Search Results (346)

To efficiently reuse endless fibre-reinforced composites after their life cycle, the recovery of endless fibres including matrix material with subsequent reprocessing in their original state is desirable. Thanks to their covalent adaptive networks, vitrimers offer ideal properties for enabling new repair and circular strategies for composites. In order to evaluate the detachability—meaning the separation of single laminate layers—and recycling potential for continuous fibre reinforcement, process routes and quality parameters must be established. In this study, the double cantilever beam test is used to test the adhesion based on the detachment of continuous fibre layers, and the interlaminare fracture toughness of mode I (G_IC) is measured as a parameter for the required energy for detachment. It was shown that G_IC increases above the vitrimer transition temperature and is higher than for reference specimens with an epoxy matrix. Surface roughness is measured to determine the mechanical and thermal degradation of the chemical network structure and additionally shows fibre cracking and defects in fibre–matrix interfaces. This allows the recycling process to be evaluated up to the production of a second generation, with the aim of identifying the recycling potential of the vitrimer matrix and implementing it for industrial processes. An efficient recycling strategy of the continuous fibre-reinforced vitrimers was thus demonstrated by hot pressing at 190 °C for 45 min, giving vitrimer samples a second life. Full article

Crushing is a critical step in the efficient utilization of quasi-brittle materials such as ores and solid wastes. During this process, materials undergo fracture, and the product particles are ejected, carrying significant kinetic energy. This study investigates typical quasi-brittle materials—concrete and quartz glass—by conducting impact crushing tests using a drop-weight apparatus under varying contact modes and input energy levels. High-speed camera was employed to capture the fracture patterns of the materials and the trajectories of the ejected particles, enabling the calculation of kinetic energy during crushing. The results indicate that under point contact loading, both kinetic energy and its proportion increase significantly with rising input energy. In contrast, under surface contact loading, the kinetic energy and its proportion exhibit minimal change as input energy increases. The average ejection velocity of particles from quartz glass specimens during crushing was 6.28 m/s, which is 2.21 times that of concrete specimens. Moreover, the average proportion of kinetic energy in quartz glass crushing was 5.049%, approximately 14.43 times greater than that in concrete. Enhancing material toughness and adopting surface contact loading help reduce both the kinetic energy and its proportion during crushing. This research contributes to minimizing kinetic energy loss and improving the efficiency of energy utilization in crushing processes. Full article

This study addresses the need for flexible and high-toughness materials for transmission tower pile foundations subjected to typhoons and earthquakes by investigating the static and dynamic mechanical behavior of rubberized concrete prepared using vibratory mixing. The objectives are to assess how vibratory mixing influences strength evolution, failure modes, strain rate sensitivity, and energy absorption of rubberized concrete compared with conventional mixing at 0%, 20%, and 30% rubber contents. Quasi-static compression tests and Split Hopkinson Pressure Bar (SHPB) dynamic compression tests were conducted to quantify these effects. The results show that vibratory mixing significantly improves the paste–aggregate–rubber interfacial structure. It increases the compressive strength by 8.4–30% compared with conventional mixing and reduces the strength loss at the 30% rubber content from 51.12% to 38.98%. Under high-speed impact loading, vibratory mixed rubber concrete exhibits higher peak strength, stronger energy absorption capacity, and a more stable strain rate response. The mixture with 20% rubber content shows the best comprehensive performance and is suitable for impact-resistant design of transmission tower foundations. Future research should extend this work by considering different rubber particle sizes and vibratory mixing frequencies to identify optimal combinations, and by incorporating quantitative fragment size distribution analysis under impact loading to further clarify the fracture mechanisms and enhance the application of rubberized concrete. Full article

