal alteration at Pulang. Titanite in the potassic alteration zone is usually shaped like an envelope. It occurs discretely or is enclosed by feldspar, with lower contents of CaO, Al, Sr, Zr and Hf; a low Nb/Ta ratio; high ∑REE + Y, U, Th, Ta, Nb, and Ga content; and high FeO/Al2O3 and LREE/HREE ratios. This is consistent with the characteristics of magmatic titanite from fresh quartz monzonite porphyry in Pulang and other porphyry Cu deposits. Titanite in the potassium silicate alteration zone has more negative Eu anomaly and a higher U content and Th/U ratio, indicating that the oxygen fugacity decreased during the transformation to phyllic alteration and propylitic alteration in Pulang. High oxygen fugacity is favorable for the enrichment of copper, gold, and other metallogenic elements. Therefore, the enrichment of copper is more closely related to the potassium silicate alteration. The molybdenum content of titanite in the potassium silicate alteration zone is 102–104 times that of the phyllic alteration zone and propylitic alteration zone, while the copper content is indistinctive, indicating that molybdenum was dissolved into the fluid or deposited in the form of sulfide before the medium- to low-temperature hydrothermal alteration, which may lead to the further separation and deposition of copper and molybdenum. Full article
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23 pages, 8147 KB  
Article
Thermochronology of the Kalba–Narym Batholith and the Irtysh Shear Zone (Altai Accretion–Collision System): Geodynamic Implications
by Alexey Travin, Mikhail Buslov, Nikolay Murzintsev, Valeriy Korobkin, Pavel Kotler, Sergey V. Khromykh and Viktor D. Zindobriy
Minerals 2025, 15(3), 243; https://doi.org/10.3390/min15030243 - 26 Feb 2025
Cited by 2 | Viewed by 1144
Abstract
The granitoids of the Kalba–Narym batholith and the Irtysh shear zone (ISZ) are among the main geological features of the late Paleozoic Altai accretion–collision system (AACS) in Eastern Kazakhstan. Traditionally, it is believed that late Paleozoic strike-slip faults played a pivotal role at [...] Read more.
The granitoids of the Kalba–Narym batholith and the Irtysh shear zone (ISZ) are among the main geological features of the late Paleozoic Altai accretion–collision system (AACS) in Eastern Kazakhstan. Traditionally, it is believed that late Paleozoic strike-slip faults played a pivotal role at all stages of the development of the AACS, they were supposed to control deformation, magmatism, and ore deposits. This work is devoted to solving the problem of the tectonic evolution of the AACS based on the reconstruction of the thermal history of granitoids of the Kalba–Narym batholith in connection with the Chechek metamorphic dome structure, which is one of the highly metamorphosed blocks mapped within the ISZ. The new geological and geochronological data presented in this work allowed us to establish the sequence of formation of the Kalba–Narym granitoid batholith and link it with the evolution of the Irtysh shear zone (ISZ). It was revealed that in the late Carboniferous–early Permian (312–289 Ma), during the NE–SW compression, the Irtysh shear zone formed as a gently dipping thrust system into which gabbro of the Surov massif intruded. The combined manifestation of magmatic and tectonic processes caused the formation of tectonic mélange with cataclastic gabbro and metamorphic rocks of the Chechek metamorphic dome structure (312–289 Ma). Compression caused the formation of a cover-thrust structure. The thickening of the crust under the probable thermal action of the Tarim plume led to the formation of the early Permian Kalba–Narym batholith (297–284 Ma) within the Kalba–Narym terrane. Denudation of the orogen occurred before the Early Triassic (280–229 Ma). In this way the sequence of formation of the Kalba–Narym batholith and the ISZ is consistent with the concepts of the stages of plume-lithosphere interaction within the AACS under the influence of the late Carboniferous–early Permian Tarim igneous province, but in the cover-thrust tectonic setting. Full article
(This article belongs to the Special Issue Developments in Geochronology and Dating of Shear Zone Deformation)
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40 pages, 14218 KB  
Article
Geochemistry and Petrogenesis of Permo–Triassic Silicic Volcanic Rocks from the Circum-Rhodope Belt in the Vardar/Axios Zone, Northern Greece: An Example of a Post-Collision Extensional Tectonic Setting in the Tethyan Realm
by Argyro Asvesta
Geosciences 2025, 15(2), 48; https://doi.org/10.3390/geosciences15020048 - 2 Feb 2025
Cited by 4 | Viewed by 2208
Abstract
The western side of the Vertiskos Unit crystalline basement in northern Greece is fringed by a Permo–Triassic low-grade metamorphic volcano-sedimentary complex that belongs to the Circum-Rhodope Belt (CRB), which is an important part of the Vardar/ Axios oceanic suture zone. The silicic volcanic [...] Read more.