To investigate the fracture behavior of super-absorbent polymer (SAP) internally cured polyvinyl alcohol (PVA) fiber-reinforced concrete (SAP-PVAC), three-point bending tests were carried out. This study systematically examined the effects of (1) PVA fiber content and (2) initial crack-depth-to-beam-height ratios (a₀/D) on the failure modes, fracture toughness (K_IC), and residual flexural tensile strength (f_R,1) of SAP-PVAC beams. The test results demonstrate that SAP particles have a weakening effect on concrete strength (reduce about 6%). Still, the addition of PVA fibers can effectively improve the crack-resistance performance of SAP-PVAC and significantly increase the residual flexural tensile strength by 4.5–42%. The softening performance of the concrete is affected by the initial crack-height ratio. An increase in a₀/D leads to an obvious increase in the crack opening displacement but has little impact on the fracture toughness, while the fracture energy shows a downward trend. SEM microscopic analysis reveals that the synergistic effect of SAP and PVA fibers exhibits a positive promoting effect on the toughening and crack resistance of SAP-PVAC specimens. These results establish a theoretical framework for SAP-PVAC fracture assessment and provide actionable guidelines for its shrinkage-crack mitigation structure engineering applications. Full article

This study investigates the Mode II fracture behavior of bamboo–coir–rubber (BCR) hybrid composite panels developed as sustainable alternatives for wood-based panels used in structural applications. The composites were fabricated using alternating bamboo and coir layers within a polypropylene (PP) thermoplastic matrix, with styrene–butadiene rubber (SBR) incorporated as an additive at 0–30 wt.% to enhance interlaminar toughness. Commercial structural plywood was tested as the benchmark. Mode II interlaminar fracture toughness (G_IIc) was evaluated using the ASTM D7905 End-Notched Flexure (ENF) test, supported by optical monitoring to study crack monitoring and Scanning Electron Microscopy (SEM) for microstructural interpretation. Results demonstrated a steady increase in G_IIc from 1.26 kJ/m² for unmodified laminates to a maximum of 1.98 kJ/m² at 30% SBR, representing a 60% improvement over the baseline and nearly double the toughness of plywood (0.7–0.9 kJ/m²). The optimum performance was obtained at 20–25 wt.% SBR, where the laminated retained approximately 85–90% of their initial flexural modulus while exhibiting enhanced energy absorption. Increasing the initial notch ratio (a₀/L) from 0.2 to 0.4 caused a reduction of 20% in G_IIc and a twofold rise in compliance, highlighting the geometric sensitivity of shear fracture to the remaining ligament. Analysis of Variance (ANOVA) confirmed that the increase in G_IIc for the 20–25% SBR laminates relative to plywood and the unmodified composite is significant at p < 0.05. SEM observations revealed rubber-particle cavitation, matrix shear yielding, and coir–fiber bridging as the dominant toughening mechanisms responsible for the transition from abrupt to stable delamination. The measured toughness levels (1.5–2.0 kJ/m²) position the BCR panels within the functional range required for reusable formwork, interior partitions, and transport flooring. The combination of renewable bamboo and coir with a thermoplastic PP matrix and rubber modification hence offers a formaldehyde-free alternative to conventional plywood for shear-dominated applications. Full article

This study explores the potential of integrating thermoplastic surfaces into fiber-reinforced plastics (FRPs) to eliminate the need for extensive surface preparation prior to bonding. Traditional bonding techniques for FRPs, especially in aerospace applications, demand meticulous surface preparation to ensure adequate adhesion. As a potential alternative to conventional methods for generating adhesion, the formation of an interpenetrating polymer network (IPN) by diffusion of the epoxy monomers into a thermoplastic surface layer is investigated. The research involved manufacturing CFRP panels with thermoplastic surfaces, polyether sulfone (PES), and polyetherimide (PEI), followed by a bonding process with and without conventional surface preparation. The performance of the joints was tested by tensile shear and Mode-I fracture toughness tests and compared to reference samples without thermoplastic surfaces. The formation and characteristics of the IPNs were analyzed using optical microscopy, laser scanning microscopy, and energy-dispersive X-ray spectroscopy. The results demonstrate that PES surfaces, even without surface treatment, can provide high mechanical performance with shear strengths ranging from 18 MPa to 23 MPa. PEI surfaces led to a shear strength from 10 MPa up to 14 MPa, correlating to a less extensive IPN formation compared to PES. However, both thermoplastics significantly improved the bonding process performance without surface preparation. Full article

Delamination remains a critical failure mode in carbon fiber-reinforced polymer (CFRP) composites, particularly under cyclic loading in aerospace and automotive applications. This study explores whether nanoscale reinforcement with graphene-based materials can enhance delamination resistance and identifies the most effective nanofiller type. Two distinct graphene nanospecies—reduced graphene oxide (rGO) and carboxyl-functionalized graphene nanoplatelets (HDPlas)—were incorporated at 0.5 wt% into CFRP laminates and tested under static and fatigue mode I loading using double cantilever beam (DCB) tests. Both nanofillers enhanced interlaminar fracture toughness compared to the neat composite: rGO improved the energy release rate by 36%, while HDPlas achieved a remarkable 67% enhancement. Fatigue testing showed even stronger effects, with the fatigue threshold energy release rate rising by 24% for rGO and 67% for HDPlas, leading to a fivefold increase in fatigue life for HDPlas-modified laminates. A compliance calibration method enabled continuous monitoring of crack growth over one million cycles. Fractography analysis using scanning electron microscopy revealed that both nanofillers activated crack bifurcation, enhancing energy dissipation. However, the HDPlas system further exhibited extensive nanoparticle pull-out, creating a more tortuous crack path and superior resistance to crack initiation and growth under cyclic loading. Full article

This research investigates the impact of coarse aggregate (CA) type, shape, and specimen size on the compressive behavior of concrete, aiming to better understand how these factors affect its mechanical performance. Eight concrete mixtures were designed according to four different concrete mix design (CMD) codes using two types of coarse aggregates: crushed basalt and naturally rounded, both with a 15 mm size. A total of 96 concrete samples were tested to evaluate their failure mode, compressive strength (CS), energy accumulation (G_A), and post-peak fracture energy (G_F). The results show that concrete made with basalt CA offered significantly higher CS (by 7% to 40%), G_A (by 34% to 57%), and G_F (10% to 48%) compared to concrete made with natural CA across different CMD codes and specimen dimensions. Larger cylinders demonstrated higher CS than smaller cylinders, ranging from 7% to 19%. The incorporation of basalt CA enhanced the toughness and ductility of concrete, leading to superior post-peak behavior. In addition to the experimental program, four machine learning algorithms, i.e., Extreme Gradient Boosting (XGB), Gradient-Enhanced Regression Tree (GBR), Random Forest (RF), and Support Vector Regression (SVR), were employed to forecast the concrete’s CS. RF (R² = 0.93) and gradient boosting models (R² = 0.92) showed remarkable accuracy, whereas SVR underperformed. The feature importance and SHAP analysis identified cement content and CA type as the primary determinants of CS, while the water–cement ratio served as a crucial regulator. Moreover, a graphical user interface tool was developed to practically allow engineers to rapidly estimate concrete CS, bridging the gap between experimental validation and practical use. Full article

Drop hammer impact tests were conducted to study crack features and the ductile–brittle transition in sea ice under low-speed impact. Crack images were analyzed using Hessian filtering and Hough transform methods, and a finite element model was created. Material parameters were validated using the crack tip strength factor. Energy dissipation, focusing on kinetic energy, was analyzed to understand energy conversion and crack propagation in sea ice during low-speed impact. The results indicate that the angular distribution of the crack mode exhibits central symmetry, with the peak frequency at each angle approximately 5°. As the initial impact kinetic energy increases, the dynamic response of the sea ice plate transitions from toughness to brittleness; the kinetic energy dissipation increases linearly, while its utilization efficiency declines. The variation in the kinetic energy conversion rate (η) is associated with the mode of ice plate failure. The crack propagation rate follows a normal distribution in relation to changes in time and kinetic energy. The stress wave effect predominates in the fracture formation mode, further elucidating the ductile–brittle transition behavior of sea ice. This research holds significant implications for ice-breaking operations. Full article