The western side of the Vertiskos Unit crystalline basement in northern Greece is fringed by a Permo–Triassic low-grade metamorphic volcano-sedimentary complex that belongs to the Circum-Rhodope Belt (CRB), which is an important part of the Vardar/ Axios oceanic suture zone. The silicic volcanic rocks from the CRB are mainly rhyolitic to rhyodacitic lavas with aphyric and porphyritic textures as well as pyroclastic deposits. In this study, geochemical data obtained with X-ray fluorescence (XRF) for the CRB silicic volcanic rocks are reported and discussed to constrain their petrogenesis and tectonic setting. The rocks are peraluminous and show enrichment in K, Rb, Th, Zr, Y, and Pb while being depleted in Ba, Sr, Nb, P, and Ti, and they have Zr + Nb + Y + Ce > 350 ppm, which are characteristic features of anorogenic A-type granites. They have a Y/Nb ratio > 1.2 and belong to A2-subtype granitoids, implying crust-derived magma in a post-collisional tectonic setting. The high Rb/Sr ratio (3.45–39.14), the low molar CaO/(MgO + FeOt) ratio, and the CaO/Na2O ratio (<0.5), which they display, indicate that metapelites are the magma sources. Their low Al2O3/TiO2 ratio (<100), consistent with their high zircon saturation temperatures (average TZr = 886 °C), and their low Pb/Ba ratio (average 0.06) reveal that they were generated by biotite dehydration melting. The increased Rb/Sr ratio relative to that of presumable parental metapelites of the Vertiskos Unit, coupled with their low Sr/Y ratio (0.12–1.08), reflects plagioclase and little or no garnet in the source residue, indicating magma derivation at low pressures of 0.4–0.8 GPa that correspond to a depth of ~15–30 km. The nearby tholeiitic basalts and dolerites, interstratified with the Triassic pelagic sediments, indicate bimodal volcanism in the region. They also support a model involving an upwelling asthenosphere that underplated the Vertiskos Unit basement, supplying the heat required for crustal melting at low pressures. The Permo–Triassic magmatism marks the transition from an orogenic to an anorogenic environment during the initial stage of continental breakup of the Variscan basement in a post-collision extensional tectonic framework, leading to the formation of the nascent Mesozoic Neo-Tethyan Maliac–Vardar Ocean. This apparently reveals that the Variscan continental collision between the Gondwana-derived Vertiskos and Pelagonian terranes must have been completed by at least the earliest Late Permian. Full article
(This article belongs to the Section Geochemistry)
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30 pages, 7272 KB  
Article
A Genetic Model for the Biggenden Gold-Bearing Fe Skarn Deposit, Queensland, Australia: Geology, Mineralogy, Isotope Geochemistry, and Fluid Inclusion Studies
by Mansour Edraki, Alireza K. Somarin and Paul M. Ashley
Minerals 2025, 15(1), 95; https://doi.org/10.3390/min15010095 - 20 Jan 2025
Cited by 2 | Viewed by 3042
Abstract
The Biggenden gold-bearing Fe skarn deposit in southeast Queensland, Australia, is a calcic magnetite skarn that has been mined for Fe and gold (from the upper portion of the deposit). Skarn has replaced volcanic and sedimentary rocks of the Early Permian Gympie Group, [...] Read more.