A series of TiB₂-Ni multilayer films with different Ni layer thicknesses was prepared by magnetron sputtering technology. The effect of Ni layer thickness on the microstructure and mechanical properties of the multilayer films was investigated, and the deformation and fracture mechanisms underlying the observed behavior were analyzed in detail. The results show that all multilayer films exhibit a well-defined layered architecture with sharp interfacial boundaries. Specifically, the Ni layers grow as columnar grains with an average diameter of approximately 10 nm, while the TiB₂ layers form a very fine acicular nanocolumnar structure. With the increase in Ni layer thickness, the hardness of the multilayer films shows a decreasing trend, gradually decreasing from 27.3 GPa at a 4 nm Ni thickness to 19.3 GPa at 50 nm. In contrast, the fracture toughness increases gradually from 1.54 MPa·m^1/2 to 2.73 MPa·m^1/2. This enhancement in toughness is primarily attributed to a transition in the deformation and fracture mechanism. With the increase in Ni layer thickness, the crack propagation mode in the multilayer films gradually changes from the integral propagation penetrating the film layers to the crack deflection propagation within the layers. This transformation is the result of the combined effect of the stress state of each layer and the crack energy dissipation. Full article

Ordinary concrete exhibits inherent brittleness, which restricts its deformation capacity and durability under extreme loading conditions. Engineered cementitious composites (ECC) have been developed to address these limitations; however, conventional ECC often suffers from relatively low compressive strength, limiting its use in demanding structural applications. To overcome this drawback, high-strength ECC (HS-ECC) was prepared by incorporating high-volume mineral admixtures and three types of synthetic fibers-polypropylene (PP), polyethylene (PE), and polyvinyl alcohol (PVA). This study aimed to investigate the influence of fiber type and dosage on the flexural behavior of HS-ECC and to propose a toughness evaluation framework better suited to its strain-hardening characteristics. A comprehensive experimental program, including compressive and four-point bending tests, was conducted to evaluate failure modes, flexural performance, and post-cracking behavior. Results showed that PE fibers significantly enhanced flexural strength and toughness, PP fibers provided superior deformability at higher dosages, while PVA fibers tended to fracture due to strong matrix bonding, limiting their effectiveness in high-strength matrices. Based on the observed load–deflection responses, a physically meaningful flexural toughness evaluation method was developed, which reliably captured elastic, hardening, and softening stages of HS-ECC. The findings not only clarify the role of different fiber types in HS-ECC but also offer a new evaluation approach that can guide fiber selection and mix design for structural applications. Full article

Adhesively bonded joints between galvanized steel and carbon fiber-reinforced polymers (CFRPs) are critical in modern lightweight structures, but their performance is often limited by failure at the zinc–adhesive interface. This study presents a parametric analysis to investigate the influence of key geometric parameters on interfacial cracking in a single-lap joint (SLJ) configuration, employing a simplified analytical methodology based on Interface Fracture Mechanics (IFM). The model combines the Goland–Reissner approach for estimating crack-tip loads with highly simplified, constant shape functions to calculate the energy release rate ($G_{int}$) and phase angle ($\psi$). To provide a practical reference, experimental data from shear tests on S350 GD galvanized steel bonded to CFRP were used to estimate the range of interfacial fracture toughness for this material system. The parametric results demonstrate that, for a constant load, increasing the overlap length reduces the crack driving force ($G_{int}$), while increasing the adhesive thickness raises it. Crucially, the model indicates that a thicker adhesive layer shifts the fracture mode from shear- to opening-dominated, a trend consistent with the established mechanics of SLJs, where increased joint rotation amplifies peel stresses. The study concludes that while the use of constant shape functions limits the model’s quantitative accuracy, this simplified analytical framework effectively captures the qualitative influence of key geometric parameters on the joint’s fracture behavior. It serves as a valuable and resource-efficient tool for preliminary design explorations and for interpreting experimentally observed failure trends in galvanized steel–CFRP joints. Full article