The Biggenden gold-bearing Fe skarn deposit in southeast Queensland, Australia, is a calcic magnetite skarn that has been mined for Fe and gold (from the upper portion of the deposit). Skarn has replaced volcanic and sedimentary rocks of the Early Permian Gympie Group, which formed in different tectonic settings, including island arc, back arc, and mid-ocean ridge. This group has experienced a hornblende-hornfels grade of contact metamorphism due to the intrusion of the Late Triassic Degilbo Granite. The intrusion is a mildly oxidized I-type monzogranite that has geochemical characteristics intermediate between those of granitoids typically associated with Fe-Cu-Au and Sn-W-Mo skarn deposits. The skarn mineralogy indicates that there was an evolution from prograde to various retrograde assemblages. Prograde garnet (Adr11-99Grs1-78Alm0-8Sps0-11), clinopyroxene (Di30-92Hd7-65Jo0-9), magnetite, and scapolite formed initially. Epidote and Cl-bearing amphibole (mainly ferropargasite) were the early retrograde minerals, followed by chlorite, calcite, actinolite, quartz, and sulfides. Late-stage retrograde reactions are indicated by the development of nontronite, calcite, and quartz. Gold is mainly associated with sulfide minerals in the retrograde sulfide stage. The fluids in equilibrium with the ore-stage calcites had δ13C and δ18O values that indicate deposition from magmatically derived fluids. The calculated δ18O values of the fluids in equilibrium with the skarn magnetite also suggest a magmatic origin. However, the fluids in equilibrium with epidote were a mixture of magmatic and meteoric water, and the fluids that deposited chlorite were at least partly meteoric. δD values for the retrograde amphibole and epidote fall within the common range for magmatic water. Late-stage chlorite was deposited from metasomatic fluids depleted in deuterium (D), implying a meteoric water origin. Sulfur isotopic compositions of the Biggenden sulfides are similar to other skarn deposits worldwide and indicate that sulfur was most probably derived from a magmatic source. Based on the strontium (87Sr/86Sr) and lead (206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb) isotope ratios, the volcanic and sedimentary rocks of the Gympie Group may have contributed part of the metals to the hydrothermal fluids. Lead isotope data are also consistent with a close age relationship between the mineralization at Biggenden and the crystallization of the Degilbo Granite. Microthermometric analysis indicates that there is an overall decrease in fluid temperature and salinity from the prograde skarn to retrograde alterations. Fluid inclusions in prograde skarn calcite and garnet yield homogenization temperatures of 500 to 600 °C and have salinities up to 45 equivalent wt % NaCl. Fluid inclusions in quartz and calcite from the retrograde sulfide-stage homogenized between 280 and 360 °C and have lower salinities (5–15 equivalent wt % NaCl). In a favored genetic model, hydrothermal fluids originated from the Degilbo Granite at depth and migrated through the shear zone, intrusive contact, and permeable Gympie Group rocks and leached extra Fe and Ca and deposited magnetite upon reaction with the adjacent marble and basalt. Full article
(This article belongs to the Special Issue Geochemistry and Genesis of Hydrothermal Ore Deposits)
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14 pages, 17261 KB  
Article
Yingde–Guangning Granitic Plutons Record Complex Tectonic Evolution During Paleozoic-Mesozoic: Implications for Gold Exploration in Western Guangdong, South China
by Buqing Wang, Huan Li, Zhihao Sun, Wei Quan, Yuxuan Huang and Mohamed Faisal
Minerals 2024, 14(12), 1259; https://doi.org/10.3390/min14121259 - 11 Dec 2024
Cited by 1 | Viewed by 1352
Abstract
Western Guangdong, a part of the South China Block, has a complex geological history characterized by significant magmatic, metamorphic, and tectonic activities. This dynamic geological past, particularly during the Mesozoic era, created favorable conditions for the formation of various mineral deposits, including Au, [...] Read more.
Western Guangdong, a part of the South China Block, has a complex geological history characterized by significant magmatic, metamorphic, and tectonic activities. This dynamic geological past, particularly during the Mesozoic era, created favorable conditions for the formation of various mineral deposits, including Au, Ag, Cu, and Pb. This makes the region a key area for precious metal resources in China. Despite extensive metallogenic studies, detailed structural information for western Guangdong remains insufficient, highlighting the need for further investigation. Thus, effective delineation of deformation periods is crucial for revealing geodynamic history and understanding regional tectonic activities, which are extremely important for guiding mineral exploration. This work focuses on the outcrops of granitic plutons in the Yingde–Guangning area of western Guangdong to establish the structure–tectonic setting. The tectonic events likely shaped the widespread Paleozoic–Mesozoic granitic bodies, which record extensive information on regional tectonic evolution. To achieve the primary objective, systematic identification and kinematic analysis of the various stages of structural traces, such as foliations and joints, have been conducted. This research proposes, for the first time, that the western Guangdong area underwent four distinct tectonic stages: (1) Early Paleozoic NW-SE compression phase; (2) Triassic NE-SW compressional stress; (3) Jurassic NW-SE compressional force; and (4) Cretaceous NW-SE extension stage. In metallogenic terms, the NW-SE trending auriferous veins of the Yingde–Guangning region were mostly formed during the Triassic NE-SW compression stage, whereas the NE-SW trending vein-type gold mineralization developed during the tectonic regime transformation from Jurassic NW-SE compression to Cretaceous NW-SE extension. This research emphasizes that systematic tectonic geological studies of regional granites can effectively guide mineral prospecting. Full article
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29 pages, 22739 KB  
Article
Interpretation of a 3D Magnetotellurics Model of the Aceh and Seulimeum Segments of the Sumatran Fault Zone
by Lisa Yihaa Roodhiyah, Nurhasan, Tiffany, Prihandhanu Mukti Pratomo, Anggie Susilawati, Supriyadi, Yasuo Ogawa, Didik Sugiyanto, Doddy Sutarno and Wahyu Srigutomo
Appl. Sci. 2024, 14(23), 11335; https://doi.org/10.3390/app142311335 - 5 Dec 2024
Cited by 3 | Viewed by 2097
Abstract
The Sumatran Fault runs from the southeast (SE) to the northwest (NW) of Sumatra Island, with the highest slip rates reaching about 3.0 cm per year in the northwestern part. There is a seismic gap along this fault, including the northern Aceh domain, [...] Read more.