This study systematically evaluates the mode-I (opening) and mode-II (shearing) interlaminar strength and fracture toughness of four co-cured fiber–metal laminates (FMLs): AL–CF (aluminum–carbon fiber fabric), AL–GF (aluminum–glass fiber fabric), AL–HC (aluminum–carbon/glass hybrid fabric), and AL–HG (aluminum–glass/carbon hybrid fabric). Epoxy adhesive films were interleaved between metal and composite plies to enhance interfacial bonding. Mode-I interlaminar tensile strength (ILTS) and mode-II interlaminar shear strength (ILSS) were measured using curved beam and short beam tests, respectively, while mode-I and mode-II fracture toughness ($G_{Ic}$ and $G_{IIc}$) were obtained from double cantilever beam (DCB) and end-notched flexure (ENF) tests. Across laminates, interlaminar tensile strength (ILTS) values lie in a narrow band of 31.6–31.8 MPa and interlaminar shear strength (ILSS) values in 41.0–41.9 MPa. The mode-I initiation ($G_{Ic,init}$) and propagation ($G_{Ic, prop}$) toughnesses are 0.44–0.56 kJ/m² and 0.54–0.64 kJ/m², respectively, and the mode-II toughness ($G_{IIc}$) is 0.65–0.79 kJ/m². Scanning electron microscopy reveals that interlaminar failure localizes predominantly at the metal–adhesive interface, displaying river-line features under mode-I and hackle patterns under mode-II, whereas the adhesive–composite interface remains intact. Collectively, the results indicate that, under the present processing and test conditions, interlaminar strength and toughness are governed by the metal–adhesive interface rather than the composite reinforcement type, providing a consistent strength–toughness baseline for model calibration and interfacial design. Full article

In this study, shot blasting was employed to enhance the wear resistance and impact toughness of SCMnH11 high-manganese steel. The steel was first fabricated via vacuum casting, followed by forging and water-toughening treatment. Subsequently, the steel was cut to the required dimensions using wire electrical discharge machining before the final shot blasting was performed. The influence of shot blasting duration on the microstructure and mechanical properties was investigated. Shot blasting introduced compressive residual stress and dislocations, resulting in the formation of numerous low-angle grain boundaries. As the shot blasting time increased, the surface grains were progressively refined. The surface hardness increased rapidly from an initial value of approximately 250 HV, reaching a maximum of 643 HV. After 60 min of shot blasting, the thickness of the surface hardened layer reached 600 µm; however, the surface hardness exhibited a trend of first increasing and then decreasing. In contrast, the wear resistance showed the opposite trend. Additionally, the dominant surface wear mechanism transitioned from adhesive wear in the heat-treated sample to abrasive wear in the shot-blasted samples. Compared to the heat-treated sample, the impact toughness of the samples subjected to 5 min and 60 min shot blasting was significantly enhanced. Correspondingly, the fracture mechanism shifted from predominantly ductile fracture to a mixed mode of ductile and cleavage fracture. In summary, shot blasting can effectively enhance the wear resistance and impact resistance of SCMnH11 steel. However, the selection of shot blasting duration is critical. Appropriate parameters can balance work hardening, compressive stress, and surface microcracks, thereby enabling the material to achieve an optimal combination of wear resistance and impact resistance. Full article

Fiber tow-gaps and overlaps formed during the Automated Fiber Placement (AFP) process pose a significant challenge by introducing non-uniform composite morphologies, often characterized by resin-rich regions and fiber waviness. These defects occur as deposited fibers sink into the gap regions during consolidation, with gap geometry determined during path planning. Such morphological inconsistencies can compromise structural reliability by initiating premature failure, particularly through localized out-of-plane waviness and resin accumulation. This study investigates the integration of high melting temperature thermoplastic veils, specifically polyetherimide (PEI), into fiber tow-gaps as a method to prevent ply sinking and reduce fiber waviness on both internal and external surfaces of the laminate. The PEI veils also serve to reinforce resin-rich regions by forming an interpenetrated network of high fracture toughness material within the brittle epoxy matrix. Tensile tests conducted on cross-ply laminates containing staggered gaps demonstrated that the inclusion of PEI veils modified the failure mode. The results suggest that the selective placement of thermoplastic veils within tow-gaps during AFP offers a viable strategy to mitigate manufacturing-induced non-uniform morphologies. Full article