The Sumatran Fault runs from the southeast (SE) to the northwest (NW) of Sumatra Island, with the highest slip rates reaching about 3.0 cm per year in the northwestern part. There is a seismic gap along this fault, including the northern Aceh domain, which consists of the Aceh and Seulimeum fault segments. Previous studies have used various methods to investigate the Sumatran Fault system, including seismic, geoelectric, gravity anomaly, and magnetotellurics (MT). The MT method has proven advantageous as it can non-destructively image a wide range of depths. However, previous studies using the two-dimensional (2D) MT inversion did not represent realistic information of the subsurface conditions. Therefore, a three-dimensional (3D) MT data inversion was used in this study to obtain more realistic information about the resistivity structure of the Aceh and Seulimeum segments. The results confirmed that the Sumatran Fault is a strike-slip fault, with a relatively northwest (NW)–southeast (SE) direction of conductivity strike with an angle of S 71.61° E from Groom–Bailey decomposition of MT data. The 3D resistivity distribution model from 33 stations showed that the Aceh Fault Segment is 20–30 km away, while the Seulimeum Fault Segment is 55–60 km away based on the MT data. The results also indicated a creeping zone at a depth of 2 km beneath the Aceh Fault Segment. Different rock formations were identified beneath the fault system, with the western part of the Aceh Segment dominated by high-resistivity metamorphic rocks (150–1000 Ωm) from the Triassic–Cretaceous age. The zone between the Aceh and Seulimeum fault segments exhibited low resistivity, characterized by volcanic rocks (1–15 Ωm) from the Lam Teuba Volcanic Formation and the Indrapuri Formation. Beneath the eastern part of the Seulimeum Fault Segment was found to consist of low-resistivity quaternary volcanic rocks (1–15 Ωm) and high-resistivity andesite rocks (4.5 × 104–1.7 × 105 Ωm). These findings correlated well with the geological map. Full article
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17 pages, 13556 KB  
Article
Structural Characteristics of E–W-Trending Shear Belts in the Northeastern Dabie Orogen, China: Evidence for Exhumation of High–Ultrahigh-Pressure Rocks
by Yongsheng Wang, Xu Zhang and Qiao Bai
Minerals 2024, 14(12), 1205; https://doi.org/10.3390/min14121205 - 26 Nov 2024
Cited by 1 | Viewed by 1133
Abstract
The Dabie–Sulu Orogen hosts the largest area of ultrahigh-pressure (UHP) rocks in the world. There is still significant divergence regarding the exhumation process and mechanism of UHP rocks in the Dabie Orogen, which mainly resulted from the erosion of large volumes of rocks [...] Read more.
The Dabie–Sulu Orogen hosts the largest area of ultrahigh-pressure (UHP) rocks in the world. There is still significant divergence regarding the exhumation process and mechanism of UHP rocks in the Dabie Orogen, which mainly resulted from the erosion of large volumes of rocks in the Orogen during the post-collisional stage. Based on detailed field investigations, this study discovered the occurrence of E–W-trending sinistral shear belts that developed on the northeastern Dabie Orogen. These shear belts formed under greenschist facies conditions and are characterized by steep foliation and gentle mineral lineation. E–W-trending shear belts developed in HP rocks with metamorphic ages ranging from 227 to 219 Ma and were cut by the older phase of ductile shear belts of the Tan-Lu Fault Zone, indicating that they were formed around 219–197 Ma. Based on a comprehensive analysis of existing data, it can be concluded that E–W-trending shear belts were formed during the exhumation process of HP–UHP rocks. When HP rocks returned to the shallow crust and the lower UHP rocks continued to move, stress concentration occurred in the HP rocks and further resulted in the formation of E–W-trending shear belts. The development of E–W-trending shear belts indicates that HP–UHP rocks had essentially returned to the shallow crust by the Late Triassic, marking the near completion of the exhumation process. Full article
(This article belongs to the Special Issue Geochemistry and Geochronology of High-Grade Metamorphic Rocks)
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